ORCID Profile
0000-0001-8740-8284
Current Organisation
University of Southampton
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Publisher: Elsevier BV
Date: 05-2016
Publisher: Springer Science and Business Media LLC
Date: 22-02-2013
Publisher: Elsevier BV
Date: 11-2013
Publisher: Elsevier BV
Date: 06-2015
Publisher: American Chemical Society (ACS)
Date: 10-08-2021
Publisher: Springer Science and Business Media LLC
Date: 10-2013
Publisher: Elsevier BV
Date: 05-2021
Publisher: Wiley
Date: 04-03-2019
DOI: 10.1002/JCTB.5947
Publisher: Elsevier BV
Date: 02-2012
Publisher: Elsevier BV
Date: 2016
Publisher: Elsevier BV
Date: 07-2015
Publisher: Royal Society of Chemistry (RSC)
Date: 2011
DOI: 10.1039/C0FD00010H
Abstract: A robust, simple methodology for analysis of isotherms for the adsorption of fluids above their critical temperature onto nanostructured materials is presented. The analysis of hydrogen adsorption in a metal-organic framework is used as an ex le to illustrate the methodology, which allows the estimation of the absolute adsorption into nanoporous systems. Further advantages of employing this analysis are that adsorption systems can be described using a small number of parameters, and that excess and absolute isotherms can be extrapolated and used to predict adsorption behaviour at higher pressures and over different temperature ranges. Thermodynamic calculations, using the exact Clapeyron equation and the Clausius-Clapeyron approximation applied to the ex le dataset, are presented and compared. Conventional compression of hydrogen and adsorptive storage are evaluated, with an illustration of the pressure ranges in which adsorption facilitates storage of greater volumes of hydrogen than normal compression in the same operating conditions.
Location: United Kingdom of Great Britain and Northern Ireland
Location: United Kingdom of Great Britain and Northern Ireland
Location: United Kingdom of Great Britain and Northern Ireland
No related grants have been discovered for Nuno Bimbo.