Roland De Marco

Transport and accumulation of ferrocene tagged poly(vinyl chloride) at the buried interfaces of plasticized membrane electrodes

Publisher: Royal Society of Chemistry (RSC)

Date: 2013

DOI: 10.1039/C3AN00464C

Abstract: Cyclic voltammetry (CV), synchrotron radiation-X-ray photoelectron spectroscopy (SR-XPS) and near edge X-ray absorption fine structure (NEXAFS) show that oxidation of ferrocene tagged PVC induces an accumulation of high molecular weight polymer at the buried interface between the substrate electrode and the plasticized membrane.

An electrochemical impedance spectroscopy and scanning electron microscopy study of the influence of positive plate compression on the electrochemical behaviour of lead-acid batteries

Publisher: Elsevier BV

Date: 02-2006

DOI: 10.1016/J.ELECTACTA.2005.07.019

Synthesis and characterization of high-integrity solid-contact polymeric ion sensors

Publisher: Springer Science and Business Media LLC

Date: 27-06-2008

DOI: 10.1007/S10008-008-0600-9

Lithium insertion into manganese dioxide electrode in MnO2/Zn aqueous battery: Part III. Electrochemical behavior of γ-MnO2 in aqueous lithium hydroxide electrolyte

Publisher: Elsevier BV

Date: 2006

DOI: 10.1016/J.JPOWSOUR.2005.03.184

Calibration of a chalcogenide glass membrane ion-selective electrode for the determination of free Fe3+ in seawater

Publisher: Elsevier BV

Date: 02-2000

DOI: 10.1016/S0304-4203(99)00084-5

Efficient BiVO₄ Photoanodes by Postsynthetic Treatment: Remarkable Improvements in Photoelectrochemical Performance from Facile Borate Modification

Publisher: Wiley

Date: 08-11-2019

DOI: 10.1002/ANGE.201911303

Abstract: Water‐splitting photoanodes based on semiconductor materials typically require a dopant in the structure and co‐catalysts on the surface to overcome the problems of charge recombination and high catalytic barrier. Unlike these conventional strategies, a simple treatment is reported that involves soaking a s le of pristine BiVO 4 in a borate buffer solution. This modifies the catalytic local environment of BiVO 4 by the introduction of a borate moiety at the molecular level. The self‐anchored borate plays the role of a passivator in reducing the surface charge recombination as well as that of a ligand in modifying the catalytic site to facilitate faster water oxidation. The modified BiVO 4 photoanode, without typical doping or catalyst modification, achieved a photocurrent density of 3.5 mA cm −2 at 1.23 V and a cathodically shifted onset potential of 250 mV. This work provides an extremely simple method to improve the intrinsic photoelectrochemical performance of BiVO 4 photoanodes.

Coulometric Sodium Chloride Removal System with Nafion Membrane for Seawater Sample Treatment

Publisher: American Chemical Society (ACS)

Date: 27-06-2012

DOI: 10.1021/AC301096R

Abstract: Seawater analysis is one of the most challenging in the field of environmental monitoring, mainly due to disparate concentration levels between the analyte and the salt matrix causing interferences in a variety of analytical techniques. We propose here a miniature electrochemical s le pretreatment system for a rapid removal of NaCl utilizing the coaxial arrangement of an electrode and a tubular Nafion membrane. Upon electrolysis, chloride is deposited at the Ag electrode as AgCl and the sodium counterions are transported across the membrane. This cell was found to work efficiently at potentials higher than 400 mV in both stationary and flow injection mode. Substantial residual currents observed during electrolysis were found to be a result of NaCl back diffusion from the outer side of the membrane due to insufficient permselectivity of the Nafion membrane. It was demonstrated that the residual current can be significantly reduced by adjusting the concentration of the outer solution. On the basis of ion chromatography results, it was found that the designed cell used in flow injection electrolysis mode reduced the NaCl concentration from 0.6 M to 3 mM. This attempt is very important in view of nutrient analysis in seawater where NaCl is a major interfering agent. We demonstrate that the pretreatment of artificial seawater s les does not reduce the content of nitrite or nitrate ions upon electrolysis. A simple diffusion/extraction steady state model is proposed for the optimization of the electrolysis cell characteristics.

Synchrotron Radiation/Fourier Transform-Infrared Microspectroscopy Study of Undesirable Water Inclusions in Solid-Contact Polymeric Ion-Selective Electrodes

Publisher: American Chemical Society (ACS)

Date: 17-06-2010

DOI: 10.1021/AC101009N

Abstract: This paper reports on three-dimensional synchrotron radiation/Fourier transform-infrared microspectroscopy (SR/FT-IRM) imaging studies of water inclusions at the buried interface of solid-contact-ion-selective electrodes (SC-ISEs). It is our intention to describe a nondestructive method that may be used in surface studies of the buried interfaces of materials, especially multilayers of polymers. Herein, we demonstrate the power of SR/FT-IRM for studying water inclusions at the buried interfaces of SC-ISEs. A poly(methyl methacrylate)-poly(decyl methacyrlate) [PMMA-PDMA] copolymer revealed the presence of micrometer sized inclusions of water at the gold/membrane interface, while a coupling of a hydrophobic solid contact of poly(3-octylthiophene 2,5-diyl) (POT) prevented the accumulation of water at the buried interface. A similar study with a poly (3,4-ethylenedioxythiophene) oly (styrenesulfonate) [PEDOT/PSS] solid contact also revealed an absence of distinct micrometer-sized pools of water however, there were signs of absorption of water accompanied by swelling of the PEDOT/PSS underlayer, and these membrane zones are enriched with respect to water.

Carbon Nanofibers Synthesized by Catalytic Decomposition of Methane and Their Electrochemical Performance in a Direct Carbon Fuel Cell

Publisher: American Chemical Society (ACS)

Date: 15-10-2009

DOI: 10.1021/EF901015G

Direct measurement of Cu(II)aq in seawater at pH 8 with the jalpaite ion-selective electrode

Publisher: Elsevier BV

Date: 08-1998

DOI: 10.1016/S0304-4203(97)00108-4

Synergistic effects of novel battery manufacturing processes for lead acid batteries. Part I: Charge/discharge cycling of batteries

Publisher: Springer Science and Business Media LLC

Date: 2002

DOI: 10.1023/A:1020941428332

Response of a copper(II) and iron(III) ion-selective electrode bielectrode array in saline media

Publisher: Elsevier BV

Date: 15-06-0002

DOI: 10.1016/J.TALANTA.2008.01.018

Abstract: A bielectrode array comprising a jalpaite membrane (i.e., Ag(1.5)Cu(0.5)S) copper(II) ion-selective electrode (ISE) and chalcogenide glass membrane (i.e., Fe(2.5)(Se(60)Ge(28)Sb(12))(97.5)) iron(III) ISE has been assembled by in idually wiring each solid-state sensor into a single electrode body. Furthermore, a dual metal ion buffer calibration standard incorporating copper(II) and iron(III) coordinating ligands to regulate the levels of free copper(II) and iron(III) in the buffer has been developed to enable simultaneous calibration of the bielectrode ISE array. In this work, the bielectrode ISE array has been employed in the continuous flow analysis (CFA) of free copper(II) and iron(III) in seawater media. It is shown that the in idual electrodes displayed Nernstian response in the metal ion buffer calibration standard over a wide dynamic range (viz., 10(-15) to 10(-5) M aCu(2+) and 10(-21) to 10(-11) M aFe(3+)), and the results of repetitive CFA analyses of free copper(II) and iron(III) in seawater are commensurate with the typical values found in coastal seawater s les. Clearly, the bielectrode ISE array may be used in the simultaneous analysis of free copper(II) and iron(III) in seawater without fear of cross-interference between the solid-state sensors.

Electrochemical and Surface Analysis Studies on the Carbon Dioxide Corrosion of X‐65 Carbon Steel

Publisher: Wiley

Date: 04-07-2016

DOI: 10.1002/ELAN.201600309

Response of the Iron Chalcogenide Glass Membrane Ion-Selective Electrode in a Seawater Ligand Mimetic Calibration Buffer

Publisher: Wiley

Date: 12-2007

DOI: 10.1002/ELAN.200704012

Lithium insertion into manganese dioxide electrode in MnO2/Zn aqueous battery

Publisher: Elsevier BV

Date: 11-2004

DOI: 10.1016/J.JPOWSOUR.2004.06.049

The effect of the ordered phase CuAu on the accuracy of emission analysis of gold alloys

Publisher: Elsevier BV

Date: 1987

DOI: 10.1016/S0003-2670(00)82825-1

Enhanced oxygen reduction at Pd catalytic nanoparticles dispersed onto heteropolytungstate-assembled poly(diallyldimethylammonium)-functionalized carbon nanotubes

Publisher: Royal Society of Chemistry (RSC)

Date: 2011

DOI: 10.1039/C0CP02036B

Abstract: Both Keggin-type phosphotungstic acid (HPW) and Pd are not prominent catalysts towards the oxygen reduction (ORR), but their composite Pd-HPW catalyst produces a significantly higher electrochemical activity for the ORR in acidic media. The novel composite catalyst was synthesized by self-assembly of HPW on multi-walled carbon nanotubes (MWCNTs) via the electrostatic attraction between negatively charged HPW and positively charged poly(diallyldimethylammonium (PDDA)-wrapped MWCNTs, followed by dispersion of Pd nanoparticles onto the HPW-PDDA-MWCNT assembly. The as-prepared catalyst was characterized by transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, thermal gravimetric analysis (TGA), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). TEM images show that Pd nanoparticles were uniformly dispersed on the surface of MWCNTs even when the Pd loading was increased to 60 wt%. Electrochemical activity of the catalysts for the ORR was evaluated by steady state polarization measurements using a rotating disk electrode. Compared with the acid treated MWCNTs, Pd nanoparticles supported on the HPW-assembled MWCNTs show a much higher ORR activity that is comparable to conventional Pt/C catalysts. The high electrocatalytic activities could be related to high dispersion of Pd nanoparticles as well as synergistic effects originating from the high proton conductivity of HPW. The Pd/HPW-PDDA-MWCNTs system as the cathode catalyst in proton exchange membrane fuel cells is demonstrated.

