ORCID Profile
0000-0001-6030-2041
Current Organisation
Central Michigan University
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Publisher: Elsevier BV
Date: 04-2010
Publisher: Elsevier BV
Date: 02-2009
DOI: 10.1016/J.CHEMOSPHERE.2008.10.028
Abstract: A lab-scale leaching bed reactor (LBR) was operated to (1) investigate the potential of in-vessel solid-state anaerobic digestion of the organic fraction of municipal solid waste (MSW) and (2) examine the feasibility of using LBRs for hydrolysis/liquefaction and acidification of organic fraction of MSW for maximum total volatile fatty acid (tVFA) and alcohol production. A hydrolysis efficiency of 60% was achieved in the LBR, which was mainly affected by the solids content of organic fraction of MSW, the amount of water addition into the LBR and the channeling through the waste bed. The net mass of tVFA produced was 7000 mg at the end of 80 d. The main in idual VFAs produced were acetic and butyric acids and the main alcohol was ethanol. The variations in the by-products of acidification were mainly due to the nature of feed and pH variations in the LBR. LBRs achieved rapid hydrolysis and acidification of organic fraction of MSW, consequently, high hydrolysis yield, chemical oxygen demand removal and tVFA production.
Publisher: Elsevier BV
Date: 2011
Publisher: AIP Publishing
Date: 07-2013
DOI: 10.1063/1.4818771
Abstract: Inappropriate management of organic wastes can cause serious damage to the environment by polluting water and air, which can lower the quality of life. Ammonia and greenhouse gases (CH4 and CO2) emitted from the waste storage units can pollute the air. Inappropriate application of nitrogen and phosphorus on fields as manure can lead to eutrophication of surface water resources and pollution of soil and ground water. Conversion of the organic wastes to biogas through anaerobic digestion will, however, reduce the adverse impact on the environment and will contribute to a reduction in the consumption of fossil fuels. This study investigated the anaerobic digestion of broiler manure and greenhouse waste as well as anaerobic co-digestion of broiler manure and dewatered and non-dewatered wastewater treatment plant sludge for the production of biogas. To this purpose, biochemical methane potential experiments were performed. Moreover, the effects of nutrient and trace metal supplementation on the biogas yield were also examined. The results of this study indicated that (1) The obtained biogas values for broiler manure and greenhouse waste were very well in agreement with relevant literature values and comparable to that of food waste reported in the literature, respectively. (2) The experimental biogas production observed for co-digestion of broiler manure and dewatered and non-dewatered wastewater treatment plant sludge is higher than literature values.
Publisher: Springer Science and Business Media LLC
Date: 12-2005
Publisher: Elsevier BV
Date: 09-2003
DOI: 10.1016/S0960-8524(03)00046-4
Abstract: The inhibitory effects and removal efficiency of dieldrin (DLD) in anaerobic reactors were investigated. Anaerobic toxicity assay (ATA) experiments conducted in batch reactors revealed that 30 mg/l DLD had inhibitory effects on the unacclimated mixed anaerobic cultures. Continuous reactor experiments performed in a lab-scale two-stage upflow anaerobic sludge blanket (UASB) reactor system which was fed with ethanol as the sole carbon source, indicated that anaerobic granular cultures could be successfully acclimated to DLD. Chemical oxygen demand (COD) removal efficiencies were 88-92% for the two-stage system. The influent DLD concentration of 10 mg/l was removed by 44-86% and 86-94% in the second stage and overall UASB system, respectively. Biosorption of DLD on granular anaerobic biomass was found to be a significant mechanism for DLD removal in the UASB system. The maximum DLD loading rate and minimum HRT achievable for the first stage UASB reactor were 0.5 mg/lday (76 microg DLD/g VSS.day) and 10 h, respectively, which resulted in the overall COD removal efficiency of 85%.
Publisher: Mary Ann Liebert Inc
Date: 11-2008
Publisher: Springer Science and Business Media LLC
Date: 10-2002
Publisher: Elsevier BV
Date: 12-2012
Publisher: Elsevier BV
Date: 02-2005
Publisher: Inderscience Publishers
Date: 2011
Publisher: Informa UK Limited
Date: 05-2011
DOI: 10.1080/09593330.2010.512925
Abstract: The removal and the recovery of nutrients, namely nitrogen (N) and phosphorus (P) from anaerobically digested and solid-liquid separated manure effluents via struvite precipitation were investigated. Both the liquid and the solid phases of the poultry manure digester effluent were subjected to struvite precipitation experiments. The Mg:N:P molar ratio of 1:1:1 in the liquid phase resulted in an average NH4-N removal efficiency of 86.4%, which increased to 97.4% by adjusting the Mg:N:P ratio to 1.5:1:1. The acidic phosphorus-dissolution process was applied to the solid phase of the effluent to obtain a phosphorus-enriched solution. Nutrient recovery experiments with NaOH as the buffering reagent were conducted with and without addition of external chemicals (Mg and P sources) to evaluate the influence of the Mg:N:P molar ratio, the Mg:P molar ratio and pH. All the experiments depicted complete PO4-P (99.6-100.0%) and partial NH4-N (3.3-65.6%) recoveries from the phosphorus-enriched solution.
