ORCID Profile
0000-0001-8521-4515
Current Organisation
COMSATS Institute of Information Technology
Does something not look right? The information on this page has been harvested from data sources that may not be up to date. We continue to work with information providers to improve coverage and quality. To report an issue, use the Feedback Form.
Publisher: Elsevier BV
Date: 04-2018
DOI: 10.1016/J.SCITOTENV.2017.10.063
Abstract: In this study, we examined the sorption of arsenite (As(III)) and arsenate (As(V)) to Japanese oak wood-derived biochar (OW-BC) in aqueous solutions, and determined its efficiency to remove As from As-contaminated well water. Results revealed that, among the four sorption isotherm models, Langmuir model showed the best fit to describe As(III) and As(V) sorption on OW-BC, with slightly greater sorption affinity for As(V) compared to As(III) (Q
Publisher: Informa UK Limited
Date: 15-11-2019
Publisher: Springer Science and Business Media LLC
Date: 05-11-2018
DOI: 10.1007/S11356-018-3605-7
Abstract: Soil contamination with heavy metals is a global issue confronting the environmental pollution and human/animal health. Much work has been done on physiological and antioxidant responses of wheat in hydroponic experiments and health risks from in idual heavy metal contamination to human, but limited information is available on their combined application in soil. Therefore, this pot study delineates the uptake of lead and cadmium, as well as physiological responses of wheat and associated health risks under different levels of alone and combined Cd and Pb treatments. Metal uptake increased with their increasing applied levels. The highest Cd (4.24, 1.38, and 0.92 mg kg
Publisher: Springer Science and Business Media LLC
Date: 30-09-2022
DOI: 10.1007/S10653-022-01402-W
Abstract: Water contamination by arsenic (As) is widespread and is posing serious health threats globally. Hence, As removal techniques/adsorbents need to be explored to minimize potentials hazards of drinking As-contaminated waters. A column scale sorption experiment was performed to assess the potential of three biosorbents (tea waste, wheat straw and peanut shells) to remove As (50, 100, 200 and 400 µg L
Publisher: Springer Science and Business Media LLC
Date: 12-10-2017
Publisher: Springer Science and Business Media LLC
Date: 18-09-2019
DOI: 10.1007/S11356-018-3169-6
Abstract: This study is based on self-reported information collected from selected farmers of Vehari District, Punjab, Pakistan, to determine their technical knowledge and awareness about pesticide use and associated environmental and health risks. Moreover, soil contamination by routinely used persistent organochlorine pesticide, endosulfan, was also evaluated. Survey data revealed very low literacy rate (on an average 9th grade education) and technical knowledge (almost missing) of the farmers in Vehari District. The farmers are unable to fully read and understand the instructions about the use of pesticide marked on the containers. They are not fully aware of pesticide persistence and toxicity (73%), unable to identify cotton pests and diseases (86%), and do not know which crop to grow in cotton adjacent fields (100%). Data also revealed that the farmers (100%) do not follow safety measure during pesticide application and are unaware of pesticide toxicity symptoms in human as well as the basic first-aid practices (89%).Poor literacy rate and lack of technical knowledge of farmers in Vehari regarding pesticide use and handling are posing serious environmental and health risks among the local inhabitants, particularly among farmers. Soil analysis results showed that concentration of α- and β-endosulfan ranged from 0-14 to 0-14.64 μg/mg, respectively. Principal component analysis showed that soil organic matter is the key soil parameter controlling the occurrence and fate of endosulfan under sandy loam soil conditions of Vehari District. There is a serious need of improving technical and environmental knowledge of farmer about pesticide risks on human health in the studied area, in particular, and the entire country in general. Findings are of great use for policymaking in Pakistan to minimize pesticide risks in Pakistan.
Publisher: Informa UK Limited
Date: 03-2019
DOI: 10.1080/15226514.2018.1540539
Abstract: Cadmium (Cd) phytoremediation potential and its accumulation in edible and nonedible plant tissues is the function of various biochemical processes taking place inside plants. This study assessed the impact of organic ligands on Cd phyto uptake and different biophysiochemical processes of Spinacia oleracea L., and associated health hazards. Plants were exposed to Cd alone and chelated with citric acid (CA) and ethylenediaminetetraacetic acid (EDTA). Results revealed that the effect of Cd on lipid peroxidation, H
Publisher: Springer International Publishing
Date: 2019
Publisher: Elsevier BV
Date: 10-2017
DOI: 10.1016/J.ECOENV.2017.06.004
Abstract: Silicon (Si) is the 2nd most abundant element in soil which is known to enhance stress tolerance in wide variety of crops. Arsenic (As), a toxic metalloid enters into the human food chain through contaminated water and food or feed. To alleviate the deleterious effect of As on human health, it is a need of time to find out an effective strategy to reduce the As accumulation in the food chain. The experiments were conducted during September-December 2014, and 2016 to optimize Si concentration for rice (Oryza sativa L.) exposed to As stress. Further experiment were carried out to evaluate the effect of optimum Si on rice seed germination, seedling growth, phosphorus and As uptake in rice plant. During laboratory experiment, rice seeds were exposed to 150 and 300µM As with and without 3mM Si supplementation. Results revealed that As application, decreased the germination up to 40-50% as compared to control treatment. Arsenic stress also significantly (P < 0.05) reduced the seedling length but Si supplementation enhanced the seedlings length. Maximum seedling length (4.94cm) was recorded for 3mM Si treatment while, minimum seedling length (0.60cm) was observed at day7 by the application of 300µM As. Silicon application resulted in 10% higher seedling length than the control treatment. In soil culture experiment, plants were exposed to same concentrations of As and Si under aerobic and anaerobic conditions. Irrigation water management, significantly (P˂0.05) affected the plant growth, Si and As concentrations in the plant. Arsenic uptake was relatively less under aerobic conditions. The maximum As concentration (9.34 and 27.70mgkg DW
Publisher: Elsevier BV
Date: 2018
DOI: 10.1016/J.ENVPOL.2017.09.051
