ORCID Profile
0000-0001-5788-6314
Current Organisation
UNSW Sydney
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Civil engineering | Fire safety engineering | Composite and hybrid materials
Publisher: Elsevier BV
Date: 05-2021
Publisher: Wiley
Date: 17-04-2020
DOI: 10.1002/FAM.2843
Publisher: MDPI AG
Date: 18-01-2021
DOI: 10.3390/MOLECULES26020478
Abstract: In recent years, the applications of lithium-ion batteries have emerged promptly owing to its widespread use in portable electronics and electric vehicles. Nevertheless, the safety of the battery systems has always been a global concern for the end-users. The separator is an indispensable part of lithium-ion batteries since it functions as a physical barrier for the electrode as well as an electrolyte reservoir for ionic transport. The properties of separators have direct influences on the performance of lithium-ion batteries, therefore the separators play an important role in the battery safety issue. With the rapid developments of applied materials, there have been extensive efforts to utilize these new materials as battery separators with enhanced electrical, fire, and explosion prevention performances. In this review, we aim to deliver an overview of recent advancements in numerical models on battery separators. Moreover, we summarize the physical properties of separators and benchmark selective key performance indicators. A broad picture of recent simulation studies on separators is given and a brief outlook for the future directions is also proposed.
Publisher: Elsevier BV
Date: 08-2019
Publisher: MDPI AG
Date: 03-11-2021
DOI: 10.3390/MOLECULES26216662
Abstract: Biomass-derived carbon has been recognised as a green, economic and promising flame retardant (FR) for polymer matrix. In this paper, it is considered that the two-dimensional (2D) structure of carbonised peanut shells (PS) can lead to a physical barrier effect on polymers. The carbonised s le was prepared by the three facile methods, and firstly adopted as flame retardants for epoxy resin. The results of thermal gravimetric analysis (TGA) and cone calorimeter tests indicate that the carbon combined with nano Cobalt provides the most outstanding thermal stability in the current study. With 3 wt.% addition of the FR, both peak heat release rate (pHRR) and peak smoke production rate (PSPR) decrease by 37.9% and 33.3%, correspondingly. The flame retardancy mechanisms of the FR are further explored by XPS and TG-FTIR. The effectiveness of carbonised PS can be mainly attributed to the physical barrier effect derived by PS’s 2D structure and the catalysis effect from Cobalt, which contribute to form a dense char layer.
Publisher: American Chemical Society (ACS)
Date: 22-12-2014
DOI: 10.1021/AM507045G
Abstract: A fire blocking coating made from chitosan, titanate nanotubes and alginate was deposited on a flexible polyurethane (FPU) foam surface by a layer-by-layer assembly technique in an effort to reduce its flammability. First, titanate nanotubes were prepared by a hydrothermal method. And then the coating growth was carried out by alternately submerging FPU foams into chitosan solution, titanate nanotubes suspension and alginate solution. The mass gain of coating on the surface of FPU foams showed dependency on the concentration of titanate nanotubes suspension and the trilayers's number. Scanning electron microscopy indicated that titanate nanotubes were distributed well on the entire surface of FPU foam and showed a randomly oriented and entangled network structure. The cone calorimeter result indicated that the coated FPU foams showed reduction in the peak heat release rate (peak HRR), peak smoke production rate (peak SPR), total smoke release (TSR) and peak carbon monoxide (CO) production compared with those of the control FPU foam. Especially for the FPU foam with only 5.65 wt % mass gain, great reduction in peak HRR (70.2%), peak SPR (62.8%), TSR (40.9%) and peak CO production (63.5%) could be observed. Such a significant improvement in flame retardancy and the smoke suppression property for FPU foam could be attributed to the protective effect of titanate nanotubes network structure formed, including insulating barrier effect and adsorption effect.
Publisher: American Chemical Society (ACS)
Date: 05-01-2016
Publisher: Elsevier BV
Date: 03-2017
Publisher: Royal Society of Chemistry (RSC)
Date: 2021
DOI: 10.1039/D0TA10073K
Abstract: The electrically conductive surface and aligned pores of a separator could effectively promote the safety and enhance the electrochemical performance of LMBs.
