ORCID Profile
0000-0001-6404-4932
Current Organisation
The University of Newcastle
Does something not look right? The information on this page has been harvested from data sources that may not be up to date. We continue to work with information providers to improve coverage and quality. To report an issue, use the Feedback Form.
Publisher: Elsevier BV
Date: 02-2020
DOI: 10.1016/J.SCITOTENV.2019.134893
Abstract: The utilisation of magnetic biosorbents (metal or metal nanoparticles impregnated onto biosorbents) has attracted increasing research attention due to their manipulable active sites, specific surface area, pore volume, pore size distribution, easy separation, and reusability that are suitable for remediation of heavy metal(loid)s and organic contaminants. The properties of magnetic biosorbents (MB) depend on the raw biomass, properties of metal nanoparticles, modification/synthesis methods, and process parameters which influence the performance of removal efficiency of organic and inorganic contaminants. There is a lack of information regarding the development of tailored materials for particular contaminants and the influence of specific characteristics. This review focuses on the synthesis/modification methods, application, and recycling of magnetic biosorbents. In particular, the mechanisms and the effect of sorbents properties on the adsorption capacity. Ion exchanges, electrostatic interaction, precipitation, and complexation are the dominant sorption mechanisms for ionic contaminants whereas hydrophobic interaction, interparticle diffusion, partition, and hydrogen bonding are the dominant adsorption mechanisms for removal of organic contaminants by magnetic biosorbents. In generally, low pyrolysis temperatures are suitable for ionic contaminants separation, whereas high pyrolysis temperatures are suitable for organic contaminants removal. Additionally, magnetic properties of the biosorbents are positively correlated with the pyrolysis temperatures. Metal-based functional groups of MB can contribute to an ion exchange reaction which influences the adsorption capacity of ionic contaminants and catalytic degradation of non-persistent organic contaminants. Metal modified biosorbents can enhance adsorption capacity of anionic contaminants significantly as metal nanoparticles are not occupying positively charged active sites of the biosorbents. Magnetic biosorbents are promising adsorbents in comparison with other adsorbents including commercially available activated carbon, and thermally and chemically modified biochar in terms of their removal capacity, rapid and easy magnetic separation which allow multiple reuse to minimize remediation cost of organic and inorganic contaminants from wastewater.
Publisher: Elsevier BV
Date: 11-2020
Publisher: Elsevier BV
Date: 08-2020
Publisher: Desalination Publications
Date: 2022
Publisher: American Chemical Society (ACS)
Date: 23-09-2022
DOI: 10.1021/ACSBIOMATERIALS.2C00642
Abstract: Obesity is a complex disorder associated with immense health consequences including high risk of cardiovascular diseases, diabetes, and cancer. Abnormality in the thyroid gland, genetics, less physical activity, uptake of excessive diet, and leptin resistance are critical factors in the development of obesity. To determine the treatment strategy, understanding the pathophysiology of obesity is crucial. For instances, leptin resistance mediated obesity defined by the presence of excessive leptin hormone (Lep) in the systemic circulation is very common in diet induced obesity. Therefore, our hypothesis is that quantitative measurement of Lep from blood can help to identify in iduals with Lep resistant mediated obesity and thereby guide toward a proper treatment strategy. In this work, we aim to utilize an electrochemical immunosensing platform for diagnosis of obesity by measuring the Lep content in systemic circulation. A porous carbon confined FeNi bimetallic system was synthesized with three different ratios of Fe and Ni ions using high temperature pyrolysis technique. The suitability of the sensor for detecting Lep was studied using both CV and EIS techniques. The limit of detection (LOD) for GCE was recorded as 157.4 fg/mL with a wide linear concentration range of 500 fg/mL to 80 ng/mL, while for SPCE the LOD was 184.9 fg/mL with a linear range of 500 fg/mL to 50 ng/mL. Finally, the feasibility and applicability of the sensor for Lep detection was tested with serum collected from high fat diet induced obese rats. The selectivity, sensitivity, storage, and experimental stability and reproducibility tests showed potential for this biosensor platform as a point-of-care Lep detection device.
Publisher: Elsevier BV
Date: 11-2022
Publisher: Elsevier BV
Date: 12-2023
Publisher: Springer Science and Business Media LLC
Date: 13-06-2021
Publisher: Elsevier BV
Date: 05-2022
DOI: 10.1016/J.IJBIOMAC.2022.03.159
Abstract: Mesoporous (~7-8 nm) biopolymer hydrogel beads (HNTs-FeNPs@Alg/β-CD) were synthesised via ionic polymerisation route to separate heavy metal ions. The adsorption capacity of HNTs-FeNPs@Alg/β-CD was higher than that of raw halloysite nano tubes (HNTs), iron nanoparticles (FeNPs), and bare alginate beads. FeNPs induce the magnetic properties of adsorbent and metal-based functional groups in and around the hydrogel beads. The mesoporous surface of the adsorbent permits access of heavy metal ions onto the polymer beads to interact with internal active sites and the mesoporous polymer network. Maximum adsorption capacities of lead (Pb), copper (Cu), cadmium (Cd), and nickel (Ni) were 21.09 mg/g, 15.54 mg/g, 2.47 mg/g, and 2.68 mg/g, respectively. HNTs-FeNPs@Alg/β-CD was able to adsorb heavy metals efficiently (75-99%) under environment-relevant concentrations (200 μg/L) from mixed metal contaminants. The adsorption and selectivity trends of heavy metals were Pb > Cu > Cd > Ni, despite electrostatic binding strength of Cd > Cu > Pb > Ni and covalent binding strength of Pb > Ni > Cu > Cd. It demonstrated that not only chemosorption but also physisorption acts as the sorption mechanism. The reduction in surface area, porosity, and pore volume of the expended adsorbent, along with sorption study results, confirmed that pore filling and intra-particle diffusion played a considerable role in removing heavy metals.
Publisher: Elsevier BV
Date: 10-2021
Publisher: American Chemical Society (ACS)
Date: 31-05-2021
Publisher: Springer Science and Business Media LLC
Date: 16-08-2023
DOI: 10.1007/S11356-022-22357-6
Abstract: Adsorption has been considered as a promising remediation technology to separate organic and inorganic agrochemicals from contaminated soil and water. Low-cost adsorbents, including waste derived materials, clay composites, biochar, and biochar modified materials, have attracted enormous attention for the removal of organic contaminants, including pesticides. In this study, iron-modified base-activated biochar (FeBBC) was prepared by pyrolysis (at 400 °C for 1 h) of iron-doped base (KOH) activated sugarcane bagasse for the removal of a widely used insecticide, namely imidacloprid (IMI) from water. The maximum adsorption capacity of the adsorbent (FeBBC) was calculated as 10.33 (± 1.57) mg/g from Langmuir isotherm model. The adsorbents could remove up to ~ 92% of IMI from aqueous solution at 23.8 mg/L IMI. Experimental data fitted well with the Freundlich model and pseudo-second-order model, demonstrating physisorption, as well as chemosorption, contributed to the sorption process. Even at highly acidic/basic solution pH, the FeBBC could remove substantial amount of IMI demonstrating hydrophobic interaction and pore diffusion play vital role for removal of IMI. The slight improving of IMI sorption with increasing solution pH indicated the sorption was also facilitated through ionic interaction alongside physical sorption. However, physical sorption including hydrophobic interaction and pore-filling interaction plays a vital role in the sorption of IMI.
No related grants have been discovered for Masud Hassan.