ORCID Profile
0000-0003-0661-2051
Current Organisation
Edith Cowan University
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In Research Link Australia (RLA), "Research Topics" refer to ANZSRC FOR and SEO codes. These topics are either sourced from ANZSRC FOR and SEO codes listed in researchers' related grants or generated by a large language model (LLM) based on their publications.
Nanoscale Characterisation | Nanotechnology | Plant Biology not elsewhere classified | Palaeontology (incl. Palynology) | Ore Deposit Petrology | Mineralogy and Crystallography | Biomechanical Engineering | Carbon Capture Engineering (excl. Sequestration) | Structural Biology (incl. Macromolecular Modelling) | Geophysical Fluid Dynamics | Nanomaterials | Functional Materials | Geomechanics and Resources Geotechnical Engineering | Manufacturing Processes and Technologies (excl. Textiles) | Soil Biology | Resources Engineering and Extractive Metallurgy | Carbon Sequestration Science | Materials Engineering | Metals and Alloy Materials | Petroleum and Reservoir Engineering | Nanofabrication, Growth and Self Assembly
Expanding Knowledge in the Biological Sciences | Ecosystem Adaptation to Climate Change | Climate Change Mitigation Strategies | Fabricated Metal Products not elsewhere classified | Oil Shale and Tar Sands Mining and Extraction | Oil and Gas Extraction | Expanding Knowledge in the Earth Sciences | Expanding Knowledge in the Chemical Sciences | Dental Health | Expanding Knowledge in the Physical Sciences | Expanding Knowledge in Engineering | Mining and Extraction of Precious (Noble) Metal Ores | Flora, Fauna and Biodiversity at Regional or Larger Scales |
Publisher: Elsevier BV
Date: 05-2019
Publisher: Elsevier BV
Date: 03-2016
Publisher: Elsevier BV
Date: 08-2015
Publisher: MDPI AG
Date: 2020
Abstract: Fe-based metallic glasses have been demonstrated as effective heterogeneous catalysts in Fenton-like processes for dye degradation. Yet, currently corresponding studies have limitations due to the limited study object (dyes) and the correlation between metallic glasses and dye pollutants in Fenton-like processes is still not comprehensively studied. Accordingly, this work intensively investigated the thermal catalytic behavior correlations between two Fe-based metallic glasses (Fe78Si9B13 and Fe73.5Si13.5B9Cu1Nb3) and eight different dyes. Results indicated a lower activation energy in the more active metallic glass and a dependence of the activation energy of Fe-based metallic glasses in dye solutions. In addition, a high H2O2 concentration led to a declined catalytic efficiency but a photo-enhanced Fenton-like process overcame this limitation at high concentration of H2O2 due to the decrease of pH and enhancement of irradiation. Furthermore, the average mineralization rates of Fe78Si9B13 and Fe73.5Si13.5B9Cu1Nb3 have been measured to be 42.7% and 12.6%, respectively, and the correlation between decolorization and mineralization revealed that a faster decolorization in a Fenton-like process contributed to a higher mineralization rate. This work provides an intrinsic viewpoint of the correlation between Fe-based metallic glasses and dyes in Fenton-like processes and holds the promise to further promote the industrial value of metallic glasses.
Publisher: Elsevier BV
Date: 06-2017
Publisher: Springer Science and Business Media LLC
Date: 10-2016
Publisher: American Chemical Society (ACS)
Date: 25-11-2020
Abstract: Integrating carbon nitride with graphene into a lateral heterojunction would avoid energy loss within the interlaminar space region on conventional composites. To date, its synthesis process is limited to the bottom-up method which lacks the targeting and homogeneity. Herein, we proposed a hydrogen-initiated chemical epitaxial growth strategy at a relatively low temperature for the fabrication of graphene/carbon nitride in-plane heterostructure. Theoretical and experimental analysis proved that methane via
Publisher: Elsevier BV
Date: 03-2014
Publisher: Elsevier BV
Date: 10-2007
Publisher: Elsevier BV
Date: 04-2014
Publisher: Trans Tech Publications, Ltd.
Date: 06-2011
DOI: 10.4028/WWW.SCIENTIFIC.NET/SSP.172-174.741
Abstract: In this work we compare and contrast the stability of retained austenite during tensile testing of Nb-Mo-Al transformation-induced plasticity steel subjected to different thermomechanical processing schedules. The obtained microstructures were characterised using optical metallography, transmission electron microscopy and X-ray diffraction. The transformation of retained austenite to martensite under tensile loading was observed by in-situ high energy X-ray diffraction at 1ID / APS. It has been shown that the variations in the microstructure of the steel, such as volume fractions of present phases, their morphology and dimensions, play a critical role in the strain-induced transition of retained austenite to martensite.
Publisher: Elsevier BV
Date: 09-2014
Publisher: Elsevier BV
Date: 2021
Publisher: Wiley
Date: 09-01-2020
Abstract: Thanks to a considerable number of fascinating properties, titanium (Ti) and Ti alloys play important roles in a variety of industrial sectors. However, Ti and Ti alloys could not satisfy all industrial requirements the degradation of Ti and Ti alloys always commences on their surfaces in service, which declines the performances of Ti workpieces. Therefore, with aim to further improve their mechanical, corrosion and biological properties, surface modification is often required for Ti and Ti alloys. This article reviews the technologies and recent developments of surface‐modification methods with respect to Ti and Ti alloys, including mechanical, physical, chemical, and biochemical technologies. Conventional methods have limited improvement in the properties and/or restriction on the geometry of workpieces. Therefore, many advanced surface‐modification technologies have emerged in recent decades. New methods make Ti and Ti alloys have better performance and extended applications. With requirement of high surface properties in future. Understanding the mechanism in various surface‐modification methods, combining the advantages of current technologies and developing new coating materials with high performance are required urgently. As such, incorporation of different surface‐modification technologies with high‐performance modified layers may be the mainstream of surface modifications for Ti and Ti alloys.
