ORCID Profile
0000-0002-6524-2815
Current Organisation
Universiti Teknologi MARA
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Publisher: Trans Tech Publications, Ltd.
Date: 12-2013
DOI: 10.4028/WWW.SCIENTIFIC.NET/KEM.594-595.219
Abstract: In order to enhance its cationic sorption capacity, untreated rubber leaf powder (RLP) was functionalized using monosodium glutamate to produce potentially biodegradable cationic sorbent. The sorption behaviors of monosodium glutamate functionalised (MGRL) against Pb (II) in a batch system are investigated. The effects of various experimental parameters (e.g. initial pH, contact time) were investigated and the sorption kinetic was elucidated. The Pb (II) removal on MGRL increased as the initial pH increased. The effect of contact time revealed that the equilibrium is reached at 90 minutes. The Pb (II) sorption process on MGRL followed the pseudo-first-order rate kinetics. The Langmuir isotherm model with a maximum adsorption capacity of 109.953 mg/g was found suited to describe the adsorption process.
Publisher: Elsevier BV
Date: 12-2009
DOI: 10.1016/J.BIORTECH.2009.06.070
Abstract: Barley straw, an agricultural waste, was chemically modified and evaluated for the removal of emulsified oils from aqueous solution. The chemical modification was performed using NaOH and a cationic surfactant, hexadecylpyridinium chloride monohydrate (CPC). The surface textural and chemical properties of the surfactant modified barley straw (BMBS) were characterized by N(2) adsorption, FT-IR, SEM and water soluble mineral content. The adsorption tests were carried out in batch adsorption system for removal of standard mineral oil (SMO) and canola oil (CO) from water. For both emulsified oils in wastewater, adsorption was found to be strongly related with solution pH. The isotherm study indicated that emulsified oil adsorption on BMBS could be fitted well with the Langmuir model other than Freundlich model. The maximum adsorption capacity for CO and SMO at 25 degrees C determined from the Langmuir isotherm is 613.3 and 584.2 mg g(-1), respectively. Desorption tests in water solution show that oil is strongly bonded with adsorbent and desorption is only about 1-2% in 24 h.
Publisher: Elsevier BV
Date: 03-2010
Publisher: Trans Tech Publications, Ltd.
Date: 05-2016
DOI: 10.4028/WWW.SCIENTIFIC.NET/MSF.857.530
Abstract: Xanthated chitosan (XC) beads synthesized from the reaction between sulphur and hydroxyl groups were applied to adsorb rare earth metal ion, Nd (III). Adsorption of Nd (III) was found to be a function of pH of initial solution, adsorbent dosage and contact time. The optimum conditions for Nd (III) adsorption were at pH 3 and adsorbent dosage of 0.02 g. Rapid adsorption process was observed as it took only 10 min for reaching the equilibrium state. Chemisorption was identified as the rate limiting step and the kinetics data correlated well with the pseudo-second-order model.
Publisher: Elsevier BV
Date: 03-2016
Publisher: Science Alert
Date: 02-2007
Publisher: Elsevier BV
Date: 2018
Publisher: Science Alert
Date: 15-06-2006
Publisher: The World Academy of Research in Science and Engineering
Date: 15-09-2020
Publisher: Elsevier BV
Date: 09-2009
DOI: 10.1016/J.BIORTECH.2009.03.063
Abstract: A barley straw was modified by a surfactant, cetylpyridinium chloride, and used as an adsorbent for acid (acid blue 40) and reactive dye (reactive black 5) adsorption in aqueous solution. Characterization of the modified barley straw was performed using N(2) adsorption, titration, and FT-IR analysis. It was found that the surfactant modified barley straw exhibits higher adsorption to acid blue 40 than reactive black 5 and adsorption of the dyes is influenced by several parameters such as dye initial concentration, adsorbent dosage, solution pH, and adsorption temperature. Adsorption isotherms show that maximum adsorption of acid blue 40 and reactive black 5 is 1.02x10(-4) and 2.54x10(-5) mol/g, respectively. Desorption studies show that both dyes are strongly bounded with the adsorbent and exhibit low desorption.
