ORCID Profile
0000-0001-9660-4383
Current Organisation
Universiti Malaya
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Publisher: Wiley
Date: 23-05-2011
Abstract: The volatilisation of ferrocene (Fc), dissolved in the ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, [C(4)mpyrr][NTf(2)], to the gas phase has been indirectly monitored by cyclic voltammetry and chrono erometry. Simulation of the observed trends in concentration with time using a simple model allowed quantification of the process. Volatilisation of dissolved Fc under flowing wet and dry dinitrogen gas (N(2)) was found to be kinetically limited with a rate constant in the region of 2×10(-7) cm s(-1). The activation energy of diffusion for Fc was found to be 28.2±0.7 kJ mol(-1), while the activation energy of volatilisation of Fc from [C(4)mpyrr][NTf(2)] to dry N(2) was found to be 85±2 kJ mol(-1).
Publisher: Royal Society of Chemistry (RSC)
Date: 2011
DOI: 10.1039/C1CC12336J
Abstract: The evaporation of dissolved ferrocene from non-volatile ionic liquids under a flow of nitrogen gas has been monitored voltammetrically and modelled mathematically. The rate of volatilisation was found to depend on the surface tension of the ionic liquid, and a model is presented.
Publisher: Wiley
Date: 20-12-2011
Publisher: Elsevier BV
Date: 06-2011
Publisher: Elsevier BV
Date: 08-2017
Publisher: Elsevier BV
Date: 11-0055
Publisher: Royal Society of Chemistry (RSC)
Date: 2012
DOI: 10.1039/C2NJ20704D
Location: United Kingdom of Great Britain and Northern Ireland
No related grants have been discovered for Ninie Suhana Abdul Manan.