ORCID Profile
0000-0002-9131-5889
Current Organisations
CSIRO
,
SDI Limited
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Publisher: Informa UK Limited
Date: 21-12-2016
Publisher: Elsevier BV
Date: 04-2021
Publisher: Elsevier BV
Date: 06-2005
DOI: 10.1016/J.DENTAL.2004.07.016
Abstract: The role of particle size and size distribution of glass powders in glass-ionomer cements (GICs) has been largely overlooked, being limited to demonstrations of the classical inverse size-strength relationship. This study investigated variation in properties of an experimental glass-ionomer cement when a combination of large ('Powder A') and small ('Powder B') particles was used. Large- (mean size 9.60mum) and small-particle (3.34mum) glass powders were blended in various proportions and mixed with powdered polyacrylic acid to make a range of glass-ionomer powders. These powders were mixed with a glass-ionomer liquid (SDI Ltd, Australia) at powder to liquid ratios of 2:1, 2.5:1, and 3:1, and the resultant cements evaluated for working time, setting time, clinical handling, and compressive strength. Results were analysed by ANOVA. An increased proportion of smaller particles corresponded to higher strengths, and an increased proportion of larger particles with a decrease in viscosity of the unset cement. When 20-30% by weight of small particles was used, the paste demonstrated a peak in cohesion and working time, with a viscosity similar to commercial restorative GICs. Optimisation of particle sizing and distribution may thus lead to glass-ionomer cements with improved clinical handling characteristics and greater strength, which may increase the longevity of the restoration.
Publisher: Springer International Publishing
Date: 2013
Publisher: Elsevier BV
Date: 12-2021
Publisher: Informa UK Limited
Date: 22-02-2017
Publisher: Elsevier BV
Date: 09-2022
DOI: 10.1016/J.JMBBM.2022.105305
Abstract: To assess the hypotheses that a restored tooth structure for a class II occlusal-distal (OD) cavity can be reinforced by optimizing the cavity geometry and choosing composites with adequate mechanical properties. A human maxillary molar tooth was scanned, and segmented. The 2D profiles of dentin and enamel were drawn and imported to ABAQUS software. Eighteen restored tooth models with different cavity occlusal depths (OcDs) and internal cavity angles were developed. A semi-circular stone part was used to apply contact loads to the restored tooth model. After setting up the required interactions and boundary conditions, a written Python code was used to automatically assign a wide range of elastic moduli, from 2 GPa to 26 GPa, to the composite restorations, and assign constant material properties to the enamel and dentine. For simplicity, the behaviour of the mechanical material was postulated homogeneous and elastic, while the FE analyses were linearly carried out in this study. Also, the code enabled the FEA software to conduct the stress analyses, determine maximum principal stresses, and record the obtained results. The internal cavity angle formed between the mesial wall and the pulpal floor of the cavity significantly changed the peak maximum principal stress both in the enamel and restoration. The peak stress concentrations were observed mostly at the enamel-restoration interface, with an almost perpendicular orientation to this interface. Regarding the effect of occlusal cavity depth (OcD), the model with the shallowest cavity (OcD = 1.5 mm) represented greater resistance to applied loads than the model with deeper cavities (OcD = 2.0 mm and OcD 2.5 mm). The composite modulus (CM) in the range of 10-18 GPa reduced the maximum principal stress concentrations in the enamel. The lowest result for maximum principal stress was observed in the model with OcD = 1.5 mm, CM = 10 GPa and internal cavity angles = 100°, which was the strongest model against contact loads. Class II OD cavities with optimal geometry have reduced induced stress levels, thus being able to be more mechanically robust against contact load transmitted by a stone. Cavity geometry designs with obtuse (more than 90°) internal cavity angles were significantly efficient in minimizing peak stress concentrations. The results indicated that for the model with obtuse internal cavity angles, choosing a composite with optimised properties can diminish stress, particularly at the tooth-restoration interface. Furthermore, the shallowest the cavity, the sturdier the restoration was, especially when the interface tooth-restoration laid on enamel and not on dentine.
Publisher: Elsevier BV
Date: 2006
DOI: 10.1016/J.DENTAL.2005.04.004
Abstract: Both boric acid (H3BO3) and phosphoric acid (H3PO4) are components of dental cements, commonly incorporated into glass (as ingredients in the melt) and occasionally added to the powder or liquid components. This study investigated the effect of boric acid addition to an experimental glass-ionomer powder and the effect of phosphoric acid addition to a glass-ionomer liquid on the 24-h compressive strength. Boric acid powder was added in various concentrations to an experimental glass-ionomer powder and, separately, phosphoric acid was added to an experimental glass-ionomer liquid. Powders and liquids were dosed into capsules at various powder:liquid ratios and cements thus formed were assessed for 24-h compressive strength. Incorporation of boric acid in glass-ionomer powder resulted in a pronounced decrease (p < 0.05 at 1% boric acid) in compressive strength. Addition of phosphoric acid produced initially stronger cements (up to 13% increase at 1% phosphoric acid) before also declining. The incorporation of less than 2% w/w phosphoric acid in glass-ionomer liquids may improve cement strengths without compromising clinical usefulness. The incorporation of boric acid in glass-ionomer cements is contraindicated.
