ORCID Profile
0000-0002-6496-383X
Current Organisation
UNSW Sydney
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Publisher: MDPI AG
Date: 04-01-2022
DOI: 10.3390/MOLECULES27010292
Abstract: Building polymers implemented into building panels and exterior façades have been determined as the major contributor to severe fire incidents, including the 2017 Grenfell Tower fire incident. To gain a deeper understanding of the pyrolysis process of these polymer composites, this work proposes a multi-scale modelling framework comprising of applying the kinetics parameters and detailed pyrolysis gas volatiles (parent combustion fuel and key precursor species) extracted from Molecular Dynamics models to a macro-scale Computational Fluid Dynamics fire model. The modelling framework was tested for pure and flame-retardant polyethylene systems. Based on the modelling results, the chemical distribution of the fully decomposed chemical compounds was realised for the selected polymers. Subsequently, the identified gas volatiles from solid to gas phases were applied as the parent fuel in the detailed chemical kinetics combustion model for enhanced predictions of toxic gas, charring, and smoke particulate predictions. The results demonstrate the potential application of the developed model in the simulation of different polymer materials without substantial prior knowledge of the thermal degradation properties from costly experiments.
Publisher: MDPI AG
Date: 18-01-2021
DOI: 10.3390/MOLECULES26020478
Abstract: In recent years, the applications of lithium-ion batteries have emerged promptly owing to its widespread use in portable electronics and electric vehicles. Nevertheless, the safety of the battery systems has always been a global concern for the end-users. The separator is an indispensable part of lithium-ion batteries since it functions as a physical barrier for the electrode as well as an electrolyte reservoir for ionic transport. The properties of separators have direct influences on the performance of lithium-ion batteries, therefore the separators play an important role in the battery safety issue. With the rapid developments of applied materials, there have been extensive efforts to utilize these new materials as battery separators with enhanced electrical, fire, and explosion prevention performances. In this review, we aim to deliver an overview of recent advancements in numerical models on battery separators. Moreover, we summarize the physical properties of separators and benchmark selective key performance indicators. A broad picture of recent simulation studies on separators is given and a brief outlook for the future directions is also proposed.
Publisher: MDPI AG
Date: 20-09-2022
DOI: 10.3390/FIRE5050140
Abstract: Demand for underground railways has rapidly increased due to accelerated urbanisation and population growth. This has elevated the importance of tunnel designs with adequate fire safety and protection measures. However, due to intricate modern rail tunnel designs, prescriptive codes are often difficult to implement and lead to over-conservative design. In this study, the current state of tunnel fire analysis was reviewed with a focus on Australia. A large-eddy simulation (LES)-based fire model was applied to investigate the temperature and smoke dispersion from a 2 MW metro tunnel fire case scenario to the cross-passage. A total of 28 cases with various cross-passage ventilation settings were examined, including longitudinal tunnel velocity, cross-passage velocity, train location relative to the cross-passage and fire location. The modelling showed that a 0.84 m/s critical velocity was sufficient for smoke control in the cross-passage. Furthermore, two empirical methods for cross-passage critical velocity were performed, which showed utilisation of the Froude number produced a less conservative critical velocity (0.610 m/s) compared to the dimensionless method (0.734 m/s). Nevertheless, both numerical and empirical results were significantly lower than the standard 1.0 m/s minimum flow rate for smoke control (AS1668.1). The results provide preliminary evidence towards the need for revision of current tunnel fire standards and response protocols.
Publisher: MDPI AG
Date: 13-10-2022
DOI: 10.3390/FIRE5050165
Abstract: In this article, a collective database from validated numerical simulation has been established to study the suppression effects of water-based suppression systems under a single-compartment fire scenario at various suppression configurations and fire locations. Five fuel locations along the axis between the centre and corner of the room were configurated to dynamically analyse how the horizontal distance between the nozzle and fuel pan affects the heat release rate (HRR), temperature cooling phenomena at different heights and also the velocity profile. Throughout the fuel pan relocations, the water-mist system has achieved an average suppression time of 25 s for all the locations, it was found that the water mist system can effectively control the fire under 200 °C that is distanced over 2 m spanwise displacement from the nozzle against the fire, while the sprinkler has exhibited an excellent fuel surface cooling effect due to large momentum and heat capacity within the coverage area with an average suppression time of 50 s. The results of this study have further explored the spray coverage and droplet penetrability of different suppression systems at different locations corresponding to the fire source, and the quantitative assessment of fuel locations could also contribute to the future development of performance-based fire safety designs.
Publisher: Springer Science and Business Media LLC
Date: 31-08-2022
Publisher: MDPI AG
Date: 03-11-2021
DOI: 10.3390/MOLECULES26216662
Abstract: Biomass-derived carbon has been recognised as a green, economic and promising flame retardant (FR) for polymer matrix. In this paper, it is considered that the two-dimensional (2D) structure of carbonised peanut shells (PS) can lead to a physical barrier effect on polymers. The carbonised s le was prepared by the three facile methods, and firstly adopted as flame retardants for epoxy resin. The results of thermal gravimetric analysis (TGA) and cone calorimeter tests indicate that the carbon combined with nano Cobalt provides the most outstanding thermal stability in the current study. With 3 wt.% addition of the FR, both peak heat release rate (pHRR) and peak smoke production rate (PSPR) decrease by 37.9% and 33.3%, correspondingly. The flame retardancy mechanisms of the FR are further explored by XPS and TG-FTIR. The effectiveness of carbonised PS can be mainly attributed to the physical barrier effect derived by PS’s 2D structure and the catalysis effect from Cobalt, which contribute to form a dense char layer.