Publisher: Elsevier BV
Date: 04-2020
DOI: 10.1016/J.JHAZMAT.2019.122006
Abstract: To date epoxy resins have been extensively used in the field of chemical engineering, aerospace and building materials. Nevertheless, the utilization of flammable epoxy resins has posed a huge threat to lives and properties, which restricted their applications. In this work, manganese-based cuprous oxides two-dimensional nanosheets (Mn@Cu
Publisher: MDPI AG
Date: 02-06-2023
DOI: 10.20944/PREPRINTS202306.0115.V1
Abstract: To date, zinc ion batteries (ZIBs) have been attracting extensive attention due to their outstanding properties and the potential to be the solution for next-generation energy storage systems. However, the uncontrollable growth of zinc dendrites and water-splitting issues seriously restrict the further scalable application. Over the past few years, solid polymer electrolytes (SPEs) have been regarded as a promising alternative to address these challenges and facilitate the practical advancement of zinc batteries. In this review, we revisited the research progress of SPEs applied in zinc batteries in the past few years and focus on introducing cutting-edge polymer science and technologies that can be utilized to prepare advanced SPEs for high-performance zinc batteries. The operating mechanism of SPEs and the functions of polymers will be summarized. To highlight the polymer functions, SPEs are categorized into three types, respectively, homogenous polymer SPEs, hybrids polymer SPEs, and nanocomposites SPEs, which are expected to reveal the roles and principles of various polymers in zinc batteries. This review presents the current research progress and fundamental mechanisms of polymer-based SPEs in zinc batteries, outlines the challenging issues encountered, and meanwhile proposes potential solutions for future endeavours.
Publisher: MDPI AG
Date: 27-06-2023
Abstract: To date, zinc-ion batteries (ZIBs) have been attracting extensive attention due to their outstanding properties and the potential to be the solution for next-generation energy storage systems. However, the uncontrollable growth of zinc dendrites and water-splitting issues seriously restrict their further scalable application. Over the past few years, solid polymer electrolytes (SPEs) have been regarded as a promising alternative to address these challenges and facilitate the practical advancement of zinc batteries. In this review, we revisit the research progress of SPEs applied in zinc batteries in the past few years and focus on introducing cutting-edge polymer science and technologies that can be utilised to prepare advanced SPEs for high-performance zinc batteries. The operating mechanism of SPEs and the functions of polymers are summarised. To highlight the polymer’s functions, SPEs are categorised into three types, homogenous polymer SPEs, hybrids polymer SPEs, and nanocomposites SPEs, which are expected to reveal the roles and principles of various polymers in zinc batteries. This review presents the current research progress and fundamental mechanisms of polymer-based SPEs in zinc batteries, outlines the challenging issues encountered, and proposes potential solutions for future endeavours.
Publisher: American Chemical Society (ACS)
Date: 30-05-2017
Publisher: MDPI AG
Date: 08-11-2022
Abstract: A novel and hierarchical hybrid composite (MnO2@CHS@SA@Ni) was synthesized utilizing manganese dioxide (MnO2) nanosheets as the core structure, self-assembly chitosan (CHS), sodium alginate (SA) and nickel species (Ni) as surface layers, and it was further incorporated into an epoxy matrix for achieving fire hazard suppression via surface self-assembly technology. Herein, the resultant hybrid epoxy composite possessed an exceptional nano-barrier and synergistic charring effect to aid the formation of a compact layered structure that enhanced its fire-resistive effectiveness. As a result, the addition of only 2 wt% MnO2@CHS@SA@Ni hybrids led to a dramatic reduction in the peak heat release rate and total heat release values (by ca. 33% and 27.8%) of the epoxy matrix. Notably, the peak smoke production rate and total smoke production values of EP/MnO2@CHS@SA@Ni 2% were decreased by ca. 16.9 and 38.4% compared to the corresponding data of pristine EP. This was accompanied by the suppression of toxic CO, NO release and the diffusion of thermal pyrolysis gases during combustion through TG-IR results. Overall, a significant fire-testing outcome of the proposed hierarchical structure was proven to be effective for epoxy composites in terms of flammability, smoke and toxicity reductions, optimizing their prospects in other polymeric materials in the respective fields.