Publisher: Elsevier BV
Date: 06-2023
Publisher: Elsevier BV
Date: 2014
Publisher: Elsevier BV
Date: 08-2010
Publisher: Elsevier BV
Date: 09-2020
Publisher: Elsevier BV
Date: 02-2019
Publisher: Wiley
Date: 18-10-2018
Abstract: With an intrinsically disordered atomic structure and a widely tunable atomic constituent, metallic glasses (MGs) have been extensively studied as promising catalysts in different catalytic fields. Particularly, Fe-based MGs with high catalytic activity, relatively low material cost, and environmental friendly compatibility also emerge as advanced catalysts. This review systematically discusses the recent advances of Fe-based MGs in catalytic applications, including wastewater remediation based on reductive degradation by multicomponent Fe-based MGs, oxidative degradation by introduction of advanced oxidation processes (AOPs) and nanocrystallization applied in Fe-based MGs up to date, and renewable energy conversion, with purposes of revealing Fe-based MG catalysts in the further improvement of catalytic performance and exploiting their promising catalytic abilities in a widely catalytic field.
Publisher: Elsevier BV
Date: 06-2017
Publisher: American Scientific Publishers
Date: 07-2014
Publisher: Informa UK Limited
Date: 28-01-2016
Publisher: Elsevier BV
Date: 10-2018
Publisher: Elsevier BV
Date: 2019
Publisher: Elsevier BV
Date: 03-2019
Publisher: American Chemical Society (ACS)
Date: 11-05-2018
Publisher: Elsevier BV
Date: 06-2016
Publisher: Elsevier BV
Date: 2007
Publisher: Springer Science and Business Media LLC
Date: 21-03-2018
Publisher: IOP Publishing
Date: 17-07-2018
Publisher: MDPI AG
Date: 24-08-2020
DOI: 10.3390/MET10091139
Abstract: β-type titanium (Ti) alloys have attracted a lot of attention as novel biomedical materials in the past decades due to their low elastic moduli and good biocompatibility. This article provides a broad and extensive review of β-type Ti alloys in terms of alloy design, preparation methods, mechanical properties, corrosion behavior, and biocompatibility. After briefly introducing the development of Ti and Ti alloys for biomedical applications, this article reviews the design of β-type Ti alloys from the perspective of the molybdenum equivalency (Moeq) method and DV-Xα molecular orbital method. Based on these methods, a considerable number of β-type Ti alloys are developed. Although β-type Ti alloys have lower elastic moduli compared with other types of Ti alloys, they still possess higher elastic moduli than human bones. Therefore, porous β-type Ti alloys with declined elastic modulus have been developed by some preparation methods, such as powder metallurgy, additive manufacture and so on. As reviewed, β-type Ti alloys have comparable or even better mechanical properties, corrosion behavior, and biocompatibility compared with other types of Ti alloys. Hence, β-type Ti alloys are the more suitable materials used as implant materials. However, there are still some problems with β-type Ti alloys, such as biological inertness. As such, summarizing the findings from the current literature, suggestions forβ-type Ti alloys with bioactive coatings are proposed for the future development.
Publisher: AIP Publishing
Date: 08-2006
DOI: 10.1063/1.2234535
Abstract: A Ti-based metallic glass matrix composite with 10vol% TiC is synthesized by mechanical alloying. The thermal stability and crystallization kinetics of the metallic glass and composite powders are investigated by differential scanning calorimetry in the mode of isochronal heating and isothermal annealing. The isothermal transformation kinetics is analyzed by the Kolmogorov-Johnson-Mehl-Avrami equation. The values of the Avrami exponent calculated for low crystallization volume fractions imply that the crystallization of both types of powders is governed by diffusion-controlled three-dimensional growth. The mean activation energy of crystallization for the composite is slightly lower than that of the Ti-based metallic glass. The addition of 10vol% TiC particles into a Ti-based metallic glass matrix may slightly affect the crystallization kinetics of the glassy matrix.
Publisher: Elsevier BV
Date: 05-2013
Publisher: Elsevier BV
Date: 10-2021
Publisher: Elsevier BV
Date: 03-2018
Publisher: Wiley
Date: 18-07-2018
Publisher: Elsevier BV
Date: 04-2023
Publisher: MDPI AG
Date: 18-01-2022
DOI: 10.3390/MET12020168
Abstract: The bond strength is a critical consideration for the plasma-sprayed NiCrBSi coatings. However, the conventional methods for testing the bond strength of NiCrBSi coatings always cost time and money. If there is a simple method that could predict the bond strength of the prepared NiCrBSi coatings without destroying the coatings, it would be significantly beneficial for industrial applications. In this work, a new method was proposed based on the total areas of the interfacial pores for the NiCrBSi coatings. The NiCrBSi coating was prepared by plasma spraying technology and the as-sprayed coating was subsequently remelted by plasma arc using the powers of 20 kW, 25 kW, and 30 kW, respectively. The interfacial microstructures, the size distributions and total areas of the interfacial pores, interfacial hardness, and bond strength of all prepared coating s les were investigated. After remelting, the number and the total area of interfacial pores decrease with increasing the remelting power. Correspondingly, the interfacial hardness and bond strength of coatings increase with increasing the remelting power The bond strength of coatings basically has a linear relationship with the total area of interfacial pores. The built relationship may be used to predict the bond strength of NiCrBSi coatings.
