ORCID Profile
0000-0002-1433-447X
Current Organisations
Universidade de São Paulo Faculdade de medicina
,
Conselho Nacional de Desenvolvimento Científico e Tecnológico
,
Hong Kong Polytechnic University
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In Research Link Australia (RLA), "Research Topics" refer to ANZSRC FOR and SEO codes. These topics are either sourced from ANZSRC FOR and SEO codes listed in researchers' related grants or generated by a large language model (LLM) based on their publications.
Functional Materials | Heat and Mass Transfer Operations | Systems engineering | Civil engineering | Materials Engineering | Interdisciplinary Engineering | Composite and Hybrid Materials | Fire safety engineering | Functional materials
Expanding Knowledge in Engineering | Expanding Knowledge in Technology |
Publisher: MDPI AG
Date: 09-04-2019
DOI: 10.3390/APP9071486
Abstract: The steam ejector is a core component of an ejector-based refrigeration system. Additionally, steam ejectors can also be potentially applied for a fire suppression system by using pressurized steam droplets to rapidly quench and extinguish the fire. The use of steam will significantly reduce the amount of water consumption and pipe flow rate compared to conventional sprinklers. However, the efficiency of the steam ejector nozzle is one of major factors that can influence the extinguishing mechanisms and the performance of pressurized steam for fire suppression. In this article, to formulate an assessment tool for studying the ideal entrainment ratio and initial flow wetness, a wet steam model has been proposed to enhance our understanding of the condensation and evaporation effects of water droplets from a numerical perspective. The entire steam-ejector system including the nozzle, mixing chamber, throat and diffuser were modeled to study the profiles in axial pressure and temperature across the system, and were compared with self-measured experimental data. In addition, the flow and heat transfer interactions between the fluid mixture and nucleating water droplets were numerically examined by comparing initial conditions with different liquid fractions, as opposed to the ideal gas assumption. With the application of the proposed wet-steam model, the numerical model showed vast improvement in the axial pressure distribution over the ideal gas model. Through numerical conditions, it was found that reducing the wetness of the secondary inlet flow will potentially optimize the system performance with a significant increase of the entrainment ratio from 0.38 to 0.47 (i.e., improvement of around 23%).
Publisher: MDPI AG
Date: 03-06-2019
Abstract: Fabricating high-performance MXene-based polymer nanocomposites is a huge challenge because of the poor dispersion and interfacial interaction of MXene nanosheets in the polymer matrix. To address the issue, MXene nanosheets were successfully exfoliated and subsequently modified by long-chain cationic agents with different chain lengths, i.e., decyltrimethylammonium bromide (DTAB), octadecyltrimethylammonium bromide (OTAB), and dihexadecyldimethylammonium bromide (DDAB). With the long-chain groups on their surface, modified Ti3C2 (MXene) nanosheets were well dispersed in N,N-dimethylformamide (DMF), resulting in the formation of uniform dispersion and strong interfacial adhesion within a polystyrene (PS) matrix. The thermal stability properties of cationic modified Ti3C2/PS nanocomposites were improved considerably with the temperatures at 5% weight loss increasing by 20 °C for DTAB-Ti3C2/PS, 25 °C for OTAB-Ti3C2/PS and 23 °C for DDAB-Ti3C2/PS, respectively. The modified MXene nanosheets also enhanced the flame-retardant properties of PS. Compared to neat PS, the peak heat release rate (PHRR) was reduced by approximately 26.4%, 21.5% and 20.8% for PS/OTAB-Ti3C2, PS/DDAB-Ti3C2 and PS/DTAB-Ti3C2, respectively. Significant reductions in CO and CO2 productions were also obtained in the cone calorimeter test and generally lower pyrolysis volatile products were recorded by PS/OTAB-Ti3C2 compared to pristine PS. These property enhancements of PS nanocomposites are attributed to the superior dispersion, catalytic and barrier effects of Ti3C2 nanosheets.
Publisher: MDPI AG
Date: 18-01-2021
DOI: 10.3390/MOLECULES26020478
Abstract: In recent years, the applications of lithium-ion batteries have emerged promptly owing to its widespread use in portable electronics and electric vehicles. Nevertheless, the safety of the battery systems has always been a global concern for the end-users. The separator is an indispensable part of lithium-ion batteries since it functions as a physical barrier for the electrode as well as an electrolyte reservoir for ionic transport. The properties of separators have direct influences on the performance of lithium-ion batteries, therefore the separators play an important role in the battery safety issue. With the rapid developments of applied materials, there have been extensive efforts to utilize these new materials as battery separators with enhanced electrical, fire, and explosion prevention performances. In this review, we aim to deliver an overview of recent advancements in numerical models on battery separators. Moreover, we summarize the physical properties of separators and benchmark selective key performance indicators. A broad picture of recent simulation studies on separators is given and a brief outlook for the future directions is also proposed.
Publisher: Elsevier BV
Date: 04-2020
Publisher: MDPI AG
Date: 03-11-2021
DOI: 10.3390/MOLECULES26216662
Abstract: Biomass-derived carbon has been recognised as a green, economic and promising flame retardant (FR) for polymer matrix. In this paper, it is considered that the two-dimensional (2D) structure of carbonised peanut shells (PS) can lead to a physical barrier effect on polymers. The carbonised s le was prepared by the three facile methods, and firstly adopted as flame retardants for epoxy resin. The results of thermal gravimetric analysis (TGA) and cone calorimeter tests indicate that the carbon combined with nano Cobalt provides the most outstanding thermal stability in the current study. With 3 wt.% addition of the FR, both peak heat release rate (pHRR) and peak smoke production rate (PSPR) decrease by 37.9% and 33.3%, correspondingly. The flame retardancy mechanisms of the FR are further explored by XPS and TG-FTIR. The effectiveness of carbonised PS can be mainly attributed to the physical barrier effect derived by PS’s 2D structure and the catalysis effect from Cobalt, which contribute to form a dense char layer.
