ORCID Profile
0000-0001-9742-3744
Current Organisation
Fritz-Haber-Institut der Max-Planck-Gesellschaft
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Publisher: American Chemical Society (ACS)
Date: 16-11-2017
Publisher: American Chemical Society (ACS)
Date: 15-04-2015
DOI: 10.1021/CM504655F
Publisher: Royal Society of Chemistry (RSC)
Date: 2019
DOI: 10.1039/C9DT02198A
Abstract: Rhenium tetrazolato complexes appended to phenol substituents are exploited for cell labelling.
Publisher: Springer Science and Business Media LLC
Date: 06-10-2020
DOI: 10.1007/S11244-020-01380-2
Abstract: The “Seven Pillars” of oxidation catalysis proposed by Robert K. Grasselli represent an early ex le of phenomenological descriptors in the field of heterogeneous catalysis. Major advances in the theoretical description of catalytic reactions have been achieved in recent years and new catalysts are predicted today by using computational methods. To tackle the immense complexity of high-performance systems in reactions where selectivity is a major issue, analysis of scientific data by artificial intelligence and data science provides new opportunities for achieving improved understanding. Modern data analytics require data of highest quality and sufficient ersity. Existing data, however, frequently do not comply with these constraints. Therefore, new concepts of data generation and management are needed. Herein we present a basic approach in defining best practice procedures of measuring consistent data sets in heterogeneous catalysis using “handbooks”. Selective oxidation of short-chain alkanes over mixed metal oxide catalysts was selected as an ex le.
Publisher: American Chemical Society (ACS)
Date: 30-06-2015
DOI: 10.1021/ACS.INORGCHEM.5B01032
Abstract: The polypyridyl compound N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine (N4Py) acts as a bridging ligand and coordinates to two Pt(II) ions giving an unexpected diplatinum(II) complex, whose photophysical and anticancer properties were investigated.
Publisher: Elsevier BV
Date: 09-2017
Publisher: American Chemical Society (ACS)
Date: 10-09-2014
DOI: 10.1021/OM500664V
Publisher: American Chemical Society (ACS)
Date: 11-08-2016
DOI: 10.1021/ACS.JPCLETT.6B01185
Abstract: The nonmirror image relationship between absorption and fluorescence spectra of conjugated polymers contrasts with most organic chromophores and is widely considered a signature of interchromopohore energy funneling. We apply broad-band ultrafast fluorescence spectroscopy to resolve the evolution of fluorescence spectra for dilute solutions of conjugated oligothiophenes, where no energy transfer is possible. Fluorescence spectra evolve from a mirror image of absorption, which lacks vibronic structure, toward a spectrally narrower and vibronically structured species on the hundreds of femtosecond to early picosecond time scale. Our analysis of this fluorescence spectral evolution shows that a broad distribution of torsional conformers is driven to rapidly planarize in the excited state, including in solid films, which is supported by Raman spectroscopy and quantum chemical modeling. Our data have important implications for understanding different energy-transfer regimes that are delineated by structural relaxation.
No related grants have been discovered for Gregory Huff.