ORCID Profile
0000-0002-5736-0336
Current Organisation
James Cook University
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In Research Link Australia (RLA), "Research Topics" refer to ANZSRC FOR and SEO codes. These topics are either sourced from ANZSRC FOR and SEO codes listed in researchers' related grants or generated by a large language model (LLM) based on their publications.
Physical Chemistry (Incl. Structural) | Structural Chemistry and Spectroscopy | Ecological applications | Theoretical and Computational Chemistry not elsewhere classified | Horticultural crop protection (incl. pests diseases and weeds) | Biosecurity science and invasive species ecology | Sociology and social studies of science and technology | Theory and Design of Materials | Nonlinear Optics and Spectroscopy
Expanding Knowledge in the Physical Sciences | Industrial Energy Conservation and Efficiency | Residential Energy Conservation and Efficiency | Expanding Knowledge in the Chemical Sciences |
Publisher: AIP Publishing
Date: 10-10-2016
DOI: 10.1063/1.4963705
Abstract: Secondary photocurrents offer an alternative mechanism to photomultiplier tubes and avalanche diodes for making high gain photodetectors that are able to operate even at extremely low light conditions. While in the past secondary currents were studied mainly in ordered crystalline semiconductors, disordered systems offer some key advantages such as a potentially lower leakage current and typically longer photocarrier lifetimes due to trapping. In this work, we use numerical simulations to identify the critical device and material parameters required to achieve high photocurrent and gain in steady state. We find that imbalanced mobilities and suppressed, non-Langevin-type charge carrier recombination will produce the highest gain. A low light intensity, strong electric field, and a large single carrier space charge limited current are also beneficial for reaching high gains. These results would be useful for practical photodetector fabrication when aiming to maximize the gain.
Publisher: Elsevier BV
Date: 05-2020
Publisher: Elsevier BV
Date: 02-2015
Publisher: American Chemical Society (ACS)
Date: 09-11-2016
DOI: 10.1021/ACS.JPCLETT.6B02106
Abstract: The competition between charge extraction and nongeminate recombination critically determines the current-voltage characteristics of organic solar cells (OSCs) and their fill factor. As a measure of this competition, several figures of merit (FOMs) have been put forward however, the impact of space charge effects has been either neglected, or not specifically addressed. Here we revisit recently reported FOMs and discuss the role of space charge effects on the interplay between recombination and extraction. We find that space charge effects are the primary cause for the onset of recombination in so-called non-Langevin systems, which also depends on the slower carrier mobility and recombination coefficient. The conclusions are supported with numerical calculations and experimental results of 25 different donor/acceptor OSCs with different charge transport parameters, active layer thicknesses or composition ratios. The findings represent a conclusive understanding of bimolecular recombination for drift dominated photocurrents and allow one to minimize these losses for given device parameters.
Publisher: Elsevier BV
Date: 2023
DOI: 10.1016/J.SCITOTENV.2022.159099
Abstract: Plastic pollution in our oceans is of growing concern particularly due to the presence of toxic additives, such as plasticisers. Therefore, this work aims to develop a comprehensive understanding of the leaching properties of plasticisers from microplastics. This work investigates the leaching of phthalate acid ester (dioctyl terephthalate (DEHT) and diethylhexyl phthalate (DEHP)) and diphenol (bisphenol A (BPA) and bisphenol S (BPS)) plasticisers from polystyrene (PS) microplastics (mean diameter = 136 μm to 1.4 mm) under controlled aqueous conditions (temperature, agitation, pH and salinity). The leaching behaviours of plasticised polymers were quantified using gel permeation chromatography, high performance liquid chromatography and thermal gravimetric analysis, and the particle's plasticisation characterised using differential scanning calorimetry. Leaching rates of phthalate acid ester and diphenol plasticisers were modelled using a diffusion and boundary layer model, whereby these behaviours varied depending on their plasticisation efficiency of PS, the size of the microplastic particle and the surrounding abiotic conditions. Leaching behaviours of DEHT and DEHP were strongly influenced by the microplastic-surface water boundary layer properties, thus wave action (i.e., water agitation) increased the leaching rate of these plasticiser up to 66 % over 21-days, whereas BPA and BPS plasticisers displayed temperature- and size-dependent leaching and were limited by molecular diffusion throughout the bulk polymer (i.e., the microplastic). This information will improve predictions of plasticiser concentration (both that remain in the plastic and released into the surrounding water) at specific time points during the lifetime of a plastic, ultimately ensuring greater accuracy in the assessment of toxicity responses and environmental water quality.
