ORCID Profile
0000-0001-5125-6661
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In Research Link Australia (RLA), "Research Topics" refer to ANZSRC FOR and SEO codes. These topics are either sourced from ANZSRC FOR and SEO codes listed in researchers' related grants or generated by a large language model (LLM) based on their publications.
Manufacturing Engineering | Manufacturing Processes and Technologies (excl. Textiles) | Materials Engineering | Composite and Hybrid Materials | Water treatment processes | Maritime engineering | Physical Chemistry of Materials | Macromolecular and Materials Chemistry | Structural Engineering | Chemical Characterisation of Materials | Textile Technology | Ship and platform structures (incl. maritime hydrodynamics) | Nanomaterials | Analytical Chemistry not elsewhere classified | Functional Materials | Polymers and Plastics | Macromolecular and Materials Chemistry not elsewhere classified | Metals and Alloy Materials | Biological control |
Education and Training Systems not elsewhere classified | Polymeric Materials (e.g. Paints) | Preference, Behaviour and Welfare | Metals (e.g. Composites, Coatings, Bonding) | Instrumentation not elsewhere classified | Natural Fibres, Yarns and Fabrics | Synthetic Fibres, Yarns and Fabrics | Plastics in Primary Forms | Plastic Products (incl. Construction Materials) | Industrial Instruments | Industrial Chemicals and Related Products not elsewhere classified | Scientific Instruments | Expanding Knowledge in Engineering | Coated Metal and Metal-Coated Products
Publisher: Mark Allen Group
Date: 11-2016
Publisher: Royal Society of Chemistry (RSC)
Date: 2013
DOI: 10.1039/C3NR01422C
Abstract: The detection and control of the temperature variation at the nano-scale level of thermo-mechanical materials during a compression process have been challenging issues. In this paper, an empirical method is proposed to predict the temperature at the nano-scale level during the solid-state phase transition phenomenon in NiTi shape memory alloys. Isothermal data was used as a reference to determine the temperature change at different loading rates. The temperature of the phase transformed zone underneath the tip increased by ∼3 to 40 °C as the loading rate increased. The temperature approached a constant with further increase in indentation depth. A few layers of graphene were used to enhance the cooling process at different loading rates. Due to the presence of graphene layers the temperature beneath the tip decreased by a further ∼3 to 10 °C depending on the loading rate. Compared with highly polished NiTi, deeper indentation depths were also observed during the solid-state phase transition, especially at the rate dependent zones. Larger superelastic deformations confirmed that the latent heat transfer through the deposited graphene layers allowed a larger phase transition volume and, therefore, more stress relaxation and penetration depth.
Publisher: Wiley
Date: 08-04-2020
Publisher: Elsevier BV
Date: 12-2012
Publisher: MDPI AG
Date: 26-10-2015
DOI: 10.3390/NANO5041766
Publisher: Elsevier BV
Date: 08-2015
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C4RA16637J
Abstract: The presence of SEBS and x GnP in PP/PS blend allows better stress transfer between the phases.
Publisher: Wiley
Date: 06-2023
Abstract: The radical‐bearing epoxy monomer could be the ideal embodiment of multifunctionality in epoxy‐based materials. This study demonstrates the potential of macroradical epoxies as surface coating materials. A diepoxide monomer derivatized with a stable nitroxide radical is polymerized with a diamine hardener under the influence of a magnetic field. The magnetically oriented and stable radicals in the polymer backbone render the coatings antimicrobial. The unconventional use of magnets during polymerization proved crucial in correlating the structure‐property relationships with antimicrobial performance inferred from oscillatory rheological technique, polarized macro‐attenuated total reflectance – infrared (macro‐ATR‐IR) spectroscopy and X‐ray photoelectron spectroscopy (XPS). The magnetic thermal curing influenced the surface morphology, resulting in a synergy of the coating's radical nature with microbiostatic performance assessed using the Kirby‐Bauer test and liquid chromatography – mass spectroscopy (LC–MS). Further, the magnetic curing of blends with a traditional epoxy monomer demonstrates that radical alignment is more critical than radical density in imparting biocidal behavior. This study shows how the systematic use of magnets during polymerization could pave for probing more significant insights into the mechanism of antimicrobial action in radical‐bearing polymers.
