ORCID Profile
0000-0002-5587-1271
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Publisher: American Geophysical Union (AGU)
Date: 07-2020
DOI: 10.1029/2020GL087888
Publisher: Wiley
Date: 13-03-2020
Publisher: American Geophysical Union (AGU)
Date: 10-2020
DOI: 10.1029/2019GB006456
Abstract: Field observations suggest that oceanic emissions of dimethylsulfide (DMS) may play a dominant role in the production of Arctic aerosols and clouds and therefore modulate the surface irradiance, during spring and summer. DMS is produced not only in the water column but also in various sea ice habitats. The ongoing recession of Arctic sea ice is expected to enhance DMS emissions, but the magnitude of this increase is highly uncertain. Here we investigate the spatiotemporal variability in bottom ice and sea surface DMS concentrations and fluxes using a regional sea ice‐ocean physical‐biogeochemical model. Model results indicate that the observed accelerated decline of Arctic sea ice extent since the beginning of the 21st century is associated with upward trends in May–August pan‐Arctic‐averaged sea surface DMS concentration and sea‐to‐air DMS flux. On the other hand, strong interannual variability and statistically insignificant trends are found for bottom ice DMS concentration and ice‐to‐sea DMS flux, owing to the counteracting effects of the shrinking horizontal extent and the vertical thinning of sea ice on ice algal production. The pan‐Arctic DMS climatology products based on model simulation and satellite algorithms provide dynamically based spatial details that are absent in the in situ measurement‐based climatology due to limited spatiotemporal data coverage and inevitable extrapolation bias. Lastly, model results indicate that the bottom ice DMS and its precursor dimethylsulfoniopropionate production can be the only local source of oceanic DMS emissions into the atmosphere during May prior to pelagic blooms, suggesting that it may be a key component of the biological control on Arctic climate at that time.
Publisher: Copernicus GmbH
Date: 28-02-2019
Abstract: Abstract. Motivated by the need to predict how the Arctic atmosphere will change in a warming world, this article summarizes recent advances made by the research consortium NETCARE (Network on Climate and Aerosols: Addressing Key Uncertainties in Remote Canadian Environments) that contribute to our fundamental understanding of Arctic aerosol particles as they relate to climate forcing. The overall goal of NETCARE research has been to use an interdisciplinary approach encompassing extensive field observations and a range of chemical transport, earth system, and biogeochemical models. Several major findings and advances have emerged from NETCARE since its formation in 2013. (1) Unexpectedly high summertime dimethyl sulfide (DMS) levels were identified in ocean water (up to 75 nM) and the overlying atmosphere (up to 1 ppbv) in the Canadian Arctic Archipelago (CAA). Furthermore, melt ponds, which are widely prevalent, were identified as an important DMS source (with DMS concentrations of up to 6 nM and a potential contribution to atmospheric DMS of 20 % in the study area). (2) Evidence of widespread particle nucleation and growth in the marine boundary layer was found in the CAA in the summertime, with these events observed on 41 % of days in a 2016 cruise. As well, at Alert, Nunavut, particles that are newly formed and grown under conditions of minimal anthropogenic influence during the months of July and August are estimated to contribute 20 % to 80 % of the 30–50 nm particle number density. DMS-oxidation-driven nucleation is facilitated by the presence of atmospheric ammonia arising from seabird-colony emissions, and potentially also from coastal regions, tundra, and biomass burning. Via accumulation of secondary organic aerosol (SOA), a significant fraction of the new particles grow to sizes that are active in cloud droplet formation. Although the gaseous precursors to Arctic marine SOA remain poorly defined, the measured levels of common continental SOA precursors (isoprene and monoterpenes) were low, whereas elevated mixing ratios of oxygenated volatile organic compounds (OVOCs) were inferred to arise via processes involving the sea surface microlayer. (3) The variability in the vertical distribution of black carbon (BC) under both springtime Arctic haze and more pristine summertime aerosol conditions was observed. Measured particle size distributions and mixing states were used to constrain, for the first time, calculations of aerosol–climate interactions under Arctic conditions. Aircraft- and ground-based measurements were used to better establish the BC source regions that supply the Arctic via long-range transport mechanisms, with evidence for a dominant springtime contribution from eastern and southern Asia to the middle troposphere, and a major contribution from northern Asia to the surface. (4) Measurements of ice nucleating particles (INPs) in the Arctic indicate that a major source of these particles is mineral dust, likely derived from local sources in the summer and long-range transport in the spring. In addition, INPs are abundant in the sea surface microlayer in the Arctic, and possibly play a role in ice nucleation in the atmosphere when mineral dust concentrations are low. (5) Amongst multiple aerosol components, BC was observed to have the smallest effective deposition velocities to high Arctic snow (0.03 cm s−1).
