ORCID Profile
0000-0003-3542-4850
Current Organisation
University Of Strathclyde
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Publisher: Royal Society of Chemistry (RSC)
Date: 2020
DOI: 10.1039/D0QI00645A
Abstract: A molecular material undergoes spin-switching as it exchanges MeOH, EtOH or n PrOH with acetone from the lattice. The subsequent thermal single-crystal-to-single-crystal desorption of n PrOH is followed by single crystal X-ray diffraction snapshots.
Publisher: Royal Society of Chemistry (RSC)
Date: 2021
DOI: 10.1039/D0FD90033H
Publisher: Royal Society of Chemistry (RSC)
Date: 2021
DOI: 10.1039/D0FD90032J
Publisher: Royal Society of Chemistry (RSC)
Date: 2012
DOI: 10.1039/C1CC15682A
Abstract: An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each "half-SMM" composing this molecular cluster pair.
Publisher: Royal Society of Chemistry (RSC)
Date: 2011
DOI: 10.1039/C0NJ00861C
Publisher: Wiley
Date: 25-03-2011
Publisher: Royal Society of Chemistry (RSC)
Date: 2019
DOI: 10.1039/C9SC00987F
Abstract: Symmetry control using DABCO generates a large easy-plane magnetic anisotropy with zero rhombic anisotropy.
Publisher: Wiley
Date: 10-11-2014
Publisher: Royal Society of Chemistry (RSC)
Date: 2017
DOI: 10.1039/C7DT02430D
Abstract: 3,5-Diamino-1,2,4-triazole derivatives direct the assembly of {MnIII5} twisted bow-ties.
Publisher: Royal Society of Chemistry (RSC)
Date: 2010
DOI: 10.1039/B927032A
Abstract: A new functionalized bis-pyrazol-pyridine ligand has been prepared by reaction with hydrazine of the corresponding bis-β-diketone precursor, also unprecedented. The aerobic reaction of this ligand with ferrous thiocyanate in the presence of ascorbic or oxalic acid affords the dinuclear complex of seven-coordinate Fe(III), [Fe₂(H₄L2)₂(ox)(NCS)₄] (1), as revealed by single crystal X-ray diffraction. This may represent an entry into a new family of [Fe₂] compounds with heptacoordinate metal centres. The capacity of this unusual chromophore to undergo magnetic super-exchange was investigated by means of bulk magnetization and DFT calculations. Both approaches confirmed the presence of antiferromagnetic interactions within the molecule. The theoretical investigation has served to describe the magnetic orbitals of Fe(III) in this unusual coordination geometry, as well as the exchange mechanism. A brief review of the scarce number of iron heptacoordinate complexes reported in the literature is also included and discussed.
Publisher: Royal Society of Chemistry (RSC)
Date: 2020
DOI: 10.1039/D0CC02382E
Abstract: Minimising geometric distortion in the first coordination sphere generates a large axial magnetic anisotropy in trigonal bipyramidal Fe( ii ) and rare slow magnetic relaxation.
Publisher: Royal Society of Chemistry (RSC)
Date: 2018
DOI: 10.1039/C7SC04460G
Abstract: The synergistic combination of high pressure techniques with ab initio methods creates a powerful tool to understand giant magnetic anisotropy.
Location: United Kingdom of Great Britain and Northern Ireland
Location: United Kingdom of Great Britain and Northern Ireland
No related grants have been discovered for Gavin Craig.