Publisher: Wiley
Date: 23-08-2010
DOI: 10.1002/APJ.506
Publisher: Springer Science and Business Media LLC
Date: 29-03-2018
DOI: 10.1007/S10661-018-6632-4
Abstract: Rapid socioeconomic development in the Linggi River Basin has contributed to the significant increase of pollution discharge into the Linggi River and its adjacent coastal areas. The toxic element contents and distributions in the sediment s les collected along the Linggi River were determined using neutron activation analysis (NAA) and inductively coupled plasma-mass spectrometry (ICP-MS) techniques. The measured mean concentration of As, Cd, Pb, Sb, U, Th and Zn is relatively higher compared to the continental crust value of the respective element. Most of the elements (As, Cr, Fe, Pb, Sb and Zn) exceeded the freshwater sediment quality guideline-threshold effect concentration (FSQG-TEC) value. Downstream stations of the Linggi River showed that As concentrations in sediment exceeded the freshwater sediment quality guideline-probable effect concentration (FSQG-PEC) value. This indicates that the concentration of As will give an adverse effect to the growth of sediment-dwelling organisms. Generally, the Linggi River sediment can be categorised as unpolluted to strongly polluted and unpolluted to strongly to extremely polluted. The correlation matrix of metal-metal relationship, principle component analysis (PCA) and cluster analysis (CA) indicates that the pollution sources of Cu, Ni, Zn, Cd and Pb in sediments of the Linggi River originated from the industry of electronics and electroplating. Elements of As, Cr, Sb and Fe mainly originated from motor-vehicle workshops and metal work, whilst U and Th originated from natural processes such as terrestrial runoff and land erosion.
Publisher: Wiley
Date: 07-2010
DOI: 10.1002/APJ.446
Publisher: Wydawnictwo Naukowe Gabriel Borowski (WNGB)
Date: 03-07-2023
Publisher: IWA Publishing
Date: 09-2010
DOI: 10.2166/WST.2010.388
Abstract: An agricultural waste derived adsorbent was prepared by chemically modified barley straw with NaOH and a cationic surfactant hexadecylpyridinium chloride monohydrate (CPC). The prepared adsorbent, BMBS, was used for removal of anionic dyes Acid Blue (AB40) and Reactive Blue 4 (RB4) from aqueous solution in a batch adsorption system. The adsorbent was characterized by FT-IR and elemental composition. The stability of CPC adsorbed on straw surface was also evaluated by exposing to aqueous solution. In adsorption tests, influence of operation parameters such as contact time, initial concentration and pH of solution on AB40 and RB4 uptake were investigated and discussed. The CPC was observed strongly attached to straw surface and removal percentage of AB40 and RB4 was increased with increasing in contact time. The adsorption of dyes on modified straw surface was favorable at high acidic condition and desorption was found relatively low upon exposing to the desorption agent (i.e water). Dynamic experiment revealed that the kinetic data fitted well to the pseudo-second-order model for both of the dyes. The isotherm study also indicated that RB4 and AB40 adsorption suited well with the Langmuir model, The maximum adsorption capacity determined from the Langmuir isotherm at 25°C was 51.95 mg g−1 and 31.5 for AB40 and RB4, respectively.
Publisher: Trans Tech Publications, Ltd.
Date: 08-2018
DOI: 10.4028/WWW.SCIENTIFIC.NET/KEM.775.359
Abstract: Cogon grass (Imperata cylindrica), an invasive, unwanted grass was used and evaluated for its applicability for the sorption of engine oil. Other than dried and ground for smaller size, no notable treatment was performed on the cogon grass. The physical and chemical properties of cogon grass were characterized by ash content, bulk density, pH slurry, and Field Emission Scanning Electron Microscopy (FESEM). The oil sorption was performed in a batch adsorption system. The effects of contact time, dosage of adsorbent and oil retention were investigated. The bulk density and ash content of the prepared carbon was 0.34 g/ml and 7.80 %, respectively. The pH slurry value was near neutrality (6.48). FESEM micrograph of cogon grass showed jagged and rough surface. FTIR spectra revealed the presence of aromatic rings of lignin and some aromatic compounds associated with CH. Carbon, hydrogen and nitrogen (CHN) analysis revealed that 41% of cogon grass consists of carbon. The cogon grass was observed to wet oil almost instantly with sorption equilibrium time of 5 min. The dose of cogon grass was found to slightly affect the sorption capacity. Oil retention experiments reveal the good ability of cogon grass to hold oil with about 96% retention after 24 h dripping. This study may provide an insight on the usefulness of cogon grass for removal of engine oils.
