ORCID Profile
0000-0003-0836-7715
Current Organisation
Institut Teknologi Sepuluh Nopember
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Publisher: Universitas Gadjah Mada
Date: 31-12-2019
DOI: 10.22146/IJC.38978
Abstract: The hydrogen adsorption, kinetic and thermodynamic of adsorption onto the zeolite templated carbon (ZTC) were examined at the temperature range of 30-50 °C and ambient pressure. The ZTC was prepared from zeolite-Y template and sucrose carbon precursor by impregnation method and showed its specific surface area of 932 m2/g as well as 0.97 cm3/g for total pore volume. Analysis of physical and chemical characteristics for materials were performed using XRD, SEM, TEM and N2 isotherm. The results indicated that the ZTC has some ordered network structure of carbon and also exhibits the formation of carbon layer outside the zeolite micropore. We observed the ZTC for hydrogen adsorption both gravimetric and volumetric method up to 1.72 and 1.16 wt.% at the lowest temperature, respectively. The kinetic process at all studied temperature was best approximated by pseudo second order kinetic model. The aspects of thermodynamic such as heat of adsorption and the entropy change were -14.41 kJ/mol and -40.93 J/K mol, respectively. Both values was negative, indicating an exothermic reaction and low disorder at the hydrogen and ZTC interface, when the adsorption process took place. While, the enthalpy change value exhibits characteristic of physical process. The Gibbs energy change calculated at 30, 40 and 50 °C were -1.99, -1.59 and -1.19 kJ/mol, respectively, indicating a spontaneous adsorption process.
Publisher: American Chemical Society (ACS)
Date: 07-06-2021
Publisher: Elsevier BV
Date: 03-2023
Publisher: The Royal Society
Date: 06-2022
DOI: 10.1098/RSOS.211371
Abstract: Recently, natural gas (mostly methane) is frequently used as fuel, while hydrogen is a promising renewable energy source. However, each gas produced contains impurity gases. As a result, membrane separation is required. The mixed matrix membrane (MMM) is a promising membrane. The huge surface area and well-defined pore structure of zeolite templated carbon (ZTC)-based MMM allow for effective separation. However, the interfacial vacuum in MMM is difficult to avoid, contributing to poor separation performance. This research tries to improve separation performance by altering membrane surfaces. MMM PSF/ZTC was modified by annealing at 120, 150, and 190°C coating using 0.01, 0.03, and 0.05 mol tetramethyl orthosilicate (TMOS) and a combination of both, i.e. annealing at 190°C and coating using 0.03 mol TMOS. MMM PSF/ZTC successfully significantly improved CO 2 /CH 4 selectivity by a combination of annealing at 190°C and coating 0.03 mol TMOS from 1.37 to 5.90 (331%), and H 2 /CH 4 selectivity by coating with 0.03 mol TMOS from 4.58 to 65.76 (1378%). The enhancement of selectivity was due to structural changes to the membrane that became denser and smoother, which SEM and AFM observed. In this study, annealing and coating treatments are the methods investigated for improving the polymer matrix and filler particle adhesion.
Publisher: IOP Publishing
Date: 06-2019
DOI: 10.1088/1757-899X/546/4/042042
Abstract: In this study, a simple coating technique to enhance the selectivity performance of P84 co-polyimide hollow fiber polymer membrane was investigated. The hollow fiber membrane was coated with polydimethylsiloxane (PDMS) to prevent gas flow through the defect surface. The prepared membranes were characterized using X-Ray Diffraction (XRD), Fourier Transform Infrared (FTIR), Scanning Electron Microscopy (SEM) and pure gas permeation measurement. The pure gas of O 2 and N 2 were used to determine the permeation properties of the hollow fiber membrane. The single gas measurement showed that the perm-selectivity of O 2 /N 2 of the hollow fiber membrane increased up to 181% after the coating treatment. It is concluded that the simple coating technique has significant effect in enhancing the selectivity performance of the hollow fiber membrane.
Publisher: Royal Society of Chemistry (RSC)
Date: 2018
DOI: 10.1039/C8RA09200A
Abstract: A micro-mesoporous structure of ZTC was synthesized via an impregnation method, and the structure assisted in a faster CO 2 adsorption–desorption equilibrium.
Publisher: MDPI AG
Date: 28-09-2020
DOI: 10.3390/MEMBRANES10100267
Abstract: This research introduces zeolite carbon composite (ZCC) as a new filler on polymeric membranes based on the BTDA-TDI/MDI (P84) co-polyimide for the air separation process. The separation performance was further improved by a polydimethylsiloxane (PDMS) coating to cover up the surface defect. The incorporation of 1 wt% ZCC into P84 co-polyimide matrix enhanced the O2 permeability from 7.12 to 18.90 Barrer (2.65 times) and the O2/N2 selectivity from 4.11 to 4.92 Barrer (19.71% improvement). The PDMS coating on the membrane further improved the O2/N2 selectivity by up to 60%. The results showed that the incorporation of ZCC and PDMS coating onto the P84 co-polyimide membrane was able to increase the overall air separation performance.
Publisher: Elsevier BV
Date: 10-2019
Publisher: Universitas Gadjah Mada
Date: 29-05-2019
DOI: 10.22146/IJC.35727
Abstract: Mixed Matrix Membranes (MMMs) which consist of 0.3 wt.% Zeolite-Carbon Composite (ZCC) dispersed in BTDA-TDI/MDI (P84 co-polyimide) have been prepared through phase inversion method by using N-methyl-2-pyrrolidone (NMP) as a solvent. Membranes were characterized by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), Thermogravimetric Analysis (TGA), and Fourier Transform Infrared (FTIR). Membrane performance was measured by a single gas permeation of CO2 and CH4. The maximum permeability of CO2 and CH4, which up to 12.67 and 6.03 Barrer, respectively. P84/ZCC mixed matrix membrane also showed a great enhancement in ideal selectivity of CO2/CH4 2.10 compared to the pure P84 co-polyimide membrane.
Location: Indonesia
No related grants have been discovered for Triyanda Gunawan.