Publisher: Elsevier BV
Date: 08-2015
DOI: 10.1016/J.JMBBM.2015.04.005
Abstract: Composite biomaterials provide alternative materials that improve on the properties of the in idual components and can be used to replace or restore damaged or diseased tissues. Typically, a composite biomaterial consists of a matrix, often a polymer, with one or more fillers that can be made up of particles, sheets or fibres. The polymer matrix can be chosen from a wide range of compositions and can be fabricated easily and rapidly into complex shapes and structures. In the present study we have examined three size fractions of collagen-containing particles embedded at up to 60% w/w in a poly(vinyl alcohol) (PVA) matrix. The particles used were bone particles, which are a mineral-collagen composite and demineralised bone, which gives naturally cross-linked collagen particles. SEM showed well dispersed particles in the PVA matrix for all concentrations and sizes of particles, with FTIR suggesting collagen to PVA hydrogen bonding. Tg of membranes shifted to a slightly lower temperature with increasing collagen content, along with a minor amount of melting point depression. The modulus and tensile strength of membranes were improved with the addition of both particles up to 10 wt%, and were clearly strengthened by the addition, although this effect decreased with higher collagen loadings. Elongation at break decreased with collagen content. Cell adhesion to the membranes was observed associated with the collagen particles, indicating a lack of cytotoxicity.
Publisher: Royal Society of Chemistry (RSC)
Date: 2013
DOI: 10.1039/C3SM50646K
Publisher: Springer Science and Business Media LLC
Date: 12-02-2202
DOI: 10.1038/S41598-018-21114-5
Abstract: Graphene based room temperature flexible nanocomposites were prepared using epoxy thermosets for the first time. Flexible behavior was induced into the epoxy thermosets by introducing charge transfer complexes between functional groups within cross linked epoxy and room temperature ionic liquid ions. The graphene nanoplatelets were found to be highly dispersed in the epoxy matrix due to ionic liquid cation–π interactions. It was observed that incorporation of small amounts of graphene into the epoxy matrix significantly enhanced the mechanical properties of the epoxy. In particular, a 0.6 wt% addition increased the tensile strength and Young’s modulus by 125% and 21% respectively. The electrical resistance of nanocomposites was found to be increased with graphene loading indicating the level of self-organization between the ILs and the graphene sheets in the matrix of the composite. The graphene nanocomposites were flexible and behave like ductile thermoplastics at room temperature. This study demonstrates the use of ionic liquid as a compatible agent to induce flexibility in inherently brittle thermoset materials and improve the dispersion of graphene to create high performance nanocomposite materials.
Publisher: Elsevier BV
Date: 03-2018
Publisher: Royal Society of Chemistry (RSC)
Date: 2017
DOI: 10.1039/C7TA01022B
Abstract: This study quantitatively defines the temperature induced chemical transformations and evolution of radial heterogeneity during the stabilisation of carbon fibre precursors.
Publisher: Elsevier BV
Date: 10-2016
Publisher: Elsevier BV
Date: 02-2017
Publisher: American Chemical Society (ACS)
Date: 09-07-2013
DOI: 10.1021/LA4017678
Abstract: Here we report a viable route to fibrillar micelles and entrapped vesicles in aqueous solutions. Nanofibrillar micelles and entrapped vesicles were prepared from complexes of a biodegradable block copolymer poly(ethylene oxide)-block-poly(lactide) (PEO-b-PLA) and a polyelectrolyte poly(acrylic acid) (PAA) in aqueous media and directly visualized using cryogenic transmission electron microscopy (cryo-TEM). The self-assembly and the morphological changes in the complexes were induced by the addition of PAA/water solution into the PEO-b-PLA in tetrahydrofuran followed by dialysis against water. A variety of morphologies including spherical wormlike and fibrillar micelles, and both unilamellar and entrapped vesicles, were observed, depending on the composition, complementary binding sites of PAA and PEO, and the change in the interfacial energy. Increasing the water content in each [AA]/[EO] ratio led to a morphological transition from spheres to vesicles, displaying both the composition- and dilution-dependent micellar-to-vesicular morphological transitions.