Publisher: Copernicus GmbH
Date: 27-01-2020
Abstract: Abstract. The Green Edge initiative was developed to investigate the processes controlling the primary productivity and fate of organic matter produced during the Arctic phytoplankton spring bloom (PSB) and to determine its role in the ecosystem. Two field c aigns were conducted in 2015 and 2016 at an ice c located on landfast sea ice southeast of Qikiqtarjuaq Island in Baffin Bay (67.4797∘ N, 63.7895∘ W). During both expeditions, a large suite of physical, chemical and biological variables was measured beneath a consolidated sea-ice cover from the surface to the bottom (at 360 m depth) to better understand the factors driving the PSB. Key variables, such as conservative temperature, absolute salinity, radiance, irradiance, nutrient concentrations, chlorophyll a concentration, bacteria, phytoplankton and zooplankton abundance and taxonomy, and carbon stocks and fluxes were routinely measured at the ice c . Meteorological and snow-relevant variables were also monitored. Here, we present the results of a joint effort to tidy and standardize the collected datasets, which will facilitate their reuse in other Arctic studies. The dataset is available at 0.17882/59892 (Massicotte et al., 2019a).
Publisher: Copernicus GmbH
Date: 12-10-2018
DOI: 10.5194/ACP-2018-995
Abstract: Abstract. Motivated by the need to predict how the Arctic atmosphere will change in a warming world, this article summarizes recent advances made by the research consortium NETCARE (Network on Climate and Aerosols: Addressing Key Uncertainties in Remote Canadian Environments) that contribute to our fundamental understanding of Arctic aerosol particles as they relate to climate forcing. The overall goal of NETCARE research has been to use an interdisciplinary approach encompassing extensive field observations and a range of chemical transport, earth system, and biogeochemical models. Several major findings and advances have emerged from NETCARE since its formation in 2013 . (1) Unexpectedly high summertime dimethyl sulfide (DMS) levels were identified in ocean water and the overlying atmosphere in the Canadian Arctic Archipelago (CAA). Furthermore, melt ponds, which are widely prevalent, were identified as an important DMS source. (2) Evidence was found of widespread particle nucleation and growth in the marine boundary layer in the CAA in the summertime. DMS-oxidation-driven nucleation is facilitated by the presence of atmospheric ammonia arising from sea bird colony emissions, and potentially also from coastal regions, tundra, and biomass burning. Via accumulation of secondary organic material (SOA), a significant fraction of the new particles grow to sizes that are active in cloud droplet formation. Although the gaseous precursors to Arctic marine SOA remain poorly defined, the measured levels of common continental SOA precursors (isoprene and monoterpenes) were low, whereas elevated mixing ratios of oxygenated volatile organic compounds were inferred to arise via processes involving the sea surface microlayer. (3) The variability in the vertical distribution of black carbon (BC) under both springtime Arctic haze and more pristine summertime aerosol conditions was observed. Measured particle size distributions and mixing states were used to constrain, for the first time, calculations of aerosol–climate interactions under Arctic conditions. Aircraft- and ground-based measurements were used to better establish the BC source regions that supply the Arctic via long-range transport mechanisms. (4) Measurements of ice nucleating particles (INPs) in the Arctic indicate that a major source of these particles is mineral dust, likely derived from local sources in the summer and long-range transport in the spring. In addition, INPs are abundant in the sea surface microlayer in the Arctic, and possibly play a role in ice nucleation in the atmosphere when mineral dust concentrations are low. (5) Amongst multiple aerosol components, BC was observed to have the smallest effective deposition velocities to high Arctic snow.
