ORCID Profile
0000-0002-7940-7297
Current Organisations
University of Southern Denmark
,
SDU
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Publisher: American Chemical Society (ACS)
Date: 06-2021
Publisher: American Chemical Society (ACS)
Date: 20-10-2020
Publisher: American Chemical Society (ACS)
Date: 02-03-2021
Publisher: MDPI AG
Date: 21-05-2020
DOI: 10.3390/MOLECULES25102388
Abstract: Here we focus on the thermal and variable temperature electrochemical stabilities of two ionic liquids (ILs) having a common tributyloctyl phosphonium cation [P4,4,4,8]+ and two different orthoborate anions: bis(mandelato)borate [BMB]− and bis(salicylato)borate [BScB]−. The thermo-gravimetric analysis data suggest that [P4,4,4,8][BScB] is thermally more stable than [P4,4,4,8][BMB] in both nitrogen atmosphere and air, while the impedance spectroscopy reveals that [P4,4,4,8][BScB] has higher ionic conductivity than [P4,4,4,8][BMB] over the whole studied temperature range. In contrast, the electrochemical studies confirm that [P4,4,4,8][BMB] is more stable and exhibits a wider electrochemical stability window (ESW) on a glassy carbon electrode surface as compared to [P4,4,4,8][BScB]. A continuous decrease in the ESWs of both ILs is observed as a function of operation temperature.
Publisher: Royal Society of Chemistry (RSC)
Date: 2022
DOI: 10.1039/D2CP03022E
Abstract: New structurally flexible 1-methyl- and 1,2-dimethyl-imidazolium phosphate ionic liquids (ILs) bearing oligoethers have been synthesized and thoroughly characterized.
Publisher: American Chemical Society (ACS)
Date: 11-06-2020
Publisher: American Chemical Society (ACS)
Date: 21-12-2020
No related grants have been discovered for Inayat Ali Khan.