Publisher: Informa UK Limited
Date: 05-06-2015
Publisher: MDPI AG
Date: 30-01-2019
DOI: 10.3390/FIRE2010007
Abstract: In this study, a Large Eddy Simulation (LES) based fire field model was applied to numerically investigate the effectiveness of smoke control using smoke vents and curtains within a large-scale atrium fire. Two compartment configurations were considered: the first case with no smoke curtains installed, while the second case included a smoke curtain at the centre of the compartment to trap smoke. Based on the thermocouple results, it was found that the model predicted the gas temperature near the fire particularly well. The time development and heat transfer of the gas temperature predictions were in good agreement with the experimental measurements. Nevertheless, the gas temperature was slightly under-predicted when the thermocouple was further away from the flaming region. Overall, it was discovered that the combination of a smoke curtain and ceiling vents was a highly effective natural smoke exhaust system. However, under the same vent configuration, if the smoke curtain height is not adequate to completely block the spread of smoke, it significantly reduces the pressure differential between the compartment and the exterior, causing reduced flow rates in the outlet vents.
Publisher: Elsevier BV
Date: 10-2022
Publisher: MDPI AG
Date: 2020
DOI: 10.3390/APP10010318
Abstract: A numerical study of the fire whirl formation under symmetrical and asymmetrical entraining configuration is presented. This work aims to assess the effect of eddy-generation configuration on the evolution of the intriguing phenomenon coupled with both flow dynamics and combustion. The numerical framework implements large-eddy simulation, detailed chemistry to capture the sophisticated turbulence-chemistry interaction under reasonable computational cost. It also adopts liquid-based clean fuel with fixed injection rate and uniformed discretisation scheme to eliminate potential interference introduced by various aspects of uncertainties. The result reveals that the nascent fire whirl formulates significantly rapidly under the symmetrical two-slit configuration, with extended flame height and constrained vortex structure, compared with the asymmetrical baseline. However, its revolution orbit gradually erges from domain centreline and eventually stabilises with a large radius of rotation, whereas the revolution pattern of that from the baseline case is relatively unchanged from the inception of nascent fire whirl. Through the analysis, the observed difference in evaluation pathway could be explained using the concept of circular motion with constant centripetal force. This methodology showcases its feasibility to reveal and visualise the fundamental insight and facilitate profound understanding of the flaming behaviour to benefit both research and industrial sectors.
Publisher: Wiley
Date: 08-04-2021
DOI: 10.1002/FAM.2973
Abstract: Multifunctional building façades have become an increasingly critical component in modern buildings, especially after the tremendous scrutiny triggered by the utilization of combustible aluminum cladding panels (ACP) in the construction sector. Following the massive effort by both industry and government agencies to reduce the fire risks of combustible façades in recent years, façades with insufficient fire ratings have been continuously causing severe building fires leading to countless human casualties and properties damages. This review aims to provide an in‐depth overview of the previous developments and current progress for establishing relevant fire standards with regards to ACPs, from an Australian standpoint. The fire spread mechanisms associate with ACPs, and their potential hazards were discussed. Furthermore, the current building regulations for ACPs have been reviewed, including detailed experimental procedures and rating criterion for all existing international standards. To address the research knowledge gap in terms of the understanding of the cladding fire mechanisms, and combustibility of existing ACP polymer composites, recent advancement in experimental and numerical studies has been summarized and discussed to identify the critical issues and concerns for current ACP products. Future perspectives involving cutting‐edge approaches such as computational fluid dynamics (CFD) modeling coupled with artificial neural network (ANN) optimization are advocated in this article. Additionally, fundamental material characterization techniques using molecular dynamics (MD) approaches can be implemented to deliver a better description of the degradation kinetics and smoke/toxicity generations.
Publisher: Elsevier BV
Date: 2021
Publisher: MDPI AG
Date: 25-02-2019
DOI: 10.3390/FIRE2010011
Abstract: Recent high-profile building fires involving highly-combustible external cladding panels in Australia as well as Dubai, China, and the United Kingdom have created a heightened awareness by the public, government, and commercial entities to act on the risks associated with non-compliant building structures. In this paper, a database of fire events involving combustible aluminium composite panels was developed based on (i) review of relevant major fire events in Australia and other countries, and (ii) numerical simulation of the ignitability, fire spread, and toxic emissions associated with composite panels. Through the application of large-eddy-simulation (LES)-based computational fire field models, the associated risks for a standardized two-storey building with external cladding was considered in this study. A total of sixteen simulation cases with different initial sizes of the fire and different air cavity widths in the exterior cladding assembly were examined to investigate the tolerable situations and their influences. It was discovered that for most cases, with an initial fire size greater than 400 kW/m−2, the fire will spread from the first to second floor before the allowed egress time period.
Publisher: Elsevier BV
Date: 12-2017
Publisher: Informa UK Limited
Date: 07-08-2020
Publisher: MDPI AG
Date: 12-10-2019
DOI: 10.3390/APP9204275
Abstract: With the escalating production of automobiles, energy efficiency and environmental friendliness have always been a major concern in the automotive industry. In order to effectively lower the energy consumption of a vehicle, it is essential to develop air-conditioning systems that can make good use of combustion waste heat. Ejector refrigeration systems have become increasingly popular for this purpose due to their energy efficiency and ability to recycle waste heat. In this article, the elements affecting the performance of a typical ejector refrigeration system have been explored using both experimental and numerical approaches. For the first time, the internal flow structure was characterized by means of comprehensive numerical simulations. In essence, three major sections of the steam ejector were investigated. Two energy processes and the shock-mixing layer were defined and analyzed. The results indicated that the length of the choking zone directly affects the entertainment ratio under different primary fluid temperature. The optimum enterainment ratio was achieved with 138 °C primary fluid temperature. The shock-mixing layer was greatly affected by secondary fluid temperature. With increasing of back pressure, the normal shock gradually shifted from the diffuser towards the throat, while the shock train length remains lunchanged.
