ORCID Profile
0000-0003-2830-4383
Current Organisation
Beijing Institute of Technology
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Publisher: American Scientific Publishers
Date: 12-2014
Publisher: Royal Society of Chemistry (RSC)
Date: 2014
DOI: 10.1039/C3CE42135J
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C4NJ01834F
Abstract: A controlled synthesis of CuS microflowers through sonochemical technique is carried out and their excellent and versatile natural light driven photodegradation capability has been witnessed.
Publisher: Royal Society of Chemistry (RSC)
Date: 2014
DOI: 10.1039/C4RA04940C
Abstract: A variety of super complex architectures of covellite copper sulfide have been successfully prepared by a simple solvothermal approach and a precise comparison has been carried out in phot-degrading various organic dyes under natural light irradiation.
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C4RA15607B
Abstract: Rigid three-dimensional (3D) Ni 3 S 4 nanosheet frames assembled from ultrathin nanosheets are synthesized via a facile solvothermal method.
Publisher: American Chemical Society (ACS)
Date: 11-08-2014
DOI: 10.1021/AM503136H
Abstract: Hierarchical nanostructures (Hs) have recently garnered enormous attention due to their remarkable performances in catalysis, electronic devices, energy storage and conversion. Considering the advantage of hierarchical nanostructures, we have formulated a facile and template free method to synthesize novel hierarchical nanospheres (NHNs) of ZnV2O4. Both zinc and vanadium are earth abundant, relatively economical and can offer several oxidation states, which can render a broad range of redox reactions favorable for electrochemical energy storage applications. Keeping these points in mind, we investigated for the first time the electrochemical supercapacitor performance of NHNs. The electrochemical measurements were performed in 2 M KOH solution. The measured specific capacitance of ZnV2O4 electrode is 360 F/g at 1 A/g with good stability and retention capacity of 89% after 1000 cycles. Moreover, the hydrogen storage properties of NHNs were measured at 473, 573, and 623 K with an absorption of 1.76, 2.03, and 2.49 wt %. respectively. These studies pave the way to consider ZnV2O4 as prospective material for energy storage applications.
Publisher: Springer Science and Business Media LLC
Date: 23-07-2015
DOI: 10.1038/SREP12389
Abstract: To explore the effect of morphology on catalytic properties of graphitic carbon nitride (GCN), we have studied oxygen reduction reaction (ORR) performance of two different morphologies of GCN in alkaline media. Among both, tubular GCN react with dissolved oxygen in the ORR with an onset potential close to commercial Pt/C. Furthermore, the higher stability and excellent methanol tolerance of tubular GCN compared to Pt/C emphasizes its suitability for fuel cells.
Publisher: American Chemical Society (ACS)
Date: 31-12-2014
DOI: 10.1021/AM405076B
Abstract: We have developed a facile, scale up, and efficient method for the preparation of graphitic-C3N4 nanofibers (GCNNFs) as electrodes for supercapacitors and photocatalysts. The as-synthesized GCNNFs have 1D structure with higher concentration of nitrogen that is favorable for higher conductivity and electrochemical performance. Secondly, the high surface area of GCNNF provides a large electrode-electrolyte contact area, sufficient light harvesting and mass transfer, as well as increased redox potential. Thus, the GCNNF supercapacitor electrode shows high capacitance of 263.75 F g(-1) and excellent cyclic stability in 0.1 M Na2SO4 aqueous electrolyte with the capacitance retention of 93.6% after 2000 cycles at 1 A g(-1) current density. GCNNFs exhibit high capacitance of 208 F g(-1) even at 10 A g(-1), with the appreciable capacitance retention of 89.5%, which proves its better rate capability. Moreover, the GCNNF shows enhanced photocatalytic activity in the photodegradation of RhB in comparison to the bulk graphitic-C3N4 (GCN). The degradation rate constant of GCNNF photocatalyst is almost 4 times higher than GCN. The enhanced photocatalytic activity of GCNNF is mainly due to the higher surface area, appropriate bandgap, and fewer defects in GCNNF as compared to GCN. As an economical precursor (melamine) and harmless, facile, and template-free synthesis method with excellent performance both in supercapacitors and in photodegradation, GCNNF is a strong candidate for energy storage and environment protection applications.
Publisher: Elsevier BV
Date: 09-2014
Publisher: Elsevier BV
Date: 10-2016
Publisher: Springer Science and Business Media LLC
Date: 04-05-2023
DOI: 10.1038/S41467-023-38285-Z
Abstract: Photoelectrochemical water splitting has long been considered an ideal approach to producing green hydrogen by utilizing solar energy. However, the limited photocurrents and large overpotentials of the anodes seriously impede large-scale application of this technology. Here, we use an interfacial engineering strategy to construct a nanostructural photoelectrochemical catalyst by incorporating a semiconductor CdS/CdSe-MoS 2 and NiFe layered double hydroxide for the oxygen evolution reaction. Impressively, the as-prepared photoelectrode requires an low potential of 1.001 V vs. reversible hydrogen electrode for a photocurrent density of 10 mA cm −2 , and this is 228 mV lower than the theoretical water splitting potential (1.229 vs. reversible hydrogen electrode). Additionally, the generated current density (15 mA cm −2 ) of the photoelectrode at a given overpotential of 0.2 V remains at 95% after long-term testing (100 h). Operando X-ray absorption spectroscopy revealed that the formation of highly oxidized Ni species under illumination provides large photocurrent gains. This finding opens an avenue for designing high-efficiency photoelectrochemical catalysts for successive water splitting.
Publisher: Royal Society of Chemistry (RSC)
Date: 2012
DOI: 10.1039/C2CE25800E
Publisher: Elsevier BV
Date: 2015
No related grants have been discovered for Chuanbao Cao.