ORCID Profile
0000-0002-6390-3296
Current Organisations
CSIR - Indian Institute of Petroleum
,
Indian Institute of Petroleum
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Publisher: Elsevier BV
Date: 08-2019
DOI: 10.1016/J.BIORTECH.2019.03.147
Abstract: In the present work, the pyrolysis of para grass (PG) and phumdi (PH) biomass s les was conducted in the temperature range of 300-500 °C to obtain the optimum temperature for obtaining the maximum yield of bio-oil. Further, co-pyrolysis experiments of PH and PG were also conducted at the same optimized temperature and varied compositions to investigate the synergistic effect. It was observed during the co-pyrolysis, that the maximum bio-oil yield of 37.80 wt% was obtained at the mass ratio of 1:1. The GC-MS, FT-IR and
Publisher: Elsevier BV
Date: 11-2019
Publisher: Elsevier BV
Date: 09-2020
Publisher: Elsevier BV
Date: 02-2019
DOI: 10.1016/J.BIORTECH.2018.11.073
Abstract: The present study illustrates the production of phenolic compounds via slow pyrolysis of coir pith biomass in a bench-scale reactor. The primary objective of the study is to optimize the pyrolysis conditions to maximize the yield of bio-oil and phenolic compounds. Up to 88.14% phenolic compounds were obtained in the organic fraction of the bio-oil obtained at 350 °C. The phenolic compounds thus extracted can be used for the production of phenol-formaldehyde resins, which reduces the dependence on petroleum-based phenols for the manufacturing of resin. An independent kinetic analysis of the apparent pyrolysis reaction was also performed using thermogravimetry and isoconversional methodology. The calculated values of activation energy showed a variation from 28.41 to 200.09 kJ/mol, with the mean value being 140 kJ/mol. The thermodynamic parameters (ΔS, ΔH, and ΔG) were subsequently evaluated at different conversions using the activation energy values obtained from the kinetic analysis.
Publisher: Elsevier BV
Date: 03-2018
DOI: 10.1016/J.BIORTECH.2017.12.083
Abstract: In this work, the influence of composting on the thermal decomposition behavior and decomposition kinetics of pig manure-derived solid wastes was analyzed using thermogravimetry. Wheat straw, biochar, zeolite, and wood vinegar were added to pig manure during composting. The composting was done in the 130 L PVC reactors with 100 L effective volume for 50 days. The activation energy of pyrolysis of s les before and after composting was calculated using Friedman's method, while the pre-exponential factor was calculated using Kissinger's equation. It was observed that composting decreased the volatile content of all the s les. The additives when added together in pig manure lead to a reduction in the activation energy of decomposition, advocating the presence of simpler compounds in the compost material in comparison with the complex feedstock.
Publisher: Elsevier BV
Date: 12-2018
Publisher: Springer Science and Business Media LLC
Date: 18-10-2016
Publisher: Wiley
Date: 17-03-2020
Publisher: Royal Society of Chemistry (RSC)
Date: 2023
DOI: 10.1039/D2GC03664A
Abstract: The ever-growing demand for sustainable energy and chemicals associated with declining fossil reserves motivates the quest for alternative feedstocks and processes.
Publisher: Elsevier
Date: 2022
Publisher: IOP Publishing
Date: 05-2018
Publisher: Elsevier BV
Date: 12-2017
DOI: 10.1016/J.BIORTECH.2017.08.189
Abstract: The thermal decomposition of sorghum straw was investigated by non-isothermal thermogravimetric analysis, where the determination of kinetic triplet (activation energy, pre-exponential factor, and reaction model), was the key objective. The activation energy was determined using different isoconversional methods: Friedman, Flynn-Wall-Ozawa (FWO), Kissinger-Akahira-Sunose (KAS), Starink, Iterative method of Chai & Chen, Vyazovkin AIC method, and Li & Tang equation. The pre-exponential factor was calculated using Kissinger's equation while the reaction model was predicted by comparison of z-master plot obtained from experimental values with the theoretical plots. The values of activation energy obtained from isoconversional methods were further used for evaluation of thermodynamic parameters, enthalpy, entropy and Gibbs free energy. Results showed three zones of pyrolysis having average activation energy values of 151.21kJ/mol, 116.15kJ/mol, and 136.65kJ/mol respectively. The data was well fitting with two-dimension 'Valensi' model for conversion values from 0 to 0.4 with a coefficient of determination (R
No related grants have been discovered for Bhaskar Thallada.