Publisher: Elsevier BV
Date: 04-2006
DOI: 10.1016/J.ENVINT.2005.10.002
Abstract: Different solid waste management system scenarios were developed and compared for the Municipal Solid Waste Management System of Ankara by using the life cycle assessment (LCA) methodology. The solid waste management methods considered in the scenarios were collection and transportation of wastes, source reduction, Material Recovery Facility (MRF)/Transfer Stations (TS), incineration, anaerobic digestion and landfilling. The goal of the study was to determine the most environmentally friendly option of MSWM system for Ankara. The functional unit of the study was the amount of solid waste generated in the system area of concern, which are the districts of Ankara. The life cycle inventory analysis was carried out by IWM Model-1. The inputs and outputs of each management stage were defined and the inventory emissions calculated by the model were classified in to impact categories non-renewable energy sources exhausting potential, final solid waste as hazardous and non-hazardous, global warming, acidification, eutrophication and human toxicity. The impacts were quantified with the weighing factors of each category to develop the environmental profiles of each scenario. In most of the categories, Source Reduction Scenario was found to be the most feasible management method, except the global warming category. The lowest contribution to GWP was calculated for the anaerobic digestion process. In the interpretation and improvement assessment stage, the results were further evaluated and recommendations were made to improve the current solid waste management system of Ankara.
Publisher: American Society of Civil Engineers (ASCE)
Date: 07-2003
Publisher: SAGE Publications
Date: 17-06-2013
Abstract: Anaerobic digestion is commonly used for the stabilization of agricultural and animal wastes. However, owing to the stringent environmental criteria, anaerobic digester effluents need to be further treated to reduce nutrient loads to the receiving water bodies. Struvite precipitation is one of the promising techniques applied for this purpose. Yet, in the majority of cases, struvite precipitation is only applied to the liquid phase of anaerobic digester effluents. This study investigated the recovery of nutrients from both the liquid and the solid phases of the phase-separated effluent of a full-scale biogas plant co-digesting poultry manure and maize silage. Struvite precipitation in the liquid phase led to 72.1% and 95.1% average removal efficiencies of ammonium-nitrogen (NH 4 -N) and orthophosphate respectively. Changing the external phosphorus source did not make any statistically significant difference in nutrient removal. An acidic phosphorus-dissolution process was applied to the solid phase s le to obtain a phosphorus-enriched solution. More than 90.0% of both NH 4 -N and PO 4 -P were recovered from the phosphorus-enriched solution with the amendments of magnesium and phosphorus. In the experiments performed without any addition of external magnesium- and phosphorus-containing chemicals, almost complete (99.6%) PO 4 -P recovery and partial (14.6%) NH 4 -N recovery were obtained. The results of this study could contribute to the understanding of nutrient recovery from anaerobic digestion residues of manure and agricultural wastes by struvite precipitation.
Publisher: Springer Science and Business Media LLC
Date: 18-01-2022
Publisher: Elsevier BV
Date: 07-1999
Publisher: Wiley
Date: 03-2011
DOI: 10.2175/106143010X12780288628093
Abstract: The aim of this study was to compare a batch-fed continuously mixed anaerobic reactor (FCMR) with an anaerobic sequencing batch reactor (ASBR), in terms of waste stabilization and methane production treating sugar-beet processing wastewater and beet-pulp simultaneously. A reactor was operated as FCMR, which then was operated as an ASBR by changing operational conditions after the steady-state was reached. Although the hydraulic retention time value of the ASBR configuration was lower (8 days) than that of the FCMR (15 days) and the corresponding organic loading rate (OLR) was higher (0.71 to 1.33 g COD/L x d), increased biomass retention enabled a significant increase in biomethanation for the ASBR configuration. So, methane production yield of 255 +/- 11 mL/g COD-added was increased to 337 +/- 15 mL/g COD-added (32.2% increase in methane yield) when the configuration was changed from FCMR to ASBR. The experimental results indicated that the ASBR configuration, which was applied to sugar-beet processing wastes for the first time, was superior to the FCMR configuration.