Publisher: American Physical Society (APS)
Date: 11-04-2017
Publisher: American Chemical Society (ACS)
Date: 20-11-2015
Publisher: Informa UK Limited
Date: 24-02-2022
DOI: 10.1080/02640414.2022.2042146
Abstract: In elite sport, inertial measurement units (IMUs) are being used increasingly to measure movement in-field. IMU data commonly sought are body segment angles as this gives insights into how technique can be altered to improve performance and reduce injury risk. The purpose of this was to assess the validity of IMU use in rowing and identify if IMUs are capable of detecting differences in sagittal torso and pelvis angles that result from changes in stroke rates. Eight elite female rowers participated. Four IMUs were positioned along the torso and over the pelvis of each athlete. Reflective markers surrounded each IMU which were used to compute gold-standard data. Maxima, minima, angle range and waveforms for ten strokes at rates of 20, 24, 28 and 32 strokes per minute were analysed. Root mean square errors as a percentage of angle range fell between 1.44% and 8.43%. In most cases when significant differences (p < 0.05) in the angles were detected between stroke rates, this was observed in both IMU and gold-standard angle data. These findings suggest that IMUs are valid for measuring torso and pelvis angles when rowing and are capable of detecting differences that result from changes in stroke rate.
Publisher: Wiley
Date: 28-02-2021
Publisher: AIP Publishing
Date: 07-07-2014
DOI: 10.1063/1.4887316
Abstract: Photovoltaic performance in relation to charge transport is studied in efficient (7.6%) organic solar cells (PTB7:PC71BM). Both electron and hole mobilities are experimentally measured in efficient solar cells using the resistance dependent photovoltage technique, while the inapplicability of classical techniques, such as space charge limited current and photogenerated charge extraction by linearly increasing voltage is discussed. Limits in the short-circuit current originate from optical losses, while charge transport is shown not to be a limiting process. Efficient charge extraction without recombination can be achieved with a mobility of charge carriers much lower than previously expected. The presence of dispersive transport with strongly distributed mobilities in high efficiency solar cells is demonstrated. Reduced non-Langevin recombination is shown to be beneficial for solar cells with imbalanced, low, and dispersive electron and hole mobilities.
Publisher: Association for Computing Machinery (ACM)
Date: 31-05-2019
DOI: 10.1145/3319618
Abstract: Many Internet of Things and embedded projects are event driven, and therefore require asynchronous and concurrent programming. Current proposals for C++20 suggest that coroutines will have native language support. It is timely to survey the current use of coroutines in embedded systems development. This article investigates existing research which uses or describes coroutines on resource-constrained platforms. The existing research is analysed with regard to: software platform, hardware platform, and capacity use cases and intended benefits and the application programming interface design used for coroutines. A systematic mapping study was performed, to select studies published between 2007 and 2018 which contained original research into the application of coroutines on resource-constrained platforms. An initial set of 566 candidate papers, collated from on-line databases, were reduced to only 35 after filters were applied, revealing the following taxonomy. The C 8 C++ programming languages were used by 22 studies out of 35. As regards hardware, 16 studies used 8- or 16-bit processors while 13 used 32-bit processors. The four most common use cases were concurrency (17 papers), network communication (15), sensor readings (9), and data flow (7). The leading intended benefits were code style and simplicity (12 papers), scheduling (9), and efficiency (8). A wide variety of techniques have been used to implement coroutines, including native macros, additional tool chain steps, new language features, and non-portable assembly language. We conclude that there is widespread demand for coroutines on resource-constrained devices. Our findings suggest that there is significant demand for a formalised, stable, well-supported implementation of coroutines in C++, designed with consideration of the special needs of resource-constrained devices, and further that such an implementation would bring benefits specific to such devices.
