ORCID Profile
0000-0002-3606-8854
Current Organisation
Universidad de Granada
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Publisher: Geological Society of America
Date: 20-09-2021
DOI: 10.1130/B36065.1
Abstract: Spinel peridotite xenoliths (one plagioclase-bearing) hosted in alkaline basalts from Tallante (southeast Spain) record the mineralogical and geochemical fingerprint of the subcontinental lithospheric mantle (SCLM) evolution beneath the southern Iberian margin. Mantle metasomatism in fertile lherzolites caused the crystallization of clinopyroxene + orthopyroxene + spinel clusters through the percolation of Miocene subalkaline melts during the westward migration of the subduction front in the western Mediterranean. In the Pliocene, heat and volatiles provided by alkaline host-magmas triggered very low melting degrees of metasomatic pyroxene-spinel assemblages, producing melt quenched to silicate glass and reactive spongy coronae around clinopyroxene and spinel. Refertilization of the Tallante peridotites induced the precipitation of base-metal sulfides (BMS) included in metasomatic clino- and orthopyroxene. These sulfides consist of pentlandite ± chalcopyrite ± bornite aggregates with homogeneous composition in terms of major elements (Ni, Fe, Cu) and semi-metals (Se, As, Te, Sb, Bi), but with wide variability of platinum-group elements (PGE) fractionation (0.14 & PdN/IrN & 30.74). Heterogeneous PGE signatures, as well as the presence of euhedral Pt-Pd-Sn-rich platinum-group minerals (PGM) and/or Au-particles within BMS, cannot be explained by conventional models of chalcophile partitioning from sulfide melt. Alternatively, we suggest that they reflect the incorporation of distinct populations of BMS, PGM, and metal nanoparticles (especially of Pt, Pd, and Au) during mantle melting and/or melt percolation. Therefore, we conclude that Miocene subalkaline melts released by asthenosphere upwelling upon slab tearing of the Iberian continental margin effectively stored metals in metasomatized domains of this sector of the SCLM. Remarkably high Au concentrations in Tallante BMS (median 1.78 ppm) support that these metasomatized domains provided a fertile source of metals, especially gold, for the ore-productive Miocene magmatism of the westernmost Mediterranean.
Publisher: Informa UK Limited
Date: 24-09-2022
Publisher: Copernicus GmbH
Date: 04-03-2021
DOI: 10.5194/EGUSPHERE-EGU21-11150
Abstract: & & Magmatic-hydrothermal gold deposits form clusters in the Earth& #8217 s crust and are heterogeneously distributed within lithospheric blocks. A global assessment of whole-rock gold abundances in mantle lithologies worldwide indicates that Au concentrations increase with increasing fertility of mantle peridotites, with median Au contents ranging from 0.50 ppb in dunites, 1.00 ppb in harzburgites, and up to 1.26 ppb in lherzolites. Of particular interest are those volumes of fertile Subcontinental Lithospheric Mantle (SCLM) veined by pyroxenites and wehrlites, usually the Au-richest lithologies in the mantle as they have 2.05 ppb median Au concentrations. Partial melting of SCLM domains endowed in gold seems to play a key role in the genesis of gold-enriched magmas parental to magmatic-hydrothermal gold deposits in continental arc settings. The mineralogical expressions of gold inventory in such fertile mantle rocks are accessory Ni-Fe-Cu sulfides and discrete micron-to-nano-sized Au mineral particles that control the extraction and transport of gold in the mantle. Mantle xenoliths from the Neogene Volcanic Province (NVP) of southeast Spain represent an excellent ex le of SCLM refertilized by gold-sulfide-rich silicate melts underlying a gold metallogenic province. Here we present mineralogical and compositional data of sulfides in mantle xenoliths from this area (Tallante volcanic center), which are anomalously rich in gold (up to 46 ppm) compared to sulfides from SCLM not associated with Au-metallogenic provinces. We propose that these gold-rich, fertile mantle sources may have melted during the Cenozoic evolution of the westernmost Mediterranean subduction system and fed the ore-productive volcanic activity in southeast Spain.& &
Publisher: Springer Science and Business Media LLC
Date: 14-07-2023
DOI: 10.1038/S43247-023-00918-Y
Abstract: The transfer of chalcophile metals across the continental lithosphere has been traditionally modeled based on their chemical equilibrium partitioning in sulfide liquids and silicate magmas. Here, we report a suite of Ni-Fe-Cu sulfide droplets across a trans-lithospheric magmatic network linking the subcontinental lithospheric mantle to the overlying continental crust. Petrographic characteristics and numerical calculations both support that the sulfide droplets were mechanically scavenged from the mantle source during partial melting and transported upwards by alkaline magmas rising through the continental lithosphere. Nanoscale investigation by high-resolution transmission electron microscopy (HR-TEM) documents the presence of galena (PbS) nanoinclusions within the sulfide droplets that are involved in the mantle-to-crust magma route. The galena nanoinclusions show a range of microstructural features that are inconsistent with a derivation of PbS by exsolution from the solid products of the Ni-Fe-Cu sulfide liquid. It is argued that galena nanoinclusions crystallized from a precursor Pb(-Cu)-rich nanomelt, which was originally immiscible within the sulfide liquid even at Pb concentrations largely below those required for attaining galena saturation. We suggest that evidence of immiscibility between metal-rich nanomelts and sulfide liquids during magma transport would disrupt the classical way by which metal flux and ore genesis are interpreted, hinting for mechanical transfer of nanophases as a key mechanism for sourcing the amounts of mantle-derived metals that can be concentrated in the crust.
No related grants have been discovered for Erwin Schettino.