Publisher: Elsevier BV
Date: 05-2020
Publisher: Elsevier BV
Date: 05-2019
Publisher: MDPI AG
Date: 08-07-2022
Abstract: The increasing popularity of lithium-ion battery systems, particularly in electric vehicles and energy storage systems, has gained broad research interest regarding performance optimization, thermal stability, and fire safety. To enhance the battery thermal management system, a comprehensive investigation of the thermal behaviour and heat exchange process of battery systems is paramount. In this paper, a three-dimensional electro-thermal model coupled with fluid dynamics module was developed to comprehensively analyze the temperature distribution of battery packs and the heat carried away. The computational fluid dynamics (CFD) simulation results of the lumped battery model were validated and verified by considering natural ventilation speed and ambient temperature. In the artificial neural networks (ANN) model, the multilayer perceptron was applied to train the numerical outputs and optimal design of the battery setup, achieving a 1.9% decrease in maximum temperature and a 4.5% drop in temperature difference. The simulation results provide a practical compromise in optimizing the battery configuration and cooling efficiency, balancing the layout of the battery system, and safety performance. The present modelling framework demonstrates an innovative approach to utilizing high-fidelity electro-thermal/CFD numerical inputs for ANN optimization, potentially enhancing the state-of-art thermal management and reducing the risks of thermal runaway and fire outbreaks.
Publisher: Informa UK Limited
Date: 26-07-2022
Publisher: IEEE
Date: 10-2019
Publisher: American Chemical Society (ACS)
Date: 31-10-2018
Abstract: A novel three-dimensional (3D) epoxy/graphene nanosheet/hydroxylated boron nitride (EP/GNS/BNOH) hybrid aerogel was successfully fabricated in this study. This was uniquely achieved by constructing a well-defined and interconnected 3D network architecture. The manufacturing process of EP/GNS/BNOH involved a simple one-pot hydrothermal strategy, followed by the treatment of freeze-drying and high-temperature curing. In comparison with EP/GNS-3, EP/GNS/BNOH-3 demonstrated improvement of 97% for compressive strength at 70% strain. Through compression tests, fracture occurred for EP/GNS-3 at ninth compression cycles, whereas EP/GNS/BNOH-3 retained its original form after twenty compression cycles, with a residual height of 97% (i.e., only 3% reduction). By the addition of BNOH in the polymer matrix, the dynamic heat transfer and dissipation rates of EP/GNS/BNOH aerogels were also considerably reduced, indicating that the aerogel with BNOH additive possessed excellent thermal insulation properties. Thermogravimetric analysis results revealed that the thermal stabilities of EP/GNS and EP/GNS/BNOH aerogels were improved with increasing loading of EP, and EP/GNS/BNOH aerogels exhibited a better thermal stability at high temperatures. Through the elevated levels attained in the compressive strength, superelasticity, and thermal resistance, EP/GNS/BNOH aerogels has the great potential of being a very effective thermal insulation material to be utilized across a board range of applications in building, automotive, spacecraft, and mechanical systems.
Publisher: Springer Science and Business Media LLC
Date: 12-10-2020
Publisher: Elsevier BV
Date: 03-2020
Publisher: Elsevier BV
Date: 05-2020
Publisher: Elsevier BV
Date: 12-2022
Publisher: SAGE Publications
Date: 20-09-2018
Abstract: In this article, a generic framework was proposed to effectively characterise the pyrolysis kinetics of any household furniture materials. To examine the validity of this method, two wooden polymeric s les, (1) furniture plywood and (2) particle board, were experimented through thermogravimetric and differential thermal analyses, as well as cone calorimetry. The framework comprises of three major parameterisation procedures including (1) using the Kissinger method for the initial approximation, (2) modification of modelling constants and (3) optimisation by comparisons with the experimental results. The finalised pyrolysis kinetics was numerically investigated through computational fluid dynamics simulation of the cone calorimeter. Numerical predictions were validated against the experimental data for three different cone radiation intensities. Good agreement was achieved between the computational and experimental results in terms of heat release rate, ignition time and burn duration. The proposed framework was capable of establishing quality pyrolysis kinetics that fully replicates the complex thermal decomposition of solid combustible materials.
Publisher: Springer Singapore
Date: 04-09-2020
Publisher: MDPI AG
Date: 12-11-2019
DOI: 10.3390/APP9224842
Abstract: A paradigm shift towards the utilization of carbon-neutral and low emission fuels is necessary in the internal combustion engine industry to fulfil the carbon emission goals and future legislation requirements in many countries. Hydrogen as an energy carrier and main fuel is a promising option due to its carbon-free content, wide flammability limits and fast flame speeds. For spark-ignited internal combustion engines, utilizing hydrogen direct injection has been proven to achieve high engine power output and efficiency with low emissions. This review provides an overview of the current development and understanding of hydrogen use in internal combustion engines that are usually spark ignited, under various engine operation modes and strategies. This paper then proceeds to outline the gaps in current knowledge, along with better potential strategies and technologies that could be adopted for hydrogen direct injection in the context of compression-ignition engine applications—topics that have not yet been extensively explored to date with hydrogen but have shown advantages with compressed natural gas.
Publisher: American Chemical Society (ACS)
Date: 20-12-2023
Publisher: Elsevier BV
Date: 07-2018
Publisher: American Chemical Society (ACS)
Date: 05-11-2020
Publisher: MDPI AG
Date: 19-10-2019
DOI: 10.3390/APP9204435
Abstract: In general, engine fuel combustion generates 30% waste heat, which is disposed to the environment. The use of the steam ejector refrigeration to recycle the waste heat and transfer them to useful energy source could be an environmentally friendly solution to such an issue. The steam ejector is the main component of the ejector refrigeration system, which can operate at a low-temperature range. In this article, the internal shock wave structure of the ejector is comprehensively studied through the computation fluid dynamics (CFD) approach. The shock wave structure can be sub ided into two regions: firstly the pseudo-shock region consisting of shock train and co-velocity region secondly the oblique-shock region composed of a single normal shock and a series of oblique shocks. The effect of the shock wave structure on both pumping performance and the critical back pressure were investigated. Numerical predictions indicated that the entrainment ratio is enhanced under two conditions including (i) a longer pseudo-shock region and (ii) when the normal shock wave occurs near the outlet. Furthermore, the system is stabilized as the back pressure and its disturbance is reduced. A critical range of the primary fluid pressure is investigated such that the pumping is effectively optimized.
