ORCID Profile
0000-0002-7885-938X
Current Organisation
National Taiwan University
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Nanoscale characterisation | Materials engineering | Metals and alloy materials | Numerical modelling and mechanical characterisation |
Publisher: Elsevier BV
Date: 06-2018
Publisher: Wiley
Date: 20-09-2021
Abstract: Recently, novel high‐entropy alloys (HEAs) of Al–Co–Cr–Fe–Ni–Ti systems containing face‐centered cubic (FCC) matrix and γ′ precipitates (L1 2 phase) have been studied. They show superior mechanical properties at room (298 K) and cryogenic temperatures (77 K). Herein, microstructure deformation and fracture after tensile strain are investigated. The results show that multiple‐layered stacking faults occur after the tensile test at 77 K, which can increase the yield strength and ultimate tensile strength by 20% and 24%, respectively. The γ′ precipitates become disordered after the alloy deforms at 77 K, which decreases the formation barrier of mechanical twinning and increases ductility at 77 K by 27%.
Publisher: Elsevier BV
Date: 08-2021
Publisher: Elsevier BV
Date: 06-2015
Publisher: Trans Tech Publications, Ltd.
Date: 15-11-2016
DOI: 10.4028/WWW.SCIENTIFIC.NET/MSF.879.2401
Abstract: Processing bulk nanoscrystalline materials for structural applications still poses a significant challenge, particularly in achieving an industrially viable process. In this context, recent work has proved that complex nanoscale steel structures can be formed by solid reaction at low temperatures. These nanocrystalline bainitic steels present the highest strength ever recorded, unprecedented ductility, fatigue on par with commercial bearing steels and exceptional rolling-sliding wear performances. A description of the characteristics and significance of these remarkable structures in the context of the atomic mechanism of transformation is provided.
Publisher: Elsevier BV
Date: 07-2020
Publisher: Elsevier BV
Date: 04-2015
Publisher: Informa UK Limited
Date: 04-2010
Publisher: Springer Science and Business Media LLC
Date: 2019
Publisher: Elsevier BV
Date: 03-2020
Publisher: Elsevier BV
Date: 09-2021
Publisher: Elsevier BV
Date: 08-2021
Publisher: AIP Publishing
Date: 13-01-2014
DOI: 10.1063/1.4861846
Abstract: We report the atomic-scale observation of parallel development of super elasticity and reversible dislocation-based plasticity from an early stage of bending deformation until fracture in GaAs nanowires. While this phenomenon is in sharp contrast to the textbook knowledge, it is expected to occur widely in nanostructures. This work indicates that the super recoverable deformation in nanomaterials is not simple elastic or reversible plastic deformation in nature, but the coupling of both.
Publisher: Oxford University Press (OUP)
Date: 29-07-2014
DOI: 10.1017/S1431927614012872
Abstract: Atom probe is a powerful technique for studying the composition of nano-precipitates, but their morphology within the reconstructed data is distorted due to the so-called local magnification effect. A new technique has been developed to mitigate this limitation by characterizing the distribution of the surrounding matrix atoms, rather than those contained within the nano-precipitates themselves. A comprehensive chemical analysis enables further information on size and chemistry to be obtained. The method enables new insight into the morphology and chemistry of niobium carbonitride nano-precipitates within ferrite for a series of Nb-microalloyed ultra-thin cast strip steels. The results are supported by complementary high-resolution transmission electron microscopy.
Publisher: Elsevier BV
Date: 06-2020
Publisher: Elsevier BV
Date: 09-2017
Publisher: Elsevier BV
Date: 04-2022
Publisher: Elsevier BV
Date: 05-2022
Publisher: Elsevier BV
Date: 08-2017
Publisher: World Scientific Pub Co Pte Lt
Date: 02-2008
DOI: 10.1142/S0218625X08011202
Abstract: The nanostructure of p-type AlGaN / GaN strained-layer superlattice (SLS) cladding in a GaN -based violet laser diode (LD) has been investigated by high-angle annular dark-field (HAADF) scanning-transmission electron microscopy (STEM). The pairs of the AlGaN and GaN layers in SLS cladding are observed, where the AlGaN and GaN layers appear as dark and bright bands. It is also found that the threading dislocations disappeared within the SLS this evidence manifests the role of SLS in suppressing threading dislocation propagation.