Publisher: Elsevier BV
Date: 09-2019
DOI: 10.1016/J.ENVPOL.2019.06.115
Abstract: The effluent stream of the anaerobic digestion processes, the digestate, accommodates high residual organic content that needs to be further treated before discharge. Anaerobic treatment of digestate would not only reduce the residual organic compounds in digestate but also has a potential to capture the associated biogas. High-rate anaerobic reactor configurations can treat the waste streams using lower hydraulic retention times which requires less footprint opposed to the conventional completely stirred tank reactors. This study investigated the high-rate anaerobic treatment performance and the associated biogas capture from the digestate of a manure mixture composed of 90% laying hen and 10% cattle manures in fixed-film reactors. The results indicated that it was possible to reduce total chemical oxygen demand content of the digestate by 57-62% in 1.3-1.4 days of hydraulic retention time. The corresponding biogas yields obtained were in the range of 0.395-0.430 L
Publisher: Wiley
Date: 20-01-1999
DOI: 10.1002/(SICI)1097-0290(19990120)62:2<200::AID-BIT10>3.0.CO;2-J
Abstract: In this study, the inhibitory effects and anaerobic biotransformation of acrylic acid in computer-controlled pH-stat completely stirred tank reactors (CSTRs) with two different cultures, namely unacclimated and acrylate-acclimated acetate-enriched Methanosarcina and homogenized (crushed) granular cultures, were investigated. The microbial acclimation, influent concentration, and loading rate of acrylic acid were studied in the experiments. The experimental results revealed that methanogenic cultures at a concentration of 3200 +/- 80 mg/L as volatile suspended solids (VSS) could be acclimated to acrylic acid up to a loading rate of 220 mg/L per day (0.068 g acrylic acid/g VSS per day) in the presence of a constant acetate concentration of 2000 +/- 200 mg/L as the primary substrate after 300 days of acclimation. The same cultures (680 +/- 80 mg/L as VSS), after 80 days of acclimation to acrylic acid as the sole carbon source, transformed acrylic acid up to the loading rate of about 200 mg/L per day (0.29 g acrylic acid/g VSS per day) almost completely (>99%) to acetic and propionic acid, but could not effectively metabolize these intermediate products. Acrylate-acclimated homogenized granular cultures (6900 +/- 80 mg/L as VSS) effectively metabolized 2200 mg/L per day (0.32 g acrylic acid/g VSS per day) of acrylic acid, as the sole carbon source, after 50 days of severe inhibition.
Publisher: Wiley
Date: 20-11-2021
DOI: 10.1002/EP.13561
Publisher: Elsevier BV
Date: 10-2016
Publisher: Elsevier BV
Date: 11-2005
Publisher: Informa UK Limited
Date: 02-12-2014
Publisher: American Meteorological Society
Date: 15-01-2013
DOI: 10.1175/JCLI-D-12-00114.1
Abstract: The influence of different types of ENSO on tropical cyclone (TC) interannual variability in the central southwest Pacific region (5°–25°S, 170°E–170°W) is investigated. Using empirical orthogonal function analysis and an agglomerative hierarchical clustering of early tropical cyclone season Pacific sea surface temperature, years are classified into four separate regimes (i.e., canonical El Niño, canonical La Niña, positive-neutral, and negative-neutral) for the period between 1970 and 2009. These regimes are found to have a large impact on TC genesis over the central southwest Pacific region. Both the canonical El Niño and the positive-neutral years have increased numbers of cyclones, with an average of 4.3 yr−1 for positive-neutral and 4 yr−1 for canonical El Niño. In contrast, during a La Niña and negative-neutral events, substantially fewer TCs (averages of ~2.2 and 2.4 yr−1, respectively) are observed in the central southwest Pacific. The enhancement of TC numbers in both canonical El Niño and positive-neutral years is associated with the extension of favorable low-level cyclonic relative vorticity, and low vertical wind shear eastward across the date line. Relative humidity and SST are also very conducive for genesis in this region during canonical El Niño and positive-neutral events. The patterns are quite different, however, with the favorable conditions concentrated in the date line region for the positive-neutral, as compared with conditions farther eastward for the canonical El Niño regime. A significant result of the study is the demonstration that ENSO-neutral events can be objectively clustered into two separate regimes, each with very different impacts on TC genesis.