Abstract: In this study, we examined the removal of arsenite (As(III)) and arsenate (As(V)) by perilla leaf-derived biochars produced at 300 and 700 °C (referred as BC300 and BC700) in aqueous environments. Results revealed that the Langmuir isotherm model provided the best fit for As(III) and As(V) sorption, with the sorption affinity following the order: BC700-As(III) > BC700-As(V) > BC300-As(III) > BC300-As(V) (Q
Publisher: Springer International Publishing
Date: 2017
Publisher: Elsevier BV
Date: 06-2019
DOI: 10.1016/J.ENVINT.2019.03.039
Abstract: Trace elements (TEs) may have toxic effects to plants and humans thus, countries and organizations impose maximum allowable regulation limits of their concentrations in soils. Usually such limits are placed in different categories according to soil use, soil properties or based on both attributes. However, some countries have regulation limits irrespective of differentiation in soil properties. In this review, we aimed at collecting TE regulation limits in soils from major countries and organizations around the globe, and critiquing them by assessing potential human health risks in the case of soils attaining the maximum allowable values. We explored the soil-to-human pathway and differentiated among three major exposures from TEs, i.e., residential, industrial and agricultural. We observed the existence of problems concerning TE regulation limits, among which the fact that limits across countries do not regulate the same TEs, not even a minimum number of TEs. This indicates that countries do not seem to agree on which regulation limits of TEs pose a high risk. Also, these regulation limits do not take into account TE mobility to neighbouring environment interphases such as plant, especially edible, and water matrices. Moreover, limits for same TEs are vastly erse across countries this indicates that those countries have conflicting information concerning TE-related health risks. Subsequently, we addressed this problem of ersity by quantifying resultant risks we did that by calculating human health risk indices, taking into consideration the cases in which the highest allowable TE limits are attained in soil. Arsenic limits were found to generate a relatively high hazard quotient (HQ
Publisher: Springer Science and Business Media LLC
Date: 27-12-2200
DOI: 10.1007/S41748-022-00336-8
Abstract: While the potential of biochar (BC) to immobilize potentially toxic elements (PTEs) in contaminated soils has been studied and reviewed, no review has focused on the potential use of BC for enhancing the phytoremediation efficacy of PTE-contaminated soils. Consequently, the overarching purpose in this study is to critically review the effects of BC on the mobilization, phytoextraction, phytostabilization, and bioremediation of PTEs in contaminated soils. Potential mechanisms of the interactions between BC and PTEs in soils are also reviewed in detail. We discuss the promises and challenges of various approaches, including potential environmental implications, of BC application to PTE-contaminated soils. The properties of BC (e.g., surface functional groups, mineral content, ionic content, and π-electrons) govern its impact on the (im)mobilization of PTEs, which is complex and highly element-specific. This review demonstrates the contrary effects of BC on PTE mobilization and highlights possible opportunities for using BC as a mobilizing agent for enhancing phytoremediation of PTEs-contaminated soils.
Publisher: Elsevier BV
Date: 06-2021
Publisher: Elsevier BV
Date: 06-2019
DOI: 10.1016/J.SCITOTENV.2019.03.062
Abstract: Removal of cadmium (Cd
Publisher: Springer Science and Business Media LLC
Date: 09-07-2018
DOI: 10.1007/S11356-018-2689-4
Abstract: The current study investigated the influence of organic amendments on cadmium (Cd) uptake and its effects on biochemical attributes of young and old leaves of bean. Bean seedlings were exposed to two levels of Cd (25 and 100 μM) in the presence and absence of different levels of ethylenediaminetetraacetic acid (EDTA) and citric acid (CA). An increase in Cd concentration in growth medium significantly enhanced Cd accumulation in bean roots and shoot. Cadmium stress increased the production of H
Publisher: Springer Science and Business Media LLC
Date: 11-02-2014
Publisher: Elsevier BV
Date: 09-2020
Publisher: Springer Science and Business Media LLC
Date: 15-09-2021
DOI: 10.1007/S10653-021-01093-9
Abstract: Plant redox homeostasis governs the uptake, toxicity and tolerance mechanism of toxic trace elements and thereby elucidates the remediation potential of a plant. Moreover, plant toxicity/tolerance mechanisms control the trace element compartmentation in edible and non-edible plant organs as well as the associated health hazards. Therefore, it is imperative to unravel the cellular mechanism involved in trace element toxicity and tolerance. The present study investigated the toxicity and tolerance/detoxification mechanisms of four levels of arsenic (As(III): 0, 5, 25 and 125 µM) in Brassica oleracea under hydroponic cultivation. Increasing As levels significantly decreased the pigment contents (up to 68%) of B. oleracea. Plants under As stress showed an increase in H
Publisher: MDPI AG
Date: 02-01-2018
Publisher: MDPI AG
Date: 18-01-2023
DOI: 10.3390/W15030391
Abstract: Chromium (Cr)-contaminated tannery wastewater is a major environmental concern, especially in developing countries, such as Pakistan, due to its use for crop irrigation, resulting in food-chain contamination and health issues. In this study, we explored the distribution, speciation, hydrogeochemical behavior and environmental risks of Cr in tannery wastewater collected from various tanneries of Kasur district in Punjab, Pakistan. Tannery wastewater s les were taken during the summer (TWW-summer n = 82) and winter (TWW-winter n = 82) seasons. The results showed that high Cr concentration was observed in TWW-winter (mean: 49 ± 32 mg L−1) compared to TWW-summer (mean: 15 ± 21 mg L−1). In TWW-summer and TWW-winter s les, the Cr concentration exceeded the National Environmental Quality Standard (1 mg L−1), with the total Cr ranging from 2.8 to 125 mg L−1. Hexavalent Cr (Cr(VI)) and trivalent Cr (Cr(III)) concentrations spanned 2.7 to 2.9 and 12.4 to 46 mg L−1, respectively. The Piper plot showed that hydrogeochemistry of wastewater was dominated by Ca-Mg-SO4 and Ca-Mg-Cl type water, and geochemical modeling indicated that the presence of Cr-iron (Fe)-bearing mineral phases—notably, FeCr2O4, MgCr2O4 and Cr(OH)3) may control the fate of Cr in the tannery wastewater. Environmental risk assessment modeling categorized the tannery wastewater as the ‘worst quality’, which is not fit for use in crop irrigation without treatment. This study highlights that immediate monitoring, remediation and mitigation strategies are required to reduce the risk of Cr exposure from tannery wastewater in many areas of Pakistan.