Publisher: Elsevier BV
Date: 2019
Publisher: Elsevier BV
Date: 10-2021
Publisher: Elsevier BV
Date: 11-2020
Publisher: Springer Science and Business Media LLC
Date: 05-09-2020
DOI: 10.1007/S11661-020-05947-2
Abstract: This is a viewpoint paper on recent progress in the understanding of the microstructure–property relations of advanced high-strength steels (AHSS). These alloys constitute a class of high-strength, formable steels that are designed mainly as sheet products for the transportation sector. AHSS have often very complex and hierarchical microstructures consisting of ferrite, austenite, bainite, or martensite matrix or of duplex or even multiphase mixtures of these constituents, sometimes enriched with precipitates. This complexity makes it challenging to establish reliable and mechanism-based microstructure–property relationships. A number of excellent studies already exist about the different types of AHSS (such as dual-phase steels, complex phase steels, transformation-induced plasticity steels, twinning-induced plasticity steels, bainitic steels, quenching and partitioning steels, press hardening steels, etc .) and several overviews appeared in which their engineering features related to mechanical properties and forming were discussed. This article reviews recent progress in the understanding of microstructures and alloy design in this field, placing particular attention on the deformation and strain hardening mechanisms of Mn-containing steels that utilize complex dislocation substructures, nanoscale precipitation patterns, deformation-driven transformation, and twinning effects. Recent developments on microalloyed nanoprecipitation hardened and press hardening steels are also reviewed. Besides providing a critical discussion of their microstructures and properties, vital features such as their resistance to hydrogen embrittlement and damage formation are also evaluated. We also present latest progress in advanced characterization and modeling techniques applied to AHSS. Finally, emerging topics such as machine learning, through-process simulation, and additive manufacturing of AHSS are discussed. The aim of this viewpoint is to identify similarities in the deformation and damage mechanisms among these various types of advanced steels and to use these observations for their further development and maturation.
Publisher: Elsevier BV
Date: 12-2019
Publisher: Elsevier BV
Date: 10-2012
Publisher: Elsevier BV
Date: 09-2022
Publisher: Elsevier BV
Date: 03-2022
Publisher: Elsevier BV
Date: 08-2019
Publisher: Elsevier BV
Date: 03-2023
Publisher: The Electrochemical Society
Date: 05-05-2020
Publisher: Wiley
Date: 13-05-2019
Publisher: Wiley
Date: 21-12-2022
Abstract: Most of the reported 2D Ruddlesden–Popper (RP) lead halide perovskites with the general formula of A n +1 B n X 3 n +1 ( n = 1, 2, …) comprise layered perovskites separated by A‐site‐substituted organic spacers. To date, only a small number of X‐site‐substituted RP perovskites have been reported. Herein, the first inorganic‐cation pseudohalide 2D phase perovskite single crystal, Cs 2 Pb(SCN) 2 Br 2 , is reported. It is synthesized by the antisolvent vapor‐assisted crystallization (AVC) method at room temperature. It exhibits a standard single‐layer ( n = 1) Ruddlesden–Popper structure described in space group of Pmmn (#59) and has a small separation ( d = 1.69 Å) between the perovskite layers. The SCN − anions are found to bend the 2D Pb(SCN) 2 Br 2 framework slightly into a kite‐shaped octahedron, limiting the formation of a quasi‐2D perovskite structure ( n 1). This 2D single crystal exhibits a reversible first‐order phase transformation to 3D CsPbBr 3 ( Pm 3 m #221) at 450 K. It has a low exciton binding energy of 160 meV—one of the lowest for 2D perovskites ( n = 1). A Cs 2 Pb(SCN) 2 Br 2 ‐single‐crystal photodetector is demonstrated with respectable responsivity of 8.46 mA W −1 and detectivity of ≈1.2 × 10 10 Jones at a low bias voltage of 0.5 V.