Publisher: Technoscience Publications
Date: 12-2020
Publisher: Trans Tech Publications, Ltd.
Date: 02-2014
DOI: 10.4028/WWW.SCIENTIFIC.NET/AMR.896.288
Abstract: The removal of Pb(II) from aqueous solutions by citric acid modified rubber leaf powder (CARL) was investigated. The higher adsorptive removal of Pb(II) from aqueous solutions by CARL compared to untreated rubber leaf powder was due to the presence of more carboxylic functional groups in the former system. Batch adsorption experiments were conducted to study the effect of pH, contact time for the removal of Pb(II) from Pb(II) aqueous systems and the mechanism of adsorption process was studied by kinetic models, pseudo-first and pseudo-second order kinetic models. The functional groups on CARL played an important role in the adsorption of Pb(II). The kinetic and equilibrium adsorption data were well modeled using pseudo-first-order kinetics. Normal 0 21 false false false MS X-NONE X-NONE /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal" mso-tstyle-rowband-size:0 mso-tstyle-colband-size:0 mso-style-noshow:yes mso-style-priority:99 mso-style-qformat:yes mso-style-parent:"" mso-padding-alt:0cm 5.4pt 0cm 5.4pt mso-para-margin:0cm mso-para-margin-bottom:.0001pt mso-pagination:widow-orphan font-size:10.0pt font-family:"Calibri","sans-serif" mso-fareast-font-family:Calibri mso-bidi-font-family:"Times New Roman" }
Publisher: Science Alert
Date: 15-07-2006
Publisher: Elsevier BV
Date: 09-2019
DOI: 10.1016/J.APRADISO.2019.05.038
Abstract: A study was carried out to determine the concentrations of rare earth elements (REEs) in Linggi river sediments collected from 113 s ling locations. The sediment analysis was performed by Neutron activation analysis (NAA) and Inductively coupled plasma - mass spectrometry (ICP-MS). The results of Linggi river sediment were normalized to "recent" reference shale values. The means of total concentrations of REEs (ΣREE), light REEs (ΣLREE) and heavy REEs (ΣHREE) in Linggi sediment were 241.2, 219.2, and 22.0 mg/kg, respectively, which indicates enrichment compared to ΣREE, ΣLREE and ΣHREE reference shale values. Results obtained from enrichment factors (EF) show no enrichment to moderate enrichment of Linggi sediments, indicating the sources of REEs pollution originated from natural and land-based activities. A similar pattern was observed by comparing the REEs values of Linggi sediments to other references shale values. Ce (δCe) and Eu (δEu) anomalies indicate Linggi sediments showed positive anomaly of Ce whilst negative anomaly of Eu.
Publisher: Science Alert
Date: 03-2006
Publisher: Elsevier BV
Date: 03-2023
Publisher: Technoscience Publications
Date: 12-2021
DOI: 10.46488/NEPT.2021.V20I04.034
Abstract: The feasibility of Mengkuang leaves (Pandanus atrocarpus) as a non-conventional low-cost adsorbent for the removal of an anionic dye, Reactive Orange 16 (RO16), was investigated. Among the dyes that have been commonly used in the Batik industry was reactive dye. In this study, Mengkuang leaves were chemically modified with cetyltrimethylammonium bromide (CTAB), a cationic surfactant, to improve their adsorption performance toward anionic dyes. The adsorbent’s morphological characteristics were analyzed using a scanning electron microscope (SEM). The surface of modified Mengkuang leaves seems to be irregular and uneven, with more porous structures than raw Mengkuang leaves. Adsorption of RO16 dye in fixed bed column using modified Mengkuang leaves adsorbent indicated the breakthrough time increased at higher bed height and lower flow rate. The breakthrough times for bed height of 0.5, 2, and 4 cm were at 16, 68, and 165 min, respectively. Meanwhile, breakthrough time for the flow rate of 2,5 and 7 mL.min-1 were at 327, 104, and 43 min, respectively. However, the study utilizing raw Mengkuang leaves showed no significant removal of RO16. Thus, it can be concluded that the cationic surfactant modification of Mengkuang leaves is advantageous for anionic dye removal. This anionic dye removal is significantly influenced by column parameters such as bed height and flow rate as the plotted breakthrough curves obtained from experimental data were similar to the typical breakthrough curve. When applied to the Yoon-Nelson model, the adsorption data provided the best fit with the R2 value above 0.95. The time taken for the breakthrough is very similar to model prediction values. Experiments with real batik dye wastewater showed the immense potential of modified Mengkuang leaves where total removal of real Batik wastewater was instantaneous.
