ORCID Profile
0000-0003-1389-7446
Current Organisation
University of Helsinki
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Publisher: Elsevier BV
Date: 2022
DOI: 10.1016/J.CIS.2021.102541
Abstract: Emulsions have gained significant importance in many industries including foods, pharmaceuticals, cosmetics, health care formulations, paints, polymer blends and oils. During emulsion generation, collisions can occur between newly-generated droplets, which may lead to coalescence between the droplets. The extent of coalescence is driven by the properties of the dispersed and continuous phases (e.g. density, viscosity, ion strength and pH), and system conditions (e.g. temperature, pressure or any external applied forces). In addition, the diffusion and adsorption behaviors of emulsifiers which govern the dynamic interfacial tension of the forming droplets, the surface potential, and the duration and frequency of the droplet collisions, contribute to the overall rate of coalescence. An understanding of these complex behaviors, particularly those of interfacial tension and droplet coalescence during emulsion generation, is critical for the design of an emulsion with desirable properties, and for the optimization of the processing conditions. However, in many cases, the time scales over which these phenomena occur are extremely short, typically a fraction of a second, which makes their accurate determination by conventional analytical methods extremely challenging. In the past few years, with advances in microfluidic technology, many attempts have demonstrated that microfluidic systems, characterized by micrometer-size channels, can be successfully employed to precisely characterize these properties of emulsions. In this review, current applications of microfluidic devices to determine the equilibrium and dynamic interfacial tension during droplet formation, and to investigate the coalescence stability of dispersed droplets applicable to the processing and storage of emulsions, are discussed.
Publisher: Elsevier BV
Date: 07-2016
DOI: 10.1016/J.FOODCHEM.2016.02.076
Abstract: This study investigated the effects of water-induced crystallization of amorphous alpha-cyclodextrin (α-CD) powder on CO2 encapsulation at 0.4-1.6 MPa pressure for 1-72 h through the addition of water (to reach to 13, 15 and 17% wet basis, w.b.) into amorphous α-CD powder prior to the encapsulation. The results showed that the α-CD encapsulation capacity was over 1 mol CO2/mol α-CD after pressurizing for longer than 48 h. The encapsulated CO2 concentration by the addition of water was considerably higher (p<0.05) than that of amorphous α-CD powder (5.51% MC, w.b.) without an addition of water and that of crystalline α-CD powders under the same MC and encapsulation conditions. A comparison of CO2 release properties (75% relative humidity, 25 °C) from complexed powders prepared from amorphous and crystalline α-CD powders under the same conditions is also presented.
Publisher: Springer Science and Business Media LLC
Date: 24-11-2022
DOI: 10.1007/S10570-022-04958-Z
Abstract: Lignocellulosic materials from the forest industry have shown potential to be used as sustainable hydrocolloids to stabilize emulsions for many applications in life science and chemical industries. However, the effect of wood species and recovery method on the product’s properties and ability to stabilize emulsions of isolated lignocellulosic compounds is not well understood. Hemicelluloses, abundant lignocellulosic side stream, exhibit differences in their water solubility, anionic character, lignin content, and degree of acetylation. Here, we explored stability and rheological properties of model emulsions (5% hexadecane and 1% stabilizer, w/w) stabilized by different grades of sprucewood galactoglucomannan (GGM) and birchwood glucuronoxylan (GX) hemicelluloses. The results were compared to known soluble, insoluble, charged, and non-charged cellulosic stabilizers, namely methyl cellulose (MC), carboxymethyl cellulose (CMC), anionic- and nonionic-cellulose nanocrystals (aCNC and dCNC). The results showed that GX emulsions were highly stable compared to GGM emulsions, and that deacetylation and lignin removal markedly reduced emulsion stability of GGM. Carboxymethylation to increase anionic characters enhanced the emulsion stabilization capacity of GGM, but not that of GX. Investigating flow behaviors of emulsions indicated that hemicelluloses primarily stabilize emulsions by adsorption of insoluble particles, as their flow behaviors were similar to those of cellulose nanocrystals rather than those of soluble celluloses. Understanding the impact of the variations in composition and properties of hemicellulose stabilizers to stabilize emulsions allows tailoring of their recovery processes to obtain desirable hydrocolloids for different applications.