Publisher: Elsevier BV
Date: 11-2004
Publisher: Elsevier BV
Date: 06-2019
Publisher: Elsevier BV
Date: 2018
Publisher: Elsevier BV
Date: 12-2019
DOI: 10.1016/J.WATRES.2019.115110
Abstract: Membrane separation and advanced oxidation processes (AOPs) have been respectively demonstrated to be effective for a variety of water and/or wastewater treatments. Innovative integration of membrane with catalytic oxidation is thus expected to be more competing for more versatile applications. In this study, ceramic membranes (CMs) integrated with manganese oxide (MnO
Publisher: Elsevier BV
Date: 02-2023
Publisher: The Electrochemical Society
Date: 2018
DOI: 10.1149/2.1191807JES
Publisher: Elsevier BV
Date: 09-2019
Publisher: Elsevier BV
Date: 05-2018
Publisher: Wiley
Date: 19-12-2017
Publisher: Elsevier BV
Date: 2013
Publisher: Elsevier BV
Date: 12-2018
Publisher: Elsevier BV
Date: 12-2017
Publisher: Elsevier BV
Date: 09-2018
Publisher: MDPI AG
Date: 14-09-2017
DOI: 10.3390/MET7090373
Publisher: Elsevier BV
Date: 05-2020
Publisher: Elsevier BV
Date: 06-2014
Publisher: Springer Science and Business Media LLC
Date: 14-10-2016
Publisher: Springer Science and Business Media LLC
Date: 17-06-2014
DOI: 10.1557/JMR.2014.122
Publisher: Informa UK Limited
Date: 07-2015
Publisher: Elsevier BV
Date: 10-2016
Publisher: Elsevier BV
Date: 07-2018
Publisher: Elsevier BV
Date: 09-2019
Publisher: Springer Science and Business Media LLC
Date: 02-07-2018
Publisher: Elsevier BV
Date: 02-2017
Publisher: Elsevier BV
Date: 2017
Publisher: Elsevier BV
Date: 2024
Publisher: Elsevier BV
Date: 02-2017
Publisher: Elsevier BV
Date: 08-2008
Publisher: Elsevier BV
Date: 2007
Publisher: Elsevier BV
Date: 07-2016
Publisher: Springer Science and Business Media LLC
Date: 24-02-2015
Publisher: Elsevier BV
Date: 11-2017
Publisher: Elsevier BV
Date: 06-2011
Publisher: Wiley
Date: 13-09-2018
Abstract: Metallic glasses (MGs) with the metastable nature and random atomic packing structure have attracted large attention in the catalytic family due to their superior catalytic performance. In contrast, their crystalline counterparts are restricted by the highly ordered packing structure, fewer surface active sites, and crystallographic defects for catalytic activity. The uncertainty of the different catalytic mechanisms and the intrinsic characteristics correlated to MGs and their crystalline counterparts become a major impediment to promote their catalytic efficiencies and widespread applications. Herein, it is reported that the excellent catalytic behavior in Fe-based MGs goes through a detrimental effect with the partial crystallization, but receives a compelling rejuvenation in the full crystallization. Further investigation reveals that multiphase intermetallics with electric potential differences in fully crystallized alloys facilitate the formation of galvanic cells. More importantly, extensively reduced grain boundaries due to grain growth greatly weaken electron trapping and promote inner electron transportation. The relatively homogenous grain-boundary corrosion in the intermetallics contributes to well-separated phases after reaction, leading to refreshment of the surface active sites, thereby quickly activating hydrogen peroxide and rapidly degrading organic pollutants. The exploration of catalytic mechanisms in the crystalline counterparts of MGs provides significant insights into revolutionize novel catalysts.
Publisher: Springer Science and Business Media LLC
Date: 29-06-2018
Publisher: Elsevier BV
Date: 07-2009
Publisher: Elsevier BV
Date: 06-2012
Publisher: Elsevier BV
Date: 10-2023
Publisher: Elsevier BV
Date: 09-2016
Publisher: Elsevier BV
Date: 09-2018
Publisher: Elsevier BV
Date: 11-2018
Publisher: MDPI AG
Date: 10-04-2017
DOI: 10.3390/MET7040131
Publisher: Elsevier BV
Date: 09-2018
Publisher: MDPI AG
Date: 16-06-2023
DOI: 10.3390/MA16124437
Abstract: With the development of high-speed and heavy-haul railway transportation, the surface failure of rail turnouts has become increasingly severe due to insufficient high hardness-toughness combination. In this work, in situ bainite steel matrix composites with WC primary reinforcement were fabricated via direct laser deposition (DLD). With the increased primary reinforcement content, the adaptive adjustments of the matrix microstructure and in situ reinforcement were obtained at the same time. Furthermore, the dependence of the adaptive adjustment of the composite microstructure on the composites’ balance of hardness and impact toughness was evaluated. During DLD, the laser induces an interaction among the primary composite powders, which leads to obvious changes in the phase composition and morphology of the composites. With the increased WC primary reinforcement content, the dominant sheaves of the lath-like bainite and the few island-like retained austenite are changed into needle-like lower bainite and plenty of block-like retained austenite in the matrix, and the final reinforcement of Fe3W3C and WC is obtained. In addition, with the increased primary reinforcement content, the microhardness of the bainite steel matrix composites increases remarkably, but the impact toughness decreases. However, compared with conventional metal matrix composites, the in situ bainite steel matrix composites manufactured via DLD possess a much better hardness-toughness balance, which can be attributed to the adaptive adjustment of the matrix microstructure. This work provides a new insight into obtaining new materials with a good combination of hardness and toughness.
Publisher: Elsevier BV
Date: 10-2006
Publisher: Elsevier BV
Date: 05-2017
Publisher: Elsevier BV
Date: 10-2014
Publisher: Elsevier BV
Date: 10-2016
Publisher: Elsevier BV
Date: 02-2014
Publisher: Elsevier BV
Date: 08-2005
Publisher: Elsevier BV
Date: 09-2019
Publisher: Springer Science and Business Media LLC
Date: 06-12-2016
DOI: 10.1038/SREP38520
Abstract: Stability and reusability are important characteristics of advanced catalysts for wastewater treatment. In this work, for the first time, sulfate radicals (SO 4 ∙ − ) with a high oxidative potential (E o = 2.5–3.1 V) were successfully activated from persulfate by a Fe 78 Si 9 B 13 metallic glass. This alloy exhibited a superior surface stability and reusability while activating persulfate as indicated by it being used for 30 times while maintaining an acceptable methylene blue (MB) degradation rate. The produced SiO 2 layer on the ribbon surface expanded strongly from the fresh use to the 20 th use, providing stable protection of the buried Fe. MB degradation and kinetic study revealed 100% of the dye degradation with a kinetic rate k = 0.640 within 20 min under rational parameter control. The dominant reactive species for dye molecule decomposition in the first 10 min of the reaction was hydroxyl radicals (∙OH, E o = 2.7 V) and in the last 10 min was sulfate radicals (SO 4 ∙ − ), respectively. Empirical operating variables for dye degradation in this work were under catalyst dosage 0.5 g/L, light irradiation 7.7 μW/cm 2 , and persulfate concentration 1.0 mmol/L. The amorphous Fe 78 Si 9 B 13 alloy in this work will open a new gate for wastewater remediation.
