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0000-0001-9134-9002
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University of Engineering and Technology
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Publisher: Elsevier BV
Date: 11-2020
Publisher: Elsevier BV
Date: 11-2020
Publisher: MDPI AG
Date: 07-2020
DOI: 10.3390/EN13133375
Abstract: This research work focuses on investigating the lubricity and analyzing the engine characteristics of diesel–biodiesel blends with fuel additives (titanium dioxide (TiO2) and dimethyl carbonate (DMC)) and their effect on the tribological properties of a mineral lubricant. A blend of palm–sesame oil was used to produce biodiesel using ultrasound-assisted transesterification. B30 (30% biodiesel + 70% diesel) fuel was selected as the base fuel. The additives used in the current study to prepare ternary fuel blends were TiO2 and DMC. B30 + TiO2 showed a significant reduction of 6.72% in the coefficient of friction (COF) compared to B30. B10 (Malaysian commercial diesel) exhibited very poor lubricity and COF among all tested fuels. Both ternary fuel blends showed a promising reduction in wear rate. All contaminated lubricant s les showed an increment in COF due to the dilution of combustible fuels. Lub + B10 (lubricant + B10) showed the highest increment of 42.29% in COF among all contaminated lubricant s les. B30 + TiO2 showed the maximum reduction (6.76%) in brake-specific fuel consumption (BSFC). B30 + DMC showed the maximum increment (8.01%) in brake thermal efficiency (BTE). B30 + DMC exhibited a considerable decline of 32.09% and 25.4% in CO and HC emissions, respectively. The B30 + TiO2 fuel blend showed better lubricity and a significant improvement in engine characteristics.
Publisher: MDPI AG
Date: 08-06-2022
DOI: 10.3390/SU14127032
Abstract: Environmental pollution caused by conventional petro-diesel initiates at time of crude oil extraction and continues until its consumption. The resulting emission of poisonous gases during the combustion of petroleum-based fuel has worsened the greenhouse effect and global warming. Moreover, exhaustion of finite fossil fuels due to extensive exploitation has made the search for renewable resources indispensable. In light of this, biodiesel is a best possible substitute for the regular petro-diesel as it is eco-friendly, renewable, and economically viable. For effective biodiesel synthesis, the selection of potential feedstock and choice of efficient catalyst is the most important criteria. The main objective of this bibliographical review is to highlight vital role of different catalytic systems acting on variable feedstock and erse methods for catalysis of biodiesel synthesis reactions. This paper further explores the effects of optimized reaction parameters, modification in chemical compositions, reaction operating parameters, mechanism and methodologies for catalysts preparation, stability enhancement, recovery, and reusability with the maximum optimum activity of catalysts. In future, the development of well-planned incentive structures is necessary for systematic progression of biodiesel process. Besides this, the selection of accessible and amended approaches for synthesis and utilization of specific potential catalysts will ensure the sustainability of eco-green biodiesel.
Publisher: MDPI AG
Date: 07-10-2021
Abstract: Effect of parameters affecting solid particle erosion of crumb rubber epoxy composite is investigated. Five important process parameters—impact velocity, impingement angle, standoff distance, erodent size, and crumb rubber content—are taken into consideration. Erosion rate and erosion efficiency are included as the chief objectives. The Taguchi coupled gray relational analysis type statistical model is implemented to study interaction, parameters’ effect on responses, and optimized parameters. ANOVA and regression model affirmed impingement angle and crumb rubber content play a significant role to minimize the erosion. Validity of the proposed model is justified with the standard probability plot and R2 value. A confirmation experiment conducted with A2B2C3D3E3 condition registers noticeable enhancement in GRG to the tune of 0.0893.
Publisher: MDPI AG
Date: 17-08-2022
DOI: 10.3390/SU141610228
Abstract: Climate change is causing adverse and erse effects on human beings in term of severe diseases, melting of ice, and increase temperatures, which are directly linked to the consumption of traditional fossil fuels. These fuels can only be replaced by exploring renewable energy technologies, and photovoltaic solar modules are the most promising choice among them. This paper investigates electrical output in term of efficiency and power of a monocrystalline photovoltaic module under climatic conditions of Lahore, Pakistan in an effort to enhance electrical performance based on laminar and turbulent flow boundary conditions. A computational model of a PV module was designed and investigated, when the solar irradiance was observed to be maximum at 920.64 W/m2. Initially, the total flux received and absorbed by PV module was observed to be at 179.37 W/m2 after ray tracing analysis in Trace Pro thereafter, the module’s temperature increased to 65.86 °C, causing an electrical efficiency drops to 15.65% from 19.40% without applying active cooling schemes. A coupling of Ansys Fluent and Steady State Thermal Analysis was performed for thermal management of a PV module by selecting water and air as a coolant at inlet temperature of 25 °C through microchannels contingent upon varying Reynolds numbers. The results maintained that the optimum coolant outlet temperature (49.86 °C), average PV cell’s layer temperature (32.42 °C), and temperature uniformity (4.16 °C) are achieved by water at 224, 6710, and 4200 Reynolds numbers respectively. In addition, again water maintained 18.65% of electrical efficiency and 33.65 W power output at 6710 Reynolds number. On the other hand, air-based cooling lagged behind water by 14% in term of efficiency and power output at maximum Reynolds number (6710).