Publisher: Elsevier BV
Date: 10-2020
Publisher: Elsevier BV
Date: 02-2023
Publisher: Springer International Publishing
Date: 2020
Publisher: CRC Press
Date: 25-11-2020
Publisher: Elsevier BV
Date: 02-2019
DOI: 10.1016/J.FOODRES.2018.08.051
Abstract: Changes in foaming properties and foam structure of raw whole, raw skim, pasteurised whole, and pasteurised skim milk during storage at 4 °C, evaluated by mechanical mixing, air and steam injection, were investigated. The results showed that storage of milk until the end of their shelf-life (day 3 for raw milk and day 21 for pasteurised milk) did not induce any significant change in pH, particle size, viscosity and their foaming properties (foaming capacity, foam stability and size of air bubbles) although there was a slight increase in free fatty acid content. Regarding foaming methods, the air injection method produced much less foam volume than mechanical mixing and steam injection, except for raw milk where mechanical mixing showed the least foamability. However, an opposite trend was observed for foam stability. Although air injection induced the largest size of air bubbles, it produced the most stable foam, which was much more stable than foam produced by mechanical mixing and steam injection.
Publisher: Springer Science and Business Media LLC
Date: 22-02-2023
DOI: 10.1007/S11947-023-03012-5
Abstract: The presence of low molecular weight surfactants is suspected as one of the causes of poorly foaming milk, as they can interfere with milk proteins in the formation and stabilization of foam. Here, we explore the effect of various surfactants on the foaming properties of reconstituted skim milk powders. Each surfactant is different in electrical charge and molecular weight, including cleaning O- and E-coded chemicals, Tween 80, sucrose stearate, sodium oleate, sodium dodecyl sulfate, cetyltrimethylammonium bromide, benzalkonium chloride, and lecithin. The results showed that surfactants had different effects on foamability, foam stability, and structure, due to their varied effects on milk properties (e.g., pH, zeta potential, and surface tension). E-coded chemicals and sucrose stearate markedly decreased milk foamability, while the impact of Tween 80 and lecithin was considered detrimental to foam stability, as they mostly induced the production of large air bubbles in the foam.
Publisher: Springer Science and Business Media LLC
Date: 13-02-2019
Publisher: Elsevier BV
Date: 10-2019
DOI: 10.1016/J.FOODCHEM.2019.05.122
Abstract: Changes in physiochemical properties of spray-dried camel milk powders during storage at 11-32% RH and 37 °C over 18 weeks were investigated. The results showed that fresh camel milk powders had amorphous structure, clumsy spherical shape particles and almost 100% solubility in water. During storage at controlled low RH levels (<32% RH), reduction in moisture content and a
Publisher: Elsevier BV
Date: 08-2023
Publisher: CRC Press
Date: 10-06-2020
Publisher: Informa UK Limited
Date: 25-02-2023
Publisher: Elsevier BV
Date: 06-2014
Publisher: Springer International Publishing
Date: 2021
Publisher: Wiley
Date: 20-04-2023
DOI: 10.1002/JSFA.12604
Abstract: The attraction of cappuccino‐style beverages is attributed to the foam layer, as it greatly improves the texture, appearance, and taste of these products. Typical milk has a low concentration of free fatty acids (FFAs), but their concentration can increase due to lipolysis during processing and storage, which is detrimental to the foamability and foam stability of milk. There are contradictory results in reported studies concerning the effects of FFAs on the foaming properties of milk due to differences in milk sources, methods inducing lipolysis, and methods of creating foam. In this study, the foaming properties and foam structure of milk s les whose lipolysis was induced by ultra‐turraxing, homogenisation, and microfluidisation (1.5–3.5 μ‐equiv. mL −1 FFAs) were investigated. Compared with others, microfluidised milk s les had the smallest particle size, lowest absolute zeta potential, and highest surface tension thus exhibited high foamability and foam stability, and very small and homogeneous air bubbles in foam structure. For all shearing methods, increasing FFA content from 1.5 to 3.5 μ‐equiv. mL −1 markedly decreased the surface tension, foamability, and foam stability of milk s les. The FFA level that led to undesirable foam structure was 1.5 μ‐equiv. mL −1 for ultra‐turraxed milk s les and 2.5 μ‐equiv. mL −1 for homogenised and microfluidised ones. Shearing‐induced lipolysis greatly affected the physical properties of milk s les and subsequently their foaming properties and foam structure. At the same FFA level, lipolysis induced by microfluidisation was much less detrimental to the foaming properties of milk than lipolysis induced by ultra‐turraxing and homogenisation. © 2023 The Authors. Journal of The Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.