Publisher: Elsevier BV
Date: 2016
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C5RA06170A
Abstract: Fire resistant coatings, composed of nanosized carbon black (CB) and polyurethane acrylate (PUA), were synthesized through a facile and low-cost method to improve the fire safety and thermal stability of flexible polyurethane foam (FPU).
Publisher: MDPI AG
Date: 16-06-2023
DOI: 10.3390/MI14061260
Abstract: Micro-cooling systems are compact refrigeration systems widely applicable in microchemical analysis, biomedicine, and microelectromechanical systems (MEMS). These systems rely on the use of micro-ejectors to achieve precise, fast, and reliable flow and temperature control. However, the efficiency of micro-cooling systems is hindered by spontaneous condensation occurring downstream of the nozzle throat and within the nozzle itself, impacting the performance of the micro-ejector. A micro-scale ejector mathematical model describing wet steam flow was simulated to investigate the steam condensation phenomenon and its influence on flow, incorporating equations for liquid phase mass fraction and droplet number density transfer. The simulation results of wet vapor flow and ideal gas flow were compared and analyzed. The findings revealed that the pressure at the micro-nozzle outlet exceeded predictions based on the ideal gas assumption, while the velocity fell below it. These discrepancies indicated that condensation of the working fluid reduces the pumping capacity and the efficiency of the micro-cooling system. Furthermore, simulations explored the impact of inlet pressure and temperature conditions on spontaneous condensation within the nozzle. The results demonstrated that the properties of the working fluid directly influence transonic flow condensation, underscoring the importance of selecting appropriate working fluid parameters for nozzle design to ensure nozzle stability and optimal micro-ejector operation.
Publisher: Elsevier BV
Date: 10-2023
Publisher: Elsevier BV
Date: 2015
DOI: 10.1016/J.CARBPOL.2014.08.084
Abstract: The self-extinguishing coating, consisting of biobased chitin derivatives, phosphorylated chitin and deacetylated chitin (chitosan), was deposited on cotton fabrics via the Layer-by-Layer (LbL) assembled method. The content of phosphorylated chitin prepared on cotton fabrics surface is dependent on the bilayers' number and concentration of phosphorylated chitin. In the vertical flame test, the cotton fabric with 20 bilayers prepared at the high phosphorylated chitin concentration (2 wt%) could extinguish the flame. Microcombustion calorimetry result showed that all coated cotton fabrics showed lower peak heat-release rate and total heat-release values compared with that of the pure one. Thermogravimetric analysis result indicated that thermal and thermal oxidation stability of all coated cotton fabrics were enhanced in the high temperature range (400-700°C). This work provided the flame retardant multilayer films based on fully biobased chitin derivatives on cotton fabrics to enhance its flame retardancy.
Publisher: Elsevier BV
Date: 08-2021
Publisher: Royal Society of Chemistry (RSC)
Date: 2016
DOI: 10.1039/C6RA24264B
Abstract: During the combustion of TPU, the release of HCN was inhibited after the incorporation of mesoporous NiCo 2 O 4 particles.
Publisher: MDPI AG
Date: 02-2019
Abstract: Manganese dioxide (MnO2), as a promising green material, has recently attracted considerable attention of researchers from various fields. In this work, a facile method was introduced to prepare binary hybrids by fabricating three-dimensional (3D) zinc hydroxystannate (ZHS) cubes on two-dimensional (2D) MnO2 nanosheets towards excellent flame retardancy and toxic effluent elimination of epoxy (EP) resin. Microstructural analysis confirmed that the morphologies and structures of MnO2@ZHS binary hybrids were well characterized, implying the successful synthesis. Additionally, the morphological characterization indicated that MnO2@ZHS binary hybrids could achieve satisfactory interfacial interaction with the EP matrix and be well dispersed in nanocomposites. Cone calorimeter test suggested that MnO2@ZHS binary hybrids effectively suppressed the peak of heat release rate and total heat release of EP nanocomposites, performing better than MnO2 or ZHS alone. Condensed-phase analysis revealed that MnO2@ZHS binary hybrids could promote the char density and graphitization degree of char residues and thereby successfully retard the permeation of oxygen and flammable gases. Moreover, through the analysis of gas phase, it can be concluded that MnO2@ZHS binary hybrids could efficiently suppress the production of toxic gases during the degradation of EP nanocomposites. This work implies that the construction of 2D/3D binary hybrids with an interfacial interaction is an effective way to fabricate high-performance flame retardants for EP.