Publisher: American Association for the Advancement of Science (AAAS)
Date: 08-09-2017
Abstract: Many industrial applications require materials to have high strength while remaining pliable, or ductile. However, the microstructure that increases strength tends to reduce ductility. He et al. used a processing mechanism to create a “forest” of line defects in manganese steel. This deformed and partitioned steel was produced by cold-rolling and low-temperature annealing and contained a dislocation network that improved both strength and ductility. Science , this issue p. 1029
Publisher: Elsevier BV
Date: 05-2021
Publisher: Trans Tech Publications, Ltd.
Date: 07-2013
DOI: 10.4028/WWW.SCIENTIFIC.NET/MSF.762.95
Abstract: In this work, the investigation of transmission electron microscopy has elucidated the morphologies of the interphase precipitated carbides in an experimental Ti-Mo-bearing steel into three types: (1) planar interphase precipitation with regular sheet spacing (designated as PIP), (2) curved interphase precipitation with regular sheet spacing (designated as Regular CIP), and (3) curved interphase precipitation with irregular sheet spacing (designated as Irregular CIP). The planar sheets of carbides have also been analyzed and found to be oriented close to ferrite planes {211}, {210} and {111} the results of transmission electron microscopy provide strong evidence to suggest that the development of interphase-precipitated carbides can be associated with the growth of incoherent ferrite/austenite interface by the ledge mechanism. The sheet spacing and inter-carbide spacing in the sheet have been measured and estimated in this work. The sheet spacing is found to be finer than the inter-carbide spacing in the sheet for all s les investigated. The result reflects that the distribution of interphase-precipitated carbides is anisotropic and cannot be considered random distribution. The relevance of the Orowan mechanism to the non-random distribution of interphase-precipitated carbides has been considered. The contribution of the dispersion of interphase-precipitated carbides to the yield strength of the steel studied has been estimated. It is revealed that an optimum component about 400 MPa contributed by interphase-precipitated carbides can be achieved, and the finding is consistent with the hardness data. Other ex les of the different alloy steels are also addressed.
Publisher: Elsevier BV
Date: 2009
Publisher: Elsevier BV
Date: 11-2020
Publisher: Informa UK Limited
Date: 03-2013
Publisher: Elsevier BV
Date: 11-2017
Publisher: Elsevier BV
Date: 2021
Publisher: Elsevier BV
Date: 2020
DOI: 10.2139/SSRN.3759133
Publisher: AIP Publishing
Date: 05-2017
DOI: 10.1063/1.4983708
Publisher: MDPI AG
Date: 06-07-2017
DOI: 10.3390/MET7070253
Publisher: Trans Tech Publications, Ltd.
Date: 2010
DOI: 10.4028/WWW.SCIENTIFIC.NET/AMR.89-91.663
Abstract: The ferrite phase strengthened by the highly dense nanometer-sized carbides is named super ferrite. The effects of Ti, Ti-Mo, and Ti-Nb micro-alloy additions on the precipitation strengthening in three experimental high-strength low-alloy steels have been investigated by using transmission electron microscopy and micro-hardness measurement. The objective of this work was to study the carbide precipitation under the conditions of isothermal transformation. It was found that interphase precipitation of nano-sized carbide in Steel Ti-Mo had very strong contribution to the hardness of the steel. The distribution of interphase precipitated carbides is associated with both the sheet spacing and the inter-particle spacing, which have been studied. The result implies that (Ti, Mo)C particles possess an excellent effect on precipitation hardening.
Publisher: Elsevier BV
Date: 03-2022
Publisher: Trans Tech Publications, Ltd.