Publisher: Elsevier BV
Date: 08-2017
Publisher: Springer Science and Business Media LLC
Date: 25-10-2021
Publisher: MDPI AG
Date: 08-10-2019
DOI: 10.3390/APP9194189
Abstract: Magnetorheological (MR) fluid is a smart material fabricated by mixing magnetic-responsive particles with non-magnetic-responsive carrier fluids. MR fluid d ers are able to provide rapid and reversible changes to their d ing coefficient. To optimize the efficiency and effectiveness of such devices, a computational model is developed and presented where the flow field is simulated using the computational fluid dynamics approach, coupled with the magnetohydrodynamics model. Three different inlet pressure profiles were designed to replicate real loading conditions are examined, namely a constant pressure, a sinusoidal pressure profile, and a pressure profile mimicking the 1994 Northbridge earthquake. When the MR fluid d er was in its off-state, a linear pressure drop between the inlet and the outlet was observed. When a uniform perpendicular external magnetic field was applied to the annular orifice of the MR d er, a significantly larger pressure drop was observed across the annular orifice for all three inlet pressure profiles. It was shown that the fluid velocity within the magnetized annular orifice decreased proportionally with respect to the strength of the applied magnetic field until saturation was reached. Therefore, it was clearly demonstrated that the present model was capable of accurately capturing the d ing characteristics of MR fluid d ers.
Publisher: Elsevier BV
Date: 06-2019
Publisher: Elsevier BV
Date: 09-2022
Publisher: Wiley
Date: 03-03-2020
DOI: 10.1002/PAT.4894
Publisher: Elsevier BV
Date: 05-2020
Publisher: MDPI AG
Date: 04-11-2022
Abstract: With the increasing demand for energy capacity and power density in battery systems, the thermal safety of lithium-ion batteries has become a major challenge for the upcoming decade. The heat transfer during the battery thermal runaway provides insight into thermal propagation. A better understanding of the heat exchange process improves a safer design and enhances battery thermal management performance. This work proposes a three-dimensional thermal model for the battery pack simulation by applying an in-house model to study the internal battery thermal propagation effect under the computational fluid dynamics (CFD) simulation framework. The simulation results were validated with the experimental data. The detailed temperature distribution and heat transfer behaviour were simulated and analyzed. The thermal behaviour and cooling performance were compared by changing the abnormal heat generation locations inside the battery pack. The results indicated that various abnormal heat locations disperse heat to the surrounding coolant and other cells. According to the current battery pack setups, the maximum temperature of Row 2 cases can be increased by 2.93%, and the temperature difference was also increased. Overall, a new analytical approach has been demonstrated to investigate several stipulating battery thermal propagation scenarios for enhancing battery thermal performances.
Publisher: Elsevier BV
Date: 04-2019
Publisher: Elsevier BV
Date: 07-2019
DOI: 10.1016/J.JHAZMAT.2019.04.026
Abstract: Thermoplastic polyurethane (TPU) has broad applications as lightweight materials due to its multiple advantages and unique properties. Nevertheless, toxicity emission under fire conditions remains a major concern, particularly in building fire scenarios. To circumvent the problem, it is imperative that an effective flame retardant is sought to suppress the flame and release of combustion/smoke products whilst maintaining the favorable material properties of TPU. In the current work, a simple method is proposed for the preparation and utilization of cetyltrimethyl ammonium bromide (CTAB) and tetrabutyl phosphine chloride (TBPC) modified Ti
Publisher: Springer Science and Business Media LLC
Date: 10-06-2019
Publisher: American Chemical Society (ACS)
Date: 02-10-2019
Abstract: Polyimide (PI) aerogels have attracted great attention owing to their low density and excellent thermal stability. However, hydrophobic surface modification is required for PI aerogels to improve their ability in oil/water separation due to their hiphilic characteristic. Two-dimensional MXenes (transition metal carbides/nitrides) can be utilized as nanofillers to enhance the properties of polymers because of their unique layered structure and versatile interface chemistry. Herein, the robust, lightweight, and hydrophobic PI/MXene three-dimensional architectures were fabricated via freeze-drying of polyamide acid/MXene suspensions and thermal imidization. Polyamide acid was synthesized using
Publisher: Elsevier BV
Date: 2020
DOI: 10.1016/J.JHAZMAT.2019.120952
Abstract: MXene/chitosan nanocoating for flexible polyurethane foam (PUF) was prepared via layer-by-layer (LbL) approach. MXene (Ti
Publisher: MDPI AG
Date: 29-06-2023
DOI: 10.3390/MOLECULES28135100
Abstract: The effect of varying the weight percentage composition (wt.%) of low-cost expandable graphite (EG), ammonium polyphosphate (APP), fibreglass (FG), and vermiculite (VMT) in polyurethane (PU) polymer was studied using a traditional intumescent flame retardant (IFR) system. The synergistic effect between EG, APP, FG, and VMT on the flame retardant properties of the PU composites was investigated using SEM, TGA, tensile strength tests, and cone calorimetry. The IFR that contained PU composites with 40 wt.% EG displayed superior flame retardant performance compared with the composites containing only 20 w.t.% or 10 w.t.% EG. The peak heat release rate, total smoke release, and carbon dioxide production from the 40 wt.% EG s le along with APP, FG, and VMT in the PU composite were 88%, 93%, and 92% less than the PU control s le, respectively. As a result, the synergistic effect was greatly influenced by the compactness of the united protective layer. The PU composite suppressed smoke emission and inhibited air penetrating the composite, thus reducing reactions with the gas volatiles of the material. SEM images and TGA results provided positive evidence for the combustion tests. Further, the mechanical properties of PU composites were also investigated. As expected, compared with control PU, the addition of flame-retardant additives decreased the tensile strength, but this was ameliorated with the addition of FG. These new PU composite materials provide a promising strategy for producing polymer composites with flame retardation and smoke suppression for construction materials.