Publisher: Elsevier BV
Date: 07-2014
Publisher: Elsevier BV
Date: 05-2017
Publisher: The Electrochemical Society
Date: 2017
DOI: 10.1149/2.1481707JES
Publisher: Springer Science and Business Media LLC
Date: 17-09-2012
Publisher: Wiley
Date: 05-2020
Publisher: Elsevier BV
Date: 2007
Publisher: Elsevier BV
Date: 08-2010
Publisher: Elsevier BV
Date: 06-2017
Publisher: Elsevier BV
Date: 08-2018
Publisher: MDPI AG
Date: 21-10-2014
DOI: 10.3390/MA7107105
Publisher: Elsevier BV
Date: 10-2015
Publisher: MDPI AG
Date: 17-12-2020
DOI: 10.3390/MET10121688
Abstract: The remelting method is introduced to improve the properties of the as-sprayed NiCrBSi coatings. In this work, tungsten carbide (WC) was selected as reinforcement and the as-sprayed and remelted NiCrBSi/WC composite coatings were investigated by X-ray diffraction, scanning electron microscopy, hardness test and tribology test. After spraying, WC particles are evenly distributed in the coating. The remelting process induced the decarburizing reaction of WC, resulting in the formation of dispersed W2C. The dispersed W2C particles play an important role in the dispersion strengthening. Meanwhile, the pores and lamellar structures are eliminated in the remelted NiCrBSi/WC composite coating. Due to these two advantages, the hardness and the high-temperature wear resistance of the remelted NiCrBSi/WC composite coating are significantly improved compared with those with an as-sprayed NiCrBSi coating the as-sprayed NiCrBSi coating, as-sprayed NiCrBSi/WC composite coating and remelted NiCrBSi/WC composite coating have average hardness of 673.82, 785.14, 1061.23 HV, and their friction coefficients are 0.3418, 0.3261, 0.2431, respectively. The wear volume of the remelted NiCrBSi/WC composite coating is only one-third of that of the as-sprayed NiCrBSi coating.
Publisher: Elsevier BV
Date: 10-2021
Publisher: Elsevier BV
Date: 05-2019
Publisher: Inderscience Publishers
Date: 2015
Publisher: Elsevier BV
Date: 09-2023
Publisher: MDPI AG
Date: 28-07-2020
DOI: 10.3390/NANO10081479
Abstract: Surface functionalization is an effective approach to change the surface properties of a material to achieve a specific goal such as improving the biocompatibility of the material. Here, the surface of the commercial biomedical Ti-6Al-7Nb alloy was functionalized through synthesizing of a porous surface layer by liquid metal dealloying (LMD). During LMD, the Ti-6Al-7Nb alloy is immersed in liquid magnesium (Mg) and both materials react with each other. Particularly, aluminum (Al) is selectively dissolved from the Ti-6Al-7Nb alloy into liquid Mg while titanium (Ti) and niobium (Nb) diffuse along the metal/liquid interface to form a porous structure. We demonstrate that the porous surface layer in the Ti-6Al-7Nb alloy can be successfully tailored by LMD. Furthermore, the concentration of harmful Al in this porous layer is reduced by about 48% (from 5.62 ± 0.11 wt.% to 2.95 ± 0.05 wt.%) after 30 min of dealloying at 1150 K. The properties of the porous layer (e.g., layer thickness) can be tuned by varying the dealloying conditions. In-vitro tests suggest improved bone formation on the functionalized porous surface of the Ti-6Al-7Nb alloy.
Publisher: American Chemical Society (ACS)
Date: 31-08-2017
Abstract: For the first time, a porous and conductive Co
Publisher: Springer Science and Business Media LLC
Date: 19-09-2016
Publisher: Royal Society of Chemistry (RSC)
Date: 2021
DOI: 10.1039/D1CP00701G
Abstract: Pulsed laser strategies ( i.e. pulsed laser ablation and fragmentation in liquid) have been reviewed with a focus on the synthesis and processing of amorphous metal nanoparticles. The possible formation criteria and mechanism have been discussed.
Publisher: Elsevier BV
Date: 02-2016
Publisher: Elsevier BV
Date: 10-2021
Publisher: Elsevier BV
Date: 2018
Publisher: Elsevier BV
Date: 08-2018
Publisher: IOP Publishing
Date: 07-2010
Publisher: Elsevier BV
Date: 10-2023
Publisher: Elsevier BV
Date: 10-2023
Publisher: American Chemical Society (ACS)
Date: 05-02-2018
Publisher: Elsevier BV
Date: 06-2020
Publisher: Elsevier BV
Date: 07-2021
Publisher: Elsevier BV
Date: 06-2014
Publisher: Elsevier BV
Date: 03-2017
Publisher: Elsevier BV
Date: 12-2017
Publisher: Elsevier BV
Date: 12-2013
Publisher: Elsevier BV
Date: 11-2015
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C5RA17506B
Abstract: Monodispersed EuS and Gd 2 O 2 S nanocrystals are synthesized in high yields by the thermal decomposition of Eu(oleate) 3 or Gd(oleate) 3 by using CS 2 as the sulfur source with an advantage of facile tuning their dimensionality.