Publisher: American Chemical Society (ACS)
Date: 17-03-2022
Publisher: Elsevier BV
Date: 06-2016
Publisher: Elsevier BV
Date: 11-2019
Publisher: Informa UK Limited
Date: 13-08-2019
Publisher: MDPI AG
Date: 13-10-2020
Abstract: Flexible piezoelectric nanogenerators (PENG) are widely applied to harvest sustainable energy from multiple energy sources. The rational and simple design of PENG have great potential in soft electronics. Here we design a highly flexible PENG using the polyvinylidene fluoride (PVDF) and its copolymer, polyvinylidene hexafluoropropylene (PVDF-HFP) with two nanoarchitectures of semiconducting metal oxides, TiO2 and ZnO. The nanotubes of TiO2 and nanoflowers of ZnO are embedded in these different polymeric media by solvent mixing, and new fiber mats are generated by coaxial electrospinning technique. This process aligns the dipoles of polymers and nanomaterials, which is normally a pre-requisite for higher piezo potential. With excellent mechanical strength and flexibility, the tailored lightweight fiber mats are capable of producing good output voltage (a maximum of 14 V) during different mechanical vibrations at various frequencies and in response to human motions. The hybrid nanocomposite PENG is durable and inexpensive and has possible applications in wearable electronics.
Publisher: AIP Publishing
Date: 04-12-2009
DOI: 10.1063/1.3268779
Abstract: We present a study of microphase separation induced by competitive hydrogen bonding in A-b-B/C diblock copolymer/homopolymer complexes where the diblock copolymer A-b-B is immiscible and the homopolymer C can interact unequally with both A and B blocks through hydrogen bonding. A model system containing poly(2-vinyl pyridine)-block-poly(methyl methacrylate) (P2VP-b-PMMA) and poly(4-vinyl phenol) (PVPh) in tetrahydrofuran was investigated. In these self-assembled complexes, microphase separation takes place due to the disparity in intermolecular interactions. Specifically, PVPh and P2VP blocks interact strongly to form complex, whereas PVPh and PMMA blocks interact weakly. The hydrogen bonding interactions were revealed by infrared spectroscopy and analyzed in terms of the difference in interassociation constants (K), i.e., interaction parameters of each blocks of the block copolymer to the homopolymer and according to the random phase approximation. The phase behavior of the complexes was investigated with small-angle x-ray scattering and transmission electron microscopy. A series of morphologies including lamellae, hexagonal cylinders, wormlike microdomains, and hierarchical structures was documented as a function of the copolymer concentration. Moreover, we outlined how hydrogen bonding determines the self-assembly and causes morphological transitions in different A-b-B/C diblock copolymer/homopolymer systems with respect to the K values.
Publisher: Elsevier BV
Date: 05-2015
Publisher: Springer Science and Business Media LLC
Date: 14-03-2014
DOI: 10.1038/SREP04375
Publisher: Royal Society of Chemistry (RSC)
Date: 2013
DOI: 10.1039/C3RA42488J
Publisher: American Chemical Society (ACS)
Date: 13-09-2016
Publisher: American Chemical Society (ACS)
Date: 24-04-2012
DOI: 10.1021/MA300458Y
Publisher: Elsevier BV
Date: 12-1991
Publisher: American Chemical Society (ACS)
Date: 05-11-2015
Publisher: Elsevier BV
Date: 03-2016
Publisher: Elsevier BV
Date: 03-2013
Publisher: Royal Society of Chemistry (RSC)
Date: 2013
DOI: 10.1039/C3CP00064H
Abstract: The effective dispersion of carbon nanotubes (CNTs) in a thermoset was achieved using ionic liquid as the dispersion-curing agent. We preferentially dispersed multiwalled carbon nanotubes (MWCNTs) down to in idual tube levels in epoxy resin. Here the dispersion is ruled by the depletion of physical bundles within the MWCNT networks, for which molecular ordering of ionic liquids is considered responsible. The quantitative analyses using ultra small angle X-ray scattering (USAXS) confirmed the dispersion of in idual MWCNTs in the matrix. The distance between the dispersed nanotubes was calculated at different nanotube loadings using the power law fitting of the USAXS data. The fine dispersion and subsequent curing, both controlled by ionic liquid, lead to composites with substantially enhanced fracture mechanical and thermomechanical properties with no reduction in thermal properties. Merging processing techniques of nanocomposites with ionic liquid for efficient dispersion of nanotubes and preferential curing of thermosets facilitates the development of new, high performance materials.