Publisher: Mary Ann Liebert Inc
Date: 12-2020
Publisher: Informa UK Limited
Date: 02-05-2016
Publisher: Begellhouse
Date: 2012
Publisher: Begell House
Date: 2013
Publisher: Elsevier BV
Date: 12-2019
Publisher: Elsevier BV
Date: 10-2018
Publisher: MDPI AG
Date: 08-06-2023
DOI: 10.3390/FIRE6060231
Abstract: This study investigates the kinetics data of glass wool (GW) and extruded polystyrene (XPS) insulation materials used in cladding systems using a systematic framework. The determination of appropriate kinetic properties, such as pre-exponential factors, activation energy and reaction orders, is crucial for accurately modelling the full-scale fire performance of insulation materials. The primary objective of this research is to extract thermal and kinetics data of XPS and GW insulation materials employed in high-rise buildings. To obtain these properties, thermogravimetric analysis (TGA) is conducted at four different heating rates: 5, 10, 15 and 20 K/min. The TGA results serve as the basis for determining the kinetic properties using a combination of model-free and model-based methods. The outcomes of this study are expected to be highly beneficial in defining the pyrolysis reaction steps and extracting kinetics data for fire modelling of such insulation materials. This information will enhance the understanding of the fire behaviour and performance of these materials during fire incidents, aiding in developing more accurate fire models and improving fire safety strategies for cladding systems in high-rise buildings.
Publisher: Elsevier BV
Date: 02-2023
Publisher: Elsevier BV
Date: 03-2023
Publisher: Informa UK Limited
Date: 1995
DOI: 10.3109/01485019508987831
Abstract: Plasma membrane proteins were extracted either from epididymal sperm after incubation with ullary gland secretion or from uterine sperm derived from surgically treated males belonging to the following groups: TX, excision of all accessory sex glands (ASG) AGX, bilateral excision of ullary glands AG, excision of all ASG except ullary glands and SH, sham-operated. Total membrane protein, glycoprotein, and SDS-PAGE of in idual polypeptide subunits were quantified. After incubation with ullary gland secretion, both protein and glycoprotein concentrations of epididymal sperm membrane were increased. The protein profile was also significantly altered, with the removal of the 43- and 71-kD subunits and the addition of the 36- and 50-kD subunits. The in vitro results confirmed this proteolytic effect of ullary gland and other ASG on the 43- and 71-kD subunits, despite a reduction in membrane protein concentration. Modification of the 17-, 20-, 25-, 28-, 56-, and 66-kD proteins were also observed. This report is the first demonstration that the ullary gland is capable of modifying proteins on the sperm surface.
Publisher: Elsevier BV
Date: 03-2014
Publisher: MDPI AG
Date: 12-05-2020
Abstract: Due to the unique two-dimensional structure and features of graphitic carbon nitride (g-C3N4), such as high thermal stability and superior catalytic property, it is considered to be a promising flame retardant nano-additive for polymers. Here, we reported a facile strategy to prepare cobalt hosphorus co-doped graphitic carbon nitride (Co/P-C3N4) by a simple and scalable thermal decomposition method. The structure of Co/P-C3N4 was confirmed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The carbon atoms in g-C3N4 were most likely substituted by phosphorous atoms. The thermal stability of polylactide (PLA) composites was increased continuously with increasing the content of Co/P-C3N4. In contrast to the g-C3N4, the Polylactide (PLA) composites containing Co/P-C3N4 exhibited better flame retardant efficiency and smoke suppression. With the addition of 10 wt % Co/P-C3N4, the peak heat release rate (PHRR), carbon dioxide (CO2) production (PCO2P) and carbon oxide (CO) production (PCOP) values of PLA composites decreased by 22.4%, 16.2%, and 38.5%, respectively, compared to those of pure PLA, although the tensile strength of PLA composites had a slightly decrease. The char residues of Co/P-C3N4 composites had a more compact and continuous structure with few cracks. These improvements are ascribed to the physical barrier effect, as well as catalytic effects of Co/P-C3N4, which inhibit the rapid release of combustible gaseous products and suppression of toxic gases, i.e., CO.
Publisher: Springer Science and Business Media LLC
Date: 17-01-2014
Publisher: MDPI AG
Date: 08-11-2022
Abstract: A novel and hierarchical hybrid composite (MnO2@CHS@SA@Ni) was synthesized utilizing manganese dioxide (MnO2) nanosheets as the core structure, self-assembly chitosan (CHS), sodium alginate (SA) and nickel species (Ni) as surface layers, and it was further incorporated into an epoxy matrix for achieving fire hazard suppression via surface self-assembly technology. Herein, the resultant hybrid epoxy composite possessed an exceptional nano-barrier and synergistic charring effect to aid the formation of a compact layered structure that enhanced its fire-resistive effectiveness. As a result, the addition of only 2 wt% MnO2@CHS@SA@Ni hybrids led to a dramatic reduction in the peak heat release rate and total heat release values (by ca. 33% and 27.8%) of the epoxy matrix. Notably, the peak smoke production rate and total smoke production values of EP/MnO2@CHS@SA@Ni 2% were decreased by ca. 16.9 and 38.4% compared to the corresponding data of pristine EP. This was accompanied by the suppression of toxic CO, NO release and the diffusion of thermal pyrolysis gases during combustion through TG-IR results. Overall, a significant fire-testing outcome of the proposed hierarchical structure was proven to be effective for epoxy composites in terms of flammability, smoke and toxicity reductions, optimizing their prospects in other polymeric materials in the respective fields.
Publisher: American Chemical Society (ACS)
Date: 06-11-2018
Publisher: MDPI AG
Date: 13-10-2022
DOI: 10.3390/FIRE5050165
Abstract: In this article, a collective database from validated numerical simulation has been established to study the suppression effects of water-based suppression systems under a single-compartment fire scenario at various suppression configurations and fire locations. Five fuel locations along the axis between the centre and corner of the room were configurated to dynamically analyse how the horizontal distance between the nozzle and fuel pan affects the heat release rate (HRR), temperature cooling phenomena at different heights and also the velocity profile. Throughout the fuel pan relocations, the water-mist system has achieved an average suppression time of 25 s for all the locations, it was found that the water mist system can effectively control the fire under 200 °C that is distanced over 2 m spanwise displacement from the nozzle against the fire, while the sprinkler has exhibited an excellent fuel surface cooling effect due to large momentum and heat capacity within the coverage area with an average suppression time of 50 s. The results of this study have further explored the spray coverage and droplet penetrability of different suppression systems at different locations corresponding to the fire source, and the quantitative assessment of fuel locations could also contribute to the future development of performance-based fire safety designs.