Publisher: Wiley
Date: 12-2009
Abstract: The aim of this study was to enrich the composition of anaerobic digester sludge in terms of nitrogen and phosphorus by struvite (MgNH4PO4) formation. Waste activated sludge was anaerobically digested in batch reactors under the conditions that the minimum stoichiometric requirement for struvite formation was satisfied in all reactors. For this purpose, different amounts of magnesium (Mg2+) and phosphate (PO4(3-)) ions were added initially to the batch reactors. The results showed the effects of adding Mg2+ and PO4(3-) ions on the performance of anaerobic digestion and on the amounts of ammonium (NH4+) and PO4(3-) ions released during digestion. The results indicated that the performance of the anaerobic digestion in chemical oxygen demand removal changed between -4.0% and 15.4% for a Mg2+ concentration range of 277.2 to 529.3 mg/L and a PO4(3-) concentration range of 377.4 to 2372.4 mg/L. There was an increase in the concentration of NH4+ in all reactors during digestion, but the extent of concentration increase could be controlled by increasing the initial concentrations of Mg2+ and PO4(3-). The maximum removal of NH4+ ions (33.7%) was observed in the reactor dosed initially by Mg2+ and PO4(3-) concentrations of 467.2 and 2123.3 mg/L, respectively. The concentration of PO4(3-) ion was lower than its initial concentration in all reactors, indicating considerable fixation of PO4(3-) as it was released, by struvite and other solid species formation. The decrease in the concentration of Mg2+ ions similar to PO4(3-) was accepted as evidence for the formation of solid species composed of Mg2+ and PO4(3), in addition to struvite. Water
Publisher: Elsevier BV
Date: 12-2005
Publisher: Elsevier BV
Date: 2011
Publisher: IWA Publishing
Date: 1997
Publisher: Elsevier BV
Date: 08-2007
DOI: 10.1016/J.BIORTECH.2006.08.027
Abstract: Research was conducted at Middle East Technical University (METU), Ankara, Turkey in 2000 to determine whether a reed bed filled with an economical Turkish fill media that has high phosphorus (P) sorption capacity, could be implemented and operated successfully under field conditions. In batch-scale P-sorption experiments, the P-sorption capacity of the blast furnace granulated slag (BFGS) of KARDEMIR Iron and Steel Ltd., Co., Turkey, was found to be higher compared to other candidate filter materials due to its higher Ca content and porous structure. In this regard, a vertical subsurface flow constructed wetland (CW) (30 m(2)), planted with Phragmites australis was implemented at METU to treat primarily treated domestic wastewater, at a hydraulic rate of 100 mm d(-1), intermittently. The layers of the filtration media constituted of sand, BFGS, and gravel. According to the first year monitoring study, average influent and effluent total phosphorus (TP) concentrations were 6.61+/-1.78 mg L(-1) and 3.18+/-1.82 mg L(-1) respectively. After 12 months, slag s les were taken from the reed bed and P-extraction experiments were performed to elucidate the dominant P-retention mechanisms. Main pools for P-retention were the loosely-bounded and Ca-bounded P due to the material's basic conditions (average pH>7.7) and higher Ca content. This study indicated the potential use of the slag reed bed with higher P-removal capacity for secondary and tertiary treatment under the field conditions. However, the P-sorption isotherms obtained under the laboratory conditions could not be used favorably to determine the longevity of the reed bed in terms of P-retention.
Publisher: AIP Publishing
Date: 11-2012
DOI: 10.1063/1.4769203
Abstract: The organic fraction of municipal solid waste can be a significant energy source for renewable energy generation. The total production of municipal solid waste in Turkey was 25 × 106 tones per year. Anaerobic digestion (AD) process may be a solution to the problems of energy demand and waste management since it provides biomethanation along with waste stabilization. AD can be operated in single or two phase configurations. Two-phase processes have some advantages over one phase systems in terms of selection of microorganisms, process efficiency, and reactor size. In this study, biochemical methane production experiments were performed in order to investigate whether phase separation enhanced the efficiency of methanogenic activity or not. The performances were compared in terms of total chemical oxygen demand (tCOD) and volatile solids (VS) reductions, and cumulative gas production. The experimental results indicated that 10% and 23% increases in tCOD and VS removals were achieved, respectively, by phase separation. The acetic and propionic acids were not detected in the reactors, which was an indication of successful methanization.
Publisher: Elsevier BV
Date: 06-2004
Publisher: Elsevier BV
Date: 03-2011
Publisher: American Meteorological Society
Date: 04-10-2013
DOI: 10.1175/JCLI-D-12-00769.1
Abstract: The number of tropical cyclones (TCs) in the Australian region exhibits a large variation between different ENSO regimes. While the difference in TC numbers and spatial distribution of genesis locations between the canonical El Niño and La Niña regimes is well known, the authors demonstrate that a statistically significant difference in TC numbers also exists between the recently identified negative-neutral and positive-neutral regimes. Compared to the negative-neutral and La Niña regimes, significantly fewer TCs form in the Australian region during the positive-neutral regime, particularly in the eastern subregion. This difference is attributed to concomitant changes in various large-scale environmental conditions such as sea level pressure, relative vorticity, vertical motion, and sea surface temperature.
Publisher: Elsevier BV
Date: 09-2007
DOI: 10.1016/J.JENVMAN.2006.06.021
Abstract: Possible cleaner production (CP) opportunities for a milk processing facility were examined in this study. The CP concept and its key tools of implementation were used to assess the potential CP opportunities in the facility studied. The general production process and its resulting environmental loads were investigated by taking possible CP opportunities as the basis of study. The methodology developed for CP opportunity assessment in the milk processing facility covered two major steps: preparation of checklists to assist auditing and CP opportunity assessment, and implementation of the mass-balance analysis. For mass-balance analysis, measurements and experimental analysis of the mass flows were utilized to determine the inputs and outputs. Prepared checklists were utilized to determine waste reduction options that could be implemented. Selected opportunities were evaluated considering their environmental benefits and economic feasibility. The results of the study indicated that 50% of the service water used, 9.3% of the current wastewater (WW) discharge, 65.36% of the chemical use and the discharge of 181.9 kg/day of chemical oxygen demand (COD) and 20.7 kg/day of total suspended solids (TSS) could be eliminated and 19.6% of the service water used could be recycled/reused.