Publisher: American Chemical Society (ACS)
Date: 04-03-2019
Publisher: Elsevier BV
Date: 05-2016
Publisher: Elsevier BV
Date: 02-2026
Publisher: Royal Society of Chemistry (RSC)
Date: 2010
DOI: 10.1039/C0SM00480D
Publisher: American Chemical Society (ACS)
Date: 19-06-2020
Publisher: Wiley
Date: 09-10-2015
DOI: 10.1002/PC.23830
Publisher: Elsevier BV
Date: 06-2011
Publisher: Royal Society of Chemistry (RSC)
Date: 2022
DOI: 10.1039/D1SM01731D
Abstract: Improving the electrical performance of macroradical epoxy thermosets to surpass the semiconductor threshold requires a comprehensive understanding of the electrical charge transport mechanisms and characteristics.
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C4CC10192H
Abstract: We report the design and synthesis of a polymer structure from a cross-linkable epoxy–ionic liquid system which behaves like a hard and brittle epoxy thermoset, perfectly ductile thermoplastic and an elastomer, all depending on controllable network compositions.
Publisher: Elsevier BV
Date: 12-2016
Publisher: Elsevier BV
Date: 2018
Publisher: Wiley
Date: 06-04-2023
Abstract: The use of the coordinated silver (I) complex based on solvate ionic liquid in epoxy resins is reported to enable unprecedented electrical and thermomechanical properties. The novel hybrid material is aligned at the molecular level using an electric field, demonstrating high electrical conductivity, excellent energy storage properties, and rapid curing behavior. The electric‐field treated epoxy resin system shows a maximum electric conductivity of 2.05 × 10 5 S m −1 , 20 folds of the same untreated system, and 3 folds of the same treated system but with 5.0% silver nanoparticles. Furthermore, this system shows an ultrafast curing rate of around 500 s at a temperature of 42.0 °C and reveals excellent energy storage achieving an average capacitance of 27.5 F g −1 at a scan rate of 1.0 mV s −1 . Quantum mechanics is applied and the synchrotron beamline is utilized to optimize and investigate the properties of the system, opening the door to the next generation of thermoset polymers with multifunctional properties.
Publisher: Elsevier BV
Date: 12-2021
Publisher: Springer International Publishing
Date: 2017
Publisher: American Chemical Society (ACS)
Date: 13-03-2020
Publisher: Elsevier BV
Date: 2020
Publisher: American Chemical Society (ACS)
Date: 20-08-2019
Publisher: Wiley
Date: 18-02-2010
DOI: 10.1002/POLB.21950
Publisher: Elsevier BV
Date: 03-2019
Publisher: Springer International Publishing
Date: 2017
Publisher: Royal Society of Chemistry (RSC)
Date: 2016
DOI: 10.1039/C6RA09823A
Abstract: The self-assembly and high temperature behavior of AB/B′ type block copolymer/homopolymer blends containing polyacrylonitrile (PAN) polymers were studied for the first time.
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C5RA05900C
Abstract: Blends between the widely used thermoset resin, epoxy, and the most abundant organic material, natural cellulose are demonstrated for the first time.
Publisher: OSA
Date: 2018
Publisher: Wiley
Date: 19-08-2009
DOI: 10.1002/POLB.21792
Publisher: Royal Society of Chemistry (RSC)
Date: 2012
DOI: 10.1039/C1SM06244A
Publisher: Elsevier BV
Date: 05-2017
Publisher: Informa UK Limited
Date: 02-04-2020
Publisher: Springer Science and Business Media LLC
Date: 09-08-2013
No related organisations have been discovered for Nishar Hameed.
Start Date: 08-2022
End Date: 08-2025
Amount: $408,019.00
Funder: Australian Research Council
View Funded ActivityStart Date: 06-2023
End Date: 06-2028
Amount: $4,930,205.00
Funder: Australian Research Council
View Funded ActivityStart Date: 06-2017
End Date: 12-2020
Amount: $360,000.00
Funder: Australian Research Council
View Funded ActivityStart Date: 07-2019
End Date: 12-2020
Amount: $514,250.00
Funder: Australian Research Council
View Funded ActivityStart Date: 06-2012
End Date: 12-2013
Amount: $220,000.00
Funder: Australian Research Council
View Funded ActivityStart Date: 03-2019
End Date: 03-2025
Amount: $4,889,410.00
Funder: Australian Research Council
View Funded Activity