In Situ Formed Phosphoric Acid/Phosphosilicate Nanoclusters in the Exceptional Enhancement of Durability of Polybenzimidazole Membrane Fuel Cells at Elevated High Temperatures

Publisher: The Electrochemical Society

Date: 2017

DOI: 10.1149/2.1051714JES

Predicting the adsorption properties of carbon dioxide corrosion inhibitors using a structure-activity relationship

Publisher: The Electrochemical Society

Date: 2005

DOI: 10.1149/1.1823991

Persistence of Carbon Dioxide Corrosion Inhibitors

Publisher: Association for Materials Protection and Performance (AMPP)

Date: 04-2002

DOI: 10.5006/1.3287686

Flow injection potentiometric determination of phosphate in waste waters and fertilisers using a cobalt wire ion-selective electrode

Publisher: Royal Society of Chemistry (RSC)

Date: 1998

DOI: 10.1039/A801244J

Tuning the electrocrystallization parameters of semiconducting Co[TCNQ]2-based materials to yield either single nanowires or crystalline thin films

Publisher: American Chemical Society (ACS)

Date: 31-01-2007

DOI: 10.1021/JA067219J

Abstract: Electrocrystallization of single nanowires and/or crystalline thin films of the semiconducting and magnetic Co[TCNQ]2(H2O)2 (TCNQ=tetracyanoquinodimethane) charge-transfer complex onto glassy carbon, indium tin oxide, or metallic electrodes occurs when TCNQ is reduced in acetonitrile (0.1 M [NBu4][ClO4]) in the presence of hydrated cobalt(II) salts. The morphology of the deposited solid is potential dependent. Other factors influencing the electrocrystallization process include deposition time, concentration, and identity of the Co2+(MeCN) counteranion. Mechanistic details have been elucidated by use of cyclic voltammetry, chrono erometry, electrochemical quartz crystal microbalance, and galvanostatic methods together with spectroscopic and microscopic techniques. The results provide direct evidence that electrocrystallization takes place through two distinctly different, potential-dependent mechanisms, with progressive nucleation and 3-D growth being controlled by the generation of [TCNQ]*- at the electrode and the diffusion of Co2+(MeCN) from the bulk solution. Images obtained by scanning electron microscopy reveal that electrocrystallization of Co[TCNQ]2(H2O)2 at potentials in the range of 0.1-0 V vs Ag/AgCl, corresponding to the [TCNQ]0/*- diffusion-controlled regime, gives rise to arrays of well-separated, needle-shaped nanowires via the overall reaction 2[TCNQ]*-(MeCN)+Co2+(MeCN)+2H2O right harpoon over left harpoon {Co[TCNQ]2(H2O)2}(s). In this potential region, nucleation and growth occur at randomly separated defect sites on the electrode surface. In contrast, at more negative potentials, a compact film of densely packed, uniformly oriented, hexagonal-shaped nanorods is formed. This is achieved at a substantially increased number of nucleation sites created by direct reduction of a thin film of what is proposed to be cobalt-stabilized {(Co2+)([TCNQ2]*-)2} dimeric anion. Despite the potential-dependent morphology of the electrocrystallized Co[TCNQ]2(H2O)2 and the markedly different nucleation-growth mechanisms, IR, Raman, elemental, and thermogravimetric analyses, together with X-ray diffraction, all confirmed the formation of a highly pure and crystalline phase of Co[TCNQ]2(H2O)2 on the electrode surface. Thus, differences in the electrodeposited material are confined to morphology and not to phase or composition differences. This study highlights the importance of the electrocrystallization approach in constructing and precisely controlling the morphology and stoichiometry of Co[TCNQ]2-based materials.

The role of biosensors in the detection of emerging infectious diseases

Publisher: Royal Society of Chemistry (RSC)

Date: 2006

DOI: 10.1039/B603402K

Abstract: Global biosecurity threats such as the spread of emerging infectious diseases (i.e., avian influenza, SARS, Hendra, Nipah, etc.) and bioterrorism have generated significant interest in recent years. There is considerable effort directed towards understanding and negating the proliferation of infectious diseases. Biosensors are an attractive tool which have the potential to detect the outbreak of a virus and/or disease. Although there is a host of technologies available, either commercially or in the scientific literature, the development of biosensors for the detection of emerging infectious diseases (EIDs) is still in its infancy. There is no doubt that the glucose biosensor, the gene chip, the protein chip, etc. have all played and are still playing a significant role in monitoring various biomolecules. Can biosensors play an important role for the detection of emerging infectious diseases? What does the future hold and which biosensor technology platform is suitable for the real-time detection of infectious diseases? These and many other questions will be addressed in this review. The purpose of this review is to present an overview of biosensors particularly in relation to EIDs. It provides a synopsis of the various types of biosensor technologies that have been used to detect EIDs, and describes some of the technologies behind them in terms of transduction and bioreceptor principles.

Impedance spectroscopy: Over 35 years of electrochemical sensor optimization

Publisher: Elsevier BV

Date: 09-2006

DOI: 10.1016/J.ELECTACTA.2006.04.025

Understanding Complex Electrochemical Impedance Spectroscopy in Corrosion Systems Using in‐situ Synchrotron Radiation Grazing Incidence X‐ray Diffraction

Publisher: Wiley

Date: 17-05-2016

DOI: 10.1002/ELAN.201600137

Response of Copper(II) Ion-Selective Electrodes in Seawater

Publisher: American Chemical Society (ACS)

Date: 10-1994

DOI: 10.1021/AC00091A033

Structures and properties of solvated and unsolvated isopropyl functionalised calix[4]arenes

Publisher: Informa UK Limited

Date: 19-08-2009

DOI: 10.1080/10610270802308403

The application of neutron reflectometry and atomic force microscopy in the study of corrosion inhibitor films

Publisher: Elsevier BV

Date: 11-2006

DOI: 10.1016/J.PHYSB.2006.05.213

Contemporary Concise Review 2021: Pulmonary nodules from detection to intervention

Publisher: Wiley

Date: 17-05-2022

DOI: 10.1111/RESP.14296

Abstract: The US Preventive Task Force (USPSTF) has updated screening criteria by expanding age range and reducing smoking history required for eligibility the International Lung Screen Trial (ILST) data have shown that PLCOM2012 performs better for eligibility than USPSTF criteria. Screening adherence is low (4%–6% of potential eligible candidates in the United States) and depends upon multiple system and patient/candidate‐related factors. Smoking cessation in lung cancer improves survival (past prospective trial data, updated meta‐analysis data) smoking cessation is an essential component of lung cancer screening. Circulating biomarkers are emerging to optimize screening and early diagnosis. COVID‐19 continues to affect lung cancer treatment and screening through delays and disruptions specific operational challenges need to be met. Over 70% of suspected malignant lesions develop in the periphery of the lungs. Bronchoscopic navigational techniques have been steadily improving to allow greater accuracy with target lesion approximation and therefore diagnostic yield. Fibre‐based imaging techniques provide real‐time microscopic tumour visualization, with potential diagnostic benefits. With significant advances in peripheral lung cancer localization, bronchoscopically delivered ablative therapies are an emerging field in limited stage primary and oligometastatic disease. In advanced stage lung cancer, small‐volume s les acquired through bronchoscopic techniques yield material of sufficient quantity and quality to support clinically relevant biomarker assessment.

Flow-injection Potentiometric Detection of Phosphates Using a Metallic Cobalt Wire Ion-selective Electrode

Publisher: Royal Society of Chemistry (RSC)

Date: 1997

DOI: 10.1039/A700771J

Electrochemical Impedance Spectroscopy and X-ray Photoelectron Spectroscopy Study of the Response Mechanism of the Chalcogenide Glass Membrane Iron(III) Ion-Selective Electrode in Saline Media

Publisher: American Chemical Society (ACS)

Date: 15-01-2000

DOI: 10.1021/AC990603X

Abstract: The response mechanism of the iron(III) chalcogenide glass membrane ion-selective electrode (ISE) in saline media has been studied using electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS). EIS equivalent circuits and XPS surface compositions for the FeIII ISE are consistent with the presence of two surface films probably comprising a outer surface layer (OSL) and an Fe-deficient modified surface layer (MSL), along with a low-frequency charge-transfer impedance that is attributable to the reduction of Fe3+. In accordance with literature data for the conductivity of low-bearing iron(III) chalcogenide glasses, a high-impedance MSL is internally consistent with XPS data for an Fe-deficient MSL. It is evident that the impedance of the MSL diminishes on exposure to solutions containing Fe3+, and this finding is consistent with the ion exchange of Fe3+ within the MSL. Likewise, the charge-transfer impedance also decreases at elevated levels of Fe3+, demonstrating that Fe3+ is a participant in the reversible charge-transfer reaction occurring at the electrolyte/electrode interface. The kinetics of charge transfer are facilitated by Fe chelating agents (e.g., citrate, salicylate, EDTA, etc.) due presumably to the complexation of the products of the charge transfer process (possibly Fe2+). It is shown unequivocally that the response of the FeIII ISE in saline buffers is independent of pH, demonstrating that the ISE is responding directly to Fe3+, not H+. A mechanism involving a combination of charge transfer and ion exchange of FeIII, at the electrode diffusion layer, has been proposed to explain the 30 mV/decade slope of the FeIII ISE.