Publisher: Informa UK Limited
Date: 27-01-2021
Publisher: Springer Science and Business Media LLC
Date: 19-06-2021
Publisher: Elsevier BV
Date: 07-2022
Publisher: Informa UK Limited
Date: 26-07-2022
Publisher: MDPI AG
Date: 02-06-2023
DOI: 10.20944/PREPRINTS202306.0115.V1
Abstract: To date, zinc ion batteries (ZIBs) have been attracting extensive attention due to their outstanding properties and the potential to be the solution for next-generation energy storage systems. However, the uncontrollable growth of zinc dendrites and water-splitting issues seriously restrict the further scalable application. Over the past few years, solid polymer electrolytes (SPEs) have been regarded as a promising alternative to address these challenges and facilitate the practical advancement of zinc batteries. In this review, we revisited the research progress of SPEs applied in zinc batteries in the past few years and focus on introducing cutting-edge polymer science and technologies that can be utilized to prepare advanced SPEs for high-performance zinc batteries. The operating mechanism of SPEs and the functions of polymers will be summarized. To highlight the polymer functions, SPEs are categorized into three types, respectively, homogenous polymer SPEs, hybrids polymer SPEs, and nanocomposites SPEs, which are expected to reveal the roles and principles of various polymers in zinc batteries. This review presents the current research progress and fundamental mechanisms of polymer-based SPEs in zinc batteries, outlines the challenging issues encountered, and meanwhile proposes potential solutions for future endeavours.
Publisher: Springer Science and Business Media LLC
Date: 25-04-2022
DOI: 10.1038/S41467-022-29912-2
Abstract: There is le support for developmental regulation of glioblastoma stem cells. To examine how cell lineage controls glioblastoma stem cell function, we present a cross-species epigenome analysis of mouse and human glioblastoma stem cells. We analyze and compare the chromatin-accessibility landscape of nine mouse glioblastoma stem cell cultures of three defined origins and 60 patient-derived glioblastoma stem cell cultures by assay for transposase-accessible chromatin using sequencing. This separates the mouse cultures according to cell of origin and identifies three human glioblastoma stem cell clusters that show overlapping characteristics with each of the mouse groups, and a distribution along an axis of proneural to mesenchymal phenotypes. The epigenetic-based human glioblastoma stem cell clusters display distinct functional properties and can separate patient survival. Cross-species analyses reveals conserved epigenetic regulation of mouse and human glioblastoma stem cells. We conclude that epigenetic control of glioblastoma stem cells primarily is dictated by developmental origin which impacts clinically relevant glioblastoma stem cell properties and patient survival.
Publisher: Elsevier BV
Date: 07-2021
Publisher: Elsevier BV
Date: 05-2022
Publisher: Elsevier BV
Date: 05-2022
Publisher: Springer Science and Business Media LLC
Date: 14-06-2021
Publisher: MDPI AG
Date: 27-06-2023
Abstract: To date, zinc-ion batteries (ZIBs) have been attracting extensive attention due to their outstanding properties and the potential to be the solution for next-generation energy storage systems. However, the uncontrollable growth of zinc dendrites and water-splitting issues seriously restrict their further scalable application. Over the past few years, solid polymer electrolytes (SPEs) have been regarded as a promising alternative to address these challenges and facilitate the practical advancement of zinc batteries. In this review, we revisit the research progress of SPEs applied in zinc batteries in the past few years and focus on introducing cutting-edge polymer science and technologies that can be utilised to prepare advanced SPEs for high-performance zinc batteries. The operating mechanism of SPEs and the functions of polymers are summarised. To highlight the polymer’s functions, SPEs are categorised into three types, homogenous polymer SPEs, hybrids polymer SPEs, and nanocomposites SPEs, which are expected to reveal the roles and principles of various polymers in zinc batteries. This review presents the current research progress and fundamental mechanisms of polymer-based SPEs in zinc batteries, outlines the challenging issues encountered, and proposes potential solutions for future endeavours.
Publisher: Elsevier BV
Date: 05-2021
Publisher: Springer Science and Business Media LLC
Date: 23-07-2023
Publisher: Elsevier BV
Date: 03-2020
Publisher: Wiley
Date: 08-04-2021
DOI: 10.1002/FAM.2973
Abstract: Multifunctional building façades have become an increasingly critical component in modern buildings, especially after the tremendous scrutiny triggered by the utilization of combustible aluminum cladding panels (ACP) in the construction sector. Following the massive effort by both industry and government agencies to reduce the fire risks of combustible façades in recent years, façades with insufficient fire ratings have been continuously causing severe building fires leading to countless human casualties and properties damages. This review aims to provide an in‐depth overview of the previous developments and current progress for establishing relevant fire standards with regards to ACPs, from an Australian standpoint. The fire spread mechanisms associate with ACPs, and their potential hazards were discussed. Furthermore, the current building regulations for ACPs have been reviewed, including detailed experimental procedures and rating criterion for all existing international standards. To address the research knowledge gap in terms of the understanding of the cladding fire mechanisms, and combustibility of existing ACP polymer composites, recent advancement in experimental and numerical studies has been summarized and discussed to identify the critical issues and concerns for current ACP products. Future perspectives involving cutting‐edge approaches such as computational fluid dynamics (CFD) modeling coupled with artificial neural network (ANN) optimization are advocated in this article. Additionally, fundamental material characterization techniques using molecular dynamics (MD) approaches can be implemented to deliver a better description of the degradation kinetics and smoke/toxicity generations.
No related grants have been discovered for Ivan Miguel De Cachinho Cordeiro.