ORCID Profile
0000-0001-5535-4867
Current Organisation
Czech Technical University in Prague
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Publisher: Royal Society of Chemistry (RSC)
Date: 2014
DOI: 10.1039/C4DT02360A
Abstract: We report the crystal structures of Ni( ii )–Ln( iii ) (where Ln = Gd or Pr) complexes and their suitably substituted diamagnetic analogues. Magnetic characterization revealed the nature of the magnetic exchange interactions and the magnetothermal properties.
Publisher: Wiley
Date: 11-09-2014
Abstract: Four isostructural [Ni2 Ln2 (CH3 CO2 )3 (HL)4 (H2 O)2 ](3+) (Ln(3+) =Dy (1), Tb (2), Ho (3) or Lu (4)) complexes and a dinuclear [NiGd(HL)2 (NO3 )3 ] (5) complex are reported (where HL=2-methoxy-6-[(E)-2'-hydroxymethyl-phenyliminomethyl]-phenolate). For compounds 1-3 and 5, the Ni(2+) ions are ferromagnetically coupled to the respective lanthanide ions. The ferromagnetic coupling in 1 suppresses the quantum tunnelling of magnetisation (QTM), resulting in a rare zero dc field Ni-Dy single-molecule magnet, with an anisotropy barrier Ueff of 19 K.
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C4CC08305A
Abstract: We have shown for the first time, by simply exploiting the hard/soft nature of ligands, single ion magnetic anisotropy of Co( ii ) tetrahedral complexes can be switched (+ve to −ve or vice versa ) rationally.
Publisher: American Chemical Society (ACS)
Date: 21-09-2016
DOI: 10.1021/ACS.INORGCHEM.6B01073
Abstract: A family of mononuclear tetrahedral cobalt(II) thiourea complexes, [Co(L
Publisher: Wiley
Date: 23-03-2017
Abstract: Four complexes containing Dy
Location: France
Location: India
No related grants have been discovered for Shefali Vaidya.