ORCID Profile
0000-0002-4559-9585
Current Organisation
University of Melbourne
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Macromolecular and Materials Chemistry | Synthesis of Materials | Analytical Spectrometry | Sociology and Social Studies of Science and Technology |
Organic Industrial Chemicals (excl. Resins, Rubber and Plastics) | Human Pharmaceutical Treatments (e.g. Antibiotics) | Workforce Transition and Employment
Publisher: Elsevier BV
Date: 09-2023
Publisher: American Chemical Society (ACS)
Date: 23-03-2016
Abstract: The prevalence of microplastics (<5 mm) in natural environments has become a widely recognized global problem. Microplastics have been shown to sorb chemical pollutants from their surrounding environment, thus raising concern as to their role in the movement of these pollutants through the food chain. This experiment investigated whether organic pollutants sorbed to microbeads (MBs) from personal care products were assimilated by fish following particle ingestion. Rainbow fish (Melanotaenia fluviatilis) were exposed to MBs with sorbed polybrominated diphenyl ethers (PBDEs BDE-28, -47, -100, -99, -153, -154, -183, 200 ng g(-1) BDE-209, 2000 ng g(-1)) and s led at 0, 21, 42, and 63 days along with two control treatments (food only and food + clean MBs). Exposed fish had significantly higher Σ8PBDE concentrations than both control treatments after just 21 days, and continued exposure resulted in increased accumulation of the pollutants over the experiment (ca. 115 pg g(-1) ww d(-1)). Lower brominated congeners showed the highest assimilation whereas higher brominated congeners did not appear to transfer, indicating they may be too strongly sorbed to the plastic or unable to be assimilated by the fish due to large molecular size or other factors. Seemingly against this trend, however, BDE-99 did not appear to bioaccumulate in the fish, which may be due to partitioning from the MBs or it being metabolized in vivo. This work provides evidence that MBs from personal care products are capable of transferring sorbed pollutants to fish that ingest them.
Publisher: Elsevier BV
Date: 12-2020
Publisher: Elsevier BV
Date: 12-2018
DOI: 10.1016/J.SCITOTENV.2018.07.048
Abstract: The purpose of this study was to investigate the contribution of per- and polyfluoroalkyl substances (PFASs) to groundwater at a location where recycled water from a wastewater treatment plant (WWTP) is used to irrigate crops. Groundwater from Werribee South, located west of Melbourne, Australia, was s led over two c aigns in 2017 and 2018, extracted using solid phase extraction (SPE) and analysed with liquid chromatography-tandem mass spectrometry (LC-MS/MS-QQQ). PFASs were detected in 100% of the groundwater s les. The sum total of twenty PFAS compounds (∑
Publisher: Elsevier BV
Date: 02-2017
DOI: 10.1016/J.AQUATOX.2016.12.007
Abstract: Chemical pollution from pharmaceuticals is increasingly recognised as a major threat to aquatic communities. One compound of great concern is fluoxetine, which is one of the most widely prescribed psychoactive drugs in the world and frequently detected in the environment. The aim of this study was to investigate the effects of 28-d fluoxetine exposure at two environmentally relevant levels (measured concentrations: 4ng/L and 16ng/L) on anti-predator behaviour in wild guppies (Poecilia reticulata). This was achieved by subjecting fluoxetine-exposed and unexposed guppies to a simulated bird strike and recording their subsequent behavioural responses. We found that exposure to fluoxetine affected the anti-predator behaviour of guppies, with exposed fish remaining stationary for longer (i.e. 'freezing' behaviour) after the simulated strike and also spending more time under plant cover. By contrast, control fish were significantly more active and explored the tank more, as indicated by the distance covered per minute over the period fish spent swimming. Furthermore, behavioural shifts were sex-dependent, with evidence of a non-monotonic dose-response among the fluoxetine-exposed fish. This is one of the first studies to show that exposure to environmentally relevant concentrations of fluoxetine can alter the anti-predator behaviour of adult fish. In addition to the obvious repercussions for survival, impaired anti-predator behaviour can have direct impacts on fitness and influence the overall population dynamics of species.
Publisher: Elsevier BV
Date: 2020
DOI: 10.1016/J.WATRES.2019.115139
Abstract: Glyphosate is the most widely-used pesticide for weed control in agriculture and in urban and residential areas. This is the first study to quantify glyphosate and AMPA levels in surface water in Australia from different land uses. Glyphosate and AMPA was measured in surface water from 10 rural streams, 30 urban stormwater wetlands and 9 urban streams located in and around the city of Melbourne, Australia on five occasions between October 2017 and February 2018. Glyphosate and AMPA were present in most of the urban surface water s les. The frequency of detection of glyphosate was 77% in wetlands and 79% in urban streams, whereas it was only detected in 4% of the rural streams. Similarly, AMPA detection was 91% in wetlands and 97% in urban streams, whereas it was only present in 6% of the rural stream s les. In both urban streams and wetlands, the highest average glyphosate concentrations occurred in November (1.8 ± 2.2 μg L
Publisher: Elsevier BV
Date: 03-2019
DOI: 10.1016/J.MARPOLBUL.2019.01.025
Abstract: In this study we have identified and characterized microplastic particles (MPs) found in six fish species of commercial importance in central Chile. The fish species belong to different trophic levels and were obtained from the oceanic and coastal habitats. To analyze MPs, the fish gastrointestinal content was extracted, analyzed and characterized using a microscopy equipped with Fourier-transform infrared spectroscopy (FT-IR). The MPs found in fish s les were mainly constituted by red microfibers (70-100%) with sizes ranging between 176 and 2842 μm. Polyester, polyethylene (PE) and polyethylene terephthalate (PET) were identified as the prevalent polymers detected. The coastal species showed the presence of microfibers with a higher size and abundance (71%) compared to oceanic species (29%), suggesting there is a greater exposure risk. These findings are consistent with results found in other investigations worldwide. However, further research is still needed to accurately establish the potential exposure risk for the public consuming these fish and the impact of MPs in the Chilean fishery activities.