Publisher: MDPI AG
Date: 17-07-2017
DOI: 10.3390/MET7070273
Publisher: Elsevier BV
Date: 08-2023
Publisher: IOP Publishing
Date: 22-06-2023
Abstract: The progress of advanced powder metallurgy techniques for manufacturing copper matrix composites and their advantages are reviewed. Influence mechanisms of ceramic particles on mechanical and thermophysical properties of composites are analyzed. The content, size, morphology and interfacial bonding of particles directly determine the comprehensive performance of composites. Research limitations and future perspectives of ceramic particles reinforced copper matrix composites are outlined.
Publisher: Elsevier BV
Date: 08-2015
Publisher: Elsevier BV
Date: 08-2015
Publisher: MDPI AG
Date: 25-09-2018
DOI: 10.3390/MET8100759
Abstract: Homogeneous distribution of fine second-phase particles (SPPs) fabricated by cycles of deformation and annealing in zirconium alloys is a critical consideration for the corrosion resistance of fuel claddings. Different deformation degrees of zirconium alloys would result in distinctive microstructures, leading to a distinct growth of SPPs during subsequent annealing. Unfortunately, the homogenization and growth behavior of SPPs in deformed zirconium alloys have not been well studied. In this work, a β-quenched Zr–Sn–Nb–Fe–Cu–Si–O alloy was rolled and annealed at 580 °C or 680 °C. The morphologies, distributions, and sizes of SPPs resulting from the different processing procedures were investigated. A linear distribution of SPPs is found in the β-quenched s le. Afterward, SPPs grow and are randomly distributed during heat treatment as the deformation degree or annealing time (or temperature) increases. The homogenization and growth of SPPs are attributed to the Ostwald ripening mechanism that is governed by lattice diffusion and short-circuit diffusion. The s le with a higher deformation degree is speculated to have a larger number of defects that provide more shortcuts for the mass transfer of SPPs, thereby facilitating a homogeneous distribution of fine SPPs during annealing.
Publisher: Elsevier BV
Date: 05-2016
Publisher: Elsevier BV
Date: 2016
Publisher: American Chemical Society (ACS)
Date: 17-02-2022
Publisher: Trans Tech Publications, Ltd.
Date: 08-2012
DOI: 10.4028/WWW.SCIENTIFIC.NET/KEM.520.226
Abstract: As many complex processing parameters are involved in Selective Laser Melting (SLM), an understanding of the scientific and technical aspects of the production route on the microstructural evolution during SLM process is required in order to obtain parts with near full density and desirable surface finish. Although the effects of the various processing parameters on the density of parts have been well documented, the effect of laser point distance on density and mechanical properties of the SLM-produced parts has not been widely studied. In this paper, we present the results of using SLM to produce biomedical beta Ti-24Nb-4Zr-8Sn components. Both the density and hardness of the material increases with increasing incident laser energy and reaches a near full density value of % without any post-processing. When the laser energy density input is high enough to fully melt powder, the laser point distance has no influence on the density or hardness of the s les. In contrast, at low energy densities, large point distances have been shown to be detrimental.
Publisher: De Gruyter
Date: 21-08-2017
Publisher: American Chemical Society (ACS)
Date: 27-10-2016
Publisher: Elsevier BV
Date: 04-2017
Publisher: Elsevier BV
Date: 06-2017
Publisher: Elsevier BV
Date: 02-2018
Publisher: Elsevier BV
Date: 07-2013
DOI: 10.1016/J.MSEC.2013.02.047
Abstract: Surface engineering through the application of super-hard, low-friction coatings as a potential approach for increasing the durability of metal-on-metal replacements is attracting significant attention. In this study innovative design strategies are proposed for the development of diamond-like-carbon (DLC) coatings against the damage caused by wear particles on the joint replacements. Finite element modeling is used to analyze stress distributions induced by wear particles of different sizes in the newly-designed coating in comparison to its conventional monolithic counterpart. The critical roles of architectural design in regulating stress concentrations and suppressing crack initiation within the coatings is elucidated. Notably, the introduction of multilayer structure with graded modulus is effective in modifying the stress field and reducing the magnitude and size of stress concentrations in the DLC diamond-like-carbon coatings. The new design is expected to greatly improve the load-carrying ability of surface coatings on prosthetic implants, in addition to the provision of damage tolerance through crack arrest.
Publisher: Elsevier BV
Date: 2011
Publisher: Elsevier BV
Date: 12-2007
Publisher: Elsevier BV
Date: 03-2023
Publisher: Springer Science and Business Media LLC
Date: 05-10-2015
Publisher: Elsevier BV
Date: 10-2019
Publisher: American Chemical Society (ACS)
Date: 10-09-2020
Publisher: Elsevier BV
Date: 11-2019
Publisher: Elsevier BV
Date: 11-2015
Publisher: Elsevier BV
Date: 2020
Publisher: Elsevier BV
Date: 06-2017
Publisher: Elsevier BV
Date: 07-2014
Publisher: Elsevier BV
Date: 02-2020
Publisher: MDPI AG
Date: 21-08-2020
DOI: 10.3390/MA13173694
Abstract: The as spun amorphous (Fe78Si9B13)99.5Zr0.5 (Zr0.5) and (Fe78Si9B13)99Zr1 (Zr1) ribbons having a Fenton-like reaction are proved to bear a good degradation performance in organic dye wastewater treatment for the first time by evaluating their degradation efficiency in methylene blue (MB) solution. Compared to the widely studied (Fe78Si9B13)100Zr0 (Zr0) amorphous ribbon for degradation, with increasing cZr (Zr atomic content), the as-spun Zr0, Zr0.5 and Zr1 amorphous ribbons have gradually increased degradation rate of MB solution. According to δc (characteristic distance) of as-spun Zr0, Zr0.5 and Zr1 ribbons, the free volume in Zr1 ribbon is higher Zr0 and Zr0.5 ribbons. In the reaction process, the Zr1 ribbon surface formed the 3D nano-porous structure with specific surface area higher than the cotton floc structure formed by Zr0 ribbon and coarse porous structure formed by Zr0.5 ribbon. The Zr1 ribbon’s high free volume and high specific surface area make its degradation rate of MB solution higher than that of Zr0 and Zr0.5 ribbons. This work not only provides a new method to remedying the organic dyes wastewater with high efficiency and low-cost, but also improves an application prospect of Fe-based glassy alloys.