Publisher: Elsevier BV
Date: 08-2019
Publisher: Elsevier BV
Date: 12-2018
DOI: 10.1016/J.MARPOLBUL.2018.11.006
Abstract: In this study, concentrations of heavy metals, rare earth elements (REEs), Uranium (U) and Thorium (Th) of the actinide group were determined from Linggi estuary sediment s les by neutron activation analysis (NAA) and inductive coupled plasma - mass spectrometry techniques. The geo-accumulation (I
Publisher: Trans Tech Publications, Ltd.
Date: 03-2017
DOI: 10.4028/WWW.SCIENTIFIC.NET/MSF.889.221
Abstract: Cocoa pod husk, an agricultural waste was chemically modified using Zinc Chloride (ZnCl 2 ) and used as an adsorbent for removal of acid dyes (i) Acid Violet 17 (AV17) and (ii) Acid Yellow 36 (AY36) from aqueous solution. The raw (CPHC) and chemically modified cocoa pod husk carbon (ZCPHC) were characterized by Field Emission Scanning Electron Microscopy (FESEM) and Energy Dispersive X-ray (EDX). The adsorption was performed on removing AV17 and AY36 from aqueous solution in batch adsorption system. The experimental data was simulated using Langmuir and Freundlich isotherm models. The isotherm study revealed that the AV17 adsorption on ZCPHC matched well with the Langmuir model, whereas AY36 adsorption on ZCPHC fitted well with Freundlich model. The maximum adsorption capacity determined from the Langmuir isotherm was 11.02 mg/g and 11.37 mg/g for AV17 and AY36 respectively at room temperature.
Publisher: Technoscience Publications
Date: 06-03-2022
DOI: 10.46488/NEPT.2022.V21I01.024
Abstract: This work presented the adsorption of Cu(II) ions using agriculture waste coming from soursop (Annona muricata L.) seeds. The chemical treatment performed on Annona muricata L. seeds was carried out using 1.0 M H2SO4 solutions. The Fourier-transform infrared (FTIR) spectrophotometer, scanning electron microscope coupled with energy dispersive X-ray (SEM-EDX), pH of point-zero-charge (pHPZC), and pHslurry analyses were done to characterize the surface properties of the adsorbent. Experimental conditions such as contact time, adsorbent dosage, pH, and initial Cu(II) ion concentrations, all of which could affect Cu(II) ions adsorption, were studied. The adsorption kinetics was successfully described by the pseudo-second-order model. The Langmuir and Freundlich models were applied to interpret the Cu(II) ions’ adsorption at equilibrium. The isotherm data fitted well with the Freundlich model and the maximum adsorption capacity was 187.83 mg.g-1 based on the Langmuir model.
Publisher: Desalination Publications
Date: 2020
Publisher: Science Alert
Date: 02-2007
Publisher: Trans Tech Publications, Ltd.
Date: 06-2014
DOI: 10.4028/WWW.SCIENTIFIC.NET/AMR.970.198
Abstract: Monosodium glutamate functionalized chitosan (MSGC) beads were synthesized and used as an adsorbent for recovering precious cerium ion from aqueous solutions. Several parameters which can affect adsorption efficiency such as effect of pH and adsorbent dosage have been investigated. The optimum pH for Ce (III) adsorption was 4. The rate of Ce (III) uptake was fast as the time to reach equilibrium was less than 10 min. Based on the applied kinetic model, Ce (III) adsorption onto MSGC fitted well with pseudo-second-order model. The maximum adsorption capacity recorded from the Langmuir isotherm model was 369.0 mg g -1 at 300 K.
Publisher: Penerbit UMT, Universiti Malaysia Terengganu
Date: 2020
No related grants have been discovered for Shariff Ibrahim.