Publisher: Elsevier BV
Date: 05-2015
DOI: 10.1016/J.JCHROMB.2015.02.045
Abstract: Polybrominated diphenyl ethers (PBDEs) have become ubiquitous environmental contaminants due to their incorporation into many consumer products. Their ability to bioaccumulate to alarming levels in fat-rich matrices such as fish demands fast and efficient methods to monitor these contaminants. We present an analytical method for selective-pressurised liquid extraction (S-PLE) of PBDEs from fish tissue. Fat removal performance of different mixtures of Florisil, silica gel and sulphuric acid-impregnated silica gel were evaluated using a response surface experimental design approach for determining the optimal fat-retaining mixture for S-PLE. Acid-silica gel had the greatest in idual effect on fat retention with a two-thirds acid-silica one-third Florisil mixture found to be the most efficient (>97%). Method validation was performed using recovery experiments at three spiked concentration levels (0.05, 0.5 and 5ngg(-1) ww). Mean recoveries of target analytes in spiked s les ranged from 70 to 124%, with relative standard deviations <27%. The S-PLE lipid removal efficiency combined with the sensitivity of triple quadrupole mass spectrometers provides a fast and comparatively inexpensive analytical method for analysis of PBDEs in fish s les.
Publisher: Elsevier BV
Date: 2011
DOI: 10.1016/J.ENVINT.2010.06.004
Abstract: A broad spectrum of organic chemicals is essential to modern society. Once discharged from industrial, domestic and urban sources into the urban wastewater collection system they may transfer to the residual solids during wastewater treatment and assessment of their significance and implications for beneficial recycling of the treated sewage sludge biosolids is required. Research on organic contaminants (OCs) in biosolids has been undertaken for over thirty years and the increasing body of evidence demonstrates that the majority of compounds studied do not place human health at risk when biosolids are recycled to farmland. However, there are 143,000 chemicals registered in the European Union for industrial use and all could be potentially found in biosolids. Therefore, a literature review of 'emerging' OCs in biosolids has been conducted for a selection of chemicals of potential concern for land application based upon human toxicity, evidence of adverse effects on the environment and endocrine disruption. To identify monitoring and research priorities the selected chemicals were ranked using an assessment matrix approach. Compounds were evaluated based upon environmental persistence, human toxicity, evidence of bioaccumulation in humans and the environment, evidence of ecotoxicity and the number and quality of studies focussed on the contaminant internationally. The identified chemicals of concern were ranked in decreasing order of priority: perfluorinated chemicals (PFOS, PFOA) polychlorinated alkanes (PCAs), polychlorinated naphthalenes (PCNs) organotins (OTs), polybrominated diphenyl ethers (PBDEs), triclosan (TCS), triclocarban (TCC) benzothiazoles antibiotics and pharmaceuticals synthetic musks bisphenol A, quaternary ammonium compounds (QACs), steroids phthalate acid esters (PAEs) and polydimethylsiloxanes (PDMSs). A number of issues were identified and recommendations for the prioritisation of further research and monitoring of 'emerging' OCs for the agricultural use of biosolids are provided. In particular, a number of 'emerging' OCs (PFOS, PFOA and PCAs) were identified for priority attention that are environmentally persistent and potentially toxic with unique chemical properties, or are present in large concentrations in sludge, that make it theoretically possible for them to enter human and ecological food-chains from biosolids-amended soil.
Publisher: Wiley
Date: 09-2015
Publisher: IWA Publishing
Date: 24-10-2013
DOI: 10.2166/WST.2013.508
Abstract: Endocrine disrupting compounds (EDCs) have been in the scientific spotlight since the 1980s. However, there has been much less research reported in Australia than in other developed countries and little information is known about how these compounds interact with native Australian species compared to European and North American fauna. This is of concern because Australia has distinct wildlife and environments that face increasing intensity and frequency of extreme, climatic events compared to northern hemisphere countries. Since oestrogenic compounds cannot be prevented from entering wastewater their management and removal must occur at wastewater treatment plants. Biological treatment is the most effective tool in this regard however the financial and environmental costs must be balanced with the environmental benefit to effectively plan treatment options. Since standard risk assessment models and procedures developed internationally are unlikely to translate well to Australian ecosystems, new, novel and localised research on both the monitoring and assessment of EDCs in Australian wastewater and receiving aquatic environments is recommended. This includes the development of relevant bioassays and application of treatment technologies that reflect the local community and climate.
