ORCID Profile
0000-0002-4007-3189
Current Organisation
Yale University
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Publisher: MDPI AG
Date: 25-01-2018
Publisher: MDPI AG
Date: 21-06-2022
DOI: 10.3390/SU14137535
Abstract: One of the most unfortunate attributes of technology’s routine and widespread use of most of the elements in the periodic table is the abysmal functional recycling rates that result from the complexity of modern technology and the rudimentary technological state of the recycling industry. In this work, we demonstrate that the vast profusion of alloys, and the complexities and miniaturization of modern electronics, render functional recycling almost impossible. This situation is particularly true of “spice metals”: metals employed at very low concentrations to realize modest performance improvements in advanced alloys or complex electronics such as smartphones or laptops. Here, we present a formal definition of spice metals and explore the significant challenges that product design decisions impose on the recycling industry. We thereby identify nine spice metals: scandium (Sc), vanadium (V), gallium (Ga), arsenic (As), niobium (Nb), antimony (Sb), tellurium (Te), erbium (Er), and hafnium (Hf). These metals are considered fundamental for the properties they provide, yet they are rarely recycled. Their routine use poses severe problems for the implementation of closed material loops and the circular economy. Based on the data and discussions in this paper, we recommend that spice metals be employed only where their use will result in a highly significant improvement, and that product designers place a strong emphasis on enabling the functional recycling of these metals after their first use.
Publisher: Elsevier BV
Date: 07-2020
Publisher: Elsevier BV
Date: 11-2020
Publisher: Springer Science and Business Media LLC
Date: 10-01-2022
DOI: 10.1038/S41467-021-27829-W
Abstract: Materials scientists employ metals and alloys that involve most of the periodic table. Nonetheless, materials scientists rarely take material criticality and reuse potential into account. In this work, we expand upon lists of “critical materials” generated by national and regional governments by showing that many materials are employed predominantly as alloying elements, which can be a deterrent to recovery and reuse at end of product life and, likely as a consequence, have low functional end-of-life recycling rates, among other problematic characteristics. We thereby single out six metals for enhanced concern: dysprosium, samarium, vanadium, niobium, tellurium, and gallium. From that perspective, the use of critical metals in low concentrations in alloys unlikely to be routinely recycled should be avoided if possible. If not, provision should be made for better identification and more efficient recycling so that materials designated as critical can have increased potential for more than a single functional use.
Publisher: American Chemical Society (ACS)
Date: 07-06-2023
Publisher: American Chemical Society (ACS)
Date: 22-11-2021
Abstract: During the 20th century, the United States went from being the largest producer and user of lithium to being heavily reliant on imports from Asia, particularly lithium-ion batteries. To explore different futures for U.S. lithium, we here generate four scenarios─including COVID-19 implications─that model lithium use for its main applications: electric and hybrid vehicles, stationary energy storage systems, and small electronics. We find that the "Sustainable Future" scenario requires the highest amount of lithium (cumulatively 1281 Gg in the period 2020-2050, peak inflow in 2040 at 53 Gg) in contrast, "Fossil Fuel Everything" requires only 500 Gg and peaks in 2050 at 26 Gg. COVID-19 implications appear to be negligible in the long run. The future electrification of the U.S. vehicle fleet and energy storage systems will depend upon a reliable and resilient international supply chain of lithium chemicals and/or batteries as well as vigorous recycling efforts.
Publisher: Wiley
Date: 15-10-2022
DOI: 10.1111/JIEC.13208
Publisher: Elsevier BV
Date: 11-2013
No related grants have been discovered for Thomas E Graedel.