Publisher: Copernicus GmbH
Date: 12-10-2018
Publisher: University of California Press
Date: 2019
DOI: 10.1525/ELEMENTA.357
Abstract: During summer, phytoplankton can bloom in the Arctic Ocean, both in open water and under ice, often strongly linked to the retreating ice edge. There, the surface ocean responds to steep lateral gradients in ice melt, mixing, and light input, shaping the Arctic ecosystem in unique ways not found in other regions of the world ocean. In 2016, we s led a high-resolution grid of 135 hydrographic stations in Baffin Bay as part of the Green Edge project to study the ice-edge bloom, including turbulent vertical mixing, the under-ice light field, concentrations of inorganic nutrients, and phytoplankton biomass. We found pronounced differences between an Atlantic sector dominated by the warm West Greenland Current and an Arctic sector with surface waters originating from the Canadian archipelago. Winter overturning and thus nutrient replenishment was h ered by strong haline stratification in the Arctic domain, whereas close to the West Greenland shelf, weak stratification permitted winter mixing with high-nitrate Atlantic-derived waters. Using a space-for-time approach, we linked upper ocean dynamics to the phytoplankton bloom trailing the retreating ice edge. In a band of 60 km (or 15 days) around the ice edge, the upper ocean was especially affected by a freshened surface layer. Light climate, as evidenced by deep 0.415 mol m–2 d–1 isolumes, and vertical mixing, as quantified by shallow mixing layer depths, should have permitted significant net phytoplankton growth more than 100 km into the pack ice at ice concentrations close to 100%. Yet, under-ice biomass was relatively low at 20 mg chlorophyll-a m–2 and depth-integrated total chlorophyll-a (0–80 m) peaked at an average value of 75 mg chlorophyll-a m–2 only around 10 days after ice retreat. This phenological peak may hence have been the delayed result of much earlier bloom initiation and demonstrates the importance of temporal dynamics for constraints of Arctic marine primary production.
Publisher: Wiley
Date: 04-2019
DOI: 10.1111/MEC.15026
Abstract: Microbial taxa range from being ubiquitous and abundant across space to extremely rare and endemic, depending on their ecophysiology and on different processes acting locally or regionally. However, little is known about how cosmopolitan or rare taxa combine to constitute communities and whether environmental variations promote changes in their relative abundances. Here we identified the Spatial Abundance Distribution (SpAD) of in idual prokaryotic taxa (16S rDNA-defined Operational Taxonomic Units, OTUs) across 108 globally-distributed surface ocean stations. We grouped taxa based on their SpAD shape ("normal-like"- abundant and ubiquitous "logistic"- globally rare, present in few sites and "bimodal"- abundant only in certain oceanic regions), and investigated how the abundance of these three categories relates to environmental gradients. Most surface assemblages were numerically dominated by a few cosmopolitan "normal-like" OTUs, yet there was a gradual shift towards assemblages dominated by "logistic" taxa in specific areas with productivity and temperature differing the most from the average conditions in the s led stations. When we performed the SpAD categorization including additional habitats (deeper layers and particles of varying sizes), the SpAD of many OTUs changed towards fewer "normal-like" shapes, and OTUs categorized as globally rare in the surface ocean became abundant. This suggests that understanding the mechanisms behind microbial rarity and dominance requires expanding the context of study beyond local communities and single habitats. We show that marine bacterial communities comprise taxa displaying a continuum of SpADs, and that variations in their abundances can be linked to habitat transitions or barriers that delimit the distribution of community members.
Publisher: American Chemical Society (ACS)
Date: 02-12-2016
Abstract: Photolysis is a major removal pathway for the biogenic gas dimethylsulfide (DMS) in the surface ocean. Here we tested the hypothesis that apparent quantum yields (AQY) for DMS photolysis varied according to the quantity and quality of its photosensitizers, chiefly chromophoric dissolved organic matter (CDOM) and nitrate. AQY compiled from the literature and unpublished studies ranged across 3 orders of magnitude at the 330 nm reference wavelength. The smallest AQY(330) were observed in coastal waters receiving major riverine inputs of terrestrial CDOM (0.06-0.5 m
No related grants have been discovered for Martí Galí.