Lithium insertion into manganese dioxide electrode in MnO2/Zn aqueous battery Part I. A preliminary study

Publisher: Elsevier BV

Date: 05-2004

DOI: 10.1016/J.JPOWSOUR.2003.12.018

A Combined Voltammetric and Synchrotron Radiation-Grazing Incidence X-ray Diffraction Study of the Electrocrystallization of Zinc Tetracyanoquinodimethane

Publisher: CSIRO Publishing

Date: 2012

DOI: 10.1071/CH11361

Abstract: The in situ electrocrystallization of zinc tetracyanoquinodimethane (TCNQ) has been explored using synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD) at potentials in the region of the cyclic voltammetric peak where reduction of TCNQ to TCNQ– occurs at a Pt electrode in acetonitrile (0.1 M [NBu4][PF6]) solution containing Zn(NO3)2·6H2O. The in situ SR-GIXRD data along with ex situ IR and Raman spectroscopy results all confirmed the formation of the kinetically favoured phase of Zn[TCNQ]2(H2O)2 as the product.

Kinetic Modulation of Pulsed Chronopotentiometric Polymeric Membrane Ion Sensors by Polyelectrolyte Multilayers

Publisher: American Chemical Society (ACS)

Date: 21-08-2007

DOI: 10.1021/AC071201P

An Electrochemical Impedance Spectroscopy/Neutron Reflectometry Study of Water Uptake in the Poly(3,4‐Ethylenedioxythiophene):Poly(Styrene Sulfonate)/Polymethyl Methacrylate‐Polydecyl Methacrylate Cop

Publisher: Wiley

Date: 13-12-2011

DOI: 10.1002/ELAN.201100524

Carbon Nanofibers Synthesized by Catalytic Decomposition of Methane and Their Electrochemical Performance in a Direct Carbon Fuel Cell

Publisher: American Chemical Society (ACS)

Date: 16-07-2009

DOI: 10.1021/EF900203H

Determination of phosphate in hydroponic nutrient solutions using flow injection potentiometry and a cobalt-wire phosphate ion-selective electrode

Publisher: Elsevier BV

Date: 29-08-2003

DOI: 10.1016/S0039-9140(03)00229-7

Proton dynamics in phosphotungstic acid impregnated mesoporous silica proton exchange membrane materials

Publisher: Elsevier BV

Date: 07-2017

DOI: 10.1016/J.GEE.2017.06.007

A Universal Seeding Strategy to Synthesis Single Atom Catalysts on 2D Materials for Electrocatalytic Applications

Publisher: Wiley

Date: 14-11-2020

DOI: 10.1002/ADFM.201906157

Electrochemical Impedance Spectroscopy Study of the Response Mechanism of the Jalpaite Cu^II Ion-Selective Electrode in Seawater

Publisher: American Chemical Society (ACS)

Date: 15-10-1998

DOI: 10.1021/AC980196+

Synergistic effects of novel battery manufacturing processes for lead/acid batteries: Part II: Mechanistic studies

Publisher: Springer Science and Business Media LLC

Date: 03-2004

DOI: 10.1023/B:JACH.0000015620.79437.5D

Electrochemical impedance spectroscopy - a simple method for the characterization of polymer inclusion membranes containing aliquat 336

Publisher: MDPI AG

Date: 23-06-2011

DOI: 10.3390/MEMBRANES1020132

Ferrocene self assembled monolayer as a redox mediator for triggering ion transfer across nanometer-sized membranes

Publisher: Elsevier BV

Date: 08-2019

DOI: 10.1016/J.ELECTACTA.2019.05.091

Continuous flow analysis of iron in zinc electrowinning electrolyte using an iron chalcogenide glass ion-selective electrode - Part I. Synthetic media

Publisher: Elsevier BV

Date: 22-04-2002

DOI: 10.1016/S0039-9140(02)00003-6

Abstract: It is shown that the iron(III) chalcogenide glass membrane ion-selective electrode (ISE) can be calibrated in continuous flow analysis (CFA) using acidified iron(III) nitrate standards, yielding a 60+/-3 mV per decade change in activity of Fe(3+) response in the range 10(-7)-10(-2) M total iron(III). Extended ageing of the iron(III) ISE in 2 M zinc(II) sulphate did not alter the potentiometric response characteristics of the electrode. Furthermore, electrochemical impedance spectroscopy and X-ray photoelectron spectroscopy in the presence and absence of zinc(II) sulphate failed to detect a zinc(II) interference on the iron(III) ISE. CFA/ISE determined activities of Fe(3+) in synthetic zinc electrolyte containing 2x10(-3)-2x10(-1) M total iron(III) yielded results falling within +/-0.2logaFe(3+) unit of the corresponding iron speciation data calculated using the minteqa2 program.

Transportation and Accumulation of Redox Active Species at the Buried Interfaces of Plasticized Membrane Electrodes

Publisher: American Chemical Society (ACS)

Date: 14-09-2015

DOI: 10.1021/ACS.LANGMUIR.5B01693

Abstract: The transportation and accumulation of redox active species at the buried interface between glassy carbon electrodes and plasticized polymeric membranes have been studied using synchrotron radiation X-ray photoelectron spectroscopy (SR-XPS), near edge X-ray absorption fine structure (NEXAFS), in situ electrochemical Fourier transform infrared-attenuated total reflectance (FTIR-ATR) spectroscopy, cyclic voltammetry (CV), chrono erometry (CA), and electrochemical impedance spectroscopy (EIS). Ferrocene tagged poly(vinyl chloride) [FcPVC], ferrocene (Fc), and its derivatives together with tetracyanoquinodimethane (TCNQ) doped plasticized polymeric membrane electrodes have been investigated, so as to extend the study of the mechanism of this reaction chemistry to different time scales (both small and large molecules with variable diffusion coefficients) using a range of complementary electrochemical and surface analysis techniques. This study also provides direct spectroscopic evidence for the transportation and electrochemical reactivity of redox active species, regardless of the size of the electrochemically reactive molecule, at the buried interface of the substrate electrode. With all redox dopants, when CA electrolysis was performed, redox active species were undetectable (<1 wt % of signature elements or below the detection limit of SR-XPS and NEXAFS) in the outermost surface layers of the membrane, while a high concentration of redox species was located at the electrode substrate as a consequence of the deposition of the reaction product (Fc(+)-anion complex) at the buried interface between the electrode and the membrane. This reaction chemistry for redox active species within plasticized polymeric membranes may be useful in the fashioning of multilayered polymeric devices (e.g., chemical sensors, organic electronic devices, protective laminates, etc.) based on an electrochemical tunable deposition of redox molecules at the buried substrate electrode beneath the membrane.

Understanding barium sulfate precipitation onto stainless steel

Publisher: Elsevier BV

Date: 03-2008

DOI: 10.1016/J.APSUSC.2007.11.062

Does presentation at multidisciplinary team meetings improve lung cancer survival? Findings from a consecutive cohort study

Publisher: Elsevier BV

Date: 10-2018

DOI: 10.1016/J.LUNGCAN.2018.07.032

Abstract: Multidisciplinary team (MDT) presentation in lung cancer has the potential to improve longterm outcomes, although this varies between studies. This study aims to evaluate outcomes including survival, according to MDT presentation and to explore the utility of data obtained from local clinical sources. Prospective cases of lung cancer recorded in our institution's cancer registry were analyzed according to MDT presentation for patient and tumour characteristics, adjusted survival and referral to palliative care. 1197 cases were included, 295 (24.6%) with MDT presentation and 902 (75.4%) without. 60% of patients were male with median (IQR) age at diagnosis of 70 years (62-78). Histopathology distribution (non-small cell lung cancer and small-cell lung cancer) was similar between the two groups. Compared with the non-MDT group, the MDT group had (1) ECOG score recorded more often (71.9% vs. 47.6%), (2) higher proportion of ECOG 0 cases (31.2% vs. 11.9%) and ECOG 1 cases (28.8% vs. 20.3%), (3) higher proportion of early stage disease (stage I - 23.1% vs. 9.7% stage II - 10.2% vs. 4.8%, stage IIIA - 14.6% vs 6.3%) and (4) lower proportion of metastatic disease (stage IV - 39.3% vs. 56.1%). Referral to palliative care was incompletely recorded in both groups (MDT: n = 116/295, 39.3% non-MDT: n = 430, 47.7%) but did not differ significantly for stage IV cases. Survival analyzed by stage was greater in the MDT group at 1, 2 and 5 years for all stages except stage IIIB at 1 year post-diagnosis. Adjusted survival analysis for the entire cohort showed improved survival at 5 years for the MDT group (HR 0.7 (0.58-0.85), p < 0.001). MDT presentation is associated with improved adjusted survival for lung cancer in this single institutional cohort in an analysis of local clinical cancer registry data.

Compression Stress-Induced Internal Magnetic Field in Bulky TiO₂ Photoanodes for Enhancing Charge-Carrier Dynamics

Publisher: American Chemical Society (ACS)

Date: 23-01-2023

DOI: 10.1021/JACSAU.2C00690

XPS studies of the fluoride ion‐selective electrode membrane LaF₃: Ion interferences

Publisher: Wiley

Date: 08-1989

DOI: 10.1002/SIA.740140806

XPS studies of the fluoride ion‐selective electrode membrane LaF₃: Evidence for a gel layer on the surface

Publisher: Wiley

Date: 08-1989

DOI: 10.1002/SIA.740140807

Extending the life of maintenance-free lead/acid batteries by etching of grids in sodium hydroxide

Publisher: Springer Science and Business Media LLC

Date: 2001

DOI: 10.1023/A:1017924630326

Surface Analysis of Adsorbed Carbon Dioxide Corrosion Inhibitors

Publisher: Association for Materials Protection and Performance (AMPP)

Date: 2001

DOI: 10.5006/1.3290335

In situ structural characterization of electrochemical systems using synchrotron-radiation techniques

Publisher: Elsevier BV

Date: 06-2010

DOI: 10.1016/J.TRAC.2010.01.011

An in situ synchrotron radiation grazing incidence X-ray diffraction study of carbon dioxide corrosion

Publisher: The Electrochemical Society

Date: 2005

DOI: 10.1149/1.2007227

Investigation of the calcareous deposits formation controlled by interfacial pH and its effect on the hydrogen entry into AISI 4135 steel in seawater

Publisher: Elsevier BV

Date: 2021

DOI: 10.1016/J.IJHYDENE.2020.11.040

Controlled One-pot Synthesis of Nickel Single Atoms Embedded in Carbon Nanotube and Graphene Supports with High Loading

Publisher: Wiley

Date: 29-04-2020

DOI: 10.1002/CNMA.202000223

Polyaniline Films as Electrochemical-Proton Pump for Acidification of Thin Layer Samples.