Publisher: Springer Science and Business Media LLC
Date: 22-07-2014
DOI: 10.1038/SREP05695
Publisher: Institute of Electrical and Electronics Engineers (IEEE)
Date: 03-2021
Publisher: Springer Science and Business Media LLC
Date: 14-02-2019
DOI: 10.1038/S41598-018-38343-3
Abstract: Robotic weed control has seen increased research of late with its potential for boosting productivity in agriculture. Majority of works focus on developing robotics for croplands, ignoring the weed management problems facing rangeland stock farmers. Perhaps the greatest obstacle to widespread uptake of robotic weed control is the robust classification of weed species in their natural environment. The unparalleled successes of deep learning make it an ideal candidate for recognising various weed species in the complex rangeland environment. This work contributes the first large, public, multiclass image dataset of weed species from the Australian rangelands allowing for the development of robust classification methods to make robotic weed control viable. The DeepWeeds dataset consists of 17,509 labelled images of eight nationally significant weed species native to eight locations across northern Australia. This paper presents a baseline for classification performance on the dataset using the benchmark deep learning models, Inception-v3 and ResNet-50. These models achieved an average classification accuracy of 95.1% and 95.7%, respectively. We also demonstrate real time performance of the ResNet-50 architecture, with an average inference time of 53.4 ms per image. These strong results bode well for future field implementation of robotic weed control methods in the Australian rangelands.
Publisher: AIP Publishing
Date: 06-2022
DOI: 10.1063/5.0091142
Abstract: Solution-processing of organic light-emitting diode films has potential advantages in terms of cost and scalability over vacuum-deposition for large area applications. However, solution processed small molecule films can have lower overall device performance. Here, novel molecular dynamics techniques are developed to enable faster simulation of solvent evaporation that occurs during solution processing and give films of thicknesses relevant to real devices. All-atom molecular dynamics simulations are then used in combination with kinetic Monte Carlo transport modeling to examine how differences in morphology stemming from solution or vacuum film deposition affect charge transport and exciton dynamics in films consisting of light-emitting bis(2-phenylpyridine)(acetylacetonate)iridium(III) [Ir(ppy)2(acac)] guest molecules in a 4,4′-bis(N-carbazolyl)biphenyl host. While the structures of the films deposited from vacuum and solution were found to differ, critically, only minor variations in the transport properties were predicted by the simulations even if trapped solvent was present.
Publisher: Wiley
Date: 16-08-2023
Abstract: A series of alternating copolymers of a dithienylethene with di‐ n ‐alkyl‐fluorene (P1‐P3), di‐ n ‐hexylphenylene (P4), 9‐heptadecanylcarbazole (P5) and 4,8‐bis(3,5‐dioctyl‐2‐thienyl)‐1,5‐dithia‐ s ‐indacene (P6) were designed, synthesized and characterized. All of the polymers were soluble in common organic solvents such as chloroform, dichloromethane, toluene and tetrahydrofuran. The side‐chain length affected the solubility of the polymer, molecular weight and the glass transition temperature. Solutions of P1‐P6 showed photochromism with high quantum yields of 6‐π electrocyclization (41‐87%) and cycloreversion (0.4‐1.1%). These polymers also formed uniform thin films and the rates of solid state photoisomerization were measured relative to P4, which had the highest cyclization and cycloreversion rates. The color of the photochromic polymer was tuned according to the comonomer and the maximum absorption wavelength ranged from 569 to 675 nm in the closed isomeric form. All the polymers were thermally stable and showed no signs of photo‐degradation after being exposed to UV‐light for 120 min in air. Based on these promising results, these polymers may be useful for multi‐functional organic electronic devices. This article is protected by copyright. All rights reserved
Publisher: Springer Science and Business Media LLC
Date: 31-08-2016
Publisher: IOP Publishing
Date: 28-07-2014
Publisher: American Physical Society (APS)
Date: 28-10-2011
Publisher: Springer Science and Business Media LLC
Date: 27-08-2020
DOI: 10.1038/S41467-020-18094-4