Publisher: Informa UK Limited
Date: 23-12-2023
Publisher: Springer International Publishing
Date: 2021
Publisher: Wiley
Date: 31-03-2016
Publisher: Informa UK Limited
Date: 05-02-2022
DOI: 10.1080/10408398.2021.1879727
Abstract: Nanoemulsion-based systems are widely applied in food industries for protecting active ingredients against oxidation and degradation and controlling the release rate of active core ingredients under particular conditions. Visualizing the interface morphology and measuring the interfacial interaction forces of nanoemulsion droplets are essential to tailor and design intelligent nanoemulsion-based systems. Atomic force microscopy (AFM) is being established as an important technique for interface characterization, due to its unique advantages over traditional imaging and surface force-determining approaches. However, there is a gap in knowledge about the applicability of AFM in characterizing the droplet interface properties of nanoemulsions. This review aims to describe the fundamentals of the AFM technique and nanoemulsions, mainly focusing on the recent use of AFM to investigate nanoemulsion properties. In addition, by reviewing interfacial studies on emulsions in general, perspectives for the further development of AFM to study nanoemulsions are also discussed.
Publisher: Elsevier BV
Date: 2022
DOI: 10.1016/J.FOODRES.2021.110818
Abstract: The biomass from cereal side streams is rich in valuable components, such as hemicelluloses. Among the hemicelluloses, arabinoxylans and β-glucans are the most acknowledged for potential health benefits. Numerous publications discuss the potential to use purified forms of these hemicelluloses for various applications. However, as the purification of hemicelluloses may not be economically feasible to upscale, sustainable and cost-effective methods are needed to make their valorization more realistic for industrial applications. Co-components present in hemicellulose-rich fractions may also provide added functionality, such as flavonoid content and antioxidant capacity. This review provides an overview on the feasibility of sustainably upscaling hemicellulose extraction processes, focusing on by-products from different cereal streams. We describe the hemicelluloses' physicochemical properties and provide various possible applications of pure and impure fractions from small scale to pilot and industrial scale. Furthermore, real case ex les on the industrial utilization of cereal side streams are enclosed. This review provides pathways for future research for developing the hemicellulose extraction methods to obtain fractions with optimized purity, and offers suggestions to valorize them.
Publisher: Elsevier BV
Date: 11-2015
Publisher: Wiley
Date: 20-10-2023
DOI: 10.1002/JSFA.13031
Publisher: Elsevier BV
Date: 12-2023
Publisher: Elsevier BV
Date: 11-2015
DOI: 10.1016/J.FOODCHEM.2015.04.094
Abstract: Carbon dioxide complexation was undertaken into solid matrices of amorphous and crystalline α-cyclodextrin (α-CD) powders, under various pressures (0.4-1.6 MPa) and time periods (4-96 h). The results show that the encapsulation capacity of crystalline α-CD was significantly lower than that of amorphous α-CD at low pressure and short time (0.4-0.8 MPa and 4-24 h), but was markedly enhanced with an increase of pressure and prolongation of encapsulation time. For each pressure level tested, the time required to reach a near equilibrium encapsulation capacity of the crystalline powder was around 48 h, which was much longer than that of the amorphous one, which only required about 8h. The inclusion complex formation of both types of α-CD powders was confirmed by the appearance of a CO2 peak on the FTIR and NMR spectra. Moreover, inclusion complexes were also characterized by DSC, TGA, SEM and X-ray analyses.