Publisher: American Chemical Society (ACS)

Date: 06-11-2019

DOI: 10.1021/ACS.ANALCHEM.9B03402

Abstract: Here, we provide the first experimental evidence of proton release from polyaniline (PANI) films subjected to anodic potentials at environmental pHs. We conducted an extensive characterization of unpolarized olarized PANI films-synthesized by traditional sequential voltammetric scanning-by using spectroelectrochemistry, synchrotron radiation-X-ray photoelectron spectroscopy, near edge X-ray absorption fine structure, and potentiometric pH sensing in the vicinity of the PANI layer. This new insight enables the utilization of PANI as a proton pump, which is actively tuned through an electrochemical pulse, so as to controllably acidify well-confined thin layer s les. Furthermore, we demonstrate the analytical significance of this system by measuring the alkalinity of artificial and natural water s les by using two faced planar PANI electrodes, one working as a proton source and the other one as pH electrode. Finally, the impact of this approach is 2-fold: (i) all-solid-state electrode materials may be used with devisible consequences in miniaturized and implementable submersible probes, and (ii) rapid determination of alkalinity as compared to traditional approaches together with a versatility in pH adjustment in any kind of s le, among other applications.

Factors That Determine the Performance of Carbon Fuels in the Direct Carbon Fuel Cell

Publisher: American Chemical Society (ACS)

Date: 07-11-2008

DOI: 10.1021/IE800891M

Atomically Dispersed Bimetallic FeNi Catalysts as Highly Efficient Bifunctional Catalysts for Reversible Oxygen Evolution and Oxygen Reduction Reactions

Publisher: Wiley

Date: 07-2019

DOI: 10.1002/CELC.201900483

Consensus minimum data set for lung cancer multidisciplinary teams: Results of a Delphi process

Publisher: Wiley

Date: 11-04-2018

DOI: 10.1111/RESP.13307

Abstract: While multidisciplinary team (MDT) care in lung cancer is widely practiced, there are few guidelines for MDT on best data collection strategies. MDT meetings need ready access to information for the provision of optimal treatment recommendations (the primary purpose of the meeting), audit of team performance and benchmarking. This study aimed to develop a practical data set designed for these goals through a recognized consensus process with health professionals who participate in formal MDT settings. A modified Delphi process with three iterations (two surveys and one consensus conference) was carried out involving over 100 Australian lung cancer MDT health professionals. In total, 122 lung cancer MDT health professionals responded to the Round 1 survey from over 350 invitees. Of the 122, 98 were available for invitation to Round 2. Of 98, 52 (53%) invitees responded to the Round 2 survey. After two rounds, 51 data elements across 8 domains (patient demographics, risk factors, biopsy data, staging, timeliness, treatment, follow-up and patient selection) achieved consensus, defined as 80% agreement. For Round 3, 33 MDT lead clinicians were invited to participate in a consensus conference. Of 33, 14 (42%) invitees distilled the 47 data elements into 23 elements across 8 domains to address the study objectives. A practical data set for lung cancer MDT to use for optimal treatment recommendations and to evaluate team performance was developed through recognized consensus methodology. Access to streamlined, relevant and feasible data collection strategies may improve MDT decision-making, audit of team performance and facilitate benchmarking.

Evidence of double layer/capacitive charging in carbon nanomaterial-based solid contact polymeric ion-selective electrodes

Publisher: Royal Society of Chemistry (RSC)

Date: 2016

DOI: 10.1039/C6CC04876E

Abstract: We report on the first direct spectroscopic evidence of the capacitive ion-to-electron transducing mechanism of carbon nanomaterials in solid contact polymeric ion-selective electrodes (SC-ISEs).

An in situ chronoamperometry/synchrotron radiation grazing incidence X-ray diffraction study of the electrochemical oxidation of pyrite in chloride media

Publisher: Elsevier BV

Date: 10-2006

DOI: 10.1016/J.ELECOM.2006.07.036

Continuous flow analysis of mercury using a chalcogenide glass ion-selective electrode

Publisher: Wiley

Date: 2000

DOI: 10.1002/1098-2728(2000)12:4<194::AID-LRA4>3.0.CO;2-O

The Influence of Diffusion Fluxes on the Detection Limit of the Jalpaite Copper Ion-Selective Electrode

Publisher: Wiley

Date: 04-2002

DOI: 10.1002/1521-4109(200204)14:7/8<493::AID-ELAN493>3.0.CO;2-C

Atomically Dispersed Transition Metals on Carbon Nanotubes with UltraHigh Loading for Selective Electrochemical Carbon Dioxide Reduction

Publisher: Wiley

Date: 09-02-2018

DOI: 10.1002/ADMA.201706287

Abstract: Single‐atom catalysts (SACs) are the smallest entities for catalytic reactions with projected high atomic efficiency, superior activity, and selectivity however, practical applications of SACs suffer from a very low metal loading of 1–2 wt%. Here, a class of SACs based on atomically dispersed transition metals on nitrogen‐doped carbon nanotubes (MSA‐N‐CNTs, where M = Ni, Co, NiCo, CoFe, and NiPt) is synthesized with an extraordinarily high metal loading, e.g., 20 wt% in the case of NiSA‐N‐CNTs, using a new multistep pyrolysis process. Among these materials, NiSA‐N‐CNTs show an excellent selectivity and activity for the electrochemical reduction of CO 2 to CO, achieving a turnover frequency (TOF) of 11.7 s −1 at −0.55 V (vs reversible hydrogen electrode (RHE)), two orders of magnitude higher than Ni nanoparticles supported on CNTs.

The influence of microstructure on the corrosion rate of various carbon steels

Publisher: Springer Science and Business Media LLC

Date: 02-2005

DOI: 10.1007/S10800-004-6207-7

Magnetizing lead-free halide double perovskites

Publisher: American Association for the Advancement of Science (AAAS)

Date: 06-11-2020

DOI: 10.1126/SCIADV.ABB5381

Abstract: Alloying magnetic ions into halide double perovskites brings new opportunities for spintronics.

Harmonic analysis of carbon dioxide corrosion

Publisher: Elsevier BV

Date: 06-2002

DOI: 10.1016/S0010-938X(01)00136-6

Characterization of an AgBr-Ag2S-AS(2)S(3)-HgI2 ion-selective electrode membrane: a X-ray photoelectron and impedance spectroscopy approach

Publisher: Elsevier BV

Date: 04-2004

DOI: 10.1016/J.APSUSC.2004.01.040

High CO tolerance of new SiO2 doped phosphoric acid/polybenzimidazole polymer electrolyte membrane fuel cells at high temperatures of 200–250 °C

Publisher: Elsevier BV

Date: 12-2018

DOI: 10.1016/J.IJHYDENE.2018.10.036

In Situ Techniques for Developing Robust Li-S Batteries

Publisher: Wiley

Date: 08-2018

DOI: 10.1002/SMTD.201800133

Development of an improved ligand mimetic calibration system for the analysis of iron(III) in seawater using the iron(III) chalcogenide glass ion selective electrode: A combined mechanistic and analyt

Publisher: Elsevier BV

Date: 02-2015

DOI: 10.1016/J.SNB.2014.09.003

Surface studies of the jalpaite-based copper(II) ion-selective electrode membrane in seawater

Publisher: Elsevier BV

Date: 12-1996

DOI: 10.1016/S0304-4203(96)00063-1

Detecting Biorecognition Events at Blocked Interface Polymeric Membrane Ion‐Selective Electrodes Using Electrochemical Impedance Spectroscopy and Atomic Force Microscopy

Publisher: Wiley

Date: 29-01-2008

DOI: 10.1002/ELAN.200704064

Transformation of Cadmium Tetracyanoquinodimethane (TCNQ) into a Cadmium Terephthalate Metal-Organic Framework

Publisher: CSIRO Publishing

Date: 2017

DOI: 10.1071/CH17187

Abstract: The transformation of cadmium 7,7,8,8-tetracyanoquinodimethane (TCNQ) into a cadmium terephthalate co-ordination polymer is reported, with the chemistry of this material elucidated using elemental analysis, X-ray photoelectron spectroscopy and synchrotron radiation single-crystal X-ray diffraction. A heptacoordinated CdII linear coordination polymer catena-poly[triaqua-(μ2-benzene-1,4-dicarboxylato-κO,O′)cadmium(ii)]hydrate (1) was isolated while attempting to recrystallize Cd(TCNQ)2. Density functional theory calculations for the oxidation of benzylic carbon attached to the cyano group provided evidence that the reaction pathway proposed herein is highly exergonic and thermodynamically plausible. This structure showed a distorted pentagonal bipyramidal geometry together with a symmetrical mononuclear unit in which each CdII ion is doubly bridged by a dicarboxylato anion. Owing to the softness and minute size of these crystals, this structure had to be elucidated using synchrotron radiation X-ray crystallography.