Abstract: Electrical pumping of organic semiconductor devices involves charge injection, transport, device on/off dynamics, exciton formation and annihilation processes. A comprehensive model analysing those entwined processes together is most helpful in determining the dominating loss pathways. In this paper, we report experimental and theoretical results of Super Yellow (Poly( p -phenylene vinylene) co-polymer) organic light emitting diodes operating at high current density under high voltage nanosecond pulses. We demonstrate complete exciton and charge carrier dynamics of devices, starting from charge injection to light emission, in a time scale spanning from the sub-ns to microsecond region, and compare results with optical pumping. The experimental data is accurately replicated by simulation, which provides a robust test platform for any organic materials. The universality of our model is successfully demonstrated by its application to three other laser active materials. The findings provide a tool to narrow the search for material and device designs for injection lasing.
Publisher: AIP Publishing
Date: 17-07-2023
DOI: 10.1063/5.0152922
Abstract: Phosphorescent organic light emitting diodes (OLEDs) suffer from efficiency roll off, where device efficiency rapidly decays at higher luminance. One strategy to minimize this loss of efficiency at higher luminance is the use of non-uniform or graded guest:host blend ratios within the emissive layer. This work applies a multi-scale modeling framework to elucidate the mechanisms by which a non-uniform blend ratio can change the performance of an OLED. Mobility and exciton data are extracted from a kinetic Monte–Carlo model, which is then coupled to a drift diffusion model for fast s ling of the parameter space. The model is applied to OLEDs with uniform, linear, and stepwise graduations in the blend ratio in the emissive layer. The distribution of the guests in the film was found to affect the mobility of the charge carriers, and it was determined that having a graduated guest profile broadened the recombination zone, leading to a reduction in second order annihilation rates. That is, there was a reduction in triplet–triplet and triplet-polaron annihilation. Reducing triplet–triplet and triplet-polaron annihilation would lead to an improvement in device efficiency.
Publisher: AIP Publishing
Date: 23-12-2019
DOI: 10.1063/1.5131680
Abstract: The correct choice of guest and host molecules in the light-emitting layer is essential for developing high performance phosphorescent organic light emitting devices. However, the effects of the energy level alignment between the guest and the host are yet to be fully elucidated. In this Letter, we use kinetic Monte Carlo simulations to investigate guest-host systems in which the energy gap of the guest and host is fixed, and only the relative energies of the ionization potential/electron affinity are changed to elucidate their effect on charge transport. It was determined that the mobility balance in the blend was sensitive to the energy level alignment, allowing balanced active layer mobility to be achieved despite the hole and electron mobilities being different by around one order of magnitude. It was also found that the mobility of the faster carrier was more sensitive to the energy level alignment than that of the slower carrier due to reduced slower carrier thermalization under deep charge trapping on the guest.
Publisher: Wiley
Date: 10-2012
Publisher: Elsevier BV
Date: 2015
Publisher: AIP Publishing
Date: 06-03-2019
DOI: 10.1063/1.5083639
Abstract: Ir(ppy)3:CBP blends have been widely studied as the emissive layer in organic light emitting diodes (OLEDs), yet crucial questions about charge transport within the layer remain unaddressed. Recent molecular dynamics simulations show that the Ir(ppy)3 molecules are not isolated from each other, but at concentrations of as low as 5 wt. % can be part of connected pathways. Such connectivity raises the question of how the iridium(iii) complexes contribute to long-range charge transport in the blend. We implement a kinetic Monte Carlo transport model to probe the guest concentration dependence of charge mobility and show that distinct minima appear at approximately 10 wt. % Ir(ppy)3 due to an increased number of trap states that can include interconnected complexes within the blend film. The depth of the minima is shown to be dependent on the electric field and to vary between electrons and holes due to their different trapping depths arising from the different ionization potentials and electron affinities of the guest and host molecules. Typical guest-host OLEDs use a guest concentration below 10 wt. % to avoid triplet-triplet annihilation, so these results suggest that optimal device performance is achieved when there is significant charge trapping on the iridium(iii) complex guest molecules and minimum interactions of the emissive chromophores that can lead to triplet-triplet annihilation.