Publisher: MDPI AG
Date: 23-08-2022
DOI: 10.3390/SU141710485
Abstract: The lubrication phenomenon is used to reduce friction and wear between two rubbed surfaces, such as in engine and cutting processes. Different oils such as mineral oil and synthetic lubricant are being used for this purpose. With the passage of time, the demand of energy will get higher and natural resources and mineral lubricants will be diminished. Furthermore, biodegradation of mineral oil is too slow, and it remains on the surface of earth for a long period of time, creating atmospheric pollution. To overcome this problem, bio lubricants are being used to reduce wear and friction due to their high biodegradability. In order to increase the lubrication capacity of castor oil, a 1 wt. % concentration of MoS2 nanoparticles was added to the base oil. Moreover, to stabilize the additives, 2 wt. % gum arabic and 1 wt. % Oleic acid (OA) were also added. Then, multiple tests, such as of physicochemical properties, Fourier transform infrared (FTIR), and atomic absorption spectroscopy (AAS) of synthetic lubricant and conventional lubricant, were carried out before and after the operational running of 100 h on the diesel engine for each lubricant at 75% throttle, 2200 rpm, and 50% of total load. The results show that the behavior of newly prepared MoS2-based synthetic lubricant possessed higher characteristics in some physicochemical properties and was marginally lacking in other properties compared to shell lubricant. The flash point and specific gravity of synthetic lubricant were decreased compared to shell oil, with relative decreases of 0.27% and 1.15%, respectively. Ash and kinematic viscosity of 40 °C had a relative increase of 4.17% and 1.61%, respectively, and at a kinematic viscosity of 100 °C, the pour points and total base number (TBN) were relatively increased at 1.09%, 6.02%, and 1.38%, respectively, with respect to the properties of the shell lubricant. Moreover, this analysis evaluated that the reduction of wear and tear in synthetic lubricant regarding chromium (Cr), copper (Cu), and iron (Fe) was decreased by 21.12%, 3.39%, and 0.96%, respectively, but in the case of aluminum (Al) the wear and tear was marginally increased, at 1.17%, compared to shell lubricant. In the case of calcium (Ca) and zinc (Zn), the concentration was decreased by 3.59% and 17.41%, respectively. The FTIR analysis shows that all the peaks of the synthetic lubricant and shell lubricant were overlapping each other in the first three regions of the mid-IR spectra from 4000 to 1500 cm−1 and had the same functional groups—hydroxyl stretch (O-H), alkanes (C-H), carbonyls (C=O), aromatic amines (C-N), and alkyl halides (C-Br)—which were attached but fluctuating in the fingerprint region. The results show that shell lubricant can be replaced with MoS2-based synthetic lubricant because the latter has superior friction reduction and load-bearing capability and can compete favorably with commercial shell oil in wear protection when additivated with MoS2-based nanoparticles, and hence can be a good alternative for diesel engine oil.
Publisher: MDPI AG
Date: 08-08-2022
DOI: 10.3390/EN15155757
Abstract: Alcoholic fuels have recently come to light as a sustainable source for powering today’s vehicles. Various studies have investigated the effects of alcoholic fuels on engine efficiency and emission characteristics. However, scarce literature is available for their effects on lubricant. Therefore, propanol-gasoline fuel mixtures, with concentrations of 9% (P9) and 18% (P18) propanol, were made to compare their engine characteristics and lubricating oil condition with that of pure gasoline (0 percent propanol (P0)). To determine the rate of deterioration, the characteristics of the lubricating oil were evaluated after 100 h of engine operation, as suggested by the manufacturer. When compared with unused lube oil, P18 showed reductions in flash point temperature and kinematic viscosity of 14% and 36%, respectively, at 100 °C. For P18, which contains Fe (27 PPM), Al (11 PPM), and Cu (14 PPM), the highest wear element concentrations in the lubricating oil were found. The moisture in the degraded oil was well within the allowable limit for the three fuel mixtures. With the increase in propanol percentage in the propanol-gasoline blend, the engine performance was increased. Compared to P9 and P0, P18 had the partially unburned emissions.
Publisher: MDPI AG
Date: 18-05-2022
DOI: 10.3390/SU14106130
Abstract: In this present study, cold flow properties of biodiesel produced from palm oil were improved by adding cotton seed oil into palm oil. Three different mixtures of palm and cotton oil were prepared as P50C50, P60C40, and P70C30. Among three oil mixtures, P60C40 was selected for biodiesel production via ultrasound assisted transesterification process. Physiochemical characteristics—including density, viscosity, calorific value, acid value, and oxidation stability—were measured and the free fatty acid composition was determined via GCMS. Response surface methodology (RSM) and artificial neural network (ANN) techniques were utilized for the sake of relation development among operating parameters (reaction time, methanol-to-oil ratio, and catalyst concentration) ultimately optimizing yield of palm–cotton oil sourced biodiesel. Maximum yield of P60C40 biodiesel estimated via RSM and ANN was 96.41% and 96.67% respectively, under operating parameters of reaction time (35 min), M:O molar ratio (47.5 v/v %), and catalyst concentration (1 wt %), but the actual biodiesel yield obtained experimentally was observed 96.32%. The quality of the RSM model was examined by analysis of variance (ANOVA). ANN model statistics exhibit contented values of mean square error (MSE) of 0.0001, mean absolute error (MAE) of 2.1374, and mean absolute deviation (MAD) of 2.5088. RSM and ANN models provided a coefficient of determination (R2) of 0.9560 and a correlation coefficient (R) of 0.9777 respectively.
Publisher: Elsevier BV
Date: 10-2020
Publisher: Elsevier BV
Date: 12-2021
Publisher: MDPI AG
Date: 06-06-2022
DOI: 10.3390/SU14116930
Abstract: This research study presents an approach for analysis of pico hydro waterwheels by both experimental and numerical methods. The purpose of this research is to harness the energy efficiently from flowing water of irrigation channels and other shallow water sources in rural areas because the electrification of rural areas through connection to grid electricity is very costly. The novelty of this research work lies in testing of the waterwheel as a high-speed device, which is not usually explored. The review of existing literature reveals that pico waterwheels have been extensively studied but without changing the blade profile immersed in the water stream ot the inclination angle of the water stream. In this study, a pico scale waterwheel was tested with three different types of blade profiles, namely a C-shape blade, V-shape blade and straight blade, through computational fluid dynamics (CFD) simulations for different tip speed ratios (TSR), varying the immersed depth of the blade in the stream and changing the angle of the water conduit while keeping the number of blades and the diameter of the wheel constant. The numerical and experimental results were validated for the C-shape blade profile. A substantial improvement in performance is observed with a C-shape blade profile at a TSR of 0.88. The results show that by varying the angle of the water conduit, the maximum performance is achieved at inclination φ = 45°, with an overall improvement of 4.87% in the efficiency.