Publisher: Elsevier BV
Date: 04-2020
DOI: 10.1016/J.SCITOTENV.2019.134749
Abstract: Environmental contamination by a non-essential and non-beneficial, although potentially toxic mercury (Hg), is becoming a great threat to the living organisms at a global scale. Owing to its various uses in numerous industrial processes, high amount of Hg is released into different environmental compartments. Environmental Hg contamination can result in food chain contamination, especially due to its accumulation in edible plant parts. Consumption of Hg-rich food is a key source of Hg exposure to humans. Since Hg does not possess any identified biological role and has genotoxic and carcinogenic potential, it is critical to monitor its biogeochemical behavior in the soil-plant system and its influence in terms of possible food chain contamination and human exposure. This review traces a plausible link among Hg levels, its chemical speciation and phytoavailability in soil, accumulation in plants, phytotoxicity and detoxification of Hg inside the plant. The role of different enzymatic (peroxidase, catalase, ascorbate peroxidase, superoxide dismutase, glutathione peroxidase) and non-enzymatic (glutathione, phytochelatins, proline and ascorbic acid) antioxidants has also been elucidated with respect to enhanced generation of reactive radicles and resulting oxidative stress. The review also outlines Hg build-up in edible plant tissues and associated health risks. The biogeochemical role of Hg in the soil-plant system and associated health risks have been described with well summarized and up-to-date data in 12 tables and 4 figures. We believe that this comprehensive review article and meta-analysis of Hg data can be greatly valuable for scientists, researchers, policymakers and graduate-level students.
Publisher: Springer International Publishing
Date: 2016
Publisher: Elsevier BV
Date: 07-2019
Publisher: Springer Science and Business Media LLC
Date: 10-02-2018
DOI: 10.1007/S11356-018-1276-Z
Abstract: Currently, several news channels and research publications have highlighted the dilemma of arsenic (As)-contaminated groundwater in Pakistan. However, there is lack of data regarding groundwater As content of various areas in Pakistan. The present study evaluated As contamination and associated health risks in previously unexplored groundwater of Hasilpur-Pakistan. Total of 61 groundwater s les were collected from different areas (rural and urban), sources (electric pump, hand pump, and tubewell) and depths (35-430 ft or 11-131 m). The water s les were analyzed for As level and other parameters such as pH, electrical conductivity, total dissolved solids, cations, and anions. It was found that 41% (25 out of 61) water s les contained As (≥ 5 μg/L). Out of 25 As-contaminated water s les, 13 water s les exceeded the permissible level of WHO (10 μg/L). High As contents have been found in tubewell s les and at high s ling depths (> 300 ft). The major As-contaminated groundwater in Hasilpur is found in urban areas. Furthermore, health risk and cancer risk due to As contamination were also assessed with respect to average daily dose (ADD), hazard quotient (HQ), and carcinogenic risk (CR). The values of HQ and CR of As in Hasilpur were up to 58 and 0.00231, respectively. Multivariate analysis revealed a positive correlation between groundwater As contents, pH, and depth in Hasilpur. The current study proposed the proper monitoring and management of well water in Hasilpur to minimize the As-associated health hazards.
Publisher: MDPI AG
Date: 05-10-2015
Publisher: Springer Science and Business Media LLC
Date: 05-03-2019
DOI: 10.1007/S11356-019-04540-4
Abstract: Nickel (Ni) is a ubiquitous and highly important heavy metal. At low levels, Ni plays an essential role in plants such as its role in urease, superoxide dismutase, methyl-coenzyme M reductase, hydrogenase, acetyl-coenzyme A synthase, and carbon monoxide dehydrogenase enzyme. Although its deficiency in crops is very uncommon, but in the past few years, many studies have demonstrated Ni deficiency symptoms in plants. On the other hand, high levels of applied Ni can provoke numerous toxic effects (such as biochemical, physiological, and morphological) in plant tissues. Most importantly, from an ecological and risk assessment point of view, this metal has narrow ranges of its essential, beneficial, and toxic concentrations to plants, which significantly vary with plant species. This implies that it is of great importance to monitor the levels of Ni in different environmental compartments from which it can enter plants. Additionally, several abiotic stresses (such as salinity and drought) have been reported to affect the biogeochemical behavior of Ni in the soil-plant system. Thus, it is also important to assess Ni behavior critically under different abiotic stresses, which can greatly affect its role being an essential or toxic element. This review summarizes and critically discusses data about sources, bioavailability, and adsorption/desorption of Ni in soil its soil-plant transfer and effect on other competing ions accumulation in different plant tissues essential and toxic effects inside plants and tolerance mechanisms adopted by plants under Ni stress.
Publisher: Springer Science and Business Media LLC
Date: 24-05-2017
DOI: 10.1007/S11356-017-9230-Z
Abstract: The current study examined the effect of calcium (Ca) and ethylenediaminetetraacetic acid (EDTA) on arsenic (As) uptake and toxicity to spinach (Spinacia oleracea) as well as assessed the potential human health risks. Spinach seedlings were exposed to three levels of As (25, 125, and 250 μM) alone or together with three levels of EDTA (25, 125, and 250 μM) and Ca (1, 5, and 10 mM). The effect of EDTA and Ca was assessed in terms of As contents in roots and shoots, hydrogen peroxide production, chlorophyll contents, and lipid peroxidation. The accumulation and toxicity of As to spinach plants increased with increasing As levels in nutrient solution. Exposure to As resulted in lipid peroxidation and reduced chlorophyll contents. The highest level of As alone (250 μM) showed highest human health risk (hazard quotient of 7.09 at As-250). Addition of EDTA enhanced As accumulation by spinach, while reduced As toxicity to spinach, as well as human health risk (hazard quotient of 4.01 at As-250). Similarly, Ca significantly reduced As toxicity to spinach and the human health risks (hazard quotient of 3.79 at As-250) by reducing its accumulation in spinach. Higher levels of Ca were more effective in reducing As uptake and toxicity as well as enhancing chlorophyll contents.