Date: 11-2016
DOI: 10.4028/WWW.SCIENTIFIC.NET/MSF.880.29
Abstract: The demand for new materials that provide excellent structural performance while reducing weight and being cost-effectively manufactured is increasing. For applications with high strength requirements, ultra-high strength steels (UHSS) have been widely used. However, with such a high strength level, UHSS are very sensitive to the hydrogen that could be ease by the tempering process. In this research, the correlation of hydrogen and tempering process on commercial UHSS 15B30 has been studied. Results show that the tensile strength (TS) of as-quenched 15B30 is about 1900MPa. After tempering treatment of the quenched 15B30, the TS decreases from 1600MPa to 1200MPa with tempering temperature increased from 200°C to 400°C. The 15B30 specimens, being subjected to hydrogen charge, exhibit the dramatic reduction of mechanical strengths.
Publisher: Elsevier BV
Date: 09-2012
Publisher: Elsevier BV
Date: 02-2017
Publisher: Informa UK Limited
Date: 21-10-2019
Publisher: Elsevier BV
Date: 02-2017
Publisher: Elsevier BV
Date: 2021
Publisher: Elsevier BV
Date: 05-2010
Publisher: Elsevier BV
Date: 09-2020
Publisher: Elsevier BV
Date: 03-2010
Publisher: Elsevier BV
Date: 09-2015
Publisher: Elsevier BV
Date: 05-2010
Publisher: Elsevier BV
Date: 09-2011
Publisher: American Physical Society (APS)
Date: 25-09-2017
Publisher: Informa UK Limited
Date: 14-04-2014
Publisher: Elsevier BV
Date: 11-2019
Publisher: Elsevier BV
Date: 06-2018
Publisher: Elsevier BV
Date: 05-2018
Publisher: Elsevier BV
Date: 05-2021
Publisher: Research Square Platform LLC
Date: 14-02-2022
DOI: 10.21203/RS.3.RS-1325909/V1
Abstract: Hydrogen embrittlement in steel gas infrastructure is a serious challenge for the use of hydrogen energy for global decarbonization. Steel gas pipelines contain a significant fraction of pearlite, which consists of lamellar cementite in ferrite. How exactly hydrogen affects deformation and failure in this structure, and hence the role that pearlite plays in embrittlement, is not well understood. Here we have studied the behavior of hydrogen around the cementite–ferrite interface, the defining microstructural feature in pearlite. Our micromechanical testing results show softening in the ferrite adjacent to the interface, consistent with hydrogen-enhanced local plasticity, rather than interfacial weakening. Atom probe tomography (APT) observations of hydrogen at the interface show no evidence of trapping at the cementite–ferrite interface, instead hydrogen trapping in pearlite occurs in the cementite bulk. Density functional theory calculations, accounting for the configuration of the lattice defects and local interfacial misfits, are consistent with the experimental observations. These findings explain how hydrogen leads to degradation in pearlite. This information is critical for the development of next-generation pipeline materials that can better withstand hydrogen embrittlement.
Publisher: Elsevier BV
Date: 02-2022
Publisher: Elsevier BV
Date: 06-2013
Publisher: Elsevier BV
Date: 05-2020
Publisher: AIP Publishing
Date: 28-12-2020
DOI: 10.1063/5.0037588
Abstract: UVC light-emitting diodes (LEDs, λ = 275 nm) with different types of contact layers and sapphire substrates were demonstrated on high-quality AlN templates. For LEDs on flat sapphire substrates (FSSs), replacing the absorbing p-GaN contact with p-AlGaN short-period superlattices (p-SPSLs) strongly enhanced the emission along the substrate normal. The integrated external quantum efficiency (EQE) increased from 2.4% to 3.9% under I = 350 mA. For LEDs with a p-SPSL contact, replacing the FSS with nano-patterned sapphire substrates slightly deteriorated the quality of epitaxy, but the overall EQE is still enhanced to 4.4% under I & 350 mA without lens encapsulation. According to the far-field intensity measurement, the light extraction is better improved along the high emission angle to the substrate normal. The interplay among substrates, dipole polarization, and EQE enhancement factors was further analyzed and discussed in the context.