Publisher: Informa UK Limited
Date: 09-08-2012
Publisher: Elsevier BV
Date: 05-2010
DOI: 10.1016/J.WASMAN.2009.11.002
Abstract: The bio-hydrogen generation potential of sugar industry wastes was investigated. In the first part of the study, acidogenic anaerobic culture was enriched from the mixed anaerobic culture (MAC) through acidification of glucose. In the second part of the study, glucose acclimated acidogenic seed was used, along with the indigenous microorganisms, MAC, 2-bromoethanesulfonate treated MAC and heat treated MAC. Two different COD levels (4.5 and 30g/L COD) were investigated for each culture type. Reactors with initial COD concentration of 4.5g/L had higher H(2) yields (20.3-87.7mL H(2)/g COD) than the reactors with initial COD concentration of 30g/L (0.9-16.6mL H(2)/g COD). The 2-bromoethanesulfonate and heat treatment of MAC inhibited the methanogenic activity, but did not increase the H(2) production yield. The maximum H(2) production (87.7mL H(2)/g COD) and minimum methanogenic activity were observed in the unseeded reactor with 4.5g/L of initial COD.
Publisher: Elsevier BV
Date: 07-2014
Publisher: Elsevier BV
Date: 03-2008
Publisher: MDPI AG
Date: 25-11-2022
DOI: 10.3390/SU142315693
Abstract: Carbon-based conductive additives have been studied for their positive effects on anaerobic digestion (AD) using synthetic substrates, but their importance in wastewater sludge digestion has not been sufficiently explored. This research investigated and compared the effects of two conductive materials (graphene and petroleum coke) with and without trace metal supplementation. The results indicated that supplementing reactors with graphene and petroleum coke could significantly improve biogas production. The supplementation of 1 g/L petroleum coke and 2 g/L graphene, without trace metal addition, led to an increase in the biogas production by 19.10 ± 1.04% and 16.97 ± 5.00%, respectively. Thus, it can be concluded that petroleum coke, which is an oil refinery by-product, can be used to enhance biogas production in a similar way to other carbon-based conductive materials that are currently available on the market. Moreover, using petroleum coke and graphene, the average chemical oxygen demand (COD) removal was 42.84 ± 1.23% and 42.80 ± 0.45%, respectively, without the addition of trace metals. On the other hand, supplementation of the reactors with trace elements resulted in a COD removal of 34.65 ± 0.43% and 34.05 ± 0.45% using petroleum coke and graphene, respectively.
Publisher: Elsevier BV
Date: 04-2003
Publisher: Springer Science and Business Media LLC
Date: 08-03-2014
Publisher: Elsevier BV
Date: 12-2005
Publisher: Elsevier BV
Date: 10-2000
Publisher: American Meteorological Society
Date: 15-11-2016
Abstract: The 5-day Rossby–Haurwitz wave is unlike other large-scale wave modes that interact with tropical rainfall in that associated rainfall presents as a modulation of localized areas of rainfall instead of propagating with the wave. This form of wave-modulated convective organization in climate models has received little attention. This study investigates the simulation of interactions between the 5-day wave and tropical convection in 30 models from phase 5 of the Coupled Model Intercomparison Project (CMIP5) and compares these with the interaction diagnosed from ERA-Interim and TRMM precipitation data. Models simulate the dry dynamics of the 5-day wave well, with realistic coherences between upper- and lower-tropospheric winds, as well as magnitudes and geographic distribution of wave wind anomalies being close to observations. The models consistently display significant coherences between 5-day-wave zonal winds and precipitation but perform less well at simulating the spatial distribution and magnitude of precipitation anomalies. For ex le, a third of the models do not reproduce significant observed anomalies near the Andes, and the best-performing model simulates only 38% of the observed variance over the tropical Andes and 24% of the observed variance over the Gulf of Guinea. Models with higher resolution perform better in simulating the magnitude of the Andean rainfall anomalies, but there is no similar relationship over the Gulf of Guinea. The evidence therefore suggests that the simulated interaction is mostly one way only, with the wave dynamics forcing the precipitation variations on the 5-day time scale.
Publisher: Springer Science and Business Media LLC
Date: 2000
Abstract: The anaerobic treatability and methane generation potential of the wastewaters of the three important agro-industries in Turkey, namely, cheese-making, poultry breeding and the olive-oil mill industries were studied. Biochemical methane potential (BMP) experiments were conducted for different initial chemical oxygen demand (COD) concentrations. The results indicate that anaerobic treatment was possible for all the wastewaters studied and the biogas produced had a high methane content.