Publisher: Elsevier BV
Date: 08-2022
Publisher: MDPI AG
Date: 27-06-2023
DOI: 10.3390/SU151310161
Abstract: In this work, the effects of different fiber loadings on the mechanical properties of the composites at the sub-micron scale were studied through nanoindentation followed by physical characterization. The composites were prepared by incorporating different loadings of wheat straw, corn stalk, and rice husk in polypropylene copolymer using a melt processing method followed by thermal–hydraulic compression technique. Nanoindentation experiments in quasi-continuous stiffness mode were performed on the surfaces of produced composites to study the composites’ elastic modulus, hardness, and creep properties. The obtained results expressed the in-depth study of the micro- and macro-level structure and behavior of particle interactions. The findings demonstrated that observable shifts in composites’ hardness, elastic modulus, and creep rate had occurred. The WS-reinforced biocomposite sheet showed the highest elastic modulus of 1.09 and hardness of 0.11 GPa at 40 wt% loading in comparison to other loadings. An impact strength of 7.55 kJ/m2 was noted for the biocomposite at 40 wt% RH loading. In addition, optical microscopy, Fourier transform infrared spectroscopy, water absorption, thickness swelling, and Vicat softening point studies were conducted on biocomposite sheets to evaluate differences in physical, mechanical, and thermal properties. The outstanding mechanical performance of the newly developed composites makes them suitable for use as a biodegradable packaging material.
Publisher: Elsevier BV
Date: 07-2022
Publisher: Elsevier BV
Date: 10-2023
Publisher: MDPI AG
Date: 17-08-2022
DOI: 10.3390/SU141610188
Abstract: In the current study, a novel green nano-catalyst from Tragacanth gum (TG) was synthesized and used for sustainable biodiesel production from Brassica juncea (L.) Czern. seed oil. Brassica juncea (L.) Czern contains 30% oil on dry basis and free fatty acid content of 0.43 mg KOH/g. Physiochemical characterization of a newly synthesized nano-catalyst was performed by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray (EDX), Transmission Electron Microscopy (TEM), and Fourier Transform Infrared Spectroscopy (FT-IR) analysis. The XRD results showed an average crystalline size of 39.29 nm. TEM analysis showed the cluster form of NiSO4 nanoparticles with a size range from 30–50.5 nm. SEM analysis of the catalyst showed semispherical and ovoid shapes with surface agglomeration. The synthesized catalyst was recovered and re-used in four repeated transesterification cycles. Maximum biodiesel yield (93%) was accomplished at 6:1 methanol to oil molar ratio, catalyst concentration of 0.3 wt%, at 90 °C for 120 min at 600 rpm using Response Surface Methodology (RSM) coupled with central composite design (CCD). Brassica juncea (L.) Czern. biodiesel was characterized by Thin Layer Chromatography (TLC), FT-IR, Nuclear Magnetic Resonance (NMR) (1H, 13C), and Gas Chromatography-Mass Spectroscopy (GCMS) analytical techniques. The major fatty acid methyl esters were 16-Octadecenoic acid and 9-Octadecenoic acid methyl ester. The fuel properties, i.e., flash point (97 °C), density (825 kg/m3 at 40 °C), kinematic viscosity (4.66 mm2/s), pour point (–10 °C), cloud point (–14 °C), sulfur content (66 wt.%), and total acid number (182 mg KOH/g) were according to the International biodiesel standards. The reaction kinetic parameters were determined, and all the reactions followed Pseudo first-order kinetics. It was concluded that non-edible Brassica juncea (L.) Czern. seed oil is one of the sustainable candidates for the future biofuel industry using a cleaner, reusable, and highly active Ni-modified TG nano-catalyst.
Publisher: MDPI AG
Date: 25-06-2020
DOI: 10.3390/SU12125186
Abstract: Rapid depletion in fossil fuels, inflation in petroleum prices, and rising energy demand have forced towards alternative transport fuels. Among these alternative fuels, diesel-ethanol and diesel-biodiesel blends gain the most attention due to their quality characteristics and environmentally friendly nature. The viscosity and density of these biodiesel blends are slightly higher than diesel, which is a significant barrier to the commercialization of biodiesel. In this study, the density and viscosity of 30 different ternary biodiesel blends was investigated at 15 °С and 40 °С, respectively. Different density and viscosity models were developed and tested on biodiesel blends soured from different feedstock’s including palm, coconut, soybean, mustard, and calophyllum oils. The prognostic ability and precisions of these developed models was assessed statistically using Absolute Percentage Error (APE) and Mean Absolute Percentage Error (MAPE). The MAPE of 0.045% and 0.085% for density model and 1.85%, 1.41%, 3.48% and 2.27%, 1.85%, 3.50% for viscosity models were obtained on % volume and % mass basis. These developed correlations are useful for ternary biodiesel blends where alcohols are the part of biodiesel blends. The modeled values of densities and viscosities of ternary blends were significantly comparable with the measured densities and viscosities, which are feasible to avoid the harm of vehicles’ operability.
Publisher: MDPI AG
Date: 16-09-2203
DOI: 10.3390/SU141710947
Abstract: Pakistan is a developing country that faces severe energy crises due to the increased use of energy. The purpose of this study is energy transition by designing a strategy for the adoption of renewable energy policies in the entire energy system by using all renewable energy resources to forecast future energy needs and carbon emission mitigation potential. This research study aims to evaluate the renewable energy policies of Pakistan and to analyze the ways to secure energy sources in the future using LEAP. The study established a path for the transformation of the Pakistan energy system by considering the potential of renewable resources, the cost of the energy system, and the primary energy supply. The highest value of energy demand is noted for the 1st scenario, while the lowest emissions are noted for the 16th scenario for each renewable source (WIN16, SOL16, and BIO16). The lowest values of energy demand and emissions (192.1 TWh and 37.7 MMT, respectively) are shown using the green solution compared to other scenarios (hydro, nuclear, BAU), concluding that the green solution is the most suitable scenario. The analysis shows, that from a technological and economic perspective, it is possible to carry out transformation with the necessary steps to effectively achieve a renewable energy system. The findings of this study show that the green scenario in Pakistan which has the lowest operational and externality costs is the best choice for the future.