Publisher: Elsevier BV
Date: 10-2022
Publisher: Royal Society of Chemistry (RSC)
Date: 2016
DOI: 10.1039/C6RA05213D
Abstract: Montmorillonite and titanate nanotube based coatings have been prepared through LbL self-assembly method, in order to enhance the thermal and thermal-oxidative stability, flame retardancy and UV protection of polyethylene terephthalate fabric.
Publisher: MDPI AG
Date: 08-07-2022
Abstract: The increasing popularity of lithium-ion battery systems, particularly in electric vehicles and energy storage systems, has gained broad research interest regarding performance optimization, thermal stability, and fire safety. To enhance the battery thermal management system, a comprehensive investigation of the thermal behaviour and heat exchange process of battery systems is paramount. In this paper, a three-dimensional electro-thermal model coupled with fluid dynamics module was developed to comprehensively analyze the temperature distribution of battery packs and the heat carried away. The computational fluid dynamics (CFD) simulation results of the lumped battery model were validated and verified by considering natural ventilation speed and ambient temperature. In the artificial neural networks (ANN) model, the multilayer perceptron was applied to train the numerical outputs and optimal design of the battery setup, achieving a 1.9% decrease in maximum temperature and a 4.5% drop in temperature difference. The simulation results provide a practical compromise in optimizing the battery configuration and cooling efficiency, balancing the layout of the battery system, and safety performance. The present modelling framework demonstrates an innovative approach to utilizing high-fidelity electro-thermal/CFD numerical inputs for ANN optimization, potentially enhancing the state-of-art thermal management and reducing the risks of thermal runaway and fire outbreaks.
Publisher: Elsevier BV
Date: 2020
DOI: 10.1016/J.JHAZMAT.2019.121028
Abstract: The extensive utilization of rigid polyurethane foam (RPUF) as construction insulation material has brought two main troubles to our society: fire risks and toxic hazards. To reduce the fire hazards of RPUF, a layered MoS
Publisher: American Chemical Society (ACS)
Date: 22-03-2019
Abstract: Owing to its mechanical performance, thermal stability, and size effects, single or few-layer black phosphorus (BP) has the potential to prepare the polymer nanocomposites as a candidate of nanoadditives, similar to graphene. The step to realize the scalable exfoliation of single or few-layer BP nanosheets is crucial to BP applications. Herein, we utilized a facile, green, and scalable electrochemical strategy for generating cobaltous phytate-functionalized BP nanosheets (BP-EC-Exf) wherein the BP crystal served as the cathode and phytic acid served as a modifier and an electrolyte simultaneously. Moreover, high-performance polyurethane acrylate/BP-EC-Exf (PUA/BP-EC) nanocomposites are easily prepared by a convenient UV-curable strategy for the first time. Significantly, the conclusion of introducing BP-EC-Exf into the PUA matrix resulted in enhancement in mechanical properties of PUA in terms of the tensile strength (increased by 59.8%) and tensile fracture strain (increased by 88.1%), in the distinct improvement in flame retardancy of PUA in terms of the decreased peak heat release rate (reduced by 44.5%) and total heat release (decreased by 34.5%), and in lower intensities of pyrolysis products including toxic CO. Moreover, it was confirmed by X-ray diffraction and Raman spectra that the air stability of PUA/BP-EC nanocomposites was maintained after exposure to environmental conditions for 4 months. The air-stable BP nanosheets, which were wrapped and embedded in the PUA matrix, can achieve the isolation and protection effect. This modified electrochemical method toward the simultaneous exfoliation and functionalization of BP nanosheets provides an efficient approach for fabricating BP-polymer-based nanocomposites.