Publisher: American Geophysical Union (AGU)
Date: 10-09-2016
DOI: 10.1002/2016GL069987
Publisher: MDPI AG
Date: 18-03-2023
DOI: 10.3390/FERMENTATION9030297
Abstract: The anaerobic digestion (AD) of compost leachate has been scarcely investigated and, to the best of our knowledge, no previous work has analyzed the kinetics of the process in completely stirred tank reactors (CSTR). To overcome this lack of knowledge, the present work aimed to deepen the study of the AD of compost leachate in CSTR and to identify the kinetics that can represent the process evolution under different operating conditions. In this regard, an experimental investigation was carried out on a laboratory anaerobic pilot plant that worked in semi-continuous mode under mesophilic conditions. After the start-up phase, the digester was fed with organic loading rates (OLR) between 4 and 30 gCOD/Ld. The chemical oxygen demand (COD) removal ranged between 80 and 85% for OLR values up to 20 gCOD/Ld and, then, it was observed as 54% at 30 gCOD/Ld. The deterioration of process performance was caused by an excessive generation of volatile fatty acids leading to a decrease of methane production yield from 0.32–0.36 LCH4/gCODremoved at 20 gCOD/Ld, to 0.23–0.26 LCH4/gCODremoved at 30 gCOD/Ld. Using kinetic analysis, the Monod model was shown to be quite accurate in modelling the trends of COD degradation rates for OLR values up to 20 gCOD/Ld. On the other hand, a better fit was achieved with the Haldane model at 30 gCOD/Ld. The conducted modelling allowed to identify the kinetic parameters for each model. The detected results could help in the management and design of the digesters for the treatment of compost leachate.
Publisher: Elsevier BV
Date: 2008
DOI: 10.1016/J.JENVMAN.2006.12.002
Abstract: Poor ammonia-nitrogen removal in methanogenic anaerobic reactors digesting animal manure has been reported as an important disadvantage of anaerobic digestion (AD) in several studies. Development of anaerobic processes that are capable of producing reduced ammonia-nitrogen levels in their effluent is one of the areas where further research must be pursued if AD technology is to be made more effective and economically advantageous. One approach to removing ammonia from anaerobically digested effluents is the forced precipitation of magnesium ammonium phosphate hexahydrate (MgNH4PO4 x 6H2O), commonly called struvite. Struvite is a valuable plant nutrient source for nitrogen and phosphorus since it releases them slowly and has non-burning features because of its low solubility in water. This study investigated coupling AD and controlled struvite precipitation in the same reactor to minimize the nitrogen removal costs and possibly increase the performance of the AD by reducing the ammonia concentration which has an adverse effect on anaerobic bacteria. The results indicated that up to 19% extra COD and almost 11% extra NH3 removals were achieved relative to a control by adding 1750 mg/L of MgCl2 x 6H2O to the anaerobic reactor.
Publisher: Elsevier BV
Date: 04-2007
Publisher: Elsevier BV
Date: 2008
DOI: 10.1016/J.WASMAN.2006.11.005
Abstract: Dry anaerobic digestion of high solids animal manure is of increasing importance since conventional slurry digestion is not an effective system for these manures. The investment costs for large-size reactors, costs for heating these reactors, handling, dewatering, and the disposal of the digested residue decrease the benefits of conventional slurry anaerobic digestion for high solids animal manure. Even though leaching bed reactors (LBR) constitute a promising option for dry anaerobic biogasification of animal manure, no study is cited in the literature for animal manure, excluding a single study on cattle waste which utilized a similar concept in a different experimental set-up, namely a packed bed digester. Therefore, this work was undertaken to investigate the anaerobic biogasification of undiluted dairy manure in LBRs. To this purpose anaerobic leaching bed reactors (ALBR) packed with a mixture of dairy manure, anaerobic seed and wood powder/chips were operated. The ALBRs were fed with water, and the leachate that was collected from their effluents was subjected to biochemical methane potential (BMP) experiments to determine the biogas production. The results revealed that LBRs can successfully be applied to anaerobic digestion of undiluted dairy manure with around 25% improvement in biogas production relative to conventional (slurry) anaerobic digesters.
Publisher: Wiley
Date: 09-2008
Publisher: Elsevier BV
Date: 03-1998
Publisher: Elsevier BV
Date: 2009
Publisher: Wiley
Date: 04-05-2005
DOI: 10.1002/JCTB.1296
Publisher: American Society of Civil Engineers (ASCE)
Date: 04-2008
Publisher: Elsevier BV
Date: 2001
DOI: 10.1016/S0956-053X(01)00013-7
Abstract: In the pulp and paper industry, lignin and other color compounds are removed by chemical agents in bleaching process. Use of chlorine-based agents results in production of degradation products which include various chloro-organic derivatives. Since these new compounds are highly chlorinated, they cause a problem in the treatment of pulp and paper industry wastewaters. Chemical precipitation, lagooning, activated sludge, and anaerobic treatment are the processes used for treating pulp and paper effluents. Furthermore, a combination of these processes is also applicable. In this study, the effluent of Dalaman SEKA Pulp and Paper Industry was examined for its toxic effects on anaerobic microorganisms by anaerobic toxicity assay. Additionally, this wastewater was applied to a sequential biotreatment process consisting of an upflow anaerobic sludge blanket as the anaerobic stage and a once-through completely mixed stirred tank as the aerobic stage. Results indicated that: (1) Dalaman SEKA Pulp and Paper Industry wastewater exerted no inhibitory effects on the anaerobic cultures under the studied conditions, and (2) application of a sequential biological (anaerobic/aerobic) system to treat the Dalaman SEKA Pulp and Paper Industry wastewater resulted in approximately 91% COD and 58% AOX removals at a HRT of 5 and 6.54 h for anaerobic and aerobic, respectively.