Publisher: MDPI AG
Date: 05-05-2023
DOI: 10.3390/SU15097601
Abstract: Growing environmental concerns over global warming and depleting fossil fuel reserves are compelling researchers to investigate green fuels such as alcoholic fuels that not only show the concrete decrement in emissions but also enhance engine performance. The current study emphasizes the influence of different alcoholic fuel blends in gasoline on engine performance and emissions for an engine speed ranging from 1200 to 4400 rpm. The obtained performance results demonstrate that the brake power and brake thermal efficiency (BTE) increased with an incrementing blend percentage of ethanol and methanol in gasoline (EM). The minimum brake specific fuel consumption (BSFC) was ascertained using pure gasoline followed by E2 and then E5M5. The NOx and CO2 emissions can be described in the decreasing order of E, EM and gasoline due to same trend of exhaust gas temperature (EGT). CO results were in reverse order of CO2. HC emissions were found in the increasing order of E, EM and pure gasoline. E10 performed better among all blends in terms of less exhaust emissions and engine performance. However, EM blended with gasoline significantly reduced NOx. E5M5 produced 1.9% lower NOx emission compared to E10 owing to 1.2% lower EGT. Moreover, greenhouse gases such as CO2, which is mainly responsible for global warming reducing by 1.1% in case E5M5 as compared to E10.
Publisher: Elsevier BV
Date: 09-2023
Publisher: MDPI AG
Date: 27-08-2021
Abstract: The effect of crump rubber on the dry sliding wear behavior of epoxy composites is investigated in the present study. Wear tests are carried out for three levels of crump rubber (10, 20, and 30 vol.%), normal applied load (30, 40, and 50 N), and sliding distance (1, 3, and 5 km). The wear behavior of crump rubber–epoxy composites is investigated against EN31 steel discs. The hybrid mathematical approach of Taguchi-coupled Grey Relational Analysis (GRA)—Principal Component Analysis (PCA) is used to examine the influence of crump rubber on the tribological response of composites. Mathematical and experimental results reveal that increasing crump rubber content reduces the wear rate of composites. Composites also show a significant decrease in specific wear values at higher applied loads. Furthermore, the coefficient of friction also shows a decreasing trend with an increase in crump rubber content, indicating the effectiveness of reinforcing crump rubber in a widely used epoxy matrix. Analysis of Variance (ANOVA) results also reveal that the crump rubber content in the composite is a significant parameter to influence the wear characteristic. The post-test temperature of discs increases with an increase in the applied load, while decreasing with an increase in filler loading. Worn surfaces are analyzed using scanning electron microscopy to understand structure–property correlations. Finally, existing studies available in the literature are compared with the wear data of the present study in the form of a property map.
Publisher: MDPI AG
Date: 03-2023
DOI: 10.3390/SU15054390
Abstract: The electrochemical treatment of canal water was investigated in a batch-wise system in the presence of stainless steel 316-grade electrodes. Three effective process parameters, including current density, reaction time, and electrode spacing, were evaluated in the range of 0.25–2.5 mA/cm2, 1–10 min, and 0.5–2.5 cm, respectively. Operational variables of electrochemical disinfection are optimized in response surface methodology (RSM) using Box–Behnken design. Before electrochemical disinfection, a pretreatment process of coagulants mixing for turbidity removal was conducted. Results revealed that a 10 ppm dosage of Ferric chloride (FeCl3.6H2O) and alum (Al2(SO4)3·16H2O) at neutral pH is appropriate. Furthermore, the RSM analysis shows that interelectrode spacing is the most prominent factor affecting the disinfection performance, and increasing electrode spacing inversely affects the disinfection efficiency. Results revealed that 1.52 mA/cm2 current density, 6.35 min reaction time, and 1.13 cm of electrode spacing are the optimum conditions, resulting in a statistically 98.08% disinfection of the total coliform. The energy required for electrochemically disinfection of water at optimum conditions was 0.256 kWh/m3.
Publisher: MDPI AG
Date: 28-11-2022
DOI: 10.3390/SU142315810
Abstract: The objective of this study is to investigate the effect of temperature and wind speed on the performance of five photovoltaic (PV) module technologies for different climatic zones of Pakistan. The PV module technologies selected were mono-crystalline silicon (MC) poly-crystalline silicon (PC) heterogeneous intrinsic thin-film (TFH) copper–indium–allium–selenide (TFC) and thin-film amorphous silicon (TFA). The module temperature and actual efficiency were calculated using measured data for one year. The actual efficiency of MC, PC, TFH, TFC, and TFA decreases by 3.4, 3.1, 2.2, 3.7, and 2.7%, respectively, considering the effect of temperature only. The actual efficiency of MC, PC, TFH, TFC, and TFA increases by 9.7, 9.0, 6.5, 9.5, and 7.0% considering the effect of both temperature and wind speed. The TFH module is the most efficient (20.76%) and TFC is the least efficient (16.79%) among the five materials. Under the effect of temperature, the actual efficiency of TFH is the least affected while the efficiency of TFC is the most affected. The actual efficiency of MC is the most affected and that of TFH is the least affected under the combined effect of wind speed and temperature. The performance ratio of TFC is the most affected and that of TFH is the least affected under the effect of temperature and the combined effect of temperature and wind speed. The performance of PV technology, under real outdoor conditions, does not remain the same due to environmental stresses (solar irradiance, ambient temperature, and wind speed). This study plays an important role in quantifying the long-term behavior of PV modules in the field, hence identifying specific technology for the PV industry in suitable climatic conditions.