Publisher: Hindawi Limited
Date: 20-10-2018
DOI: 10.1111/JFPP.13514
Publisher: Springer Science and Business Media LLC
Date: 22-12-2023
DOI: 10.1007/S11947-022-02963-5
Abstract: The use of wood hemicelluloses, including galactoglucomannans (GGM) and glucuronoxylans (GX), in spray-dried microencapsulation of bioactive compounds has not been reported. Our study aims to investigate the benefits of spray-dried GGM and GX powders (sGGM and sGX) along with the effects of homogenization techniques (magnetic stirring, ultrasonication, and a combination of UltraTurrax homogenization and microfluidization) on the physicochemical properties of feed solutions (10–20%, w/w). Feed solutions of bilberry juice with sGGM, sGX, and mixtures of either sGGM or sGX with methylcellulose (MC) or carboxymethylcellulose (CMC) were examined to produce highly stable feed solutions for spray-dried microencapsulation. The effects of ultrasonication litudes (30–80%) on the viscosity and particle size distribution of sGGM feed solutions were more profound than observed in their sGX counterparts. Unlike sGX feed solutions, sGGM feed solutions homogenized by ultrasonication and microfluidization formed a gel-like structure. Microfluidization also caused a loss of total anthocyanin content (TAC) of the feed solutions. Magnetic stirring resulted in no gel formation and in the lowest viscosity of the feed solutions hence, it is an effective method for preparing hemicellulose feed solutions. sGGM and sGX powders have high heat stability with melting temperatures of 170–180 °C. The sGGM + CMC combination was more stable over 1 week of storage than the sGGM and sGX feed solutions. Storing the feed solutions reduced TAC and increased sGGM viscosity. Our results indicated that GGM and GX have high potential for use as wall materials in the spray-dried microencapsulation of bioactive compounds.
Publisher: Informa UK Limited
Date: 02-02-2022
DOI: 10.1080/10408398.2021.1879002
Abstract: For many dairy products such as cappuccino-style beverages, the top foam layer determines the overall product quality (e.g. their appearance, texture, mouthfeel and coffee aroma release rate) and the consumer acceptance. Proteins in milk are excellent foaming agents, but the foaming properties of milk are greatly affected by several factors such as the protein content, ratio of caseins to whey proteins, casein micelle size, pH, minerals, proteolysis, presence of low molecular weight compounds (lipids and their hydrolyzed products) and high molecular weight compounds (polysaccharides) milk processing conditions (e.g. homogenization, heat treatment and aging) and foaming method and temperature. These factors either induce changes in the molecular structure, charge and surface activity of the milk proteins or interfere and/or compete with milk proteins in the formation of highly viscoelastic film to stabilize the foam. Some factors affect the foamability while others determine the foam stability. In this review, functionality of milk proteins in the production and stabilization of liquid foam, under effects of these factors is comprehensively discussed. This will help to control the foaming process of milk on demand for a particular application, which still is difficult and challenging for researchers and the dairy industry.
Publisher: Elsevier BV
Date: 08-2021
Publisher: Informa UK Limited
Date: 14-04-2015
Publisher: Informa UK Limited
Date: 03-04-2017
DOI: 10.1080/09168451.2016.1274643
Abstract: Food powders can exist in amorphous, crystalline or mixed structure depending on the order of molecular arrangement in the powder particle matrices. In food production, the structure of powders has a greatly effect on their stability, functionality, and applicability. The undesirable structure of powders can be accidentally formed during production. Therefore, characterization of powder structure as well as quantification of amorphous–crystalline proportions presenting in the powders are essential to control the quality of products during storage and further processing. For these purposes, many analytical techniques with large differences in the degree of selectivity and sensitivity have been developed. In this review, differences in the structure of food powders are described with a focus being placed on applications of amorphous powders. Essentially, applicability of common analytical techniques including X-ray, microscopic, vapor adsorption, thermal, and spectroscopic approaches for quantitative and qualitative structural characterization of food powders is also discussed.