Publisher: American Chemical Society (ACS)
Date: 30-01-2017
Publisher: Elsevier BV
Date: 12-2016
Publisher: Elsevier BV
Date: 10-2017
Publisher: Elsevier BV
Date: 06-2023
Publisher: Public Library of Science (PLoS)
Date: 17-05-2018
Publisher: Elsevier BV
Date: 11-2021
Publisher: American Chemical Society (ACS)
Date: 30-05-2019
Publisher: Elsevier BV
Date: 06-2019
Publisher: MDPI AG
Date: 2020
Abstract: Epoxy resin (EP) has widespread applications in thermosetting materials with great versatility and desirable properties such as high electrical resistivity and satisfactory mechanical properties. At present, 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) is widely applied to EP matrix for high flame resistance. Nevertheless, EP/DOPO composites acquire highly toxic decomposition products and smoke particles produced during combustion due to the gaseous fire-inhibition mechanism, which will be a major problem. To address this concern, an effective hyper-branched aluminum phosphonate (AHPP) was rationally designed and then coupled with DOPO into EP matrix to fabricate the fire-safe epoxy resin composites. On the basis of the results, significant increment in limiting oxygen index value (an achievement of 32% from 23.5% for pristine EP) and reduction in peak heat release rate and total heat release (59.4% and 45.6%) with the DOPO/AHPP ratio of 2:1 were recorded. During the cone calorimeter test, both the smoke production and total CO yield of EP-4 composite with the DOPO/AHPP ratio of 1:2 were dramatically decreased by 42.7% and 53.6%, which was mainly associated with the excellent catalytic carbonization of AHPP submicro-particles for EP composite. Future applications of submicro-scaled flame-retardant with various phosphorus oxidation states will have good prospects for development.
Publisher: Elsevier BV
Date: 11-2015
Publisher: Royal Society of Chemistry (RSC)
Date: 2016
DOI: 10.1039/C6RA17108G
Abstract: Inherent flame retardation has the advantage that it will allow polymers to impart the flame retardancy permanently, and the introduction of a few weight percent of the flame retardant unit can lead to improvements in the overall flame retardancy.
Publisher: Elsevier BV
Date: 12-2020
Publisher: Royal Society of Chemistry (RSC)
Date: 2016
DOI: 10.1039/C6RA15522G
Abstract: Flame retardant multilayer films based on graphene materials were deposited on the surface of flexible polyurethane (FPU) foam by an advanced layer by layer assembly method (hybrid bilayer approach) in an effort to reduce its flammability.
Publisher: Springer Science and Business Media LLC
Date: 11-01-2015
Publisher: Oxford University Press (OUP)
Date: 05-2016
DOI: 10.1093/JSCR/RJW068
Publisher: Elsevier BV
Date: 02-2021
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C5RA09553K
Abstract: In the present work, magnesium hydroxide were successfully deposited on the surface of flexible polyurethane foam to suppress its flammability and smoke production.
Publisher: Elsevier BV
Date: 09-2022
DOI: 10.1016/J.JCIS.2022.04.101
Abstract: A novel linear polymeric charring agent (PEPAPC) was synthesized via the nucleophilic substitution reaction, and then embedded into polypropylene (PP) substrate to improve the fire retardancy and anti-dripping performance. Unfortunately, the opposite polarity between intumescent flame retardant (IFR) and polymer-matrix could seriously deteriorate the interfacial compatibility, harmful to the flame-retardant efficiency and smoke toxicity suppression of PP/IFR composites. For the foregoing reasons, flame retardant PP/IFR/Organo-montmorillonite (OMMT) nanocomposites with the combination of maleic anhydride-grafted PP as compatibilizer have been prepared via melt intercalation technique. When 2 wt% well-dispersed OMMT were incorporated, it showed a significant reduction in peak heat release rate and total heat release (90.5 and 62.7%) compared with pristine PP, and an achievement in limiting oxygen index value of 32% from 18.5% for pristine PP, which can be attributed to the nano-barrier and catalytic carbonization effect of well-dispersed OMMT within the polymer-matrix. More importantly, the well-dispersed OMMT displays significant smoke toxicity suppression, toughening and strengthening effect on PP/IFR system. The peak CO release and total smoke production for PP-6 were decreased by 89.8 and 64.7%, respectively. This work may provide an effective approach towards fabricating high-performance polymeric materials on organic/inorganic hybrid nanocomposites with homogenous dispersion, thereby effectively reducing the fire hazard risk.