Publisher: Elsevier BV
Date: 11-2020
Publisher: Elsevier BV
Date: 07-2022
Publisher: MDPI AG
Date: 14-09-2021
DOI: 10.3390/SU131810261
Abstract: This critical review report highlights the enormous potentiality and availability of renewable energy sources in the Gulf region. The earth suffers from extreme air pollution, climate changes, and extreme problems due to the enormous usage of underground carbon resources applications materialized in industrial, transport, and domestic sectors. The countries under Gulf Cooperation Council, i.e., Bahrain, Kuwait, Oman, Qatar, Saudi Arabia, and the United Arab Emirates, mainly explore those underground carbon resources for crude oil extraction and natural gas production. As a nonrenewable resource, these are bound to be exhausted in the near future. Hence, this review discusses the importance and feasibility of renewable sources in the Gulf region to persuade the scientific community to launch and explore renewable sources to obtain the maximum benefit in electric power generation. In most parts of the Gulf region, solar and wind energy sources are abundantly available. However, attempts to harness those resources are very limited. Furthermore, in this review report, innovative areas of advanced research (such as bioenergy, biomass) were proposed for the Gulf region to extract those resources at a higher magnitude to generate surplus power generation. Overall, this report clearly depicts the current scenario, current power demand, currently installed capacities, and the future strategies of power production from renewable power sources (viz., solar, wind, tidal, biomass, and bioenergy) in each and every part of the Gulf region.
Publisher: MDPI AG
Date: 03-02-2021
DOI: 10.20944/PREPRINTS202102.0115.V1
Abstract: The present study examines the effect of SiO2 nano-additives on the performance and emission characteristics of a diesel engine fuelled with soybean biodiesel. Soybean biofuel was prepared using the transesterification process. Nano-additives characterisations were done using different tests such as FESEM, XRD, EDS, etc., to study the morphology of nano-additives. For proper blending of nano-additives with biodiesel, the ultrasonication process was used. Surfactant was used for the stabilisation of nano-additives. After making all the combinations of nano fuel blends, physicochemical properties were measured as per ASTM standards. Performance and emissions readings were taken at different load conditions. It was found that with the addition of SiO2 nano-additives, brake thermal efficiency (BTE) and brake specific fuel consumption (BSFC) was increased by 3.48-6.39% and 5.81-9.88%, respectively. Significant reduction of CO, CO2, NOx, and smoke emissions were also observed compared to baseline fule due to better combustion efficiency with the use of SiO2 nano-additive.
Publisher: Elsevier BV
Date: 11-2021
Publisher: MDPI AG
Date: 22-04-2022
DOI: 10.3390/SU14095062
Abstract: Biodiesel is gaining recognition as a good replacement for typical diesel owing to its renewability, sustainability, and eco-friendly nature. Transesterification is the leading route for biodiesel generation, which occurs during homogeneous/heterogeneous/enzymatic catalysis. Besides this, the usage of heterogeneous catalysts is considered more advantageous over homogeneous catalysts due to the easy catalyst recovery. Consequently, numerous heterogeneous catalysts have been synthesized from multiple sources with the intention of making the manufacturing process more efficient and cost-effective. Alongside this, numerous researchers have attempted to improve the biodiesel yield using heterogeneous catalysts by introducing cosolvents, such that phase limitation between oil and alcohol can be minimized. This short review is aimed at examining the investigations performed to date on heterogeneously catalyzed biodiesel generation in the presence of different cosolvents. It encompasses the techniques for heterogeneous catalyst synthesis, reported in the literature available for heterogeneous catalyzed biodiesel generation using cosolvents and their effects. It also suggests that the application of cosolvent in heterogeneously catalyzed three-phase systems substantially reduces the mass transfer limitation between alcohol and oil phases, which leads to enhancements in biodiesel yield along with reductions in values of optimized parameters, with catalyst weight ranges from 1 to 15 wt. %, and alcohol/oil ratio ranges from 5.5 to 20. The reaction time for getting the maximum conversion ranges from 10 to 600 min in the presence of different cosolvents. Alongside this, most of the time, the biodiesel yield remained above 90% in the presence of cosolvents.
Publisher: Elsevier BV
Date: 11-2021
Publisher: Elsevier BV
Date: 11-2021
Publisher: Elsevier BV
Date: 12-2022
Publisher: MDPI AG
Date: 13-11-2020
DOI: 10.3390/EN13225941
Abstract: In this study, waste cooking oil (WCO) was used as a feedstock for biodiesel production, where the pretreatment of WCO was performed using mineral acids to reduce the acid value. The response surface methodology (RSM) was used to create an interaction for different operating parameters that affect biodiesel yield. The optimised biodiesel yield was 93% at a reaction temperature of 57.50 °C, catalyst concentration 0.25 w/w, methanol to oil ratio 8.50:1, reaction stirring speed 600 rpm, and a reaction time of 3 h. Physicochemical properties, including lower heating value, density, viscosity, cloud point, and flash point of biodiesel blends, were determined using American Society for Testing and Materials (ASTM) standards. Biodiesel blends B10, B20, B30, B40, and B50 were tested on a compression ignition engine. Engine performance parameters, including brake torque (BT), brake power (BP), brake thermal efficiency (BTE), and brake specific fuel consumption (BSFC) were determined using biodiesel blends and compared to that of high-speed diesel. The average BT reduction for biodiesel blends compared to HSD at 3000 rpm were found to be 1.45%, 2%, 2.2%, 3.09%, and 3.5% for B10, B20, B30, B40, and B50, respectively. The average increase in BSFC for biodiesel blends compared to HSD at 3500 rpm were found to be 1.61%, 5.73%, 8.8%, 12.76%, and 18% for B10, B20, B30, B40, and B50, respectively.