Publisher: Elsevier BV
Date: 11-2014
Publisher: American Chemical Society (ACS)
Date: 19-12-2018
Publisher: Elsevier BV
Date: 2018
Publisher: Elsevier BV
Date: 02-2015
Publisher: Elsevier BV
Date: 03-2012
Publisher: Elsevier BV
Date: 02-2018
Publisher: Wiley
Date: 06-10-2016
Publisher: Public Library of Science (PLoS)
Date: 15-01-2016
Publisher: Elsevier BV
Date: 05-2018
Publisher: Elsevier BV
Date: 12-2017
Publisher: Elsevier BV
Date: 08-2021
Publisher: Elsevier BV
Date: 07-2018
Publisher: Elsevier BV
Date: 02-2018
Publisher: AIP Publishing
Date: 30-07-2007
DOI: 10.1063/1.2766861
Abstract: The authors report on ductile ultrafine-grained (Ti0.72Fe0.28)100−xTax (0⩽x⩽4) alloys with not only high fracture strength but simultaneously high yield strength exceeding 2000MPa along with distinct plasticity, which are superior to high-strength Ti-based bulk metallic glasses and bimodal composites. All alloys mainly consist of β-Ti and FeTi solid solutions but display different microstructures. The alloys exhibit a high fracture strength & MPa and a high yield strength & MPa as well as large plasticity of ∼5%–7.5%. The microstructure-property correlation of these ultrafine-grained alloys is discussed.
Publisher: Elsevier BV
Date: 05-2014
Publisher: Springer Science and Business Media LLC
Date: 05-2007
Abstract: Ni 60 Nb 40 metallic glass particles, prepared by mechanical alloying, were used to fabricate Al–30 wt% Ni 60 Nb 40 metal matrix composites (MMCs) at 823 K by sintering, hot pressing, and hot extrusion. The Ni 60 Nb 40 reinforcements remained amorphous in all the MMCs fabricated by the different methods. Compression tests revealed that the Young’s modulus and yield strength of the MMCs produced by hot-pressing and hot-extrusion are higher than those for the sintered specimens. Differential scanning calorimeter (DSC) annealing of the as-produced MMCs at 913 K revealed there are severe interfacial reactions between the Al matrix and the Ni 60 Nb 40 reinforcements. The DSC isotherms indicate that the Al matrix reacts faster with Ni 60 Nb 40 in the hot-pressed and hot-extruded MMCs than it does in the sintered material.
Publisher: Springer Science and Business Media LLC
Date: 05-2007
Abstract: Al 85 Ni 9 Nd 4 Co 2 metallic glass/nanostructured ribbons and powders were used as starting materials for producing bulk amorphous/nanostructured Al-based alloys. Glassy ribbons were obtained by melt spinning at wheel surface velocities ranging from 5 to 37 m/s. The amorphous ribbons exhibited a supercooled liquid region of ∼20 K, a reduced glass transition temperature of ∼0.47 and γ ∼ 0.328. Mechanical alloying of the elemental powder mixture did not lead to amorphization. However, amorphous powders obtained by milling the glassy ribbons for 9 h exhibited a thermal stability similar to the initial ribbons. Isothermal differential scanning calorimetry measurements were used to determine the consolidation parameters of the glassy powders. Consolidation at 513 K by uniaxial hot pressing and hot extrusion indicated that the former method leads to bulk glassy s les, whereas the latter one yields nanostructured α-Al/glassy matrix composites.
Publisher: Elsevier BV
Date: 03-2016
DOI: 10.1016/J.MSEC.2015.11.072
Abstract: A series of Ti-7Fe-xNb (x=0, 1, 4, 6, 9, 11 wt.%) alloys was designed and cast to investigate the β→α″ martensitic phase transformation, β phase stability, the resulting microstructure and mechanical properties. Phase analysis revealed that only Ti-7Fe-11Nb alloy shows a single body-centred cubic β phase microstructure while the others are comprised of β and orthorhombic α″ phases. Moreover, Nb addition up to 11 wt.% enhances the stability and volume fraction of β phase in the microstructure, hence reducing the propensity of the alloy system to form α″ phase during quenching. Compressive yield strength and hardness of the alloys are (985-1847) MPa and (325-520) Hv respectively. Additionally, Ti-7Fe-11Nb possesses the lowest Young's modulus (84 GPa) and the highest deformability (42% strain) among the designed alloys due to the single β phase microstructure. This high deformability is also corroborated by the large plastic deformation zone underneath the Vickers indenter. In contrast, the fractured surfaces of Ti-7Fe and Ti-7Fe-1Nb alloys after compressive tests mostly contain shallow dimples, verifying their low ductility. The good combination of mechanical properties obtained for Ti-7Fe-11Nb renders it more desirable than commonly used CP-Ti and Ti-6Al-4V materials and makes it a promising candidate for biomedical application.
Publisher: Elsevier BV
Date: 05-2018
Publisher: Elsevier BV
Date: 2017
Publisher: Elsevier BV
Date: 02-2017
Publisher: AIP Publishing
Date: 14-05-2007
DOI: 10.1063/1.2740476
Abstract: Instead of applying severe plastic deformation, high-temperature heat treatment or high pressure, grain refinement and high-temperature phase separation induced by deformation in single-phase body-centered-cubic (bcc) coarse-grained Co–Fe alloys have been achieved by simple room-temperature compression. The alloys exhibit large plasticity over 140% without fracture. Phase separation from the bcc phase to nanoscale face-centered-cubic Fe and Co phases, which generally occurs at high temperature above ∼1150K, is formed in the deformed s les. The possible mechanisms are shear deformation and deformation-enhanced atomic diffusion rather than the temperature rise during deformation.
