ORCID Profile
0000-0001-9239-1827
Current Organisation
Chinese Academy of Sciences Dalian Institute of Chemical Physics
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Publisher: Royal Society of Chemistry (RSC)
Date: 2010
DOI: 10.1039/C0CP00850H
Abstract: We present exact quantum differential cross sections and exact and estimated integral cross sections and branching ratios for the title reaction. We employ a time-dependent wavepacket method as implemented in the DIFFREALWAVE code including all Coriolis couplings and also an adapted DIFFREALWAVE code where the helicity quantum number and with this the Coriolis couplings have been truncated. Our exact differential cross sections at 0.453 eV total energy, one of the experimental energies, show good agreement with the experimental results for one of the product channels. While the truncated calculation present a significant reduction in the computational effort needed they overestimate the exact integral cross sections.
Publisher: Wiley
Date: 24-08-2010
Publisher: Royal Society of Chemistry (RSC)
Date: 2010
DOI: 10.1039/C0JM01794A
Publisher: American Chemical Society (ACS)
Date: 22-03-2010
DOI: 10.1021/JO100119Y
Abstract: We have synthesized three new carbazole-based fluorescent boronic acid sensors to investigate the fluorescence transduction efficiency of the novel d-PET effect, in which the fluorophore acts as the electron donor and the protonated amine/boronic acid group as the electron acceptor of the photoinduced electron transfer process (PET). Aryl ethynyl groups are attached at the 3,6-position of carbazole (aryl = 4-dimethylaminophenyl for sensor 1 or phenyl for sensor 2). Sensor 3 is without 3,6-substitutions. The phenylboronic acid moiety is attached at the 9-position (N-atom) of the carbazole in these sensors. We found that 1 and 3 are d-PET sensors (fluorophore as the electron donor, supported by DFT/TDDFT calculations), which show diminished emission at acidic pH but intensified emission at neutral/basic pH, which is in stark contrast to the normal a-PET (fluorophore as the electron acceptor) sensors, e.g., 2, which shows intensified emission at acidic pH but diminished emission at neutral pH. The fluorescence modulation efficiency of the d-PET effect of the new sensors, i.e., the emission intensity enhancement upon switching from acidic pH to neutral pH, is up to 10-fold, which is greatly improved compared to our previous d-PET sensors (ca. 3-fold). The efficient d-PET effect of the new sensors is attributed to the proper orientation of the electron donor/acceptor i.e., the dipole moment and the transition moment (the direction of PET) of the new sensors are oriented in the same direction, and the dipole moment values of the new sensors along the vector direction of the PET are larger than that of the reported d-PET sensors. Selective recognition of alpha-hydroxyl carboxylic acids, such as tartaric acid, was achieved with the d-PET sensors, and a novel fluorescence transduction profile of enhancement/diminishment for chemoselectivity was observed. Herein we propose that the orientation of the electron donor/acceptor may significantly affect the fluorescence modulation efficiency of the PET effect this discovery will be important for the future design of PET sensors with improved fluorescence transduction efficiencies.
Publisher: American Chemical Society (ACS)
Date: 23-05-2018
DOI: 10.1021/ACS.JPCLETT.8B01116
Abstract: We developed a high-performance photodetector based on (CH
Publisher: Royal Society of Chemistry (RSC)
Date: 2010
DOI: 10.1039/C003930F
Abstract: Nonadiabatic quantum dynamics calculations on the two coupled potential energy surfaces (PESs) (1(2)A' and 2(2)A') and also adiabatic quantum calculations on the lowest adiabatic PES are reported for the title reaction. Reaction probabilities for total angular momenta, J, varying from 0 to 160, are calculated to obtain the integral cross section (ICS) for collision energies ranging from 0.05 to 1.0 eV. Calculations using both the close coupling and the Centrifugal Sudden (CS) approximation are carried out to evaluate the role of Coriolis coupling effects for this reaction. The results of the nonadiabatic calculations show that the nonadiabatic effects in the title reaction for the initial state of NH (v = 0, j = 0) could be neglected, at least in the collision energy range considered in this study.
Location: China
No related grants have been discovered for Keli Han.