ORCID Profile
0000-0003-1173-6825
Current Organisation
University of Wollongong
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Publisher: American Chemical Society (ACS)
Date: 31-07-2019
Abstract: Electronic spectra of mass-selected HC
Publisher: AIP Publishing
Date: 22-08-2017
DOI: 10.1063/1.4990572
Abstract: The B̃
Publisher: American Chemical Society (ACS)
Date: 23-01-2020
Publisher: American Chemical Society (ACS)
Date: 02-03-2020
Publisher: AIP Publishing
Date: 13-07-2023
DOI: 10.1063/5.0152570
Abstract: Electronic transitions are observed for the O2+–Ar and O2+–N2 complexes over the 225–350 nm range. The transitions are not associated with recognized electronic band systems of the respective atomic and diatomic constituents (Ar+, Ar, O2+, O2, N2+, and N2) but rather are due to charge transfer transitions. Onsets of the O2+–Ar and O2+–N2 band systems occur at 3.68 and 3.62 eV, respectively, corresponding to the difference in the ionization potentials of Ar and O2 (3.69 eV), and N2 and of O2 (3.51 eV), suggesting the band systems arise from intramolecular charge transfer transitions to states correlating with O2(X3Σg−) + Ar+ (2Pu) and O2(X3Σg−) + N2+(X2Σg+) limits, respectively. The dominant vibronic progressions have ωe values of 1565 cm−1 for O2+–Ar and 1532 cm−1 for O2+–N2, reasonably close to the value for the neutral O2 molecule in its X3Σg− state (1580 cm−1). Higher energy band systems for O2+–Ar and O2+–N2 are assigned to transitions to states correlating with the O2 (a1Δg) + Ar+ (2Pu) and O2 (a1Δg) + N2+(X2Σg+) limits, respectively.
Publisher: AIP Publishing
Date: 25-01-2017
DOI: 10.1063/1.4974338
Abstract: The electronic spectrum of the methyl propargyl cation (2-butyn-1-yl cation, H
No related grants have been discovered for Giel Muller.