ORCID Profile
0000-0002-8025-307X
Current Organisation
Fritz-Haber-Institut der Max-Planck-Gesellschaft
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Publisher: American Chemical Society (ACS)
Date: 07-12-2021
DOI: 10.1021/JACS.1C05357
Abstract: The differentiation between missing linker defects and missing cluster defects in MOFs is difficult, thereby limiting the ability to correlate materials properties to a specific type of defects. Herein, we present a novel and easy synthesis strategy for the creation of solely "missing cluster defects" by preparing mixed-metal (Zn, Zr)-UiO-66 followed by a gentle acid wash to remove the Zn nodes. The resulting material has the
Publisher: IOP Publishing
Date: 22-06-2022
Abstract: Renewable fuel generation is essential for a low carbon footprint economy. Thus, over the last five decades, a significant effort has been dedicated towards increasing the performance of solar fuels generating devices. Specifically, the solar to hydrogen efficiency of photoelectrochemical cells has progressed steadily towards its fundamental limit, and the faradaic efficiency towards valuable products in CO 2 reduction systems has increased dramatically. However, there are still numerous scientific and engineering challenges that must be overcame in order to turn solar fuels into a viable technology. At the electrode and device level, the conversion efficiency, stability and products selectivity must be increased significantly. Meanwhile, these performance metrics must be maintained when scaling up devices and systems while maintaining an acceptable cost and carbon footprint. This roadmap surveys different aspects of this endeavor: system benchmarking, device scaling, various approaches for photoelectrodes design, materials discovery, and catalysis. Each of the sections in the roadmap focuses on a single topic, discussing the state of the art, the key challenges and advancements required to meet them. The roadmap can be used as a guide for researchers and funding agencies highlighting the most pressing needs of the field.
Publisher: American Chemical Society (ACS)
Date: 03-07-2019
Abstract: Gold nanoparticles are unique electrocatalysts for oxygen reduction, carbon dioxide reduction, and alcohol oxidation. Electrocatalytic processes are influenced by the interaction with the solvent, yet the direct investigation of the solvation of nanoparticles is scarce. Here, we select gold nanoparticles as ∼10 nm sized solutes of which we can control the charge. We perform mid-infrared and terahertz spectroscopy to compare the behavior of the water in solution with micelles loaded with neutral and positive gold nanoparticles. We find indications that the hydration water around the gold-loaded micelles is characterized by weaker hydrogen bonds than bulk water. A positive nanoparticle charge is observed to result in a larger blue shift of the OH stretch, quenches the intensity of the collective translational mode, and increases the absorption by librating water molecules. Water at the interface of a positive gold nanoparticle is suggested to experience a stiffer potential energy surface which, in turn, might unveil local thermodynamic properties.
Publisher: American Chemical Society (ACS)
Date: 10-01-2023
Publisher: Springer Science and Business Media LLC
Date: 18-11-2020
Publisher: Springer Science and Business Media LLC
Date: 05-01-2021
No related grants have been discovered for Beatriz Roldan Cuenya.