Publisher: Mary Ann Liebert Inc
Date: 09-2009
Publisher: Elsevier BV
Date: 11-2009
DOI: 10.1016/J.CHEMOSPHERE.2009.08.027
Abstract: In this study, anaerobic acidification of sugar beet processing wastes and subsequent liquid-liquid extraction of produced fermentation metabolites were investigated. The aim of extraction experiments was to asses the influence of pH and extractant (trioctylphosphine oxide (TOPO) in kerosene) concentrations on the recovery of volatile fatty acids (VFAs) from fermentation broth. The effect of TOPO in kerosene concentration was as crucial as the effect of pH on the recovery of VFAs via extraction. Consequently, pH 2.5 was determined as optimum. At this pH, percent recoveries of VFAs were changed from 43% to 98%, depending on the type of the acid extracted (acetic, butyric, propionic and valeric acids) and the concentration of TOPO in kerosene (5-20%). As the concentration of TOPO in kerosene was increased, efficiency of extraction was increased. As a result, highest VFA recoveries (61-98%) were observed at 20% TOPO in kerosene with distribution ratio values ranging between 1.54 and 40.79. At pH 2.5, the increase in TOPO concentration directly increased the chemical oxygen demand (COD) removal efficiencies, as it does for total VFA recovery. Up to 72% COD removals were achieved, at 20% TOPO in kerosene at pH 2.5, while the removal efficiencies remained between 19% and 22% at pH 5.5.
Publisher: Elsevier BV
Date: 2001
DOI: 10.1016/S0956-053X(00)00114-8
Abstract: Anaerobic treatability and methane generation potential of cheese whey were determined in batch reactors. Furthermore, the effect of nutrient and trace metal supplementation on the batch anaerobic treatment, and the high-rate anaerobic treatability of cheese whey in upflow anaerobic sludge blanket (UASB) reactors were investigated. To this purpose biochemical methane potential experiments were conducted and single- and two-stage UASB reactors with granular cultures were operated. In UASB experiments significance of process staging, operational parameters such as hydraulic retention time (HRT), influent chemical oxygen demand (COD) concentration and loading rate were also investigated. The results revealed that nutrient and trace metal supplementation is vital for the anaerobic treatment of cheese whey the anaerobic methane generation for the cheese whey studied was found to be 424 ml CH4/g COD (23.4 1 CH4/l cheese whey) undiluted cheese whey could be treated anaerobically at relatively short HRT values (2.06-4.95 days) without any significant stability problems HRT values as low as 2-3 days can be used for the anaerobic treatment of cheese whey, with a COD removal efficiency of 95-97% at influent COD concentration of 42 700 +/- 141-55 100 +/- 283 mg/l.
Publisher: Springer Science and Business Media LLC
Date: 23-10-2013
DOI: 10.1007/S00253-012-4499-9
Abstract: Is it possible to create conditions in the anaerobic digesters to control nutrients without changing the performance of a reactor? This study investigates an answer for this question. To this purpose, anaerobic reactors are operated at high concentrations of Mg(2+) ion to harvest the nutrient ions (NH4 (+) and PO4 (3-)) in the form of struvite, that is, magnesium ammonium phosphate. The effects of this modification on the anaerobic digestion of sewage sludge were investigated in terms of chemical oxygen demand (COD) removal and cumulative CH4 production as well as the changes in the biological ersity. The results showed that approximately 50 % of the nutrients (NH4 (+) and PO4 (3-)) were removed regardless of the method adopted for the addition of Mg(2+) ion, slug or daily dosing. The numbers of Methanosaeta and Methanosarcina in the s les withdrawn prior to and after the addition of Mg(2+) did not show significant difference according to the results obtained from qPCR analyses. The research results showed that the addition of Mg(2+) into the anaerobic digesters in municipal wastewater treatment facilities may help to remove the nutrients from the effluent while recovering in their solid forms.
