ORCID Profile
0000-0002-0625-0639
Current Organisation
Dalian Institute of Chemical Physics
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Publisher: Springer Science and Business Media LLC
Date: 12-12-2014
Publisher: Wiley
Date: 26-04-2016
Abstract: Ammonium aminodiboranate ([NH4 ][BH3 NH2 BH3 ]) is a long-sought isomer of diammoniate of diborane ([NH3 BH2 NH3 ][BH4 ]) and ammonia borane (NH3 BH3 ) dimer. Our results show that [NH4 ][BH3 NH2 BH3 ] is stable in tetrahydrofuran at -18 °C and decomposes rapidly to NH3 BH2 NH2 BH3 and H2 at elevated temperatures. The decomposition pathway is dictated by the dihydrogen bonding between H(δ+) on NH4 (+) and H(δ-) on BH3 , as confirmed by theoretical calculations. This is in contrast to the interconversion between [NH3 BH2 NH3 ][BH4 ] and (NH3 BH3 )2 , although all three have dihydrogen bonds and the same stoichiometry.
Publisher: Wiley
Date: 11-10-2010
Publisher: American Chemical Society (ACS)
Date: 23-03-2022
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C5TA01158B
Abstract: Guanidinium octahydrotriborate, with a melting point of −10 °C, releases wt% high purity hydrogen below 100 °C.
Publisher: Elsevier BV
Date: 09-2016
Publisher: Elsevier BV
Date: 06-2020
Publisher: IOP Publishing
Date: 2023
Abstract: Efficient storage of hydrogen is one of the biggest challenges towards a potential hydrogen economy. Hydrogen storage in liquid carriers is an attractive alternative to compression or liquefaction at low temperatures. Liquid carriers can be stored cost-effectively and transportation and distribution can be integrated into existing infrastructures. The development of efficient liquid carriers is part of the work of the International Energy Agency Task 40: Hydrogen-Based Energy Storage. Here, we report the state-of-the-art for ammonia and closed CO 2 -cycle methanol-based storage options as well for liquid organic hydrogen carriers.
Publisher: Elsevier BV
Date: 03-2019
No related grants have been discovered for Ping Chen.