ORCID Profile
0000-0003-4838-0236
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Publisher: Royal Society of Chemistry (RSC)
Date: 2017
DOI: 10.1039/C6SC03533G
Abstract: A type B radical-SAM methylase homologue catalyses thiazoline C-methylation as the final step of watasemycin biosynthesis in Streptomyces venezuelae ATCC10712.
Publisher: Elsevier BV
Date: 07-2013
Publisher: Elsevier BV
Date: 11-2019
Publisher: Elsevier BV
Date: 02-2011
Publisher: Springer Science and Business Media LLC
Date: 25-09-2019
DOI: 10.1038/S41467-019-12285-4
Abstract: The shape-selective catalysis enabled by zeolite micropore’s molecular-sized sieving is an efficient way to reduce the cost of chemical separation in the chemical industry. Although well studied since its discovery, HZSM-5′s shape-selective capability has never been fully exploited due to the co-existence of its different-sized straight channels and sinusoidal channels, which makes the shape-selective p -xylene production from toluene alkylation with the least m -xylene and o -xylene continue to be one of the few industrial challenges in the chemical industry. Rather than modifications which promote zeolite shape-selectivity at the cost of stability and reactivity loss, here inverse Al zoned HZSM-5 with sinusoidal channels predominantly opened to their external surfaces is constructed to maximize the shape-selectivity of HZSM-5 sinusoidal channels and reach 99 % p -xylene selectivity, while keeping a very high activity and good stability ( 220 h) in toluene methylation reactions. The strategy shows good prospects for shape-selective control of molecules with tiny differences in size.
Publisher: Elsevier BV
Date: 05-2017
Publisher: Elsevier BV
Date: 08-2016
Publisher: Royal Society of Chemistry (RSC)
Date: 2012
DOI: 10.1039/C2JM30935A
Publisher: MDPI AG
Date: 06-2017
DOI: 10.3390/CATAL7060171
Publisher: Elsevier BV
Date: 12-2020
Publisher: Elsevier BV
Date: 09-2018
Publisher: Elsevier BV
Date: 2018
Publisher: Elsevier BV
Date: 10-2020
No related grants have been discovered for Chuanfu Wang.