Modification of Coal as a Fuel for the Direct Carbon Fuel Cell

Publisher: American Chemical Society (ACS)

Date: 07-10-2009

DOI: 10.1021/JP9062719

Abstract: As a promising high-temperature fuel cell, the direct carbon fuel cell (DCFC) has a much higher efficiency and a lower emission as compared with conventional coal-fired power plants. To develop an increased understanding of the relationship between the microstructure, surface chemistry, and electrochemical performance of coal as a fuel for the DCFC, a coal s le from Central Queensland has been subjected to various pretreatments, including acid washing, air oxidation, and pyrolysis. It has been found that an acid treatment of the coal enhanced its electrochemical reactivity due to an increase in oxygen-containing surface functional groups. By contrast, heat treatment of the coal results in a sharp decrease in the electrochemical reactivity in the DCFC due to a decrease in the oxygen-containing surface functional groups, particularly CO(2)-yielding surface groups. A higher surface area of coal may also be helpful, but much less important than surface chemistry.

Electronic cigarettes in physician practice: a complex debate

Publisher: Wiley

Date: 04-2019

DOI: 10.1111/IMJ.14256

Abstract: E-cigarettes, or electronic nicotine delivery systems (ENDS), have been suggested as a potential aid for smoking cessation, but many questions about their efficacy and safety remain unanswered. Until very recently, the evidence for ENDS in smoking cessation was largely based on observational studies or randomised controlled trials with methodological flaws and did not provide adequate evidence to support strongly ENDS for smoking cessation. Concerns about the uptake of ENDS by nonsmoking populations (such as adolescents) remain. More recent evidence may indicate the effect of ENDS in smoking cessation, but many questions remain unanswered. In this article, we address recent claims that failure to recommend ENDS for smoking cessation represents unethical practice. We strongly dispute this claim, analysing the many complex issues that clinicians working in smoking cessation should consider.

Characterization of turbostratic carbons synthesized by catalytic decomposition of acetylene

Publisher: IEEE

Date: 2006

DOI: 10.1109/ICONN.2006.340694

Hydrogen release from carbon steel in chloride solution under anodic polarization

Publisher: Elsevier BV

Date: 2020

DOI: 10.1016/J.IJHYDENE.2019.11.218

Surface studies of a chalcogenide glass ferric ion‐selective electrode Part 2: The effects of inorganic ions, organic ligands and seawater on sensor response

Publisher: Wiley

Date: 09-2002

DOI: 10.1002/SIA.1450

Clinical impact of data feedback at lung cancer multidisciplinary team meetings: A mixed methods study

Publisher: Wiley

Date: 12-11-2019

DOI: 10.1111/AJCO.13278

Abstract: Multidisciplinary team (MDT) meetings can facilitate optimal lung cancer care, yet details of structured data collection and feedback remain sparse. This study aimed to investigate data collection and the impact of feedback to lung cancer MDTs. A mixed-methods study using pre and post-test surveys, semistructured interviews, and observation to evaluate data collection and response to modeled data feedback in three Australian lung cancer MDTs at different locations and development stage (site A: outer metropolitan, established site B, outer metropolitan, new and site C, inner metropolitan, established). MDT attendees (range 13-25) discussed 5-8 cases per meeting. All sites collected data prospectively (80% prepopulated) into local oncology medical information systems. The pretest survey had 17 respondents in total (88% clinicians). At sites A and C, 100% of respondents noted regular data audits, occasional at site B. Regular audit data included number of cases, stage, final diagnosis, and time to diagnosis and treatment. The post-test survey had 25 respondents in total, all clinicians. The majority (88-96%) of respondents found modeled data easy to interpret, relevant to clinical practice and the MDT, and welcomed future regular data presentations (as rated on a 5-point Likert scale mean weighted average 4.5 where > 4 demonstrates agreement). Semistructured interviews identified five major themes for MDTs: current practice, attitudes, enablers, barriers, and benefits for the MDT. MDT teams exhibited positive responses to modeled data feedback. Key characteristics of MDT data were identified and may assist with future team research and development.

Electrochemistry-Assisted Photoelectrochemical Reduction of Nitrogen to Ammonia

Publisher: American Chemical Society (ACS)

Date: 14-10-2021

DOI: 10.1021/ACS.JPCC.1C07278

Surface studies of the silver sulfide ion selective electrode membrane

Publisher: American Chemical Society (ACS)

Date: 11-1990

DOI: 10.1021/AC00220A015

In situ synchrotron radiation grazing incidence X-ray diffraction - A powerful technique for the characterization of solid-state ion-selective electrode surfaces

Publisher: Elsevier BV

Date: 06-2006

DOI: 10.1016/J.ELECTACTA.2006.01.034

Electrochemically substituted metal phthalocyanines, e-MPc (M = Co, Ni), as highly active and selective catalysts for CO2 reduction

Publisher: Royal Society of Chemistry (RSC)

Date: 2018

DOI: 10.1039/C7TA09208C

Abstract: The Fe center in FePc can be electrochemically substituted by Co and Ni, achieving high activity and stability for CO 2 reduction.

High activity electrocatalysts from metal–organic framework-carbon nanotube templates for the oxygen reduction reaction

Publisher: Elsevier BV

Date: 02-2015

DOI: 10.1016/J.CARBON.2014.10.085

Reversible electrochemical monitoring of surface confined reactions at liquid–liquid interfaces by modulation of ion transfer fluxes

Publisher: Royal Society of Chemistry (RSC)

Date: 2005

DOI: 10.1039/B503548A

Abstract: The adsorption of the neutral surfactant Brij35 at a liquid-liquid interface is reversibly monitored via its disturbance of an electrochemically imposed ion flux across the interface, forming a promising experimental tool for the detection of surface confined reactions at such liquids and polymers.

Influence of lead(II) carbonate films of non-antimonial grids on the deep discharge cycling behaviour of maintenance-free lead/acid batteries

Publisher: Springer Science and Business Media LLC

Date: 1997

DOI: 10.1023/A:1026427201906

A near edge X-ray absorption fine structure (NEXAFS) study of the response mechanism of the iron (III) chalcogenide glass membrane ion-selective electrode

Publisher: Elsevier BV

Date: 04-2014

DOI: 10.1016/J.ELECOM.2014.01.017

One-pot pyrolysis method to fabricate carbon nanotube supported ni single-atom catalysts with ultrahigh loading

Publisher: American Chemical Society (ACS)

Date: 20-09-2018

DOI: 10.1021/ACSAEM.8B00903

Development of a Structure‐Activity Relationship for Oil Field Corrosion Inhibitors

Publisher: The Electrochemical Society

Date: 05-1999

DOI: 10.1149/1.1391837

Abstract: Corrosion rate data for mild steel corrosion inhibitors in carbonated brine media were fitted to the Temkin adsorption isotherm. The fundamental constants of the Temkin adsorption isotherm, i.e., molecular interaction and adsorption equilibrium constants, were used to glean important information about the behavior of adsorbed corrosion inhibitors. Adsorption data were also used to calculate Δ ad H , Δ ad G , and Δ ad S , and the results demonstrated that some compounds are chemisorbed onto the electrode. Significantly, it has been found that chemisorption of corrosion inhibitors can yield very good film persistency (i.e.. corrosion protection even when the inhibitor is no longer present). Molecular modeling using the quantum mechanical program PCSpartan plus , along with a comparative analysis of adsorption data for a broad range of inhibitor molecules, has been used to derive a tentative structure/activity relationship for some oil field corrosion inhibitors. © 1999 The Electrochemical Society. All rights reserved.

A study of the adsorption properties of commercial carbon dioxide corrosion inhibitor formulations

Publisher: Springer Science and Business Media LLC

Date: 2001

DOI: 10.1023/A:1012716911305

Calibration of the Hg chalcogenide glass membrane ion-selective electrode in seawater media

Publisher: Elsevier BV

Date: 06-1999

DOI: 10.1016/S0039-9140(99)00003-X

Abstract: It is shown that a chalcogenide glass mercury(II) ion-selective electrode (ISE) can be calibrated in chloride-free unbuffered and saline buffered standards, displaying near-Nernstian response over 19 orders of magnitude (i.e. 10(-20) to 10(-1) M Hg(2+)). Extended ageing of the ISE in seawater induced a memory effect, causing the electrode to respond in a sub-Nernstian fashion. Electrochemical impedance spectroscopy (EIS) demonstrated that the response of the Hg(II) ISE is underpinned by a charge transfer process, and seawater matrix effects are due to electrode passivation. It is shown that standard addition ISE potentiometry may compensate for interferences caused by the seawater matrix.