Publisher: Springer Science and Business Media LLC
Date: 24-03-2017
Publisher: Informa UK Limited
Date: 27-10-2015
Publisher: Springer Science and Business Media LLC
Date: 02-04-2021
Publisher: Informa UK Limited
Date: 16-12-2014
Publisher: Elsevier BV
Date: 02-2022
DOI: 10.1016/J.CHEMOSPHERE.2021.133203
Abstract: Use of untreated municipal wastewater (WW) contains toxic trace elements that pose a serious threat to the soil-plant-human continuum. The use of biochar (BC) is a promising approach to minimize trace element induced toxicity in the ecosystem. Therefore, the present study aims to evaluate the efficacy of BC derived from wheat straw and iron oxide nanoparticles doped biochar (IO-BC) to reduce trace element buildup in soil and plants that consequently affect tomato plant growth and physiological activity under WW irrigation. The BC and IO-BC were applied at four levels (0, 0.5, 1, and 1.5%) in WW irrigated soils. The results indicated that the addition of WW + BC and WW + IO-BC resulted in significant reduction in trace element mobility in soil. Interestingly, the application of WW + IO-BC (1.5%) was more effective in reducing trace element mobility and bioavailability in soil by 78% (As), 58% (Cr), 46% (Pb) and 50% (Cd) compared to WW irrigation, and thus reduced trace element accumulation and toxicity in plants. Results revealed that WW irrigation negatively affected tomato growth, fruit yield, physiology and antioxidative response. Addition of WW + BC and WW + IO-BC ameliorated the oxidative stress (up to 65% and 58% in H
Publisher: Elsevier BV
Date: 09-2021
Publisher: Springer Science and Business Media LLC
Date: 24-11-2020
Publisher: Elsevier BV
Date: 03-2017
DOI: 10.1016/J.JHAZMAT.2016.11.063
Abstract: Anthropologic activities have transformed global biogeochemical cycling of heavy metals by emitting considerable quantities of these metals into the atmosphere from erse sources. In spite of substantial and progressive developments in industrial processes and techniques to reduce environmental emissions, atmospheric contamination by toxic heavy metals and associated ecological and health risks are still newsworthy. Atmospheric heavy metals may be absorbed via foliar organs of plants after wet or dry deposition of atmospheric fallouts on plant canopy. Unlike root metal transfer, which has been largely studied, little is known about heavy metal uptake by plant leaves from the atmosphere. To the best of our understanding, significant research gaps exist regarding foliar heavy metal uptake. This is the first review regarding biogeochemical behaviour of heavy metals in atmosphere-plant system. The review summarizes the mechanisms involved in foliar heavy metal uptake, transfer, compartmentation, toxicity and in plant detoxification. We have described the biological and environmental factors that affect foliar uptake of heavy metals and compared the biogeochemical behaviour (uptake, translocation, compartmentation, toxicity and detoxification) of heavy metals for root and foliar uptake. The possible health risks associated with the consumption of heavy metal-laced food are also discussed.
Publisher: Elsevier BV
Date: 07-2017
DOI: 10.1016/J.CHEMOSPHERE.2017.03.074
Abstract: Chromium (Cr) is a potentially toxic heavy metal which does not have any essential metabolic function in plants. Various past and recent studies highlight the biogeochemistry of Cr in the soil-plant system. This review traces a plausible link among Cr speciation, bioavailability, phytouptake, phytotoxicity and detoxification based on available data, especially published from 2010 to 2016. Chromium occurs in different chemical forms (primarily as chromite (Cr(III)) and chromate (Cr(VI)) in soil which vary markedly in term of their biogeochemical behavior. Chromium behavior in soil, its soil-plant transfer and accumulation in different plant parts vary with its chemical form, plant type and soil physico-chemical properties. Soil microbial community plays a key role in governing Cr speciation and behavior in soil. Chromium does not have any specific transporter for its uptake by plants and it primarily enters the plants through specific and non-specific channels of essential ions. Chromium accumulates predominantly in plant root tissues with very limited translocation to shoots. Inside plants, Cr provokes numerous deleterious effects to several physiological, morphological, and biochemical processes. Chromium induces phytotoxicity by interfering plant growth, nutrient uptake and photosynthesis, inducing enhanced generation of reactive oxygen species, causing lipid peroxidation and altering the antioxidant activities. Plants tolerate Cr toxicity via various defense mechanisms such as complexation by organic ligands, compartmentation into the vacuole, and scavenging ROS via antioxidative enzymes. Consumption of Cr-contaminated-food can cause human health risks by inducing severe clinical conditions. Therefore, there is a dire need to monitor biogeochemical behavior of Cr in soil-plant system.
Publisher: Elsevier BV
Date: 2022
DOI: 10.1016/J.JHAZMAT.2021.126926
Abstract: Water scarcity is a major threat to agriculture and humans due to over abstraction of groundwater, rapid urbanization and improper use in industrial processes. Industrial consumption of water is lower than the abstraction rate, which ultimately produces large amounts of wastewater such as from tannery industry containing high concentration of chromium (Cr). Chromium-contaminated tannery industry wastewater is used for irrigation of food crops, resulting in food safety and public health issues globally. In contrast to conventional treatment technologies, constructed wetlands (CWs) are considered as an eco-friendly technique to treat various types of wastewaters, although their application and potential have not been discussed and elaborated for Cr treatment of tannery wastewater. This review briefly describes Cr occurrence, distribution and speciation in aquatic ecosystems. The significance of wetland plant species, microorganisms, various bedding media and adsorbents have been discussed with a particular emphasis on the removal and detoxification of Cr in CWs. Also, the efficiency of various types of CWs is elaborated for advancing our understanding on Cr removal efficiency and Cr partitioning in various compartments of the CWs. The review covers important aspects to use CWs for treatment of Cr-rich tannery wastewater that are key to meet UN's Sustainable Development Goals.
Publisher: Springer International Publishing
Date: 2016
DOI: 10.1007/398_2016_8
Abstract: This review summarizes the findings of the most recent studies, published from 2000 to 2016, which focus on the biogeochemical behavior of Cd in soil-plant systems and its impact on the ecosystem. For animals and people not subjected to a Cd-contaminated environment, consumption of Cd contaminated food (vegetables, cereals, pulses and legumes) is the main source of Cd exposure. As Cd does not have any known biological function, and can further cause serious deleterious effects both in plants and mammalian consumers, cycling of Cd within the soil-plant system is of high global relevance.The main source of Cd in soil is that which originates as emissions from various industrial processes. Within soil, Cd occurs in various chemical forms which differ greatly with respect to their lability and phytoavailability. Cadmium has a high phytoaccumulation index because of its low adsorption coefficient and high soil-plant mobility and thereby may enter the food chain. Plant uptake of Cd is believed to occur mainly via roots by specific and non-specific transporters of essential nutrients, as no Cd-specific transporter has yet been identified. Within plants, Cd causes phytotoxicity by decreasing nutrient uptake, inhibiting photosynthesis, plant growth and respiration, inducing lipid peroxidation and altering the antioxidant system and functioning of membranes. Plants tackle Cd toxicity via different defense strategies such as decreased Cd uptake or sequestration into vacuoles. In addition, various antioxidants combat Cd-induced overproduction of ROS. Other mechanisms involve the induction of phytochelatins, glutathione and salicylic acid.