Publisher: Elsevier BV
Date: 07-2022
Publisher: Elsevier BV
Date: 2023
Publisher: Elsevier BV
Date: 07-2019
Publisher: No publisher found
Date: 2016
DOI: 10.1039/C6RA21804K
Publisher: Elsevier BV
Date: 09-2019
Publisher: Royal Society of Chemistry (RSC)
Date: 2019
DOI: 10.1039/C8TA11795K
Abstract: A freeze-drying method is firstly used to prepare a flexible and robust HAPs/PVA separator for stable, safe and sustainable Li metal batteries.
Publisher: Elsevier BV
Date: 04-2018
Publisher: Wiley
Date: 05-02-2023
Abstract: Lithium metal batteries (LMBs) attract considerable attention for their incomparable energy density. However, safety issues caused by uncontrollable lithium dendrites and highly flammable electrolyte limit large‐scale LMBs applications. Herein, a low‐cost, thermally stable, and low environmentally‐sensitive lithium nitrate (LiNO 3 ) is proposed as the only lithium salt to incorporate with nonflammable triethyl phosphate and fluoroethylene carbonate (FEC) co‐solvent as the electrolyte anticipated to enhance the performance of LMBs. Benefiting from the presence of NO 3 − and FEC with strong solvation effect and easily reduced ability, a Li 3 N–LiF‐rich stable solid electrolyte interphase is constructed. Compared to commercial electrolytes, the proposed electrolyte has a high Coulombic efficiency of 98.31% in Li‐Cu test at 1 mA cm −2 of 1.0 mAh cm −2 with dendrite‐free morphology. Additionally, the electrolyte system shows high voltage stability and cathode electrolyte interphase film‐forming properties with stable cycling performances, which exhibit outstanding capacity retention rates of 96.39% and 83.74% after 1000 cycles for LFP//Li and NCM811//Li, respectively. Importantly, the non‐flammable electrolyte delays the onset of combustion in lithium metal soft pack batteries by 255 s and reduces the peak heat release by 21.02% under the continuous external high‐temperature heating condition. The novel electrolyte can contribute immensely to developing high‐electrochemical‐performance and high‐safety LMBs.
Publisher: Elsevier BV
Date: 11-2019
Publisher: CRC Press
Date: 20-06-2023
Publisher: Elsevier BV
Date: 06-2017
DOI: 10.1016/J.CARBPOL.2017.02.084
Abstract: Green polyelectrolytes including chitosan (CS), phytic acid (PA) and oxidized sodium alginate (OSA) were deposited on polyamide 66 (PA66) fabrics in a quadralayer (QL) fashion like (CS-PA-CS-OSA)
Publisher: Elsevier BV
Date: 02-2016
Publisher: MDPI AG
Date: 04-11-2022
Abstract: With the increasing demand for energy capacity and power density in battery systems, the thermal safety of lithium-ion batteries has become a major challenge for the upcoming decade. The heat transfer during the battery thermal runaway provides insight into thermal propagation. A better understanding of the heat exchange process improves a safer design and enhances battery thermal management performance. This work proposes a three-dimensional thermal model for the battery pack simulation by applying an in-house model to study the internal battery thermal propagation effect under the computational fluid dynamics (CFD) simulation framework. The simulation results were validated with the experimental data. The detailed temperature distribution and heat transfer behaviour were simulated and analyzed. The thermal behaviour and cooling performance were compared by changing the abnormal heat generation locations inside the battery pack. The results indicated that various abnormal heat locations disperse heat to the surrounding coolant and other cells. According to the current battery pack setups, the maximum temperature of Row 2 cases can be increased by 2.93%, and the temperature difference was also increased. Overall, a new analytical approach has been demonstrated to investigate several stipulating battery thermal propagation scenarios for enhancing battery thermal performances.