Publisher: Elsevier BV
Date: 03-2022
Publisher: Elsevier BV
Date: 08-2018
Publisher: Elsevier BV
Date: 02-2020
Publisher: MDPI AG
Date: 26-01-2018
DOI: 10.3390/NANO8020070
Abstract: High-performance poly(1,4-butylene terephthalate) (PBT) nanocomposites have been developed via the consideration of phosphorus-containing agents and amino-carbon nanotube (A-CNT). One-pot functionalization method has been adopted to prepare functionalized CNTs via the reaction between A-CNT and different oxidation state phosphorus-containing agents, including chlorodiphenylphosphine (DPP-Cl), diphenylphosphinic chloride (DPP(O)-Cl), and diphenyl phosphoryl chloride (DPP(O3)-Cl). These functionalized CNTs, DPP(Ox)-A-CNTs (x = 0, 1, 3), were, respectively, mixed with PBT to obtain the CNT-based polymer nanocomposites through a melt blending method. Scanning electron microscope observations demonstrated that DPP(Ox)-A-CNT nanoadditives were homogeneously distributed within PBT matrix compared to A-CNT. The incorporation of DPP(Ox)-A-CNT improved the thermal stability of PBT. Moreover, PBT/DPP(O3)-A-CNT showed the highest crystallization temperature and tensile strength, due to the superior dispersion and interfacial interactions between DPP(O3)-A-CNT and PBT. PBT/DPP(O)-A-CNT exhibited the best flame retardancy resulting from the excellent carbonization effect. The radicals generated from decomposed polymer were effectively trapped by DPP(O)-A-CNT, leading to the reduction of heat release rate, smoke production rate, carbon dioxide and carbon monoxide release during cone calorimeter tests.
Publisher: Informa UK Limited
Date: 02-08-2017
Publisher: Elsevier BV
Date: 03-2017
Publisher: Springer Science and Business Media LLC
Date: 19-06-2021
Publisher: Elsevier BV
Date: 07-2021
Publisher: Avestia Publishing
Date: 05-2016
DOI: 10.11159/FFHMT16.165
Publisher: MDPI AG
Date: 08-03-2019
DOI: 10.3390/EN12050910
Abstract: In this article, the evolution of in-flame soot species in a slow speed, buoyancy-driven diffusion flame is thoroughly studied with the implementation of the population balance approach in association with computational fluid dynamics (CFD) techniques. This model incorporates interactive fire phenomena, including combustion, radiation, turbulent mixing, and all key chemical and physical formation and destruction processes, such as particle inception, surface growth, oxidation, and aggregation. The in-house length-based Direct Quadrature Method of Moments (DQMOM) soot model is fully coupled with all essential fire sub-modelling components and it is specifically constructed for low-speed flames. Additionally, to better describe the combustion process of the parental fuel, ethylene, the strained laminar flamelet model, which considers detailed chemical reaction mechanisms, is adopted. Numerical simulation is validated against a self-conducted co-flow slot burner experimental measurement. A comprehensive assessment of the effect of adopting different nucleation laws, oxidation laws, and various fractal dimension and diffusivity values is performed. The results suggest the model employing Moss law of nucleation, modified NSC law of oxidation, and adopting a fractal dimension value of 2.0 and Schmidt number of 0.9 yields the simulation result that best agreed with experimental data.
Publisher: Elsevier BV
Date: 11-2019
Publisher: Elsevier BV
Date: 10-2021
Publisher: American Chemical Society (ACS)
Date: 03-07-2019
Publisher: Informa UK Limited
Date: 1995
DOI: 10.3109/01485019508987848
Abstract: Plasma membrane proteins were extracted either from epididymal spermatozoa after incubation with ventral prostate gland secretion or from spermatozoa recovered from uteri of females mated with surgically treated males belonging to the following groups: TX (excision of all accessory sex glands, ASG), VPX (bilateral excision of ventral prostate), VP (bilateral excision of all ASG except the ventral prostate), and SH (sham-operated). Incubation of spermatozoa with ventral prostatic secretion resulted in an 11-fold increase in glycoprotein content of the plasma membrane, but total protein concentration remained unchanged. The in vivo study indicated that interactions of ASG secretions and spermatozoa were complicated by the presence of uterine secretions. Glycoprotein content was reduced in the presence of ventral prostatic secretions. SDS-PAGE profiles showed that both uterine and ASG secretions could modify proteins on the sperm surface. Enrichment of a 25-kD subunit was apparently effected by uterine secretions and further promoted by combined secretions of the ullary gland, coagulating gland, dorsolateral prostate, and seminal vesicle, but was reduced by the ventral prostate. A number of other protein subunits appeared to be specifically modified by the ventral prostate, while other ASG secretions were also shown to alter the effects of the ventral prostate on the sperm surface.
Publisher: Informa UK Limited
Date: 27-01-2021
Publisher: Elsevier BV
Date: 07-2018
Publisher: MDPI AG
Date: 13-10-2023
Publisher: American Chemical Society (ACS)
Date: 10-04-2018
Publisher: IEEE
Date: 04-2019
Publisher: Trans Tech Publications, Ltd.
Date: 10-2013
DOI: 10.4028/WWW.SCIENTIFIC.NET/AMM.444-445.1579
Abstract: The Wall Adpating Local Eddy Viscosity (WALE) subgrid-scale turbulence model was adopted for an in-house large eddy simulation (LES) fire code in which the turbulence is fully coupled combustion and radiation models. The traditional Smagorinsky subgrid-scale model accounts only strain rate of the turbulent structure while the WALE model considers both the strain and the rotation rates. Furthermore, the WALE model automatically recovers the near wall-scaling for the eddy viscosity hence more adaptive for wall bounded flows.A 15 m long test hall fire was reconstructed by the in-house fire code with 1.5 MW fire source. The performance of the WALE model was assessed by comparingpredicted transient gas temperatures and velocities at various spatial locations.