Publisher: MDPI AG
Date: 09-10-2021
Abstract: In this modern era, it has become essential to transform waste materials into valuables because of their excessive availability, along with achieving the targets of environmental protocols and waste management policies. With a growing population, the utilization and consumption of agricultural products have been increased extensively. In addition, it has increased the probability of agricultural waste generation. Waste produced from agricultural sources is considered as a viable source for synthesizing economical and ecofriendly catalysts and suitable ways for its disposal are sought. This study is targeted at agricultural waste-derived heterogeneous catalysts, which have been effectively employed for biodiesel generation. The types of agricultural waste, catalyst synthesis techniques, recent literature stated for agricultural waste-derived catalysts to produce biodiesel, the elemental composition and catalytic activity of agricultural waste ashes, the effect of reaction parameters to maximize biodiesel yield and catalyst reusability have been discussed. This work concludes that catalysts derived from agricultural waste are efficient in transesterification reaction, and they are easy to produce, and are cheap and ecofriendly. Moreover, this study encourages researchers to see the options for unexplored agricultural waste, which can be potentially converted into useful materials
Publisher: MDPI AG
Date: 09-01-2023
DOI: 10.3390/ELECTRONICS12020341
Abstract: The source of energy extracted in renewable form has turned out to be a primary mainstream energy source, especially in the telecom sectors. Rapid growth of renewable sources has led to telecom operators concentrating more on designing the system with appropriate energy storage elements, providing control facilities, improving system efficiency and verifying uninterrupted power supplies. Therefore, this paper gives a novel approach of utilizing embedded control in energy generation consisting of a solar-wind hybrid energy system placed in isolated areas. For the purpose of integration of wind, together with the solar energy sources, into an increasingly efficient system, a single Cuk-Luo integrated DC-DC converter has been put forward. The proposed system has been modeled using MATLAB/Simulink and verified under various combinations of solar-wind energy sources without compromising the required power. In order to verify the proposed Cuk-Luo integrated converter with the energy management controller system, a prototype hardware is implemented and tested.
Publisher: Elsevier BV
Date: 10-2020
Publisher: MDPI AG
Date: 11-10-2022
DOI: 10.3390/MOLECULES27206783
Abstract: Diabetes mellitus is a chronic metabolic disorder in which the pancreas secretes insulin but the body cells do not recognize it. As a result, carbohydrate metabolism causes hyperglycemia, which may be fatal for various organs. This disease is increasing day by day and it is prevalent among people of all ages, including young adults and children. Acarbose and miglitol are famous alpha-glucosidase inhibitors but they complicate patients with the problems of flatulence, pain, bloating, diarrhea, and loss of appetite. To overcome these challenges, it is crucial to discover new anti-diabetic drugs with minimal side effects. For this purpose, benzotriazinone sulfonamides were synthesized and their structures were characterized by FT-IR, 1H-NMR and 13C-NMR spectroscopy. In vitro alpha-glucosidase inhibition studies of all synthesized hybrids were conducted using the spectrophotometric method. The synthesized compounds revealed moderate-to-good inhibition activity in particular, nitro derivatives 12e and 12f were found to be the most effective inhibitors against this enzyme, with IC50 values of 32.37 ± 0.15 µM and 37.75 ± 0.11 µM. In silico studies, including molecular docking as well as DFT analysis, also strengthened the experimental findings. Both leading compounds 12e and 12f showed strong hydrogen bonding interactions within the enzyme cavity. DFT studies also reinforced the strong binding interactions of these derivatives with biological molecules due to their lowest chemical hardness values and lowest orbital energy gap values.
Publisher: Elsevier BV
Date: 12-2021
Publisher: MDPI AG
Date: 09-07-2021
DOI: 10.3390/SU13147688
Abstract: In this study, engine performance on thermal factors for different biodiesels has been studied and compared with diesel fuel. Biodiesels were produced from Pongamia pinnata (PP), Calophyllum inophyllum (CI), waste cooking oil (WCO), and acid oil. Depending on their free fatty acid content, they were subjected to the transesterification process to produce biodiesel. The main characterizations of density, calorific range, cloud, pour, flash and fire point followed by the viscosity of obtained biodiesels were conducted and compared with mineral diesel. The characterization results presented benefits near to standard diesel fuel. Then the proposed diesel engine was analyzed using four blends of higher concentrations of B50, B65, B80, and B100 to better substitute fuel for mineral diesel. For each blend, different biodiesels were compared, and the relative best performance of the biodiesel is concluded. This diesel engine was tested in terms of BSFC (brake-specific fuel consumption), BTE (brake thermal efficiency), and EGT (exhaust gas temperature) calculated with the obtained results. The B50 blend of acid oil provided the highest BTE compared to other biodiesels at all loads while B50 blend of WCO provided the lowest BSFC compared to other biodiesels, and B50 blends of all biodiesels provided a minimum % of the increase in EGT compared to diesel.
Publisher: MDPI AG
Date: 20-08-2021
DOI: 10.3390/SU13169373
Abstract: The prevailing massive exploitation of conventional fuels has staked the energy accessibility to future generations. The gloomy peril of inflated demand and depleting fuel reservoirs in the energy sector has supposedly instigated the urgent need for reliable alternative fuels. These very issues have been addressed by introducing oxyhydrogen gas (HHO) in compression ignition (CI) engines in various flow rates with diesel for assessing brake-specific fuel consumption (BSFC) and brake thermal efficiency (BTE). The enrichment of neat diesel fuel with 10 dm3/min of HHO resulted in the most substantial decrease in BSFC and improved BTE at all test speeds in the range of 1000–2200 rpm. Moreover, an Artificial Intelligence (AI) approach was employed for designing an ANN performance-predicting model with an engine operating on HHO. The correlation coefficients (R) of BSFC and BTE given by the ANN predicting model were 0.99764 and 0.99902, respectively. The mean root errors (MRE) of both parameters (BSFC and BTE) were within the range of 1–3% while the root mean square errors (RMSE) were 0.0122 kg/kWh and 0.2768% for BSFC and BTE, respectively. In addition, ANN was coupled with the response surface methodology (RSM) technique for comprehending the in idual impact of design parameters and their statistical interactions governing the output parameters. The R2 values of RSM responses (BSFC and BTE) were near to 1 and MRE values were within the designated range. The comparative evaluation of ANN and RSM predicting models revealed that MRE and RMSE of RSM models are also well within the desired range but to be outrightly accurate and precise, the choice of ANN should be potentially endorsed. Thus, the combined use of ANN and RSM could be used effectively for reliable predictions and effective study of statistical interactions.