Publisher: Elsevier BV
Date: 05-2020
Publisher: Elsevier BV
Date: 04-2019
Publisher: Elsevier BV
Date: 08-2017
DOI: 10.1016/J.CARBPOL.2017.04.065
Abstract: Bio-based and phosphorus-free coating was fabricated by layer-by-layer assembly method to obtain the flame retardant cotton fabric. For the first time, the modified cotton fabrics were prepared by utilizing positively charged polyethylenimine and negatively charged alginate together with subsequent crosslinking of barium, nickel and cobalt ions. Scanning electron microscopy and energy-dispersive X-ray demonstrated that the metal ions crosslinked coating was successfully constructed on the substrate. The thermal stability and flame retardancy were investigated by thermogravimetric analysis (TGA) and horizontal flame tests. TGA results showed that the degradation of the coated cotton fabrics were retarded at high temperature and the char residue of the cotton fabrics were improved after covered with the barium, nickel and cobalt ions crosslinked coatings. Furthermore, the fire resistance of cotton-Ba s le was enhanced significantly compared with the untreated s le, as evidenced by the obvious reduction (28%) of flame spread rate and complete char residue. Finally, the washing durability of coating on the fabric was enhanced after metal ions crosslinked with alginate based coating.
Publisher: Elsevier BV
Date: 08-2022
Publisher: Elsevier BV
Date: 04-2023
Publisher: American Chemical Society (ACS)
Date: 08-09-2014
DOI: 10.1021/IE502215P
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C5RA19414H
Abstract: A layered double hydroxide-based fire-blocking coating was deposited on the surface of a flexible polyurethane foam using a layer-by-layer method to improve its thermal stability, flame retardancy and smoke suppression properties.
Publisher: American Chemical Society (ACS)
Date: 30-10-2015
Publisher: MDPI AG
Date: 29-06-2023
DOI: 10.3390/MOLECULES28135100
Abstract: The effect of varying the weight percentage composition (wt.%) of low-cost expandable graphite (EG), ammonium polyphosphate (APP), fibreglass (FG), and vermiculite (VMT) in polyurethane (PU) polymer was studied using a traditional intumescent flame retardant (IFR) system. The synergistic effect between EG, APP, FG, and VMT on the flame retardant properties of the PU composites was investigated using SEM, TGA, tensile strength tests, and cone calorimetry. The IFR that contained PU composites with 40 wt.% EG displayed superior flame retardant performance compared with the composites containing only 20 w.t.% or 10 w.t.% EG. The peak heat release rate, total smoke release, and carbon dioxide production from the 40 wt.% EG s le along with APP, FG, and VMT in the PU composite were 88%, 93%, and 92% less than the PU control s le, respectively. As a result, the synergistic effect was greatly influenced by the compactness of the united protective layer. The PU composite suppressed smoke emission and inhibited air penetrating the composite, thus reducing reactions with the gas volatiles of the material. SEM images and TGA results provided positive evidence for the combustion tests. Further, the mechanical properties of PU composites were also investigated. As expected, compared with control PU, the addition of flame-retardant additives decreased the tensile strength, but this was ameliorated with the addition of FG. These new PU composite materials provide a promising strategy for producing polymer composites with flame retardation and smoke suppression for construction materials.
Publisher: Elsevier BV
Date: 10-2017
DOI: 10.1016/J.JHAZMAT.2017.06.068
Abstract: Zinc hydroxystannate (ZHS) was fabricated on the surface of amorphous hydrous TiO
Publisher: Elsevier BV
Date: 04-2017
Publisher: American Chemical Society (ACS)
Date: 10-10-2016
Publisher: Elsevier BV
Date: 2022
Publisher: Elsevier BV
Date: 04-2018
Start Date: 01-2023
End Date: 01-2026
Amount: $436,554.00
Funder: Australian Research Council
View Funded Activity