Publisher: Elsevier BV
Date: 11-2022
DOI: 10.1016/J.ENVRES.2022.114033
Abstract: There are scarce data about the accumulation pattern and risk assessment of potentially toxic elements (PTEs) in soil and associated potential ecological risks, especially in less-developed countries. This study aims to assess the pollution levels and potential ecological risks of PTEs (As, Cr, Cd, Cu, Ni, Mn, Pb and Zn) in wastewater-irrigated arable soils and different edible-grown plants in selected areas of Vehari, Pakistan. The results revealed that the values of PTEs in soil s les were higher than their respective limit values by 20% for As, 87% for Cd, 15% for Cu, 2% for Cr, 83% for Mn, 98% for Fe, and 7% for Zn. The values of soil risk indices such as the potential ecological risk (PERI >380 for all s les), pollution load index (PLI >4 for 94% of studied s les), and degree of contamination (Dc > 24 for all s les) showed severe soil contamination in the study area. Some vegetables exhibited a high metal accumulation index (e.g., 8.1 for onion), signifying potential associated health hazards. Thus, long-term wastewater irrigation has led to severe soil contamination, which can pose potential ecological risks via PTE accumulation in crops, particularly Cd. Therefore, to ensure food safety, frequent wastewater irrigation practices need to be minimized and managed in the study area.
Publisher: Informa UK Limited
Date: 02-08-2017
Publisher: Springer Science and Business Media LLC
Date: 10-09-0031
DOI: 10.1038/S41598-019-49404-6
Abstract: Coincidence of high temperature with terminal reproductive pheno-stages of cotton is chief constraint to achieve yield potential. This high temperature interfere plant defensive system, physiological process, water relations and lint yield production. In this study, we modulated the detrimental outcomes of heat stress on cotton through the foliar spray of nutrients. Cotton crop was exposed to sub-optimal and supra-optimal thermal regimes for a period of one week at squaring, flowering and boll formation stages under glass house and field conditions. Foliar spray of potassium (K-1.5%), zinc (Zn-0.2%) and boron (B-0.1%) were applied at three reproductive stages one day prior to expose high temperature regimes. High temperature increased lipid membrane damage through increased malondialdehyde (MDA) contents in cotton leaves. High temperature stress also reduced leaf chlorophyll contents, net photosynthetic rate, stomatal conductance, water potential, averaged boll weight (g) and seed cotton yield per plant. Various nutrients variably influenced growth and physiology of heat-stressed cotton plants. Zinc outclassed all other nutrients in increasing leaf SOD, CAT, POX, AsA, TPC activity, chlorophyll contents, net photosynthetic rate, stomatal conductance, water potential, boll weight and seed cotton yield per plant. For ex le, zinc improved seed cotton yield under supra-optimal thermal regime by 17% and under sub-optimal thermal regime by 12% of glasshouse study while 19% under high temperature sowing dates of field study than the water treated plants under the same temperatures. Conclusively, increasing intensities of temperature adversely affected the recorded responses of cotton and exogenous application of Zn efficaciously alleviated heat induced perturbations. Moreover, exogenous nutrients mediated upregulations in physiochemical attributes induced heat tolerance at morphological level.
Publisher: Elsevier
Date: 2019
Publisher: Elsevier
Date: 2016
Publisher: Elsevier BV
Date: 06-2021
Publisher: Springer Science and Business Media LLC
Date: 02-09-2020
Publisher: Springer Science and Business Media LLC
Date: 19-05-2021
Publisher: Informa UK Limited
Date: 11-05-2017
DOI: 10.1080/15226514.2016.1278427
Abstract: In this study, we examined the potential role of phosphate (P 0, 50, 100 mg kg
Publisher: Informa UK Limited
Date: 11-05-2017
DOI: 10.1080/15226514.2016.1278426
Abstract: In this study, we determined the effect of ethylenediaminetetraacetic acid (EDTA) and calcium (Ca) on arsenic (As) uptake and toxicity to Pisum sativum. Plants were treated with three levels of As (25, 125, and 250 µM) in the presence and absence of three levels of Ca (1, 5, and 10 mM) and EDTA (25, 125, and 250 µM). Exposure to As caused an overproduction of hydrogen peroxide (H
Publisher: Elsevier BV
Date: 07-2017
Publisher: Elsevier BV
Date: 02-2021
Publisher: Elsevier BV
Date: 11-2017
Publisher: Springer Science and Business Media LLC
Date: 03-05-2020
DOI: 10.1007/S10653-019-00306-6
Abstract: Arsenic (As) is a highly toxic and carcinogenic element. It has received considerable consideration worldwide in recent years due to its highest toxicity to human, and currently, high concentrations observed in the groundwater. Some recent media and research reports also highlighted possible As contamination of groundwater systems in Pakistan. However, there is a scarcity of data about As contents in groundwater in different areas/regions of the country. Consequently, the current study estimated the As concentration in the groundwater used for drinking purpose in 15 peri-urban sites of district Vehari, Pakistan. In total, 127 groundwater s les were collected and examined for As contents in addition to physicochemical characteristics such as temperature, electrical conductivity, pH, total soluble salts, chloride, carbonates, bicarbonates, sodium, potassium, lithium, calcium and barium. Results indicated that the groundwater s les were not fully fit for drinking purposes with several parameters, especially the alarming levels of As (mean As: 46.9 µg/L). It was found that 83% groundwater s les of peri-urban sites in district Vehari have As concentration greater than WHO lower permissible limit (10 µg/L). The risk assessment parameters (mean hazard quotient: 3.9 and mean cancer risk: 0.0018) also showed possible carcinogenic and non-carcinogenic risks associated with ingestion of As-contaminated groundwater at peri-urban sites. Based on the findings, it is anticipated that special monitoring and management of groundwater is necessary in the studied area in order to curtail the health risks associated with the use of As-contaminated drinking water. Moreover, appropriate remediation and removal of As from groundwater is also imperative for the study area before being used for drinking purpose to avoid As exposure and related risks to the local community.