Publisher: Elsevier BV
Date: 09-2016
DOI: 10.1016/J.FOODCHEM.2016.03.044
Abstract: This study aims to characterize CO2-α-cyclodextrin (α-CD) inclusion complexes produced from amorphous α-CD powder at moisture contents (MC) close to or higher than the critical level of crystallization (e.g. 13, 15 and 17% MC on wet basis, w.b.) at 0.4 and 1.6MPa pressure for 72h. The results of (13)C NMR, SEM, DSC and X-ray analyses showed that these MC levels were high enough to induce crystallization of CO2-α-CD complexed powders during encapsulation, by which amount of CO2 encapsulated by amorphous α-CD powder was significantly increased. The formation of inclusion complexes were well confirmed by results of FTIR and (13)C NMR analyses through an appearance of a peak associated with CO2 on the FTIR (2334cm(-1)) and NMR (125.3ppm) spectra. Determination of crystal packing patterns of CO2-α-CD complexed powders showed that during crystallization, α-CD molecules were arranged in cage-type structure in which CO2 molecules were entrapped in isolated cavities.
Publisher: Springer Science and Business Media LLC
Date: 11-08-2022
DOI: 10.1007/S11947-022-02890-5
Abstract: This study investigated the effects of glucono-delta-lactone (GDL) concentrations (0.8–1.2%, w/w), gelatin content (0.6–1.0%, w/w) and processing conditions on the properties of camel milk acid gels. Although the pH of camel milk reduced to 4.3 within 4 h of acidification at 1.0% GDL, it was unable to form a suitable gel for a yoghurt-like product unless gelatin was added. At 0.8% gelatin, camel milk gels had similar hardness, lower viscosity and rheological strength, and higher water holding capacity as compared to cow milk gels. Heating of camel milk (85 °C/15–20 min), 2-stage homogenization (150/50 bar) or their combination did not significantly affect the water holding capacity, hardness, viscosity, rheological strength and microstructure of camel milk gels. These processing conditions did not affect protein integrity as confirmed by sodium dodecyl-sulphate polyacrylamide gel electrophoresis (SDS-PAGE) analysis.
Publisher: Elsevier BV
Date: 11-2021
Publisher: Elsevier BV
Date: 04-2017
DOI: 10.1016/J.FOODCHEM.2016.11.003
Abstract: An innovative method to encapsulate tea tree oil (TTO) by direct complexation with solid amorphous beta-cyclodextrin (β-CD) was investigated. A β-CD to TTO ratio of 90.5:9.5 (104.9mg TTO/g β-CD) was used in all complexation methods. The encapsulation was performed by direct mixing, and direct mixing was followed by the addition of water (13-17% moisture content, MC) or absolute ethanol (1:1, 1:2, 1:3 and 1:4 TTO:ethanol). The direct mixing method complexed the lowest amount of TTO (60.77mg TTO/g β-CD). Powder recrystallized using 17% MC included 99.63mg of TTO/g β-CD. The addition of ethanol at 1:2 and 1:3 TTO:ethanol ratios resulted in the inclusion of 94.3 and 98.45mg of TTO/g β-CD respectively, which was similar to that of TTO encapsulated in the conventional paste method (95.56mg TTO/g β-CD), suggesting an effective solid encapsulation method. The XRD and DSC results indicated that the amorphous TTO-β-CD complex was crystallized by the addition of water and ethanol.
Publisher: Elsevier BV
Date: 03-2022
Publisher: Elsevier BV
Date: 02-2021
Publisher: Elsevier BV
Date: 07-2023
Publisher: Springer International Publishing
Date: 2021
Publisher: Elsevier BV
Date: 02-2023
Publisher: Springer International Publishing
Date: 2021
No related grants have been discovered for Ho Minh Thao.