Flow Dependence of Carbon Dioxide Corrosion Using Short Electrodes by Jet Impingement

Publisher: Association for Materials Protection and Performance (AMPP)

Date: 12-2009

DOI: 10.5006/1.3319103

Electron Hopping between Fe 3 d States in Ethynylferrocene‐doped Poly(Methyl Methacrylate)‐poly(Decyl Methacrylate) Copolymer Membranes

Publisher: Wiley

Date: 10-10-2017

DOI: 10.1002/ELAN.201700510

Surface studies of the copper/silver sulfide based ion-selective electrode membrane

Publisher: American Chemical Society (ACS)

Date: 15-03-0033

DOI: 10.1021/AC00030A006

A flow cell for transient voltammetry and in situ grazing incidence X-ray diffraction characterization of electrocrystallized cadmium(II) tetracyanoquinodimethane

Publisher: Elsevier BV

Date: 2011

DOI: 10.1016/J.ELECTACTA.2010.09.106

Ion-selective electrode potentiometry in environmental analysis

Publisher: Wiley

Date: 10-2007

DOI: 10.1002/ELAN.200703916

Abstract: This review will illustrate how it is possible to develop ion‐selective electrode (ISE) methodologies that meet the stringent requirements (i.e., high selectivities and very low detection limits) for the analysis of important analytes in the environment, and will present a variety of ex les on the application of ISEs in environmental analysis. Despite the experimental biases that have limited the analytical performance of ISEs through apparently high detection limits and modest selectivities, there has been a plethora of research in the application of ISEs in the monitoring of environmentally important trace metals and anions in natural waters and soils. Most popular has been the analysis of free metals in natural waters, as this parameter is known to be a master variable in the uptake and toxicology of trace metals on aquatic biota reflecting the bioavailability of trace metals in the environment. Furthermore, as copper is a major trace metal in coastal waters due to its extensive use in antifouling paints on sea vessels and structures, there are many reports in the literature on the use of the copper ISE in assays of either free copper or the copper complexing capacity of natural waters and soil peats. Moreover, there have been a variety of studies showing a strong correlation between free copper levels and the toxicity of copper on a variety of marine and fresh water organisms. Nevertheless, there are numerous reports in the literature that have used ISEs to monitor important anions such as fluoride, phosphate, sulfate, nitrate, nitrite, chloride, cyanide, etc., as well as other important cations such as ammonium and chromium(VI) in waste and natural waters. In conclusion, this review will present new and interesting perspectives on the application of ISEs in environmental analysis using approaches such as real‐time remote monitoring of water quality, shipboard monitoring of environmentally important analytes using flow analysis instrumentation, the use of robust all‐solid‐state ISEs in submersible instruments for long‐term deployment in the field, and innovative analytical approaches such as backside calibration and switchtrodes that avoid standard addition analysis and the concomitant perturbation in analyte speciation in natural s les.

Water uptake in the hydrophilic poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) solid-contact of all-solid-state polymeric ion-selective electrodes

Publisher: Royal Society of Chemistry (RSC)

Date: 2011

DOI: 10.1039/C1AN15267J

Abstract: Solid-contact (SC) ion-selective electrodes (ISEs) utilizing thin films of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) and plasticized poly(vinylchloride) (PVC) have been produced using a spin casting procedure. This study was carried out with a view of characterizing this popular and well known SC ISE using a series of complementary surface analysis techniques. This work revealed that PEDOT:PSS prevents the separation of an undesirable water layer at the buried interface of this SC ISE due to the high miscibility of water in the hydrophilic PEDOT:PSS layer. The lack of a clearly defined and molecularly sharp buried interface prohibits the formation of a distinct water layer presumably by eliminating sites that promote the accumulation of water. This outcome is important to the chemical sensor community since it provides further insights into the compatibility of sensor components in SC ISEs.

Impedance measurements of a chalcogenide membrane iron(III)-selective electrode in contact with aqueous electrolytes

Publisher: Elsevier BV

Date: 09-2004

DOI: 10.1016/J.ELECTACTA.2004.03.029

Iron Single Atoms on Graphene as Nonprecious Metal Catalysts for High-Temperature Polymer Electrolyte Membrane Fuel Cells

Publisher: Wiley

Date: 13-03-2019

DOI: 10.1002/ADVS.201802066

In situ electrochemical impedance spectroscopy/synchrotron radiation grazing incidence X-ray diffraction- A powerful new technique for the characterization of electrochemical surfaces and interfaces

Publisher: Elsevier BV

Date: 08-2006

DOI: 10.1016/J.ELECTACTA.2006.03.030

Continuous flow analysis of iron (III) in seawater using a chalcogenide glass ion-selective electrode

Publisher: Wiley

Date: 1999

DOI: 10.1002/(SICI)1098-2728(1999)11:5<284::AID-LRA7>3.0.CO;2-8

Reply to “Comments on ‘Calibration of a chalcogenide glass membrane ion-selective electrode for the determination of free Fe3+ in seawater: I. Measurements in UV photooxidised seawater’ by De Marco an

Publisher: Elsevier BV

Date: 08-2000

DOI: 10.1016/S0304-4203(00)00063-3

Photoelectrochemical N₂‐to‐NH₃ Fixation with High Efficiency and Rates via Optimized Si‐Based System at Positive Potential versus Li^0/+

Publisher: Wiley

Date: 30-03-2023

DOI: 10.1002/ADMA.202211894

Abstract: As a widely used commodity chemical, ammonia is critical for producing nitrogen‐containing fertilizers and serving as the promising zero‐carbon energy carrier. Photoelectrochemical nitrogen reduction reaction (PEC NRR) can provide a solar‐powered green and sustainable route for synthesis of ammonia (NH 3 ). Herein, an optimum PEC system is reported with an Si‐based hierarchically‐structured PdCu/TiO 2 /Si photocathode and well‐thought‐out trifluoroethanol as the proton source for lithium‐mediated PEC NRR, achieving a record high NH 3 yield of 43.09 µg cm −2 h −1 and an excellent faradaic efficiency of 46.15% under 0.12 MPa O 2 and 3.88 MPa N 2 at 0.07 V versus lithium(0/+) redox couple (vs Li 0/+ ). PEC measurements coupled with operando characterization reveal that the PdCu/TiO 2 /Si photocathode under N 2 pressures facilitate the reduction of N 2 to form lithium nitride (Li 3 N), which reacts with active protons to produce NH 3 while releasing the Li + to reinitiate the cycle of the PEC NRR. The Li‐mediated PEC NRR process is further enhanced by introducing small amount of O 2 or CO 2 under pressure by accelerating the decomposition of Li 3 N. For the first time, this work provides mechanistic understanding of the lithium‐mediated PEC NRR process and opens new avenues for efficient solar‐powered green conversion of N 2 ‐to‐NH 3 .

Selective Hydrogen Evolution on Manganese Oxide Coated Electrodes: New Cathodes for Sodium Chlorate Production

Publisher: American Chemical Society (ACS)

Date: 15-06-2019

DOI: 10.1021/ACSSUSCHEMENG.9B01279

Electrochemical Ion Transfer with Thin Films of Poly(3-octylthiophene)

Publisher: American Chemical Society (ACS)

Date: 17-06-2016

DOI: 10.1021/ACS.ANALCHEM.6B01800

Abstract: We report on the limiting conditions for ion-transfer voltammetry between an ion-exchanger doped and plasticized poly(vinyl chloride) (PVC) membrane and an electrolyte solution that was triggered via the oxidation of a poly(3-octylthiophene) (POT) solid-contact (SC), which was unexpectedly related to the thickness of the POT SC. An electropolymerized 60 nm thick film of POT coated with a plasticized PVC membrane exhibited a significant sodium transfer voltammetric signal whereas a thicker film (180 nm) did not display a measurable level of ion transfer due to a lack of oxidation of thick POT beneath the membrane film. In contrast, this peculiar phenomenon was not observed when the POT film was in direct contact with an organic solvent-based electrolyte. This evidence is indicative of three key points: (i) the coated membrane imposes a degree of rigidity to the system, which restricts the swelling of the POT film and its concomitant p-doping (ii) this phenomenon is exacerbated with thicker POT films due to an initial morphology (rougher comprising a network of large POT nanoparticles), which gives rise to a diminished surface area and electrochemical reactivity in the POT SC (iii) the rate of sodium transfer is higher with a thin POT film due to a smoother surface morphology made up of a network of smaller POT nanoparticles with an increased surface area and electrochemical reactivity. A variety of techniques including cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), ellipsometry, scanning electron microscopy (SEM), atomic force microscopy (AFM), and synchrotron radiation-X-ray photoelectron spectroscopy (SR-XPS) were used to elucidate the mechanism of the POT thickness/POT surface roughness dependency on the electrochemical reactivity of the PVC/POT SC system.

Study on the Temperature Dependence of Pitting Behaviour of AISI 4135 Steel in Marine Splash Zone

Publisher: The Electrochemical Society of Japan

Date: 2015

DOI: 10.5796/ELECTROCHEMISTRY.83.541

Evidence of a water layer in solid-contact polymeric ion sensors

Publisher: Royal Society of Chemistry (RSC)

Date: 2008

DOI: 10.1039/B714248J

Thin layer coulometric determination of nitrate in fresh waters

Publisher: Elsevier BV

Date: 09-2012

DOI: 10.1016/J.ACA.2012.07.026

Abstract: A nitrate ion-selective electrode (ISE) employing a permeable tubular membrane impregnated with a conventional ISE cocktail has been used successfully in the coulometric analysis of nitrate in fresh waters. The liquid ISE membrane comprising a nitrate ionophore [tridodecylmethylammonium nitrate (TDMAN)], lipophilic electrolyte [tetradodecyl-ammoniumtetrakis(4-chlorophenyl)borate (ETH 500)] and plasticizer [bis(3-ethyl-hexyl)sebacate (DOS)] was supported on a porous polypropylene tube. Coulometric analysis with the tubular membrane ISE showed that nitrate could be detected in the range 10-100 μM with a precision of 2.3% relative standard deviation (RSD), limit of detection of 1.1 μM and relative accuracy of 4.4% compared to a certified reference material (CRM) Lake s le.