Publisher: MDPI AG
Date: 02-09-2022
DOI: 10.3390/SU141710962
Abstract: Heterogeneous catalyst prepared from Ailanthus altissima oil cake along with cadmium sulphide catalyst proved to be an efficient, cost-effective and sustainable source of biodiesel synthesis from Ailanthus altissima (Mill.) seed oil. Ailanthus altissima (Mill.) is a non-edible wild plant having significant oil content of 40%, being an ideal low cost and sustainable source of biodiesel production. After extraction of oil from the seeds, the remaining Ailanthus cake was treated through different techniques to be used as a novel heterogeneous catalyst. Free fatty acid content of the seeds was measured as 0.7%, which is very reasonable for effective trans-esterification process. The potassium hydroxide (KOH)-activated Ailanthus cake (KAC), calcined Ailanthus cake (CAC) and cadmium sulphide nanoparticles (CdS) were characterised with different techniques such as SEM at different magnifications, XRD and EDX. These catalysts were effectively utilised for biodiesel production owing to promising reusability, cost-effective and eco-friendly behaviour. For trans-esterification of Ailanthus altissima oil (AAO), the operating conditions on which maximum biodiesel yield obtained were 3:1 methanol to oil molar ratio, 0.5 wt.% catalyst concentration, 90 min reaction time, 60 °C and 600 rpm. The fuel properties of biodiesel obtained from Ailanthus altissima (Mill.) were also determined and analysed in detail. These properties, such as viscosity, density, pour point and cloud point, fall within the limits set by international standards of biodiesel.
Publisher: MDPI AG
Date: 17-09-2021
DOI: 10.3390/EN14185879
Abstract: The engine performance has been improved by modifying the combustion chamber shape of the diesel engine for dual-fuel operation with liquid fuel and producer gas (PG). The combined effect of gaseous fuel from redgram stalk and combustion chamber type on the emission and performance of blended-fuel of diesel and HOME biodiesel–PG has been investigated. In this experimental study, four varieties of combustion chambers hemispherical (HCC), low swirl (LSCC), dual swirl (DSCC), and toroidal re-entrant (TRCC) were analyzed comprehensively. The results presented that the TRCC configuration with a given nozzle geometry has 9% improved brake thermal efficiency (BTE) and 10.4% lower exhaust gas temperature (EGT). The smoke, unburnt hydrocarbon (UBHC), and carbon monoxide (CO) decreased by 10–40%, but a 9% increase in nitrogen oxides (NOX) emission levels was observed with TRCC. The delay period and combustion period were decreased by 5% and 7%. The fuel replacement of about 71% for the diesel–PG combination with HCC and 68% for the HOME–PG combination with TRCC was achieved.
Publisher: SAGE Publications
Date: 2022
DOI: 10.1177/09673911221093646
Abstract: This study aims to determine the optimum reinforcement required to attain the best combination of flexural strength of modified green composites (graphene oxide + hemp fibre reinforced epoxy composites) for potential use in structural applications. An attempt was also made for the combination of graphene and hemp fibres to enhance load-bearing ability. The infusion of hemp and graphene was made by the weight of the base matrix (epoxy composite). Results showed that graphene reinforcement at 0.4 wt.% of matrix showed load-sustaining capacity of 0.76 kN or 760 MPa. In the case of hemp fibre reinforcement at 0.2 wt.% of the matrix, infusion showed enhanced load-bearing ability (0.79 kN or 790 MPa). However, the combination of graphene (0.1 wt.% graphene nanofillers) and hemp (5 wt.% hemp fibre) indicated a load-sustaining ability of 0.425 kN or 425 MPa, whereas maximum deflection was observed for specimen with hemp 7.5 % + graphene 0.2 % with 1.9 mm. Graphene addition to the modified composites in combination with natural fibres showed promising results in enhancing the mechanical properties under study. Moreover, graphene-modified composites exhibited higher thermal resistance compared to natural fibre reinforced composites. However, when nanofiller reinforcement exceeded a threshold value, the composites exhibited reduced flexural strength as a result of nanofiller agglomeration.
Publisher: Springer Science and Business Media LLC
Date: 13-10-2019
Publisher: Elsevier BV
Date: 12-2021
Publisher: MDPI AG
Date: 17-05-2023
DOI: 10.3390/SU15108125
Abstract: Highly concentrated triple-junction solar cells (HCTJSCs) are cells that have erse applications for power generation. Their electrical efficiency is almost 45%, which may be increased to 50% by the end of the year 2030. Despite their overwhelming ability to generate power, their efficiency is lower when utilized in a concentrated manner, which introduces a high-temperature surge, leading to a sudden drop in output power. In this study, the efficiency of a 10 mm × 10 mm multijunction solar cell (MJSC) was increased to almost 42% under the climatic conditions in Lahore, Pakistan. Active cooling was selected, where SiO2–water- and Al2O3–water-based nanofluids with varying volume fractions, ranging from 5% to 15% by volume, were used with a 0.001 kg/s mass flow rate. In addition, two- and three-layer microchannel heat sinks (MCHSs) with squared microchannels were designed to perform thermal management. Regarding the concentration ratio, 1500 suns were considered for 15 August at noon, with 805 W/m2 and 110 W/m2 direct and indirect radiation, respectively. A complete model including a triple-junction solar cell and allied assemblies was modeled in Solidworks software, followed by temperature profile generation in steady-state thermal analyses (SSTA). Thereafter, a coupling of SSTA and Ansys Fluent was made, in combination with the thermal management of the entire model, where the temperature of the TJSC was found to be 991 °C without active cooling, resulting in a decrease in electrical output. At 0.001 kg/s, the optimum average surface temperature (44.5 °C), electrical efficiency (41.97%), and temperature uniformity (16.47 °C) were achieved in the of MJSC with SiO2–water nanofluid with three layers of MCHS at a 15% volume fraction. Furthermore, the average outlet temperature of the Al2O3–water nanofluid at all volume fractions was high, between 29.53 °C and 31.83 °C, using the two-layer configuration. For the three-layer arrangement, the input and output temperatures of the working fluid were found to be the same at 25 °C.