Publisher: American Chemical Society (ACS)
Date: 23-06-2014
DOI: 10.1021/ES405717Z
Abstract: Microplastic particles (MPPs <5 mm) are found in skin cleansing soaps and are released into the environment via the sewage system. MPPs in the environment can sorb persistent organic pollutants (POPs) that can potentially be assimilated by organisms mistaking MPPs for food. Amphipods (Allorchestes compressa) exposed to MPPs isolated from a commercial facial cleansing soap ingested ≤45 particles per animal and evacuated them within 36 h. Amphipods were exposed to polybrominated diphenyl ether (PBDEs) congeners (BDE-28, -47, -99, -100, -153, -154, and -183) in the presence or absence of MPPs. This study has demonstrated that PBDEs derived from MPPs can be assimilated into the tissue of a marine hipod. MPPs reduced PBDE uptake compared to controls, but they caused greater proportional uptake of higher-brominated congeners such as BDE-154 and -153 compared to BDE-28 and -47. While MPPs in the environment may lower PBDE uptake compared to unabsorbed free chemicals, our study has demonstrated they can transfer PBDEs into a marine organism. Therefore, MPPs pose a risk of contaminating aquatic food chains with the potential for increasing public exposure through dietary sources. This study has demonstrated that MPPs can act as a vector for the assimilation of POPs into marine organisms.
Publisher: American Chemical Society (ACS)
Date: 09-06-2022
Abstract: The field-based distribution and bioaccumulation factor (BAF) for per- and polyfluoroalkyl substances (PFASs) were determined in residential Black Swans (
Publisher: Elsevier BV
Date: 12-2016
DOI: 10.1016/J.CHEMOSPHERE.2016.08.017
Abstract: Polybrominated diphenyl ethers (PBDEs) have been used as flame retardants in a variety of materials and products. PBDEs have been shown to accumulate in the environment and human populations while exhibiting a range of toxic effects. In this study, surface soil s les from 30 sites in the city of Melbourne, Australia, were analysed for PBDEs. Eight congeners of environmental concern (BDE-28, -47, -99, -100, -153, -154 -183 and -209) were assessed using selective pressurized liquid extraction (S-PLE) and gas chromatography coupled to triple quadrupole mass spectrometry (GC-MS/MS). PBDEs were detected in 29/30 s les with Σ
Publisher: Elsevier BV
Date: 04-2018
DOI: 10.1016/J.ENVINT.2018.01.026
Abstract: Polybrominated diphenyl ethers (PBDEs) and novel brominated flame retardants (NBFR) have been used in a range of polymers to inhibit the spread of fires but also have a propensity to migrate out of consumer materials and contaminate indoor dust. In this study, a total of 57 dust s les were collected from 12 homes, eight offices and eight vehicles in Melbourne, Australia and analysed for eight PBDEs (-28, -47, -99, -100, -153, -154, -183 and -209) and seven NBFRs (PBT, PBEB, HBB, EH-TBB, BEH-TEBP, BTBPE and DBDPE) to determine human exposure risks from dust ingestion. S les were analysed using selective pressurized liquid extraction (S-PLE) and gas chromatography coupled to tandem mass spectrometry (GC-MS/MS). Legacy and replacement flame retardants were detected in all s les with overall ∑PBDE concentrations ranging from 120 to 1700,000 ng/g (median 2100 ng/g) and ∑NBFRs ranging from 1.1 to 10,000 ng/g (median 1800 ng/g). BDE-209 and DBDPE were the dominant compounds in dust s les, followed by congeners associated with commercial Penta-BDE formulations (-47, -99, -100, -153 and -154) and then EH-TBB of the FireMaster 550 and BZ-54 products. ∑Penta-BDE concentrations were elevated in office s les compared with homes and vehicles, while EH-TBB and BDE-209 measured higher concentrations in vehicles compared with their respective levels in homes and offices. Risk assessment estimates revealed the majority of exposure to occur in the home for both adults and toddlers in the City of Melbourne. Generally, body weight adjusted exposure to PBDEs and NBFRs was predicted to be 1 to 2 orders of magnitude higher for toddlers than adults. Estimated rates of BDE-47, -99, -153 and -209 ingestion were each 2 orders of magnitude or more below the USEPA's prescribed oral reference dose values (RfDs) for typical exposure scenarios. However, exposure rates for BDE-47 and -99 reached as high as 52 and 95% of RfDs, respectively, for adults and 4.4 and 7.4%, respectively, for toddlers in high exposure scenarios. This study provides the first wide-ranging survey of NBFRs in indoor dust from homes, offices and vehicles in Australia and offers further evidence of human exposure to legacy and novel brominated flame retardants via dust ingestion.