Publisher: MDPI AG
Date: 15-10-2022
Abstract: Thermoplastic polyurethane (TPU) is widely used in daily life due to its characteristics of light weight, high impact strength, and compression resistance. However, TPU products are extremely flammable and will generate toxic fumes under fire attack, threatening human life and safety. In this article, a nanohybrid flame retardant was designed for the fire safety of TPU. Herein, Co3O4 was anchored on the surface of exfoliated ultra-thin boron nitride nanosheets (BNNO@Co3O4) via coprecipitation and subsequent calcination. Then, a polyphosphazene (PPZ) layer was coated onto BNNO@Co3O4 by high temperature polymerization to generate a nanohybrid flame retardant named BNNO@Co3O4@PPZ. The cone calorimeter results exhibited that the heat release and smoke production during TPU combustion were remarkably restrained after the incorporation of the nanohybrid flame retardant. Compared with pure TPU, the peak heat release rate (PHRR) decreased by 44.1%, the peak smoke production rate (PSPR) decreased by 51.2%, and the peak CO production rate (PCOPR) decreased by 72.5%. Based on the analysis of carbon residues after combustion, the significant improvement in fire resistance of TPU by BNNO@Co3O4@PPZ was attributed to the combination of quenching effect, catalytic carbonization effect, and barrier effect. In addition, the intrinsic mechanical properties of TPU were well maintained due to the existence of the PPZ organic layer.
Publisher: Springer Science and Business Media LLC
Date: 13-01-2020
Publisher: American Chemical Society (ACS)
Date: 04-08-2018
DOI: 10.1021/ACS.LANGMUIR.8B01457
Abstract: Gold nanoparticle (GNP) aggregation has a strong influence on the plasmonic resonance and hence the effectiveness in various photothermal applications. In relation to this, a comprehensive numerical model is developed to simulate and characterize the GNP aggregation process at various particle volume fractions and base fluid pH levels. Computational fluid dynamics techniques are utilized to model the base fluid, whereas discrete phase modeling is adopted in determining the nanoparticle trajectories. Two-way coupling is implemented to handle the particle-fluid interactions. Discrete dipole approximation approach is utilized to further examine the absorption and scattering efficiency of various GNP aggregate structures. At lower particle volume fraction, short chain-like structures are formed in the particle aggregation process, with a more complex interconnected "particle network" structure formed at higher particle volume fractions. With the three base fluid pH levels investigated, GNP aggregates are more compact with larger fractal dimensions and higher mean coordination numbers at pH = 3.5, whereas a more "loose" structure formed at pH = 6.7 and 9.4 because of larger electrostatic repulsive forces as a result of changes in the zeta potential and Debye length of the GNPs. Among the typical GNP aggregate structures characterized in this paper, the chain-like tetramer demonstrates the highest absorption efficiency of 1.83 at 700 nm wavelength-comparable to the plasmonic resonance of a nanorod-which lies in the optical window of biological tissue. Predictions of GNP optical properties are found to be in good agreement with the published experimental data.
Publisher: MDPI AG
Date: 04-01-2022
DOI: 10.3390/MOLECULES27010292
Abstract: Building polymers implemented into building panels and exterior façades have been determined as the major contributor to severe fire incidents, including the 2017 Grenfell Tower fire incident. To gain a deeper understanding of the pyrolysis process of these polymer composites, this work proposes a multi-scale modelling framework comprising of applying the kinetics parameters and detailed pyrolysis gas volatiles (parent combustion fuel and key precursor species) extracted from Molecular Dynamics models to a macro-scale Computational Fluid Dynamics fire model. The modelling framework was tested for pure and flame-retardant polyethylene systems. Based on the modelling results, the chemical distribution of the fully decomposed chemical compounds was realised for the selected polymers. Subsequently, the identified gas volatiles from solid to gas phases were applied as the parent fuel in the detailed chemical kinetics combustion model for enhanced predictions of toxic gas, charring, and smoke particulate predictions. The results demonstrate the potential application of the developed model in the simulation of different polymer materials without substantial prior knowledge of the thermal degradation properties from costly experiments.
Publisher: Elsevier BV
Date: 05-2016
Publisher: MDPI AG
Date: 17-01-2018
DOI: 10.20944/PREPRINTS201801.0161.V1
Abstract: High-performance poly(1,4-butylene terephthalate (PBT) nanocomposites have been developed via the consideration of phosphorus-containing agents and amino-carbon nanotube (A-CNT). One-pot functionalization method has been adopted to prepare functionalized CNTs via the reaction between A-CNT and different oxidation state phosphorus-containing agents, including chlorodiphenylphosphine (DPP-Cl), diphenylphosphinic chloride (DPP(O)-Cl), and diphenyl phosphoryl chloride (DPP(O3)-Cl). These functionalized CNTs, DPP(Ox)-A-CNTs (x = 0, 1, 3), were respectively mixed with PBT to obtain the CNTs-based polymer nanocomposites through a melt blending method. SEM observations demonstrated that DPP(Ox)-A-CNT nano-additives were homogeneously distributed within PBT matrix compared to A-CNT. The incorporation of DPP(Ox)-A-CNT improved the thermal stability of PBT. Moreover, PBT/DPP(O3)-A-CNT showed the highest crystallization temperature and tensile strength, due to the superior dispersion and interfacial interactions between DPP(O3)-A-CNT and PBT. PBT/DPP(O)-A-CNT exhibited the best flame retardancy resulting from the excellent carbonization effect. The radicals generated from decomposed polymer were effectively trapped by DPP(O)-A-CNT, leading to the reduction of heat release rate, smoke production rate, carbon dioxide and carbon monoxide release during cone calorimeter tests.