Publisher: Elsevier BV
Date: 03-2005
Publisher: Springer Science and Business Media LLC
Date: 15-01-2018
DOI: 10.1038/S41598-018-19190-8
Abstract: Nanocrystalline (NC) materials have fascinating physical and chemical properties, thereby they exhibit great prospects in academic and industrial fields. Highly efficient approaches for fabricating bulk NC materials have been pursued extensively over past decades. However, the instability of nanograin, which is sensitive to processing parameters (such as temperature and time), is always a challenging issue to be solved and remains to date. Herein, we report an ultrafast nanostructuring strategy, namely ultrasonic vibration consolidation (UVC). The strategy utilizes internal friction heat, generated from mutually rubbing between Ti-based metallic glass powders, to heat the glassy alloy rapidly through its supercooled liquid regime, and accelerated viscous flow bonds the powders together. Consequently, bulk NC-Ti alloy with grain size ranging from 10 to 70 nm and nearly full density is consolidated in 2 seconds. The novel consolidation approach proposed here offers a general and highly efficient pathway for manufacturing bulk nanomaterials.
Publisher: Elsevier BV
Date: 2015
Publisher: Springer Science and Business Media LLC
Date: 19-11-2018
Publisher: Springer Science and Business Media LLC
Date: 12-2010
Abstract: The structural evolution of the Ti 40 Zr 10 Cu 34 Pd 14 Sn 2 bulk metallic glass (BMG) upon was investigated by means of in situ high-energy x-ray diffraction. The position, width, and intensity of the first peak in diffraction patterns are fitted through Voigt function below 800 K. All the peak position, width, and intensity values show a nearly linear increase with the increasing temperature to the onset temperature of structural relaxation, T r = 510 K. However, these values start to deviate from the linear behavior between T r and T g (the glass transition temperature). The changes in free volume and the coefficient of volume thermal expansion prove that the aforementioned phenomenon is closely related to the structural relaxation releasing excess free volume arrested during rapid quenching of the BMG. Above 800 K, three crystallization events are detected and the first exothermic event is due to the formation of metastable nanocrystals.
Publisher: Wiley
Date: 21-06-2023
Abstract: This work investigates the corrosion behavior and mechanism of laser powder bed fusion produced (LPBFed) Ti5Cu and its heat‐treated counterparts in 3.5 wt% NaCl solution. The results indicate that heat treatment can enhance the corrosion resistance of LPBFed Ti5Cu by generating Ti 2 Cu phase, and heat treatment at higher temperature enhances corrosion resistance by forming a stable oxide film with a lower electron diffusion rate. The existence of Ti 2 Cu phase in the heat‐treated s le acts as the microanode that decelerates the corrosion on α‐Ti phase (prior dissolution of Ti 2 Cu phase). The long‐term immersion test results also confirm that the Ti 2 Cu phase present in HT900 (at higher heat‐treatment temperature) provides a better protective effect against corrosion compared to the one in HT740 and as‐LPBFed s les. Compared with the heat‐treated counterparts, the worst corrosion resistance of the as‐LPBFed Ti5Cu is attributed to that the acidic environment (e.g., Cl − ) increases the electron diffusion rate in the film/solution interface, which makes the thermodynamically unstable α'‐Ti phase be preferentially corroded.
Publisher: MDPI AG
Date: 02-08-2019
DOI: 10.3390/MET9080850
Abstract: The growth of oxide film, which results from the inward oxygen diffusion from a corrosive environment, is a critical consideration for the corrosion resistance of zirconium alloys. This work calculates the oxygen diffusion coefficients in the oxide films formed on zirconium alloys annealed at 400~500 °C and investigates the related corrosion behavior. The annealed s les have a close size for the second-phase particles but a distinctive hardness, indicating the difference in substrate conditions. The weight gain of all s les highly follows parabolic laws. The weight gain of the s le annealed at 400 °C has the fastest increase rate at the very beginning of the corrosion test, but its oxide film has the slowest growth rate as the corrosion proceeds. By contrast, the s le annealed at 500 °C shows the lowest weight gain but the highest corrosion rate constant. Such a corrosion behavior is attributed to the amount of defects existing in the oxide film formed on the annealed s les fewer defects would provide a lower fraction of short-circuit diffusion in total diffusion, resulting in a lower diffusion coefficient of oxygen in the oxide film, thereby producing better corrosion resistance. This is consistent with the calculated diffusion coefficients of oxygen in the oxide films: 3.252 × 10−11 cm2/s, 3.464 × 10−11 cm2/s and 3.740 × 10−11 cm2/s for the s les annealed at 400 °C, 450 °C, and 500 °C, respectively.
Publisher: Elsevier BV
Date: 2016
Publisher: BMJ
Date: 12-2017
Publisher: Wiley
Date: 20-03-2019
Publisher: Elsevier BV
Date: 07-2015
Publisher: Springer Science and Business Media LLC
Date: 19-08-2015
Publisher: MDPI AG
Date: 12-12-2019
DOI: 10.3390/MET9121342
Abstract: Particle size is a critical consideration for many powder coating-related industries since it significantly influences the properties of the produced materials. However, the effect of particle size on the characteristics of plasma sprayed NiCrBSi coatings is not well understood. This work investigates the microstructures, hardness and electrochemical corrosion behavior of plasma sprayed NiCrBSi coatings synthesized using different-sized powders. All coatings mainly consist of Ni, N3B, CrB, Cr7C3 and Cr3C2 phases. The coatings produced by small particles (50–75 μm) exhibit lower porosity (2.0 ± 0.8%). Such coatings show a higher fraction (15.5 vol.%) of the amorphous phase and lower hardness (700 HV0.5) than the counterparts (8.7 vol.% and 760 HV0.5, respectively) produced by large particles (75–100 μm) with higher porosity (3.0 ± 1.6%). Meanwhile, the coatings produced from smaller particles possess a larger number of non-bonded boundaries, leading to the easier penetration of corrosive medium, as well as a higher corrosion current density (0.254 ± 0.062 μA/cm2) and a lower charge transfer resistance (0.37 ± 0.07 MΩ cm2). These distinctions are attributed to particle size-induced different melting degrees and stackings of in-flight particles during deposition.