Publisher: Elsevier BV
Date: 06-2020
Publisher: Elsevier BV
Date: 04-2023
Publisher: Elsevier BV
Date: 03-2022
DOI: 10.1016/J.SCITOTENV.2021.152528
Abstract: Elevated concentrations of PFASs in the liver may pose a toxicological risk to bird species and humans that consume them. This study aimed to determine concentrations of 43 per- and polyfluoroalkyl substances (PFASs) in livers (n = 80) of Australian Shelducks (Tadorna tadornoides), Pacific Black Ducks (Anas superciliosa), and Teals (Anas sp.), as well as water and sediment from a remote Australian environment. Maximum concentrations of PFBA (1.9 ng L
Publisher: Royal Society of Chemistry (RSC)
Date: 2017
DOI: 10.1039/C6AY02707E
Abstract: In this review the analytical techniques for measuring microplastics in sediment have been evaluated.
Publisher: Elsevier BV
Date: 08-2016
DOI: 10.1016/J.CHROMA.2016.06.021
Abstract: Polybrominated diphenyl ethers (PBDEs) are a class of flame retardant registered as UN POPs due to their persistence in the environment, bioaccumulation potential and toxicity. Replacement novel brominated flame retardants (NBFRs) have exhibited similar health hazards and environmental distribution, becoming recognized as significant contaminants. This work describes the development and validation of a sensitive and reliable method for the simultaneous quantitation of PBDEs and NBFRs in environmental soil s les using selective pressurized liquid extraction (S-PLE) and gas chromatography coupled to triple quadrupole mass spectrometry (GC-(EI)-MS/MS). Under optimal conditions, extraction of eight PBDEs (-28, -47, -99, -100, -153, -154, -183 and -209) and five NBFRs pentabromotoluene (PBT), pentabromoethylbenzene (PBEB), hexabromobenzene (HBB), 2-ethylhexyl-2,3,4,5-tetrabromobenzoate (EH-TBB) and bis(2,4,6-tribromophenoxy)ethane (BTBPE) was performed at 100°C and 1500psi using a 1:1 mixture of hexane and dichloromethane. The method utilized 33mL capacity PLE cells containing, from bottom to top, a single cellulose filter, 3g activated Florisil, 6g acid silica (10% w/w), 3g Na2SO4, another cellulose filter, 2g activated copper powder and 3g soil s le dispersed in 2g Na2SO4 and 1g of Hydromatrix. The method was evaluated by repeated extraction and analysis of all analytes from 3g soil at three spike concentrations. Good recoveries were observed for most analytes at each of the spiking levels with RSD values generally below 20%. MDLs ranged from 0.01 to 4.8ng/g dw for PBDEs and 0.01-0.55ng/g dw for NBFRs. The described one-step combined extraction and cleanup method reduces s le processing times compared with traditional procedures, while delivering comparable analytical performance. The method was successfully applied to environmental soil s les (n=5), detecting PBDEs in each s le and providing the first account of NBFR contamination in Australian soils.
Publisher: Elsevier BV
Date: 06-2020
Publisher: Elsevier BV
Date: 03-2017
DOI: 10.1016/J.ENVPOL.2016.10.010
Abstract: Pharmaceuticals are increasingly being detected in aquatic ecosystems worldwide. Particularly concerning are pharmaceutical pollutants that can adversely impact exposed wildlife, even at extremely low concentrations. One such contaminant is the widely prescribed antidepressant fluoxetine, which can disrupt neurotransmission and behavioural pathways in wildlife. Despite this, relatively limited research has addressed the behavioural impacts of fluoxetine at ecologically realistic exposure concentrations. Here, we show that 28-day fluoxetine exposure at two ecologically relevant dosages-one representing low surface water concentrations and another representing high effluent flow concentrations-alters antipredator behaviour in Eastern mosquitofish (Gambusia holbrooki). We found that fluoxetine exposure at the lower dosage resulted in increased activity levels irrespective of the presence or absence of a predatory dragonfly nymph (Hemianax papuensis). Additionally, irrespective of exposure concentration, fluoxetine-exposed fish entered the predator 'strike zone' more rapidly. In a separate experiment, fluoxetine exposure reduced mosquitofish freezing behaviour-a common antipredator strategy-following a simulated predator strike, although, in females, this reduction in behaviour was seen only at the lower dosage. Together, our findings suggest that fluoxetine can cause both non-monotonic and sex-dependent shifts in behaviour. Further, they demonstrate that exposure to fluoxetine at environmentally realistic concentrations can alter antipredator behaviour, with important repercussions for organismal fitness.
Publisher: Elsevier BV
Date: 05-2021
Publisher: Elsevier BV
Date: 11-2017
DOI: 10.1016/J.ENVPOL.2017.07.009
Abstract: Polybrominated diphenyl ethers (PBDEs) have been used in a broad array of polymeric materials such as plastics, foams, resins and adhesives to inhibit the spread of fires since the 1970s. The widespread environmental contamination and well documented toxic effects of PBDEs have led to bans and voluntary withdrawals in many jurisdictions. Replacement novel brominated flame retardants (NBFRs) have, however, exhibited many of the same toxic characteristics as PBDEs and appear to share similar environmental fate. This paper presents a critical review of the scientific literature regarding PBDE and NBFR contamination of surface soils internationally, with the secondary objective of identifying probable pollution sources. An evaluation of NBFR distribution in soil was also conducted to assess the suitability of the newer compounds as replacements for PBDEs, with respect to their land contamination potential. Principle production of PBDEs and NBFRs and their consequent use in secondary polymer manufacture appear to be processes with strong potential to contaminate surrounding soils. Evidence suggests that PBDEs and NBFRs are also released from flame retarded products during disposal via landfill, dumping, incineration and recycling. While the land application of sewage sludge represents another major pathway of soil contamination it is not considered in this review as it is extensively covered elsewhere. Both PBDEs and NBFRs were commonly detected at background locations including Antarctica and northern polar regions. PBDE congener profiles in soil were broadly representative of the major constituents in Penta-, Octa- and Deca-BDE commercial mixtures and related to predicted market place demand. BDE-209 dominated soil profiles, followed by BDE-99 and BDE-47. Although further research is required to gain baseline data on NBFRs in soil, the current state of scientific literature suggests that NBFRs pose a similar risk to land contamination as PBDEs.