Publisher: AIP Publishing
Date: 04-08-2014
DOI: 10.1063/1.4891369
Abstract: Charge carrier recombination is studied in operational organic solar cells made from the polymer:fullerene system PCDTBT:PC71BM (poly[N-9′′-heptadecanyl-2,7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole)]: [6,6]-phenyl-C70-butyric acid methyl ester). A newly developed technique High Intensity Resistance dependent PhotoVoltage is presented for reliably quantifying the bimolecular recombination coefficient independently of variations in experimental conditions, thereby resolving key limitations of previous experimental approaches. Experiments are performed on solar cells of varying thicknesses and varying polymeric molecular weights. It is shown that solar cells made from low molecular weight PCDTBT exhibit Langevin recombination, whereas suppressed (non-Langevin) recombination is found in solar cells made with high molecular weight PCDTBT.
Publisher: AIP Publishing
Date: 22-04-2021
DOI: 10.1063/5.0044177
Abstract: Emissive layers in phosphorescent organic light-emitting diodes commonly make use of guest–host blends such as Ir(ppy)3:CBP to achieve high external quantum efficiencies. However, while the Ir(ppy)3:CBP blend has been studied experimentally, crucial questions remain regarding how exciton diffusion is dependent on the distribution of the guest in the host, which can currently only be addressed at the atomic level via computational modeling. In this work, kinetic Monte Carlo simulations are utilized to gain insight into exciton diffusion in Ir(ppy)3:CBP blend films. The effects of both guest concentration and exciton density on various system properties are analyzed, including the probability of singlet excitons being converted to triplets, and the probability of those triplets decaying radiatively. Significantly, these simulations suggest that triplet diffusion occurs almost exclusively via guest–guest Dexter transfer and that concentration quenching of triplets induced by guest–guest intermolecular dipole-dipole interactions has a negligible effect at high exciton densities due to the prevalence of triplet–triplet annihilation. Furthermore, results for vacuum deposited morphologies derived from molecular dynamics simulations are compared to the results obtained using a simple cubic lattice approximation with randomly distributed guest molecules. We show that while differences in host-based processes such as singlet diffusion are observed, overall, the results on the fate of the excitons are in good agreement for the two morphology types, particularly for guest-based processes at low guest concentrations where guest clustering is limited.
Publisher: Institute of Electrical and Electronics Engineers (IEEE)
Date: 2023
Publisher: Springer Science and Business Media LLC
Date: 02-02-2018
DOI: 10.1038/S41598-018-19711-5
Abstract: We derive third-order transport coefficients of skewness for a phase-space kinetic model that considers the processes of scattering collisions, trapping, detrapping and recombination losses. The resulting expression for the skewness tensor provides an extension to Fick’s law which is in turn applied to yield a corresponding generalised advection-diffusion-skewness equation. A physical interpretation of trap-induced skewness is presented and used to describe an observed negative skewness due to traps. A relationship between skewness, diffusion, mobility and temperature is formed by analogy with Einstein’s relation. Fractional transport is explored and its effects on the flux transport coefficients are also outlined.