Publisher: Wiley
Date: 12-04-2011
DOI: 10.1002/JCTB.2622
Publisher: Wiley
Date: 14-09-2004
DOI: 10.1002/JCTB.1138
Publisher: Elsevier BV
Date: 08-2013
Publisher: Elsevier BV
Date: 02-2014
Publisher: Wiley
Date: 12-2010
Publisher: WIT Press
Date: 11-04-2011
DOI: 10.2495/ESUS110121
Publisher: Elsevier BV
Date: 2003
DOI: 10.1016/S0045-6535(02)00552-0
Abstract: In this study, the inhibitory effects of lindane (LIN) on originally unacclimated mixed anaerobic cultures were investigated by anaerobic toxicity assay (ATA) experiments. ATA experiments revealed that 10 mg/l LIN exerted inhibitory effects on anaerobic cultures, which was recoverable. Continuous reactor experiments conducted to determine the inhibitory effects of LIN and the maximum LIN loading rate achievable in two-stage upflow anaerobic sludge blanket (UASB) reactors indicated that anaerobic granular cultures were successfully acclimated to 30 mg/l LIN. The maximum LIN loading rate and minimum hydraulic retention time (HRT) possible for the UASB system were 10 mg/l day and 18 h, respectively, which resulted in the overall chemical oxygen demand (COD) removal efficiency of 89%.
Publisher: Wiley
Date: 29-08-2023
DOI: 10.1002/BTPR.3385
Abstract: The use of carbon‐based conductive materials has been shown to lead to an increase in biogas and methane yields during anaerobic digestion (AD). The effect of these additives on AD using synthetic substrates has been extensively studied, yet their significance for wastewater sludge digestion has not been adequately investigated. Therefore, the aim of this research was to optimize the concentration of petroleum coke (PC) that is a waste by‐product of oil refineries, for the anaerobic digestion of wastewater sludge and investigation of phosphate removal in the AD process in the mesophilic temperature range. According to the results of the experiments, supplementing reactors with PC could significantly improve biogas and methane production. Supplementation of reactors with 1.5 g/L PC led to 23.40 ± 0.26% and 42.55 ± 3.97% increase in biogas production and methane generation, respectively. Moreover, the average volatile solids (VS), phosphate, and chemical oxygen demand (COD) removals were 43.43 ± 0.73, 46.74 ± 0.77%, and 60.40 ± 0.38%, respectively.
Publisher: Elsevier BV
Date: 09-2010
DOI: 10.1016/J.JHAZMAT.2010.05.004
Abstract: The formation of struvite (MgNH(4)PO(4).6H(2)O) in wastewater treatment plants can lead to scaling and thus operational problems reducing the treatment efficiency. However, struvite has significant commercial value as an agricultural fertilizer. Therefore, controlled struvite formation in wastewater treatment plants not only presents an opportunity to recover nutrients but also corresponds to the valorization of wastes. NH(4)-N and PO(4)-P removal and recovery from the effluent of a full-scale sewage sludge anaerobic digester via controlled struvite precipitation were investigated in this study. The effect of the residual heavy metal and micropollutant content of the formed struvite on fertilizer quality was also evaluated. Removal efficiencies of NH(4)-N, PO(4)-P and COD were 89.35%, 95% and 39.78% when Mg:N:P molar ratio was 1.5:1:1 and pH was 9.0. Mercury, nickel, zinc and chrome concentrations derived from struvite precipitation were below the regulatory limit for fertilizer usage in Turkey. The precipitate did not contain polychlorinated biphenyls (PCB). X-ray diffraction (XRD) analysis conducted on the precipitate indicated a struvite formation.
Publisher: Elsevier BV
Date: 11-2003
Publisher: American Society of Civil Engineers (ASCE)
Date: 08-2019
Publisher: Springer Science and Business Media LLC
Date: 18-01-2022
Publisher: American Meteorological Society
Date: 11-2017
Abstract: Reanalysis data and satellite-derived rainfall measurements are examined to determine possible mechanisms linking the “5 day” Rossby–Haurwitz wave to localized variations of tropical convection. The mechanisms in all regions rely on the modulation of zonal winds near the equator by the wave, but the nature of these mechanisms depends strongly on local topography and local climate. In the upper Amazon basin, the wave modulates the strength of prevailing easterlies and thus the upslope flow and associated convection on the eastern edge of the Andes. Similar modulation of upslope flow is involved off the Panamanian and Colombian Pacific coasts, but the deflection and confluence of low-level wind in the presence of the Andes and moisture transports across the Andes from the Amazon basin are also factors. Similar deflection and confluence of winds around and through the Maritime Continent lead to low-level ergence and convection anomalies over the eastern Indian Ocean. Anomalous moisture transports from the Congo basin to the eastern and northeastern Gulf of Guinea due to the wave affect atmospheric moisture over the Gulf of Guinea and thus convection in the region. Over oceanic convergence zones, modulations of the prevailing winds by the wave affect the overall wind magnitude, changing evaporation from the ocean surface and atmospheric moisture. Most of these mechanisms arise from the nonuniform nature of Earth’s surface and suggest that other external Rossby–Haurwitz waves may have similar interactions with convection.
Publisher: Mary Ann Liebert Inc
Date: 04-2008
No related grants have been discovered for Goksel Demirer.