ORCID Profile
0000-0001-9223-9681
Current Organisation
Middle East Technical University
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Publisher: Elsevier BV
Date: 09-2010
DOI: 10.1016/J.JHAZMAT.2010.05.004
Abstract: The formation of struvite (MgNH(4)PO(4).6H(2)O) in wastewater treatment plants can lead to scaling and thus operational problems reducing the treatment efficiency. However, struvite has significant commercial value as an agricultural fertilizer. Therefore, controlled struvite formation in wastewater treatment plants not only presents an opportunity to recover nutrients but also corresponds to the valorization of wastes. NH(4)-N and PO(4)-P removal and recovery from the effluent of a full-scale sewage sludge anaerobic digester via controlled struvite precipitation were investigated in this study. The effect of the residual heavy metal and micropollutant content of the formed struvite on fertilizer quality was also evaluated. Removal efficiencies of NH(4)-N, PO(4)-P and COD were 89.35%, 95% and 39.78% when Mg:N:P molar ratio was 1.5:1:1 and pH was 9.0. Mercury, nickel, zinc and chrome concentrations derived from struvite precipitation were below the regulatory limit for fertilizer usage in Turkey. The precipitate did not contain polychlorinated biphenyls (PCB). X-ray diffraction (XRD) analysis conducted on the precipitate indicated a struvite formation.
Publisher: Informa UK Limited
Date: 05-2011
DOI: 10.1080/09593330.2010.512925
Abstract: The removal and the recovery of nutrients, namely nitrogen (N) and phosphorus (P) from anaerobically digested and solid-liquid separated manure effluents via struvite precipitation were investigated. Both the liquid and the solid phases of the poultry manure digester effluent were subjected to struvite precipitation experiments. The Mg:N:P molar ratio of 1:1:1 in the liquid phase resulted in an average NH4-N removal efficiency of 86.4%, which increased to 97.4% by adjusting the Mg:N:P ratio to 1.5:1:1. The acidic phosphorus-dissolution process was applied to the solid phase of the effluent to obtain a phosphorus-enriched solution. Nutrient recovery experiments with NaOH as the buffering reagent were conducted with and without addition of external chemicals (Mg and P sources) to evaluate the influence of the Mg:N:P molar ratio, the Mg:P molar ratio and pH. All the experiments depicted complete PO4-P (99.6-100.0%) and partial NH4-N (3.3-65.6%) recoveries from the phosphorus-enriched solution.
Publisher: SAGE Publications
Date: 17-06-2013
Abstract: Anaerobic digestion is commonly used for the stabilization of agricultural and animal wastes. However, owing to the stringent environmental criteria, anaerobic digester effluents need to be further treated to reduce nutrient loads to the receiving water bodies. Struvite precipitation is one of the promising techniques applied for this purpose. Yet, in the majority of cases, struvite precipitation is only applied to the liquid phase of anaerobic digester effluents. This study investigated the recovery of nutrients from both the liquid and the solid phases of the phase-separated effluent of a full-scale biogas plant co-digesting poultry manure and maize silage. Struvite precipitation in the liquid phase led to 72.1% and 95.1% average removal efficiencies of ammonium-nitrogen (NH 4 -N) and orthophosphate respectively. Changing the external phosphorus source did not make any statistically significant difference in nutrient removal. An acidic phosphorus-dissolution process was applied to the solid phase s le to obtain a phosphorus-enriched solution. More than 90.0% of both NH 4 -N and PO 4 -P were recovered from the phosphorus-enriched solution with the amendments of magnesium and phosphorus. In the experiments performed without any addition of external magnesium- and phosphorus-containing chemicals, almost complete (99.6%) PO 4 -P recovery and partial (14.6%) NH 4 -N recovery were obtained. The results of this study could contribute to the understanding of nutrient recovery from anaerobic digestion residues of manure and agricultural wastes by struvite precipitation.
No related grants have been discovered for Yasemin Dilsad Yilmazel.