Publisher: Elsevier BV
Date: 2020
Publisher: Wiley
Date: 24-01-2020
DOI: 10.1002/ETC.4640
Abstract: Per‐ and poly‐fluoroalkyl substances (PFAS) are ubiquitously distributed throughout aquatic environments and can bioaccumulate in organisms. We examined dietary uptake and depuration of a mixture of 3 PFAS: perfluorooctanoic acid (PFOA C 8 HF 15 O 2 ), perfluorooctane sulfonate (PFOS C 8 HF 17 SO 3 ), and hexafluoropropylene oxide dimer acid (HPFO‐DA C 6 HF 11 O 3 trade name GenX). Benthic fish (blue spot gobies, Pseudogobius sp.) were fed contaminated food (nominal dose 500 ng g –1 ) daily for a 21‐d uptake period, followed by a 42‐d depuration period. The compounds PFOA, linear‐PFOS (linear PFOS), and total PFOS (sum of linear and branched PFOS) were detected in freeze‐dried fish, whereas GenX was not, indicating either a lack of uptake or rapid elimination ( h). Depuration rates (d –1 ) were 0.150 (PFOA), 0.045 (linear‐PFOS), and 0.042 (linear+branched‐PFOS) with corresponding biological half‐lives of 5.9, 15, and 16 d, respectively. The PFOS isomers were eliminated differently, resulting in enrichment of linear‐PFOS (70–90%) throughout the depuration period. The present study is the first reported study of GenX dietary bioaccumulation potential in fish, and the first dietary study to investigate uptake and depuration of multiple PFASs simultaneously, allowing us to determine that whereas PFOA and PFOS accumulated as expected, GenX, administered in the same way, did not appear to bioaccumulate. Environ Toxicol Chem 2020 :595–603. © 2019 SETAC
Publisher: Elsevier BV
Date: 11-2018
DOI: 10.1016/J.CHEMOSPHERE.2018.06.138
Abstract: Geochemical ratios between elements of environmental concern and Fe have been recommended for estimation of "background" concentrations of Cr, Cu, Ni and Zn in soil. However, little research has occurred to assess the consistency of geochemical ratios across soils developed in different environments. Broad application of generic geochemical ratios could result in under or over estimation of anthropogenic impacts to soil and subsequent inaccurate assessment of risk to the environment. A soil survey was undertaken in Victoria, Australia, including collection of s les (n = 622) from surface (0-0.1 m below ground level) and sub-surface (0.3-0.6 m below ground level) soils, overlying Tertiary-Quaternary basalt, Tertiary sediments and Silurian siltstones and sandstones. S les were analyzed for metals and soil physical and chemical properties (particle size, cation exchange capacity, organic matter and pH). Geochemical correlations between elements in soils from different parent materials and environments were compared against geochemical relationships reported in Australia and internationally. Ratios of Cr and Fe were relatively consistent across parent materials, and comparable to published models for estimation of background Cr. Conversely, ratios between Cu, Ni, and Zn with Fe, were variable between soils developed in different weathering environments and/or soil depths. Alternative regression equations and rule based regression tree models were developed as an improved means for prediction of ambient background Cu, Ni and Zn concentrations in soil. Ambient background concentrations of Ni and Cr were predictable across parent materials and depths, allowing these models to be extended to soils across Australia and potentially internationally.
Publisher: PeerJ
Date: 15-04-2019
DOI: 10.7717/PEERJ.6784
Abstract: Biochar, the product of biomass pyrolysis, has been explored as a soil amendment and carbon capture vessel. Recent literature has aligned biochar as a novel sorbent for a host of environmental contaminants. Through the variation of pyrolysis conditions, biochars can be engineered to have qualities desirable in sorbents whilst maintaining their agronomic benefits. This study focuses on identifying the effects that feedstock type and process temperature have on biochar characteristics which may in turn shed light on their potential environmental applications. Using this approach, six biochars were created from two waste biomasses. The biochars exhibited wide ranges of pH (5.6–11.1), surface area (16.2–397.4 m 2 /g), electrical conductivity (19–2,826 µS/cm), fixed carbon (72–97%), heavy metal and polycyclic aromatic hydrocarbons (PAHs). Statistically significant trends ( P 0.05) in biochar characteristics dependent upon increasing pyrolysis temperature and feedstock type were identified. Arsenic ( mg/kg), chromium ( mg/kg), copper ( mg/kg) and PAH ( mg/kg) concentrations presented themselves as obstacles to land application in a small number of biochars with respects to International Biochar Initiative (IBI) guidelines. However, it was demonstrated that these could be eliminated through employing pyrolysis processes which encompass higher temperatures ( °C) and ensuring the use of contaminant-free feedstocks. The variation in surface areas, carbonized fractions and surface functional groups achieved suggest that using the correct feedstock and process, biochar could be produced in Victoria (Australia) from common organic waste streams to the ends of acting as a sorbent, soil enhancer, and a waste management strategy.