Publisher: Elsevier BV
Date: 2018
Publisher: MDPI AG
Date: 20-09-2022
DOI: 10.3390/FIRE5050140
Abstract: Demand for underground railways has rapidly increased due to accelerated urbanisation and population growth. This has elevated the importance of tunnel designs with adequate fire safety and protection measures. However, due to intricate modern rail tunnel designs, prescriptive codes are often difficult to implement and lead to over-conservative design. In this study, the current state of tunnel fire analysis was reviewed with a focus on Australia. A large-eddy simulation (LES)-based fire model was applied to investigate the temperature and smoke dispersion from a 2 MW metro tunnel fire case scenario to the cross-passage. A total of 28 cases with various cross-passage ventilation settings were examined, including longitudinal tunnel velocity, cross-passage velocity, train location relative to the cross-passage and fire location. The modelling showed that a 0.84 m/s critical velocity was sufficient for smoke control in the cross-passage. Furthermore, two empirical methods for cross-passage critical velocity were performed, which showed utilisation of the Froude number produced a less conservative critical velocity (0.610 m/s) compared to the dimensionless method (0.734 m/s). Nevertheless, both numerical and empirical results were significantly lower than the standard 1.0 m/s minimum flow rate for smoke control (AS1668.1). The results provide preliminary evidence towards the need for revision of current tunnel fire standards and response protocols.
Publisher: MDPI AG
Date: 15-05-2020
DOI: 10.3390/APP10103428
Abstract: The fundamental flow structure and temperature distribution of small-scale fire whirls, including tangential and axial velocities, temperature variation, and air entrainment in the lower boundary layer, were successfully captured using a generic fire field model with large eddy simulation (LES) turbulence closure. Numerical predictions were validated thoroughly against two small-scale experimental measurements, where detailed temperature and velocity distributions were recorded. Good agreement between numerical and experimental results was achieved. Normalization was also performed to compare the numerical predictions with the empirical correlations by Lei et al. (2015) developed from medium-scale fire whirl measurements. The transient development stages of small-scale fire whirls and the impact of air entrainment on the stability of the fire whirls were also investigated based on the validated numerical results. The numerical validations showed the potential of the current LES fire field model in capturing the dynamic behaviour of the fire whirl plume and performing a quantitative analysis on its onset criteria and combustion dynamics in future.
Publisher: CRC Press
Date: 20-06-2023
Publisher: Elsevier BV
Date: 2013
Publisher: MDPI AG
Date: 24-09-2019
DOI: 10.3390/APP9193989
Abstract: This paper numerically examines the characterisation of fire whirl formulated under various entrainment conditions in an enclosed configuration. The numerical framework, integrating large eddy simulation and detailed chemistry, is constructed to assess the whirling flame behaviours. The proposed model constraints the convoluted coupling effects, e.g., the interrelation between combustion, flow dynamics and radiative feedback, thus focuses on assessing the impact on flame structure and flow behaviour solely attribute to the eddy-generation mechanisms. The baseline model is validated well against the experimental data. The data of the comparison case, with the introduction of additional flow channelling slit, is subsequently generated for comparison. The result suggests that, with the intensified circulation, the generated fire whirl increased by 9.42 % in peak flame temperature, 84.38 % in visible flame height, 6.81 % in axial velocity, and 46.14 % in velocity dominant region. The fire whirl core radius of the comparison case was well constrained within all monitored heights, whereas that of the baseline tended to disperse at 0.5 m height-above-burner. This study demonstrates that lified eddy generation via the additional flow channelling slit enhances the mixing of all reactant species and intensifies the combustion process, resulting in an elongated and converging whirling core of the reacting flow.
Publisher: Elsevier BV
Date: 02-2022
Publisher: Royal Society of Chemistry (RSC)
Date: 2017
DOI: 10.1039/C7RA11437K
Abstract: A novel functionalized POSS greatly reinforced the mechanical, thermal stability, and flame retardant properties of PBT.
Publisher: Elsevier BV
Date: 04-2020
Publisher: Elsevier BV
Date: 04-2020
Publisher: Elsevier BV
Date: 02-2020
Publisher: MDPI AG
Date: 21-09-2022
Abstract: Natural fibre biopolymer composites with both fibres and matrix being derived from biomaterials are increasingly used in demanding applications, such as sensing, packaging, building, and transport, and require good electrical, thermal, and flame retardant properties. Herein, an investigation of the effectiveness of functionalising nonwoven cotton oly(lactic acid) (PLA) fibre mats with graphene oxide nanosheets has been reported by using a facile dip-coating method followed by thermal reduction for enhancing the electric, thermal, and abrasion-resistance properties. The manufacturing processes for preparing biocomposites and introducing functionality are readily scalable. Experimental results reveal that with the addition of less than 0.5 wt% graphene nanoplatelets, the biocomposites showed significant improvements in abrasion resistance, electrical conductivity, thermal conductivity, and diffusivity. Furthermore, the composite shows excellent piezo-resistivity to act as strain sensors with a gauge factor of 2.59 at strains up to 1%.
Publisher: MDPI AG
Date: 18-09-2022
DOI: 10.3390/FIRE5050139
Abstract: Building polymers are highly flammable and produce a vast amount of toxic chemical compounds in the event of a fire which can lead to potential incapacitation and death. To gain an in-depth understanding of this issue, smoke toxicity and thermal characteristics of seven commonly used building polymers were analysed through a systematic fire performance evaluation system using a Thermogravimetric Analyzer and a Cone Calorimeter coupled with an FTIR arrangement. Four Fractional Effective Dose (FED) expressions were compared to assess the smoke toxicity of the fire effluents based on different assumptions. It was found that FEDN2, calculated using Purser’s equation, reported the highest values of FED with the following order of potential smoke toxicity at 50 kW/m2 radiative heat flux: LDPU HDPU PE HDEPS XPS EVA LDEPS. Furthermore, fire performance evaluation of the polymers was carried out by considering three key fire risk parameters, i.e., flashover propensity, total heat released, and toxic hazard. At 50 kW/m2 radiative heat flux, HDPU exhibited 11.7 times flashover propensity compared to the least flammable polymer (HDEPS), EVA exhibited 5 times total heat release compared to the polymer with the lowest total heat release (LDEPS) and, LDPU exhibited 6.7 potential times toxic hazard compared to the least toxic polymer (EVA).
Location: No location found
Location: Brazil
Start Date: 08-2022
End Date: 07-2025
Amount: $332,338.00
Funder: Australian Research Council
View Funded ActivityStart Date: 04-2024
End Date: 04-2029
Amount: $4,999,700.00
Funder: Australian Research Council
View Funded ActivityStart Date: 07-2018
End Date: 07-2023
Amount: $4,272,072.00
Funder: Australian Research Council
View Funded Activity