Evaluation of raw coals as fuels for direct carbon fuel cells

Publisher: Elsevier BV

Date: 07-2010

DOI: 10.1016/J.JPOWSOUR.2010.01.048

ELECTRODES | Ion-Selective Electrodes

Publisher: Elsevier

Date: 2009

DOI: 10.1016/B978-044452745-5.00848-0

A multi-technique surface study of the mercury(II) chalcogenide ion-selective electrode in saline media

Publisher: Royal Society of Chemistry (RSC)

Date: 2003

DOI: 10.1039/B212914K

Abstract: X-ray photoelectron spectroscopy (XPS), secondary ion mass spectrometry (SIMS), rotating disc electrode-electrochemical impedance spectroscopy (RDE-EIS) and synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD) have been used to study the response mechanism of the mercury(II) chalcogenide ion-selective electrode (ISE) in saline media. XPS and SIMS have shown that the chalcogenide surface is poisoned by silver chloride, or a mixture of silver halides, on continuous exposure to synthetic and real seawater. Significantly, the in-situ SR-GIXRD study demonstrated that electrode fouling in synthetic seawater is linked to the formation of poorly crystalline or amorphous silver chloride, and that the low level of free mercury(II) in a calibration buffer (i.e., 10(-14) M) is able to undergo metathesis with silver(II) sulfide in the membrane generating mercury(II) sulfide. Significantly, the results of this detailed surface study have shown that silver chloride fouling of the electrode is ameliorated in real seawater comprising natural organic ligands, and this has been attributed to the peptization of silver chloride by the surfactant-like nature of seawater ligands at pH 8. RDE-EIS aging studies have revealed that the chalcogenide membrane experiences a sluggish charge transfer reaction in seawater, and contrary to a previous report for a static electrode, the seawater matrix does not passivate the RDE. The results of this XPS, SIMS, RDE-EIS and SR-GIXRD study have elucidated the response mechanism of the mercury(II) ISE in saline media.

Response Mechanisms and New Approaches with Solid‐State Ion‐Selective Electrodes: A Powerful Multitechnique Materials Characterization Approach

Publisher: Wiley

Date: 07-2006

DOI: 10.1002/ELAN.200503524

Abstract: In modern materials science, there is a plethora of characterization techniques of materials that can provide valuable insights into the fundamental chemical physics of solid‐state devices such as chalcogenide glass ion‐selective electrodes (ISEs). In this paper, electrochemical impedance spectroscopy (EIS), X‐ray photoelectron spectrometry (XPS) and secondary ion mass spectrometry (SIMS) have been used in the elucidation of the mechanistic chemistry of the cadmium chalcogenide glass ISE. Furthermore, in situ synchrotron radiation‐grazing incidence X‐ray diffraction (SR‐GIXRD), in situ EIS/SR‐GIXRD, along with small angle neutron scattering (SANS), can be used to unravel the complex relationship between the nanostructure, bulk electrical conductivity and concomitant electrochemical reactivity of an iron chalcogenide glass ISE. Significantly, exciting preliminary modified atomic force microscopy (AFM) data – utilizing AFM cantilevers with attached microparticles of the copper sensing material jalpaite – demonstrate the tremendous potential of selective force ISE‐AFM in the imaging of important molecular structures such as the copper ion channels of cell membranes in fish gills and/or phytoplankton.

Surface modification of carbon fuels for direct carbon fuel cells

Publisher: Elsevier BV

Date: 2009

DOI: 10.1016/J.JPOWSOUR.2008.09.070

Effect of heat treatment on hydrogen permeation behaviour of AISI 4135 steel under splash zone conditions

Publisher: Informa UK Limited

Date: 02-04-2016

DOI: 10.1179/1743278215Y.0000000043

Changes in positive lead/acid battery plates during charge/discharge cycling

Publisher: Springer Science and Business Media LLC

Date: 2000

DOI: 10.1023/A:1003886931171

Efficient BiVO₄ Photoanodes by Postsynthetic Treatment: Remarkable Improvements in Photoelectrochemical Performance from Facile Borate Modification

Publisher: Wiley

Date: 08-11-2019

DOI: 10.1002/ANIE.201911303

Abstract: Water‐splitting photoanodes based on semiconductor materials typically require a dopant in the structure and co‐catalysts on the surface to overcome the problems of charge recombination and high catalytic barrier. Unlike these conventional strategies, a simple treatment is reported that involves soaking a s le of pristine BiVO 4 in a borate buffer solution. This modifies the catalytic local environment of BiVO 4 by the introduction of a borate moiety at the molecular level. The self‐anchored borate plays the role of a passivator in reducing the surface charge recombination as well as that of a ligand in modifying the catalytic site to facilitate faster water oxidation. The modified BiVO 4 photoanode, without typical doping or catalyst modification, achieved a photocurrent density of 3.5 mA cm −2 at 1.23 V and a cathodically shifted onset potential of 250 mV. This work provides an extremely simple method to improve the intrinsic photoelectrochemical performance of BiVO 4 photoanodes.

Battery performance enhancement with additions of bismuth

Publisher: Elsevier BV

Date: 02-1994

DOI: 10.1016/0378-7753(94)80012-X

A calixarene-based ion-selective electrode for thallium(I) detection

Publisher: Elsevier BV

Date: 08-2014

DOI: 10.1016/J.ACA.2014.08.046

Abstract: Three new calixarene Tl(+) ionophores have been utilized in Tl(+) ion-selective electrodes (ISEs) yielding Nernstian response in the concentration range of 10(-2)-10(-6)M TlNO3 with a non-optimized filling solution in a conventional liquid contact ISE configuration. The complex formation constants (logβIL) for two of the calixarene derivatives with thallium(I) (i.e. 6.44 and 5.85) were measured using the sandwich membrane technique, with the other ionophore immeasurable due to eventual precipitation of the ionophore during these long-term experiments. Furthermore, the unbiased selectivity coefficients for these ionophores displayed excellent selectivity against Zn(2+), Ca(2+), Ba(2+), Cu(2+), Cd(2+) and Al(3+) with moderate selectivity against Pb(2+), Li(+), Na(+), H(+), K(+), NH4(+) and Cs(+), noting that silver was the only significant interferent with these calixarene-based ionophores. When optimizing the filling solution in a liquid contact ISE, it was possible to achieve a lower limit of detection of approximately 8nM according to the IUPAC definition. Last, the new ionophores were also evaluated in four solid-contact (SC) designs leading to Nernstian response, with the best response noted with a SC electrode utilizing a gold substrate, a poly(3-octylthiophene) (POT) ion-to-electron transducer and a poly(methyl methacrylate)-poly(decyl methacrylate) (PMMA-PDMA) co-polymer membrane. This electrode exhibited a slope of 58.4mVdecade(-1) and a lower detection limit of 30.2nM. Due to the presence of an undesirable water layer and/or leaching of redox mediator from the graphite redox buffered SC, a coated wire electrode on gold and graphite redox buffered SC yielded grossly inferior detection limits against the polypyrrole/PVC SC and POT/PMMA-PDMA SC ISEs that did not display signs of a water layer or leaching of SC ingredients into the membrane.

Corrosion Performance of High Strength Low Alloy Steel AISI 4135 in the Marine Splash Zone

Publisher: The Electrochemical Society of Japan

Date: 2017

DOI: 10.5796/ELECTROCHEMISTRY.85.7

Response of the jalpaite membrane copper(II) ion‐selective electrode in marine waters

Publisher: Wiley

Date: 03-1997

DOI: 10.1002/ELAN.1140090414

Elimination of Undesirable Water Layers in Solid-Contact Polymeric Ion-Selective Electrodes

Publisher: American Chemical Society (ACS)

Date: 08-2008

DOI: 10.1021/AC800823F

Isoconversional Kinetic Analysis of the Combustion of Heavy Hydrocarbons

Publisher: American Chemical Society (ACS)

Date: 15-10-2009

DOI: 10.1021/EF901013A

Surface analysis of commercial lead/acid battery grids

Publisher: Elsevier BV

Date: 03-1995

DOI: 10.1016/0169-4332(94)00550-8

Determination of major constituents in metal samples by emission spectrometry using a demountable hollow cathode source and internal standardization

Publisher: Elsevier BV

Date: 1986

DOI: 10.1016/0584-8547(86)80070-2

Synthesis and characterization of turbostratic carbons prepared by catalytic chemical vapour decomposition of acetylene

Publisher: Elsevier BV

Date: 08-2006

DOI: 10.1016/J.APCATA.2006.05.013

Surface studies of a chalcogenide glass ferric ion-selective electrode - Part 1: Influence of ferric and hydroxide ions on interfacial kinetics

Publisher: Wiley

Date: 09-2002

DOI: 10.1002/SIA.1449

Precision and accuracy of quantitative emission spectrometry with particular reference to gold alloys

Publisher: Elsevier BV

Date: 1987

DOI: 10.1016/S0003-2670(00)84772-8

Deactivation and selectivity for electrochemical ozone production at Ni- and Sb-doped

Publisher: Elsevier BV

Date: 03-2020

DOI: 10.1016/J.ELECTACTA.2020.135645

PEDOT(PSS) as Solid Contact for Ion-Selective Electrodes: The Influence of the PEDOT(PSS) Film Thickness on the Equilibration Times.

Publisher: American Chemical Society (ACS)

Date: 27-02-2017

DOI: 10.1021/ACS.ANALCHEM.6B04625

Abstract: To understand the rate determining processes during the equilibration of poly(3,4-ethylenedioxythiophene):polystyrenesulfonate-based (PEDOT(PSS)-based) solid contact (SC) ion-selective electrodes (ISEs), the surfaces of Pt, Au, and GC electrodes were coated with 0.1, 1.0, 2.0, and 4.0 μm thick galvanostatically deposited PEDOT(PSS) films. Next, potential vs time transients were recorded with these electrodes, with and without an additional potassium ion-selective membrane (ISM) coating, following their first contact with 0.1 M KCl solutions. The transients were significantly different when the multilayered sensor structures were assembled on Au or GC compared to Pt. The differences in the rate of equilibration were interpreted as a consequence of differences in the hydrophilicity of PEDOT(PSS) in contact with the substrate electrode surfaces based on X-ray photoelectron spectroscopy (XPS) and synchrotron radiation-XPS (SR-XPS) analysis of 10-100 nm thick PEDOT(PSS) films. The influence of the layer thickness of the electrochemically deposited PEDOT(PSS)-films on the hydrophilicity of these films has been documented by contact angle measurements over PEDOT(PSS)-coated Au, GC, and Pt electrode surfaces. This study demonstrates that it is possible to minimize the equilibration (conditioning) time of SC ISEs with aqueous solutions before usage by optimizing the thickness of the SC layer with a controlled ISM thickness. PEDOT(PSS)-coated Au and GC electrodes exhibit a significant negative potential drift during their equilibration in an aqueous solution. By coating the PEDOT(PSS) surface with an ISM, the negative potential drift is compensated by a positive potential drift related to the hydration of the ISM and activity changes at the PEDOT(PSS)|ISM interface. The potential drifts related to activity changes in the ISM have been determined by a novel adaptation of the "sandwich membrane" method.