Publisher: Elsevier BV
Date: 08-2006
DOI: 10.1016/J.DENTAL.2005.11.001
Abstract: While clinical advantages of glass-ionomers include fluoride release and radiopacity, disadvantages include low strength, slow initial setting times and opacity. The addition of nanoparticles, in particular those containing fluoride and cross-linkable ions, may mitigate the disadvantages while further improving the advantages. This investigation evaluated the effects of the addition of ytterbium fluoride (YbF3) and barium sulphate (BaSO4) on the strength and reactivity of a commercial glass-ionomer cement. YbF3 and BaSO4 nanoparticles were incorporated into the powder component of Riva SC (SDI Ltd., Bayswater, Australia) at 1, 2, 5, 10, 15, and 25% by weight. Capsules were assembled at a powder:liquid ratio of 2.9:1, activated and mixed, and the resultant pastes evaluated for working time, initial setting time, 24-h surface hardness and 24-h compressive strength. Working and initial setting times were reduced with the addition of YbF3. Addition of BaSO4 at low concentrations reduced working and initial setting times, but further addition delayed the setting reaction. Compressive strength decreased with the addition of either YbF3 or BaSO4, while surface hardness was slightly but insignificantly higher at 1-2% nanoparticles and then decreased with increasing nanoparticle concentrations. Nanoparticles modified the setting characteristics, strength and surface hardness of a commercial glass-ionomer cement, and may be useful for refining the handling characteristics of these materials. Further improvements in powder blending may result in more significant improvements in mechanical properties.
Publisher: Elsevier BV
Date: 04-2023
Publisher: Springer Science and Business Media LLC
Date: 2007
DOI: 10.1007/S10856-006-0670-0
Abstract: The release of ions from a glass-ionomer glass, which in the polyacid matrix effects the cross-linking and setting of a cement, can be modelled and initiated by acid-treatment in a dilute acid. This study examined the effect of time of acetic acid leaching on the working time, setting time, and strength of a model GIC. A reactive fluoride glass was immersed in hot acetic acid for 0 (control), 5, 15, 35, 65, 95 and 125 min, filtered and dried. The glass was mixed with an experimental GI liquid in a capsule system and the mixed pastes assessed for working and initial setting time. Compressive strength testing was undertaken according to ISO9917:2003. Immersion time had a significant effect on both working and setting time of the resultant pastes only up to 65 min of immersion, and corresponded with a thin-film ion diffusion model. Compressive strength did not vary significantly with immersion time. The glass-ionomer setting reaction can be conveniently retarded by immersion of the powder in acetic acid, without affecting strength. A reactivity model was developed, whereby the effects of various changes to the leaching process may be usefully examined.
Publisher: Elsevier BV
Date: 2006
DOI: 10.1016/J.ACTBIO.2005.08.007
Abstract: Oxalic acid and its metal oxalate salts have been used extensively in dentistry in a range of applications: as desensitisers, in cavity preparation, and as bonding agents. This study investigated the influence of oxalic acid upon the working time, initial setting time, 24-h hardness and compressive strength of a glass-ionomer cement. Conventional glass-ionomer liquids were prepared from polyacrylic acid, tartaric acid, water, and oxalic acid at concentrations of 0-7% w/w. Liquids were dosed into capsules with a commercial glass-ionomer powder, activated and mixed. The resultant pastes were assessed for working time, initial setting time, 24-h hardness and 24-h compressive strength. Liquids containing 0.5-1% oxalic acid lengthened the working time and initial setting time. At concentrations greater than 2%, both working and initial setting times decreased with increasing oxalic acid. Surface hardness values using liquids with 3% and 7% oxalic acid were less hard than the control. Compressive strength was unchanged over the concentrations tested. Oxalic acid may be a useful reaction modifier in glass-ionomer systems. It accelerated the setting reaction without affecting strength, but was limited to low concentrations because of its relatively poor solubility in water.
Publisher: Elsevier BV
Date: 08-2005
DOI: 10.1016/J.DENTAL.2004.09.006
Abstract: The effects of varying mixing times on the properties of glass-ionomer cements have been poorly investigated, and many clinicians are uninformed about the potential changes in handling achieved by this. This study aims to explore the effects of mixing time variation. An experimental glass-ionomer system was dosed into a capsule, activated, and triturated for varying lengths of time, from 2 to 14 s. Measurements were made of working time, initial setting time, compressive strength and compressive modulus, and a subjective assessment of handling conducted. The working time and initial setting time decreased as mixing time increased, while compressive strength and compressive modulus increased to a maximum at 12 s mixing time. The material essentially pre-gelled after 14 s of mixing, which resulted in breaking of the gel matrix and poorer properties. Clinicians should feel confident, within limits, of varying mixing times of glass ionomer cements to improve properties or to slow the reaction.
Publisher: Elsevier BV
Date: 02-2022
Publisher: Informa UK Limited
Date: 06-2013
Publisher: Informa UK Limited
Date: 06-2013
Publisher: Wiley
Date: 02-2014
Location: Australia
No related grants have been discovered for Leon Prentice.