Publisher: American Chemical Society (ACS)
Date: 13-07-2018
Abstract: Informal recycling of electronic waste (e-waste) has been shown to cause significant brominated flame retardant (BFR) contamination of surrounding soils in a number of Asian and West African countries. However, to the authors' knowledge, there have been no published studies demonstrating polybrominated diphenyl ether (PBDE) and novel brominated flame retardant (NBFR) soil contamination from regulated "formal" e-waste processing facilities in developed countries. This study reports on PBDEs (-28, -47, -99, -100, -153, -154, -183, and -209) and NBFRs (PBT, PBEB, HBB, EH-TBB, BTBPE and DBDPE) in 36 soil s les surrounding two Australian e-waste recycling plants and a further eight reference soils. Overall ∑PBDE concentrations ranged 0.10-98 000 ng/g dw (median 92 ng/g dw) and ∑NBFRs ranged ND-37 000 ng/g dw (median 2.0 ng/g dw). Concentrations in soils were found to be significantly negatively associated with distance from one of the e-waste facilities for ∑penta-BDEs, BDE-183, BDE-209, and ∑NBFR compound groups. ANOVA tests further illustrated the potential for e-waste recycling to significantly elevate concentrations of some BFRs in soils over distances up to 900 m compared to references sites. This study provides the first evidence of soil contamination with PBDEs and NBFRs originating from formal e-waste recycling facilities in Australia, which may have implications for e-waste recycling practices throughout the world.
Publisher: Wiley
Date: 28-12-2021
DOI: 10.1002/ETC.4924
Abstract: We investigated the concentrations of 45 per‐ and polyfluoroalkyl substances (PFASs) in fledgling flesh‐footed shearwater ( Ardenna carneipes n = 33) and wedge‐tailed shearwater ( A. pacifica n = 9) livers via liquid chromatography–tandem mass spectrometry and their relationship to body morphometrics and ingested plastic mass recorded in 2019 on Lord Howe Island (NSW, Australia). Sixteen PFASs were detected, of which perfluorooctanesulfonate (PFOS) was the dominant compound, detected in 100% of birds (1.34–13.4 ng/g wet wt). Long‐chain perfluorocarboxylic acids, including perfluorodecanoic acid (PFDA .04–0.79 ng/g wet wt) and perfluorotridecanoic acid (PFTrDA .05–1.6 ng/g wet wt) were detected in % of birds. There was a positive correlation between PFDA and PFTrDA concentrations and wing chord length ( R s = 0.36, p = 0.0204 R s = 0.44, p = 0.0037, respectively), and between PFDA concentrations and total body mass ( R s = 0.33, p = 0.032), suggesting that these compounds may impact shearwater fledgling morphometrics. Plastic was present in the intestinal tract of 79% of in iduals ( .6 g), although there was no correlation between PFAS concentrations and plastic mass, indicating that ingested plastic is not the likely primary exposure source. The widespread occurrence of PFASs in fledgling marine birds from a relatively pristine location in the Southern Hemisphere suggests that further studies in adult shearwaters and other marine birds are warranted to investigate whether there are any long‐term physiological effects on bird species. Environ Toxicol Chem 2021 :799–810. © 2020 SETAC
Publisher: Elsevier BV
Date: 2018
DOI: 10.1016/J.CHEMOSPHERE.2017.10.038
Abstract: Currently, there are conflicting views on the best statistical methods for managing censored environmental data. The method commonly applied by environmental science researchers and professionals is to substitute half the limit of reporting for derivation of summary statistics. This approach has been criticised by some researchers, raising questions around the interpretation of historical scientific data. This study evaluated four complete soil datasets, at three levels of simulated censorship, to test the accuracy of a range of censored data management methods for calculation of the geometric mean. The methods assessed included removal of censored results, substitution of a fixed value (near zero, half the limit of reporting and the limit of reporting), substitution by nearest neighbour imputation, maximum likelihood estimation, regression on order substitution and Kaplan-Meier/survival analysis. This is the first time such a comprehensive range of censored data management methods have been applied to assess the accuracy of calculation of the geometric mean. The results of this study show that, for describing the geometric mean, the simple method of substitution of half the limit of reporting is comparable or more accurate than alternative censored data management methods, including nearest neighbour imputation methods.