Publisher: Informa UK Limited
Date: 11-2017
DOI: 10.1080/15226514.2017.1319330
Abstract: The current study evaluated the effect of groundwater and wastewater irrigation on lead (Pb) accumulation in soil and vegetables, and its associated health implications. A pot experiment was conducted in which spinach (Spinacia oleracea), radish (Raphanus sativus), and cauliflower (Brassica oleracea) were irrigated with groundwater and wastewaters containing varying concentrations of Pb. Lead contents were measured in wastewaters, soils and root and shoot of vegetables. We also measured health risk index (HRI) associated with the use of vegetables irrigated by wastewaters. Results revealed that Pb contents in groundwater and wastewater s les (range: 0.18-0.31 mg/L) were below the permissible limits (0.5 mg/L) set by the Food and Agriculture Organization (FAO). Application of Pb-containing groundwater and wastewater increased Pb concentration in soil and vegetables. Lead concentrations in all soils ranged from 10 to 31 mg/kg and were below the permissible limits of 300 mg/kg set by the European Union. Significant Pb enrichment was observed in the soils whereby all types of vegetables were grown and assessed for Pb risk. Our data showed that Pb contents, in all three vegetables (21-28 mg/kg DW), were higher than the permissible Pb limit of FAO (5 mg/kg Dry Weight (DW)). The HRI values were > 1.0 for radish and cauliflower. It is proposed that Vehari city wastewater/groundwater must be treated prior to its use for irrigation to avoid vegetable contamination by Pb, and as such for reducing Pb-induced human health risk.
Publisher: Informa UK Limited
Date: 11-2017
DOI: 10.1080/15226514.2017.1303815
Abstract: The present study was conducted to explore arsenic (As) tolerance and phytostabilization potential of the two tree species, buttonwood (Conocarpus erectus) and eastern cottonwood (Populus deltoides). Both plant species were grown in pots and were exposed to various soil As levels (control, 5, 10, 15, and 20 mg kg
Publisher: Informa UK Limited
Date: 29-03-2019
DOI: 10.1080/15226514.2018.1501340
Abstract: In this study, column-scale laboratory experiments were performed to evaluate the arsenic (As) removal efficiency of different agricultural biowastes-derived biosorbents (orange peel, banana peel, rice husk) and biochar, using As-containing solutions and As-contaminated groundwater. All the biosorbents and biochar efficiently removed (50-100%) As from groundwater (drinking well water). Arsenic removal potential of biosorbents varied with their type, As concentration, contact time, and As solution type. After 1 h, the As removal efficiency of all the biosorbents was 100%, 100% and 90% for 5, 10, and 50 µg/L As-contaminated groundwater s les, respectively and it was 50%, 90%, and 90% for 10, 50, and 100 µg/L As solutions, respectively. After 2 h, all the biosorbents and biochar removed 100% As from aqueous solutions except for 100 µg/L As solution. This showed that the biosorbents and biochar could be used to reduce As contents below the WHO safe limit of As in drinking water (10 µg/L). Fourier transform infrared (FTIR) spectroscopy indicated possible role of various surface functional moieties on biosorbents/biochar surface to remove As from solution and groundwater. This pilot-scale column study highlights that the biosorbents and biochar can be effectively used in remediation of As-contaminated groundwater, although the soluble salts in groundwater increased after treatment with biochar.
Publisher: Informa UK Limited
Date: 11-05-2017
DOI: 10.1080/15226514.2016.1256372
Abstract: In the present study, we examined sorption of chromate (Cr(VI)) to acid-activated banana peel (AABP) and organo-montmorillonite (O-mont) as a function of pH, initial Cr(VI) concentration at a sorbent dose of 4 g L
Publisher: Informa UK Limited
Date: 12-03-2021
Publisher: Springer Science and Business Media LLC
Date: 04-01-2019
DOI: 10.1007/S11356-018-04068-Z
Abstract: Reutilization of putrescible municipal solid wastes (MSW) in agriculture can provide valuable plant nutrients. However, it may pose serious noncarcinogenic health risks for a human when contaminants, especially the heavy metals in MSW, end up in plants through the waste-soil-plant continuum. This study examined the effects of composting methods viz. aerobically (AC), anaerobically (ANC), and aerobic-anaerobically (AANC) composted MSW material on (i) fertilizer value: vegetable yield, nitrogen (N) mineralization, and apparent N recovery (ANR) and (ii) associated health risks: selected heavy metal concentration, daily intake of metals (DIM), health risk index (HRI), hazard index (HI), and target hazard quotient (THQ) when applied to a loamy soil. All the aforementioned compost materials were incorporated into the sandy loam soil filled in pots and carrot and spinach were cultivated for 85 and 90 days, respectively. After soil application, between 51 and 56% of the applied organic N was mineralized from ANC material, while the values in case of AC and AANC were 26-31% and 34-40%, respectively. Consequently, dry matter yield and vegetable N uptake from composts were in the order ANC > AANC > AC (P < 0.05). Further, vegetable ANR was the highest from ANC (56 and 56%) than AANC (42 and 45%), and AC (30 and 33%) for spinach and carrot, respectively (P < 0.05). Interestingly, plant uptake of lead and cadmium was lowest from ANC as compared to AC or AANC (P < 0.05), irrespective of the vegetable type. Consequently, DIM, HRI, and THQ for these metals were substantially lower in the former as compared to the latter compost materials. Further, HI from ANC material was 50% lower over the unfertilized control indicating the absence of noncarcinogenic human health risks via vegetable intake. This all indicates that from viewpoint of sustainable waste recycling in agriculture, anaerobic composting is superior to the other composting methods.
