ORCID Profile
0000-0002-3191-8944
Current Organisation
University of Sydney
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Publisher: Wiley
Date: 27-03-2019
Abstract: The reaction of 4,4',4'',4'''-(ethene-1,1,2,2-tetrayl)tetraaniline with 2-pyridinecarboxaldehyde and iron(II) chloride resulted, after aqueous workup, in the diastereoselective formation of an [Fe
Publisher: Royal Society of Chemistry (RSC)
Date: 2020
DOI: 10.1039/D0OB00036A
Abstract: The effects of substitution, ring size and cyclisation on the p K a values of imidazolinium salts, higher homologues and formamidinium salts in DMSO are quantified, considering structural and electronic motifs along with crystallographic analyses.
Publisher: Informa UK Limited
Date: 15-10-2015
Publisher: Elsevier BV
Date: 03-2019
Publisher: American Chemical Society (ACS)
Date: 23-01-2019
DOI: 10.1021/ACS.INORGCHEM.8B03457
Abstract: A family of five easily prepared tridentate monoanionic 2,5-dipyridyl-3-(R
Publisher: Royal Society of Chemistry (RSC)
Date: 2021
DOI: 10.1039/D1NJ00388G
Abstract: Using a hydrazone exchange methodology, resin beads were functionalised with [2]rotaxanes at up to 80% efficiency—higher than using other dynamic or irreversible synthetic approaches to form self-assembled structures on solid supports.
Publisher: Royal Society of Chemistry (RSC)
Date: 2021
DOI: 10.1039/D1CC01583D
Abstract: An interconverting system of self-assembled [Fe 2 L 3 ] 4+ triple helicates and [Fe 4 L 6 ] 8+ tetrahedral cages is reported. The rates of interconversion between these two assemblies were measured allowing for a mechanism of interconversion to be proposed.
Publisher: American Chemical Society (ACS)
Date: 30-11-2016
DOI: 10.1021/ACS.INORGCHEM.6B02007
Abstract: A series of enantiopure ruthenium(II) polypyridyl complexes are reported that feature pendant pyridyl groups suitable for building larger self-assembled structures. The complexes are characterized in detail in solution using NMR spectroscopy, cyclic voltammetry, and photophysical methods and in the solid state using single-crystal X-ray crystallography. The complexes are luminescent, displaying long excited-state lifetimes that are quenched when the pendant pyridyl groups are protonated. Reaction with cadmium(II) ions results in the formation of a mixed-metal one-dimensional coordination polymer, which was characterized by single-crystal X-ray crystallography.
Publisher: American Chemical Society (ACS)
Date: 03-07-2018
DOI: 10.1021/ACS.INORGCHEM.8B01157
Abstract: We have designed linear metalloligands which contain a central photoactive [Ru(N
Publisher: American Chemical Society (ACS)
Date: 24-06-2020
Publisher: Wiley
Date: 11-10-2018
DOI: 10.1002/JRS.5501
Publisher: Royal Society of Chemistry (RSC)
Date: 2018
DOI: 10.1039/C8SC03218A
Abstract: Surprisingly small structural changes in Donor–Acceptor Stenhouse Adducts (DASAs) result in predictable, robust and effective photochromic switches.
Publisher: Informa UK Limited
Date: 19-06-2016
Publisher: Elsevier BV
Date: 12-2015
DOI: 10.1016/J.BIORTECH.2015.08.056
Abstract: Aqueous solutions of tetrabutylphosphonium hydroxide have been evaluated as pretreatment media for rice husks, prior to sulphuric acid hydrolysis or cellulase enzymatic hydrolysis. Varying the water:tetrabutylphosphonium hydroxide ratio varied the rate of delignification, as well as silica, lignin and cellulose solubility. Pre-treatment with 60wt% hydroxide dissolved the rice husk and the regenerated material was thus heavily disrupted. Sulphuric acid hydrolysis of 60wt%-treated s les yielded the highest amount of glucose per gram of rice husk. Solutions with good lignin and silica solubility but only moderate to negligible cellulose solubility (10-40wt% hydroxide) were equally effective as pre-treatment media for both acid and enzymatic hydrolysis. However, pre-treatment with 60wt% hydroxide solutions was incompatible with downstream enzymatic hydrolysis. This was due to significant incorporation of phosphonium species in the regenerated biomass, which significantly inhibited the activity of the cellulase enzymes.
Publisher: Royal Society of Chemistry (RSC)
Date: 2020
DOI: 10.1039/D0CC05115B
Abstract: Thinking outside the (blue)box: electron transfer mass spectrometry as a dual-purpose synthetic and analytical tool for supramolecular complexes.
Start Date: 2021
End Date: 2023
Funder: Irish Research Council
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