Publisher: MDPI AG
Date: 30-06-2023
DOI: 10.3390/MA16134750
Abstract: It is well known that the development of lightweight alloys with improved comprehensive performance and application value are the future development directions for the ultra-high-strength 7xxx series Al-Zn-Mg-Cu alloys used in the aircraft field. As the lightest metal element in nature, lithium (Li) has outstanding advantages in reducing the density and increasing the elastic modulus in aluminum alloys, so Al-Zn-Mg-Cu alloys containing Li have gained widespread attention. Furthermore, since the Al-Zn-Mg-Cu alloy is usually strengthened by aging treatment, it is crucial to understand how Li addition affects its aging precipitation process. As such, in this article, the effects and mechanism of Li on the aging precipitation behavior and the impact of Li content on the aging precipitation phase of Al-Zn-Mg-Cu alloys are briefly reviewed, and the influence of Li on the service properties, including mechanical properties, wear resistance, and fatigue resistance, of Al-Zn-Mg-Cu alloys are explained. In addition, the corresponding development prospects and challenges of the Al-Zn-Mg-Cu-Li alloy are also proposed. This review is helpful to further understand the role of Li in Al-Zn-Mg-Cu alloys and provides a reference for the development of high-strength aluminum alloys containing Li with good comprehensive properties.
Publisher: Elsevier BV
Date: 04-2017
Publisher: Elsevier BV
Date: 12-2018
Publisher: Elsevier BV
Date: 02-2017
Publisher: Elsevier BV
Date: 03-2015
Publisher: Springer Science and Business Media LLC
Date: 06-04-2016
DOI: 10.1038/SREP23905
Abstract: NiTi wires were brazed together via eutectic reaction between NiTi and Nb powder deposited at the wire contact region. Phase transformation and deformation behavior of the NiTi-Nb eutectic microstructure were investigated using transmission electron microscopy (TEM) and cyclic loading-unloading tests. Results show that R phase and B19′ martensite transformation are induced by plastic deformation. R phase transformation, which significantly contributes to superelasticity, preferentially occurs at the interfaces between NiTi and eutectic region. Round-shaped Nb-rich phase with rod-like and lamellar-type eutectics are observed in eutectic regions. These phases appear to affect the deformation behavior of the brazed NiTi-Nb region via five distinct stages in stress-strain curves: (I) R phase reorientation, (II) R phase transformation from parent phase, (III) elastic deformation of reoriented martensite accompanied by the plastic deformation of Nb-rich phase and lamellar NiTi-Nb eutectic, (IV) B19′ martensitic transformation and (V) plastic deformation of the specimen.
Publisher: Elsevier BV
Date: 10-2017
Publisher: Elsevier BV
Date: 07-2017
Publisher: Elsevier BV
Date: 02-2012
Publisher: Elsevier BV
Date: 08-2011
Publisher: Wiley
Date: 02-08-2017
Publisher: Elsevier BV
Date: 12-2016
Publisher: Elsevier BV
Date: 07-2007
Publisher: Elsevier BV
Date: 08-2021
Publisher: Elsevier BV
Date: 10-2021
Publisher: Springer Science and Business Media LLC
Date: 31-03-2016
DOI: 10.1038/SREP23467
Abstract: It is well known that semi-solid forming could only obtain coarse-grained microstructure in a few alloy systems with a low melting point, such as aluminum and magnesium alloys. This work presents that semi-solid forming could also produce novel bimodal microstructure composed of nanostructured matrix and micro-sized (CoFe)Ti 2 twins in a titanium alloy, Ti 62 Nb 12.2 Fe 13.6 Co 6.4 Al 5.8 . The semi-solid sintering induced by eutectic transformation to form a bimodal microstructure in Ti 62 Nb 12.2 Fe 13.6 Co 6.4 Al 5.8 alloy is a fundamentally different approach from other known methods. The fabricated alloy exhibits high yield strength of 1790 MPa and plastic strain of 15.5%. The novel idea provides a new insight into obtaining nano-grain or bimodal microstructure in alloy systems with high melting point by semi-solid forming and into fabricating high-performance metallic alloys in structural applications.
Publisher: Elsevier BV
Date: 2019
Publisher: Elsevier BV
Date: 10-2019
Publisher: Elsevier BV
Date: 07-2019
Publisher: Elsevier BV
Date: 04-2022
Publisher: Elsevier BV
Date: 04-2023
Publisher: Elsevier BV
Date: 09-2022
Publisher: Elsevier BV
Date: 10-2015
Publisher: Elsevier BV
Date: 05-2018
Publisher: Wiley
Date: 12-05-2015
Publisher: Elsevier BV
Date: 08-2018
Publisher: Wiley
Date: 13-09-2010
Publisher: Elsevier BV
Date: 05-2018
Publisher: Wiley
Date: 30-07-2018
Abstract: Quasi-1D cadmium chalcogenide quantum rods (QRs) are benchmark semiconductor materials that are combined with noble metals to constitute QR heterostructures for efficient photocatalysis. However, the high toxicity of cadmium and cost of noble metals are the main obstacles to their widespread use. Herein, a facile colloidal synthetic approach is reported that leads to the spontaneous formation of cadmium-free alloyed ZnS
Publisher: American Chemical Society (ACS)
Date: 18-12-2019
Location: Germany
Location: China
Start Date: 08-2014
End Date: 03-2016
Amount: $580,000.00
Funder: Australian Research Council
View Funded ActivityStart Date: 01-2012
End Date: 12-2013
Amount: $620,000.00
Funder: Australian Research Council
View Funded ActivityStart Date: 2015
End Date: 12-2015
Amount: $1,060,000.00
Funder: Australian Research Council
View Funded ActivityStart Date: 06-2013
End Date: 12-2016
Amount: $480,000.00
Funder: Australian Research Council
View Funded Activity