Publisher: Springer Science and Business Media LLC
Date: 02-2022
DOI: 10.1007/S10661-022-09799-8
Abstract: Potentially hazardous element (PHE) contamination of aquifers is an issue of global concern, as this not only affects soil and plants but also exerts a negative impact on livestock. The current study assessed the extent of PHE (cadmium, copper, nickel, and lead) contamination of groundwater, soil, and forage crops in Shorkot, Punjab, Pakistan. Low concentrations of PHEs, particularly Cd and Cu, were found in drinking water which remained below detection limits. The concentrations of Ni and Pb in water s les were 0.1 and 0.06 mg L
Publisher: Springer Science and Business Media LLC
Date: 17-12-2018
DOI: 10.1007/S11356-018-3867-0
Abstract: Atmospheric contamination by heavy metal(loid)-enriched particulate matter (metal-PM) is highly topical these days because of its high persistence, toxic nature, and health risks. Globally, foliar uptake of metal(loid)s occurs for vegetables/crops grown in the vicinity of industrial or urban areas with a metal-PM-contaminated atmosphere. The current study evaluated the foliar uptake of arsenic (As), accumulation of As in different plant organs, its toxicity (in terms of ROS generation, chlorophyll degradation, and lipid peroxidation), and its defensive mechanism (antioxidant enzymes) in spinach (Spinacia oleracea) after foliar application of As in the form of nanoparticles (As-NPs). The As-NPs were prepared using a chemical method. Results indicate that spinach can absorb As via foliar pathways (0.50 to 0.73 mg/kg in leaves) and can translocate it towards root tissues (0.35 to 0.68 mg/kg). However, health risk assessment parameters showed that the As level in the edible parts of spinach was below the critical limit (hazard quotient < 1). Despite low tissue level, As-NP exposure caused phytotoxicity in terms of a decrease in plant dry biomass (up to 84%) and pigment contents (up to 38%). Furthermore, several-fold higher activities of antioxidant enzymes were observed under metal stress than control. However, no significant variation was observed in the level of hydrogen peroxide (H
Publisher: MDPI AG
Date: 29-09-2020
DOI: 10.3390/MOLECULES25194468
Abstract: Textile dyes and microbial contamination of surface water bodies have been recognized as emerging quality concerns around the globe. The simultaneous resolve of such impurities can pave the route for an amicable technological solution. This study reports the photocatalytic performance and the biocidal potential of nitrogen-doped TiO2 against reactive black 5 (RB5), a double azo dye and E. coli. Molecular docking was performed to identify and quantify the interactions of the TiO2 with β-lactamase enzyme and to predict the biocidal mechanism. The sol-gel technique was employed for the synthesis of different mol% nitrogen-doped TiO2. The synthesized photocatalysts were characterized using thermal gravimetric analysis (TGA), scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Brunauer–Emmett–Teller (BET) and diffuse reflectance spectroscopy (DRS). The effects of different synthesis and reaction parameters were studied. RB5 dye degradation was monitored by tracking shifts in the absorption spectrum and percent chemical oxygen demand (COD) removal. The best nanomaterial depicted 5.57 nm crystallite size, 49.54 m2 g−1 specific surface area, 11–40 nm particle size with spherical morphologies, and uniform distribution. The RB5 decolorization data fits well with the pseudo-first-order kinetic model, and the maximum monolayer coverage capacity for the Langmuir adsorption model was found to be 40 mg g−1 with Kads of 0.113 mg−1. The LH model yielded a higher coefficient KC (1.15 mg L−1 h−1) compared to the adsorption constant KLH (0.3084 L mg−1). 90% COD removal was achieved in 60 min of irradiation, confirmed by the disappearance of spectral peaks. The best-optimized photocatalysts showed a noticeable biocidal potential against human pathogenic strain E. coli in 150 min. The biocidal mechanism of best-optimized photocatalyst was predicted by molecular docking simulation against E. coli β-lactamase enzyme. The docking score (−7.6 kcal mol−1) and the binding interaction with the active site residues (Lys315, Thr316, and Glu272) of β-lactamase further confirmed that inhibition of β-lactamase could be a most probable mechanism of biocidal activity.
Publisher: Elsevier BV
Date: 12-2018
DOI: 10.1016/J.SCITOTENV.2018.07.218
Abstract: Contamination of groundwater with toxic arsenic (As) has become an emerging health and environmental problem around the world, which has seen significant attention amongst the scientists for development of new sorbents to remediate As-contaminated water. Here, we explored the arsenate (As(V)) and arsenite (As(III)) sorption to natural water melon rind (WMR), xanthated WMR and citric acid-modified WMR in aqueous solutions, and determined potential of the most potent sorbent for As removal in groundwater. Xanthated WMR (X-WMR) showed relatively higher As(V) and As(III) removal than the citric acid modified WMR (CA-WMR) and natural WMR. The maximum As(III) (99%) and As(V) (98%) removal was obtained at pH 8.2 and 4.6, respectively, by X-WMR at 4 mg L
Publisher: MDPI AG
Date: 05-2018
Publisher: Elsevier BV
Date: 04-2018
Publisher: Springer Science and Business Media LLC
Date: 27-02-2019
DOI: 10.1038/S41598-018-38076-3
Abstract: A correction to this article has been published and is linked from the HTML and PDF versions of this paper. The error has not been fixed in the paper.
Publisher: Elsevier BV
Date: 05-2018
DOI: 10.1016/J.CHEMOSPHERE.2018.02.002
Abstract: In this study, we tested 123 groundwater wells from five different areas of Punjab, Pakistan for arsenic (As) contamination level and species, as well as delineated hydrogeochemical behaviour of As in aquifers. Results revealed that 75% and 41% of the groundwater wells exceeded the safe As limit of World Health Organisation (WHO, 10 μg L
Publisher: Springer International Publishing
Date: 2019
DOI: 10.1007/398_2019_38
Abstract: Atmospheric contamination by heavy metal-enriched particulate matter (metal-PM) is highly topical nowadays because of its high persistence and toxic nature. Metal-PMs are emitted to the atmosphere by various natural and anthropogenic activities, the latter being the major source. After being released into the atmosphere, metal-PM can travel over a long distance and can deposit on the buildings, water, soil, and plant canopy. In this way, these metal-PMs can contaminate different parts of the ecosystem. In addition, metal-PMs can be directly inhaled by humans and induce several health effects. Therefore, it is of great importance to understand the fate and behavior of these metal-PMs in the environment. In this review, we highlighted the atmospheric contamination by metal-PMs, possible sources, speciation, transport over a long distance, and deposition on soil, plants, and buildings. This review also describes the foliar deposition and uptake of metal-PMs by plants. Moreover, the inhalation of these metal-PMs by humans and the associated health risks have been critically discussed. Finally, the article proposed some key management strategies and future perspectives along with the summary of the entire review. The abovementioned facts about the biogeochemical behavior of metal-PMs in the ecosystem have been supported with well-summarized tables (total 14) and figures (4), which make this review article highly informative and useful for researchers, scientists, students, policymakers, and the organizations involved in development and management. It is proposed that management strategies should be developed and adapted to cope with atmospheric release and contamination of metal-PM.