Publisher: Elsevier BV
Date: 05-2019
DOI: 10.1016/J.ENVPOL.2019.02.018
Abstract: The extent of per- and polyfluoroalkyl substances (PFAS) in groundwater surrounding legacy landfills is currently poorly constrained. Seventeen PFAS were analysed in groundwater surrounding legacy landfills in a major Australian urban re-development precinct. S ling locations (n = 13) included sites installed directly in waste material and down-gradient from landfills, some of which exhibited evidence of leachate contamination including elevated concentrations of ammonia-N (≤106 mg/L), bicarbonate (≤1,740 mg/L) and dissolved methane (≤10.4 mg/L). Between one and fourteen PFAS were detected at all sites and PFOS, PFHxS, PFOA and PFBS were detected in all s les. The sum of detected PFAS (∑
Publisher: Springer Science and Business Media LLC
Date: 19-02-2022
DOI: 10.1007/S00216-022-03962-3
Abstract: Advances in analytical techniques have allowed greater detection of environmental contaminants from small volumes of s le. Four methodologies were evaluated for the extraction of 53 per- and polyfluoroalkyl substances (PFASs) from eight classes in 200 µL of avian and mammal serum. Spiked serums at four concentrations (0, 0.5, 5.0 and 25 ng mL
Publisher: Elsevier BV
Date: 02-2020
Publisher: Elsevier BV
Date: 11-2018
DOI: 10.1016/J.ENVPOL.2018.07.083
Abstract: Excess exposure to fluoride causes substantive health burden in humans and livestock globally. However, few studies have assessed the distribution and controls of variability of ambient background concentrations of fluoride in soil. Ambient background concentrations of fluoride in soil were collated for Greater Melbourne, Greater Geelong, Ballarat and Mitchell in Victoria, Australia (n = 1005). Correlation analysis and machine learning techniques were used to identify environmental and anthropogenic influences of fluoride variability in soil. Sub-soils (>0.3 m deep), in some areas overlying siltstone and sandstone, and to a lesser extent, overlying basalt, were naturally enriched with fluoride at concentrations above ecological thresholds for grazing animals. Soil fluoride enrichment was predominantly influenced by parent material (mineralogy), precipitation (illuviation), leaching during palaeoclimates and marine inputs. Industrial air pollution did not significantly influence ambient background concentrations of fluoride at a regional scale. However, agricultural practices (potentially the use of phosphate fertilisers) were indicated to have resulted in added fluoride to surface soils overlying sediments. Geospatial variables alone were not sufficient to accurately model ambient background soil fluoride concentrations. A multiple regression model based on soil chemistry and parent material was shown to accurately predict ambient background fluoride concentrations in soils and support assessment of fluoride enrichment in the environment.
Publisher: Elsevier BV
Date: 11-2022
Publisher: Elsevier BV
Date: 05-2015
DOI: 10.1016/J.CHEMOSPHERE.2015.02.030
Abstract: Landfill leachate s les (n=11) were collected from five USA municipal solid waste (MSW) landfills and analyzed for ten trace organic pollutants that are commonly detected in surface and municipal wastewater effluents (viz., carbamazepine, DEET, fluoxetine, gemfibrozil, PFOA, PFOS, primidone, sucralose, sulfamethoxazole and trimethoprim). Carbamazepine, DEET, PFOA and primidone were detected in all leachate s les analyzed and gemfibrozil was detected in s les from four of the five-landfill sites. The contaminants found in the highest concentrations were DEET (6900-143000 ng L(-1)) and sucralose (<10-621000 ng L(-1)). Several compounds were not detected (fluoxetine) or detected infrequently (sulfamethoxazole, trimethoprim and PFOS). Using the average mass of DEET in leachate amongst the five landfills and scaling the mass release from the five test landfills to the USA population of landfills, an order of magnitude estimate is that over 10000 kg DEET yr(-1) may be released in leachate. Some pharmaceuticals have similar annual mean discharges to one another, with the estimated annual discharge of carbamazepine, gemfibrozil, primidone equating to 53, 151 and 128 kg year(-1). To the authors knowledge, this is the first time that primidone has been included in a landfill leachate study. While the estimates developed in this study are order of magnitude, the values do suggest the need for further research to better quantify the amount of chemicals sent to wastewater treatment facilities with landfill leachate, potential impacts on treatment processes and the significance of landfill leachate as a source of surface water contamination.
Publisher: Wiley
Date: 10-09-2023
DOI: 10.1111/ETH.13403
Publisher: Elsevier BV
Date: 04-2023
Publisher: Springer Science and Business Media LLC
Date: 18-06-2013
Abstract: The widespread utilization of organic compounds in modern society and their dispersion through wastewater have resulted in extensive contamination of source and drinking waters. The vast majority of these compounds are not regulated in wastewater outfalls or in drinking water while trace amounts of certain compounds can impact aquatic wildlife. Hence it is prudent to monitor these contaminants in water sources until sufficient toxicological data relevant to humans becomes available. A method was developed for the analysis of 36 trace organic contaminants (TOrCs) including pharmaceuticals, pesticides, steroid hormones (androgens, progestins, and glucocorticoids), personal care products and polyfluorinated compounds (PFCs) using a single solid phase extraction (SPE) technique with ultra-high performance liquid chromatography coupled to tandem mass spectrometry (UHPLC-MS/MS). The method was applied to a variety of water matrices to demonstrate method performance and reliability. UHPLC-MS/MS in both positive and negative electrospray ionization (ESI) modes was employed to achieve optimum sensitivity while reducing s le analysis time ( min) compared with previously published methods. The detection limits for most compounds was lower than 1.0 picogram on the column while reporting limits in water ranged from 0.1 to 15 ng/L based on the extraction of a 1 L s le and concentration to 1 mL. Recoveries in ultrapure water for most compounds were between 90-110%, while recoveries in surface water and wastewater were in the range of 39-121% and 38-141% respectively. The analytical method was successfully applied to analyze s les across several different water matrices including wastewater, groundwater, surface water and drinking water at different stages of the treatment. Among several compounds detected in wastewater, sucralose and TCPP showed the highest concentrations. The proposed method is sensitive, rapid and robust hence it can be used to analyze a large variety of trace organic compounds in different water matrixes.