Ion-Exchange-Induced Selective Etching for the Synthesis of Amino-Functionalized Hollow Mesoporous Silica for Elevated-High-Temperature Fuel Cells

Publisher: American Chemical Society (ACS)

Date: 07-09-2017

DOI: 10.1021/ACSAMI.7B09591

Abstract: As differentiated from conventional synthetic processes, amino-functionalized hollow mesoporous silica (NH

Variations in lung cancer care and outcomes: How best to identify and improve standards of care?

Publisher: Wiley

Date: 10-2021

DOI: 10.1111/RESP.14155

Tuning the Electron Localization of Gold Enables the Control of Nitrogen‐to‐Ammonia Fixation

Publisher: Wiley

Date: 04-11-2019

DOI: 10.1002/ANIE.201909477

Abstract: The (photo)electrochemical N

Electronic cigarettes: A position statement from the Thoracic Society of Australia and New Zealand*

Publisher: Wiley

Date: 26-07-2020

DOI: 10.1111/RESP.13904

An in situ electrochemical impedance spectroscopy/synchrotron radiation grazing incidence X-ray diffraction study of the influence of acetate on the carbon dioxide corrosion of mild steel

Publisher: Elsevier BV

Date: 03-2007

DOI: 10.1016/J.ELECTACTA.2006.10.048

In situ SERS study of the adsorption of inhibitors of carbon dioxide corrosion

Publisher: Wiley

Date: 2003

DOI: 10.1002/SIA.1567

A small angle neutron scattering and electrochemical impedance spectroscopy study of the nanostructure of the iron chalcogenide glass ion-selective electrode

Publisher: Elsevier BV

Date: 10-05-2004

DOI: 10.1016/J.TALANTA.2003.11.025

Abstract: This paper presents a preliminary structural and interfacial study of the iron chalcogenide glass [i.e., Fe(x)(Ge(28)Sb(12)Se(60))(100-x)] ion-selective electrode (ISE) using small angle neutron scattering (SANS) and electrochemical impedance spectroscopy (EIS). SANS detected variations in the neutron scattering as a function of iron content in the chalcogenide glass. Furthermore, a change in the chalcogenide glass structure was observed at elevated iron dopant levels. Conversely, EIS was used to show that the iron chalcogenide membrane comprises various time constants, and the interfacial charge transfer reaction depends on the membrane iron content. Equivalent circuit modeling revealed that the charge transfer resistance decreases at elevated iron levels, and this may be related to the presence of iron defects in the glass. It is proposed that the iron chalcogenide membrane comprises an iron nanostructural network embedded in the amorphous matrix, and this directly influences the electrical conductivity and concomitant electrochemical reactivity of the glass.

Graphitic Carbon Nanofibers Synthesized by the Chemical Vapor Deposition (CVD) Method and Their Electrochemical Performances in Supercapacitors

Publisher: American Chemical Society (ACS)

Date: 06-09-2008

DOI: 10.1021/EF8004306

Severe disseminated primary varicella in a patient on long term inhaled corticosteroids

Publisher: Wiley

Date: 30-07-2022

DOI: 10.1002/RCR2.1010

Abstract: Disseminated primary varicella infection can carry risks of significant morbidity and mortality particularly in immunocompromised populations. Routine, funded childhood vaccination against varicella has significantly reduced associated hospitalization and deaths, however, uptake and efficacy among adults is unknown. We present a case of disseminated primary varicella infection (including rash, pneumonitis, hepatitis and thrombocytopenia) in an immunocompetent patient on long term inhaled corticosteroids for asthma. This case highlights potential risk factors for severe varicella which require further study in adults and raises the need to discuss vaccination in at risk groups including appropriate counselling in those who may be at higher risk.

Electrochemistry at the interface between an aqueous droplet and 1,2-dichloroethane

Publisher: Elsevier BV

Date: 06-2012

DOI: 10.1016/J.ELECOM.2012.02.044

Continuous flow methods for evaluating the response of a copper ion selective electrode to total and free copper in seawater

Publisher: Royal Society of Chemistry (RSC)

Date: 1999

DOI: 10.1039/A903819A

Abstract: This work describes the development of an instrument for measuring free and total copper in seawater by continuous flow analysis (CFA) with an Orion copper (II) ion selective electrode (CuISE). S le analysis times are reduced considerably by using an extrapolation technique based on the fitting of an empirical mathematical expression to the electrode time-response curve enabling a prediction of the final equilibrium potential. CuISE measurements in seawater s les containing nanomolar levels of total copper can be very time consuming, and this predictive approach significantly reduces s le analysis time, and improves s le throughput. The time taken to measure pCu in seawater to a precision of +/- 0.1, using conventional potentiometry, varies considerably depending on the condition of the electrode membrane but can be reduced by a factor of 3-6 (typically from 60 to 10 min) by using the extrapolation technique in conjunction with CFA. Details are given of the protocols used for preconditioning the CuISE. The system can be used as a portable instrument for field measurements or for shipboard measurements of free copper in seawater. Extrapolated equilibrium potentials are within +/- 0.5 mV of true steady state values.

Electrochemical Mechanism of Ferrocene-Based Redox Molecules in Thin Film Membrane Electrodes

Publisher: Elsevier BV

Date: 06-2017

DOI: 10.1016/J.ELECTACTA.2017.04.047

University Of Tasmania

Location: Australia

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CSIRO

Location: Australia

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University Of Queensland

Location: Australia

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La Trobe University

Location: Australia

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RMIT University

Location: Australia

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Curtin University

Location: Australia

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Linkage Infrastructure, Equipment And Facilities - Grant ID: LE120100026

Start Date: 01-2012

End Date: 12-2013

Amount: $480,000.00

Funder: Australian Research Council

Discovery Projects - Grant ID: DP0987851

Start Date: 2009

End Date: 12-2013

Amount: $800,000.00

Funder: Australian Research Council

Discovery Projects - Grant ID: DP180100568

Start Date: 07-2018

End Date: 12-2021

Amount: $564,124.00

Funder: Australian Research Council

Linkage - International - Grant ID: LX0776015

Start Date: 02-2007

End Date: 06-2010

Amount: $36,000.00

Funder: Australian Research Council

Discovery Projects - Grant ID: DP150102025

Start Date: 2015

End Date: 12-2017

Amount: $375,500.00

Funder: Australian Research Council

Discovery Projects - Grant ID: DP0452563

Start Date: 11-2004

End Date: 12-2007

Amount: $120,000.00

Funder: Australian Research Council

Linkage Infrastructure, Equipment And Facilities - Grant ID: LE140100051

Start Date: 2014

End Date: 06-2015

Amount: $320,000.00

Funder: Australian Research Council

Discovery Projects - Grant ID: DP0344746

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End Date: 08-2005

Amount: $160,000.00

Funder: Australian Research Council

Linkage Infrastructure, Equipment And Facilities - Grant ID: LE140100012

Start Date: 2014

End Date: 04-2015

Amount: $890,000.00

Funder: Australian Research Council

Linkage Infrastructure, Equipment And Facilities - Grant ID: LE100100236

Start Date: 12-2011

End Date: 12-2011

Amount: $180,000.00

Funder: Australian Research Council

Discovery Projects - Grant ID: DP120102325

Start Date: 2012

End Date: 06-2015

Amount: $420,000.00

Funder: Australian Research Council

Special Research Initiatives - Grant ID: SR0354560

Start Date: 01-2004

End Date: 12-2004

Amount: $10,000.00

Funder: Australian Research Council

Linkage Infrastructure, Equipment And Facilities - Grant ID: LE180100179

Start Date: 03-2018

End Date: 12-2019

Amount: $3,189,000.00

Funder: Australian Research Council

Discovery Projects - Grant ID: DP0665400

Start Date: 2006

End Date: 06-2009

Amount: $210,000.00

Funder: Australian Research Council

Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0882634

Start Date: 2008

End Date: 12-2009

Amount: $220,000.00

Funder: Australian Research Council

Linkage Infrastructure, Equipment And Facilities - Grant ID: LE110100174

Start Date: 12-2011

End Date: 12-2012

Amount: $800,000.00

Funder: Australian Research Council

Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0989759

Start Date: 2009

End Date: 12-2010

Amount: $360,000.00

Funder: Australian Research Council

Linkage Infrastructure, Equipment And Facilities - Grant ID: LE170100158

Start Date: 05-2017

End Date: 05-2018

Amount: $470,000.00

Funder: Australian Research Council

Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0989675

Start Date: 2009

End Date: 04-2010

Amount: $180,000.00

Funder: Australian Research Council

Linkage - International - Grant ID: LX0454397

Start Date: 2004

End Date: 12-2006

Amount: $27,200.00

Funder: Australian Research Council

Linkage Infrastructure, Equipment And Facilities - Grant ID: LE190100144

Start Date: 03-2019

End Date: 03-2020

Amount: $844,947.00

Funder: Australian Research Council

Linkage Infrastructure, Equipment And Facilities - Grant ID: LE210100036

Start Date: 07-2021

End Date: 12-2023

Amount: $950,000.00

Funder: Australian Research Council