Publisher: Elsevier BV
Date: 2021
Publisher: Elsevier BV
Date: 10-2021
Publisher: Elsevier BV
Date: 2023
Publisher: Springer Science and Business Media LLC
Date: 04-02-2022
Publisher: MDPI AG
Date: 03-09-2020
DOI: 10.3390/EN13174578
Abstract: This study considered the impacts of diesel–soybean biodiesel blends mixed with 3% cerium coated zinc oxide (Ce-ZnO) nanoparticles on the performance, emission, and combustion characteristics of a single cylinder diesel engine. The fuel blends were prepared using 25% soybean biodiesel in diesel (SBME25). Ce-ZnO nanoparticle additives were blended with SBME25 at 25, 50, and 75 ppm using the ultrasonication process with a surfactant (Span 80) at 2 vol.% to enhance the stability of the blend. A variable compression ratio engine operated at a 19.5:1 compression ratio (CR) using these blends resulted in an improvement in overall engine characteristics. With 50 ppm Ce-ZnO nanoparticle additive in SBME25 (SBME25Ce-ZnO50), the brake thermal efficiency (BTE) and heat release rate (HRR) increased by 20.66% and 18.1%, respectively brake specific fuel consumption (BSFC) by 21.81% and the CO, smoke, and hydrocarbon (HC) decreased by 30%, 18.7%, and 21.5%, respectively, compared to SBME25 fuel operation. However, the oxides of nitrogen slightly rose for all the nanoparticle added blends. As such, 50 ppm of Ce-ZnO nanoparticle in the blend is a potent choice for the enhancement of engine performance, combustion, and emission characteristics.
Publisher: MDPI AG
Date: 28-04-2022
DOI: 10.3390/PR10050876
Abstract: Over the years, due to the surge in energy demand, the use of alternative fuels has emerged as an interesting area of research. In the current work, a comparative study was conducted by employing gasoline, 6% ethanol–gasoline (E6), and 12% ethanol–gasoline (E12) in a spark-ignition engine. Performance, emissions, and lube oil damage tests were conducted at a constant load by varying engine speed. E12 showed improved performance, i.e., 7.82% higher torque and 14.69% improved brake thermal efficiency (BTE) in comparison with neat gasoline. In addition, CO, CO2, HC, and NOx emissions were found to be minimal for E12. Furthermore, lubricating oil properties (kinematic viscosity, flash point, and total base number (TBN)) and wear debris (iron, aluminum, and copper) showed a visibly improved performance with gasoline compared to E6 and E12. The highest decline in kinematic viscosity of 27.87%, compared to fresh oil, was recorded for E12. Thus, the lube oil properties have to be modified according to the chemical properties of the alternative fuel.
Publisher: Elsevier BV
Date: 02-2022
DOI: 10.1016/J.CHEMOSPHERE.2021.132450
Abstract: Biodiesel commercialization is questionable due to poor brake thermal efficiency. Biodiesel utilization should be improved with the addition of fuel additives. Hydrogen peroxide is a potential fuel additive due to extra hydrogen and oxygen content, which improves the combustion process. In this experimental study, biodiesel has been produced from Jatropha oil employing catalyzed transesterification homogeneously to examine its influence on the performance and emissions at engine loads with 1500 rpm utilizing a four-stroke single-cylinder diesel engine. D60B40 (having 60% diesel and 40% biodiesel) and D60B30A10 (60% diesel, 30% biodiesel and 10% hydrogen peroxide (H
Publisher: MDPI AG
Date: 30-08-2021
DOI: 10.3390/SU13179731
Abstract: Biodiesel is a seemingly suitable alternative substitute for conventional fossil fuels to run a diesel engine. In the first part of the study, the production of biodiesel by modified direct transesterification (MDT) is reported. An enhancement in the biodiesel yield with a considerable reduction in reaction time with the MDT method was observed. The required duration for diesel and biodiesel blending was minimized including glycerol separation time from biodiesel in the MDT method. The development in the automotive sector mainly focuses on the design of an efficient, economical, and low emission greenhouse gas diesel engine. In the current experimental work Ceiba pentandra/Nigella sativa and diesel blends (CPB10 and NSB10) were used to run the diesel engine. A variety of approaches were implemented to improve the engine performance for these combinations of fuels. The fuel injector opening pressure (IOP) was set at 240 bar, the torriodal re-entrant combustion chamber (TRCC) having a six-hole injector with a 0.2 mm orifice diameter each, provided better brake thermal efficiency (BTE) with lower emissions compared with the hemispherical combustion chamber (HCC) and trapezoidal combustion chamber (TCC) for both CPB10 and NSB10. CPB10 showed better performance compared with NSB10. A maximum BTE of 29.1% and 28.6% were achieved with CPB10 and NSB10, respectively, at all optimized conditions. Diesel engine operation with CPB10 and NSB10 at 23° bTDC fuel injection timing, and 240 bar IOP with TRCC can yield better results, close to a diesel run engine at 23° bTDC fuel injection timing, and 205 bar IOP with HCC.
Publisher: MDPI AG
Date: 09-03-2021
DOI: 10.3390/EN14051489
Abstract: The present study examines the effect of silicon dioxide (SiO2) nano-additives on the performance and emission characteristics of a diesel engine fuelled with soybean biodiesel. Soybean biofuel was prepared using the transesterification process. The morphology of nano-additives was studied using scanning electron microscopy (SEM), X-ray diffraction (XRD) and energy-dispersive X-ray spectroscopy (EDS). The Ultrasonication process was used for the homogeneous blending of nano-additives with biodiesel, while surfactant was used for the stabilisation of nano-additives. The physicochemical properties of pure and blended fuel s les were measured as per ASTM standards. The performance and emissions characteristics of different fuel s les were measured at different loading conditions. It was found that the brake thermal efficiency (BTE) and brake specific fuel consumption (BSFC) increased by 3.48–6.39% and 5.81–9.88%, respectively, with the addition of SiO2 nano-additives. The carbon monoxide (CO), hydrocarbon (HC) and smoke emissions for nano-additive added blends were decreased by 1.9–17.5%, 20.56–27.5% and 10.16–23.54% compared to SBME25 fuel blends.
Publisher: Elsevier BV
Date: 06-2022
No related grants have been discovered for M.A Mujtaba.