Publisher: Elsevier BV
Date: 09-2022
DOI: 10.1016/J.SCITOTENV.2022.155329
Abstract: The presence of microplastics in the environment is substantially documented however, the pathways of dietary exposure to microplastics are not yet well understood. This is the first study to document the presence of microplastics in bottled water sold in Australia from commercial outlets. In total, 16 brands of bottled water (Australian Sourced: n = 11, Imported: n = 5) sold in the two largest supermarkets in Australia were analysed in triplicate (n = 48) for the presence of polyethylene, PE polystyrene, PS polypropylene, PP polyvinyl chloride, PVC polyethylene terephthalate, PET polycarbonate, PC polymethylmethacrylate, PMMA and polyamide, PA. Microplastics were detected in 94% (n = 15) of the s les, with PP (n = 14, 88%), PET (n = 10, 63%), PA (n = 7, 44%), and PE (n = 6, 38%) the most frequently detected. On average, a litre of bottled water contained 13 ± 19 (St Dev) microplastics, ranging from 0 to 80 microplastics/L. The average size of the microplastics identified in this study was 77 ± 22 μm. It was found that bottled water sourced and packaged overseas contained four times as many microplastics compared to bottled water sourced in Australia. It was estimated that in 2017, 28.3% of the Australian population consumed on average 30.8 L of bottled water therefore, using the result from this study it is estimated that Australians are exposed to 400 microplastics annually through the consumption of bottled water. To understand the total amount of microplastics that Australians could be exposed to through dietary routes, further work is required to observe the presence of microplastics in other beverages and food.
Publisher: Elsevier BV
Date: 2022
Publisher: Elsevier BV
Date: 03-2018
Publisher: Elsevier BV
Date: 03-2017
Publisher: Frontiers Media SA
Date: 09-03-2022
DOI: 10.3389/FENDO.2021.799043
Abstract: Per-fluoroalkyl and polyfluoroalkyl substances (PFAS) are a erse group of synthetic fluorinated chemicals used widely in industry and consumer products. Due to their extensive use and chemical stability, PFAS are ubiquitous environmental contaminants and as such, form an emerging risk factor for male reproductive health. The long half-lives of PFAS is of particular concern as the propensity to accumulate in biological systems prolong the time taken for excretion, taking years in many cases. Accordingly, there is mounting evidence supporting a negative association between PFAS exposure and an array of human health conditions. However, inconsistencies among epidemiological and experimental findings have hindered the ability to definitively link negative reproductive outcomes to specific PFAS exposure. This situation highlights the requirement for further investigation and the identification of reliable biological models that can inform health risks, allowing sensitive assessment of the spectrum of effects of PFAS exposure on humans. Here, we review the literature on the biological effects of PFAS exposure, with a specific focus on male reproduction, owing to its utility as a sentinel marker of general health. Indeed, male infertility has increasingly been shown to serve as an early indicator of a range of co-morbidities such as coronary, inflammatory, and metabolic diseases. It follows that adverse associations have been established between PFAS exposure and the incidence of testicular dysfunction, including pathologies such as testicular cancer and a reduction in semen quality. We also give consideration to the mechanisms that render the male reproductive tract vulnerable to PFAS mediated damage, and discuss novel remediation strategies to mitigate the negative impact of PFAS contamination and/or to ameliorate the PFAS load of exposed in iduals.
Publisher: Elsevier BV
Date: 06-2021
Publisher: Elsevier BV
Date: 11-2022
DOI: 10.1016/J.ENVPOL.2022.120055
Abstract: In 2018, over 30,000 L of fluorine-free firefighting foam was used to extinguish an industrial warehouse fire of uncharacterized chemical and industrial waste. Contaminated firewater and runoff were discharged to an adjacent freshwater creek in Melbourne, Australia. In this study, we applied nontarget analysis using liquid chromatography quadrupole time-of-flight mass spectrometry (LC-QToF-MS) to 15 surface water s les to investigate the presence of legacy, novel and emerging per-and polyfluoroalkyl substances (PFAS). We identified six novel and emerging fluorotelomer-based fluorosurfactants in the Australian environment for the first time, including: fluorotelomer sulfonamido betaines (FTABs or FTSA-PrB), fluorotelomer thioether amido sulfonic acids (FTSASs), and fluorotelomer sulfonyl amido sulfonic acids (FTSAS-So). Legacy PFAS including C
Start Date: 07-2018
End Date: 12-2024
Amount: $3,279,502.00
Funder: Australian Research Council
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