Publisher: Springer Science and Business Media LLC
Date: 28-04-2016
Publisher: American Physical Society (APS)
Date: 11-03-2016
Publisher: Informa UK Limited
Date: 19-09-2019
DOI: 10.1080/17461391.2019.1666167
Abstract: Inertial measurement units (IMUs) enable human movements to be captured in the field and are being used increasingly in high performance sport. One key metric that can be derived from IMUs are relative angles of body segments which are important for monitoring form in many sports. The purpose of this study was to (a) examine the validity of relative angles derived from IMUs placed on the torso and pelvis and (b) determine optimal positioning for torso mounted sensors such that the IMU relative angles match closely with gold standard torso-pelvis and thorax-pelvis relative angle data derived from an optoelectronic camera system. Seventeen adult participants undertook a variety of motion tasks. Four IMUs were positioned on the torso and one was positioned on the pelvis between the posterior superior iliac spines. Reflective markers were positioned around each IMU and over torso and pelvis landmarks. Results showed that the IMUs are valid with the root mean square errors expressed as a percentage of the angle range (RMSE%) ranging between 1% and 7%. Comparison between the IMU relative angles and the torso-pelvis and thorax-pelvis relative angles showed there were moderate to large differences with RMSE% values ranging between 4% and 57%. IMUs are highly accurate at measuring orientation data however, further work is needed to optimise positioning and modelling approaches so IMU relative angles align more closely with relative angles derived using traditional motion capture methods.
Publisher: AIP Publishing
Date: 13-11-2013
DOI: 10.1063/1.4829456
Abstract: The relationship between charge carrier lifetime and mobility in a bulk heterojunction based organic solar cell, utilizing diketopyrrolopyrole-naphthalene co-polymer and PC71BM in the photoactive blend layer, is investigated using the photoinduced charge extraction by linearly increasing voltage technique. Light intensity, delay time, and temperature dependent experiments are used to quantify the charge carrier mobility and density as well as the temperature dependence of both. From the saturation of photoinduced current at high laser intensities, it is shown that Langevin-type bimolecular recombination is present in the studied system. The charge carrier lifetime, especially in Langevin systems, is discussed to be an ambiguous and unreliable parameter to determine the performance of organic solar cells, because of the dependence of charge carrier lifetime on charge carrier density, mobility, and type of recombination. It is revealed that the relation between charge mobility (μ) and lifetime (τ) is inversely proportional, where the μτ product is independent of temperature. The results indicate that in photovoltaic systems with Langevin type bimolecular recombination, the strategies to increase the charge lifetime might not be beneficial because of an accompanying reduction in charge carrier mobility. Instead, the focus on non-Langevin mechanisms of recombination is crucial, because this allows an increase in the charge extraction rate by improving the carrier lifetime, density, and mobility simultaneously.
Publisher: Springer Science and Business Media LLC
Date: 28-04-2015
DOI: 10.1038/SREP09949
Abstract: Light harvesting systems based upon disordered materials are not only widespread innature, but are also increasingly prevalent in solar cells and photodetectors.Ex les include organic semiconductors, which typically possess low charge carriermobilities and Langevin-type recombination dynamics – both of whichnegatively impact the device performance. It is accepted wisdom that the“drift distance” (i.e., the distance a photocarrier driftsbefore recombination) is defined by the mobility-lifetime product in solar cells. Wedemonstrate that this traditional figure of merit is inadequate for describing thecharge transport physics of organic light harvesting systems. It is experimentallyshown that the onset of the photocarrier recombination is determined by theelectrode charge and we propose the mobility-recombination coefficient product as analternative figure of merit. The implications of these findings are relevant to awide range of light harvesting systems and will necessitate a rethink of thecritical parameters of charge transport.
Publisher: IOP Publishing
Date: 15-05-2018
Start Date: 2023
End Date: 12-2027
Amount: $5,000,000.00
Funder: Australian Research Council
View Funded ActivityStart Date: 04-2021
End Date: 04-2025
Amount: $460,000.00
Funder: Australian Research Council
View Funded ActivityStart Date: 07-2021
End Date: 06-2024
Amount: $538,590.00
Funder: Australian Research Council
View Funded Activity