Publisher: Elsevier BV
Date: 2021
Publisher: CRC Press
Date: 23-08-2019
Publisher: Elsevier BV
Date: 2022
Publisher: Elsevier BV
Date: 04-2020
DOI: 10.1016/J.SCITOTENV.2019.134645
Abstract: Pesticides are extensively used in the modern agricultural system. The inefficient and extensive use of pesticides during the last 5 to 6 decades inadvertently led to serious deterioration of environmental quality with health risk to living organisms, including humans. It is important to use some environmentally-friendly and sustainable approaches to remediate, restore and maintain soil quality. Biochar has gained considerable attention globally as a promising soil amendment because it has the ability to adsorb and as such minimize the bioavailability of pesticides in soils. This review emphasizes the recent trends and implications of biochar in pesticide-contaminated soils, as well as highlights need of the pesticides use and associated environmental issues in context of the biochar application. The overarching aim of this review is to signify the role of biochar on primary processes such as effect of biochar on the persistence, mineralization, leaching and efficacy of pesticides in soil. Notably, the effects of biochar on pesticide adsorption-desorption, degradation and bioavailability under various operating roduction conditions are critically discussed. This review delineates the indirect impact of biochar on pesticides persistence in soils and proposes key recommendations for future research which are essential for the remediation and restoration of pesticides-impacted soils.
Publisher: Elsevier BV
Date: 03-2018
DOI: 10.1016/J.ENVPOL.2017.12.019
Abstract: Selenium (Se) is an essential trace element for humans and animals, although controversial for different plant species. There exists a narrow line between essential, beneficial and toxic levels of Se to living organisms which greatly varies with Se speciation, as well as the type of living organisms. Therefore, it is crucial to monitor its solid- and solution-phase speciation, exposure levels and pathways to living organisms. Consumption of Se-laced food (cereals, vegetables, legumes and pulses) is the prime source of Se exposure to humans. Thus, it is imperative to assess the biogeochemical behavior of Se in soil-plant system with respect to applied levels and speciation, which ultimately affect Se status in humans. Based on available relevant literature, this review traces a plausible link among (i) Se levels, sources, speciation, bioavailability, and effect of soil chemical properties on selenium bioavailability/speciation in soil (ii) role of different protein transporters in soil-root-shoot transfer of Se and (iii) speciation, metabolism, phytotoxicity and detoxification of Se inside plants. The toxic and beneficial effects of Se to plants have been discussed with respect to speciation and toxic/deficient concentration of Se. We highlight the significance of various enzymatic (catalase, peroxidase, superoxide dismutase, ascorbate peroxidase, glutathione peroxidase) and non-enzymatic (phytochelatins and glutathione) antioxidants which help combat Se-induced overproduction of reactive oxygen species (ROS). The review also delineates Se accumulation in edible plant parts from soils containing low or high Se levels elucidates associated health disorders or risks due to the consumption of Se-deficient or Se-rich foods discusses the potential role of Se in different human disorders/diseases.
Publisher: Springer International Publishing
Date: 2016
Publisher: Elsevier BV
Date: 11-2018
DOI: 10.1016/J.ENVPOL.2018.06.083
Abstract: Globally, millions of people who rely on groundwater for potable purposes and agriculture have been inadvertently exposed to toxic arsenic (As) because of its natural occurrence in groundwater in several countries of Asia, Europe and America. While the presence of As in groundwater and its impacts on human health have been documented in many countries, there is little information on As contamination in Pakistan. This review highlights, for the first time, the extent and severity of As-induced problems in Pakistan based on relevant published papers discusses possible sources of As contamination of aquifers and estimates As-induced potential health hazards in the country in relation to global data. Data from 43 studies (>9882 groundwater s les) were used to describe As variability in groundwater of Pakistan and for comparison with global data. The mean groundwater As content reported in these studies was 120 μg/L (range: 0.1-2090 μg/L SD: ±307). About 73% of the values for mean As contents in the 43 studies were higher than the World Health Organization (WHO) permissible limit (10 μg/L) for drinking water, while 41% were higher than the permissible limit of As in Pakistan (50 μg/L). It was observed that groundwater s les in some areas of Punjab and Sindh provinces contained high As concentrations which were almost equal to concentrations reported in the most contaminated areas of the world. We predicted that the mean values of ADD, HQ and CR were 4.4 μg kg
Publisher: Informa UK Limited
Date: 03-05-2018
DOI: 10.1080/15226514.2017.1413339
Abstract: In this study, we explored the effect of salinity on cadmium (Cd) tolerance and phytoremediation potential of Acacia nilotica. Two-month-old uniform plants of A. nilotica were grown in pots contaminated with various levels of Cd (0, 5, 10, and 15 mg kg
Publisher: Elsevier BV
Date: 02-2019
DOI: 10.1016/J.ENVINT.2018.12.049
Abstract: Globally, contamination of groundwater with toxic arsenic (As) is an environmental and public health issue given to its carcinogenic properties, thereby threatening millions of people relying on drinking As-contaminated well water. Here, we explored the efficiency of various biosorbents (egg shell, java plum seed, water chestnut shell, corn cob, tea waste and pomegranate peel) for arsenate (As(V)) and arsenite (As(III)) removal from As-contaminated water. Significantly, egg shell and java plum seed displayed the greatest As(III) elimination (78-87%) at 7 pH followed by water chestnut shell (75%), corn cob (67%), tea waste (74%) and pomegranate peel (65%). In contrast, 71% and 67% of As(V) was removed at pH 4.1 and 5.3 by egg shell and java plum seed, respectively. The maximum As(V) and As(III) sorption by all the biosorbents was obtained, notably for egg shell and java plum seed, after 2 h contact time. Langmuir isotherm and pseudo-second order models best fitted the sorption data for both forms of As. The -OH, -COOH, -NH
No related grants have been discovered for Muhammad Shahid.