Publisher: Frontiers Media SA
Date: 14-01-2021
DOI: 10.3389/FMATS.2020.611390
Abstract: This work investigated hydrogen trapping and hydrogen embrittlement (HE) in two press-hardened steels, 22MnB5 for 1,500 MPa grade and 34MnB5V for 2000 MPa grade, respectively. Superior to the 22MnB5 steel, the newly developed 34MnB5V steel has an ultimate tensile strength of over 2000 MPa without sacrificing ductility due to the formation of vanadium carbides (VCs). Simulated press hardening was applied to two steels, and hydrogen was induced by cathodic charging. Susceptibility to HE was validated by slow strain-rate tensile test. When hydrogen content was high, the 34MnB5V steel fractured in elastic regime. However, when hydrogen content was 0.8–1.0 ppmw, the 34MnB5V steel bore much higher stress than the 22MnB5 steel before fracture. The behavior of hydrogen trapping was investigated by thermal desorption analyses. Although the two steels trapped similar amounts of hydrogen after cathodic charging, their trapping mechanisms and effective trapping sites were different. In summary, a finer prior austenite grain size due to the pinning effect of VCs can also improve the toughness of 34MnB5V steel. Moreover, trapping hydrogen by grain boundary suppresses the occurrence of hydrogen-enhanced local plasticity. Microstructural refinement enhanced by VCs improves the resistance to HE in 34MnB5V steel. Importantly, the correlation between hydrogen trapping by VCs and improvement of HE is not significant. Hence, this work presents the challenge in designing irreversible trapping sites in future press-hardened steels.
Publisher: Elsevier BV
Date: 03-2022
Publisher: Trans Tech Publications, Ltd.
Date: 06-2201
DOI: 10.4028/WWW.SCIENTIFIC.NET/SSP.172-174.67
Abstract: An Fe-1.0C-17Cr (wt.%) stainless steel was subjected to subzero treatment to investigated the structure of martensite midrib. The midrib region appeared in the thin plate and lenticular martensites have been observed detailed by TEM. The TEM result reveals that the transformations of thin plate martensite and lenticular martensite are initiated at the same midrib region. The former keeps the lattice-invariant deformation mode of twinning during subsequent growth, whereas the latter combines both twinning and slip modes. Midrib region is a preferential position for carbide precipitations after tempering. M 3 C and M 23 C 6 carbide were found in this alloy, and related to the ferrite by Bagaryatsky OR and K-S OR, respectively.
Publisher: Elsevier BV
Date: 02-2014
Publisher: Elsevier BV
Date: 06-2012
Publisher: Elsevier BV
Date: 04-2020
Publisher: American Physical Society (APS)
Date: 13-10-2017
Publisher: Elsevier BV
Date: 09-2009
Publisher: Springer Science and Business Media LLC
Date: 19-02-2018
DOI: 10.1038/S41598-018-21712-3
Abstract: [Pd/Fe] 2 multilayers were deposited on a flat MgO(001) to study the effect of hydrogen on magnetic interlayer coupling. Complex magnetic hysteresis behavior, including single, double, and triple loops, were measured as a function of the azimuthal angle in a longitudinal and transverse direction. With a combination of a 2-fold magnetic anisotropy energy (MAE) in the bottom-Fe and a 4-fold MAE in the top-Fe, the complex magnetic hysteresis behavior could be clearly explained. Two well-split hysteresis loops with almost zero Kerr remanence were measured by choosing a suitable Pd thickness and applying the magnetic field perpendicular to the easy axis of the bottom-Fe. The split double loops originated from the 90°-rotation of the top-Fe moment. On exposure to a hydrogen gas atmosphere, the separation of the two minor loops increased, indicating that Pd-hydride formation enhanced the ferromagnetic coupling between the two Fe layers. Based on these observations, we proposed that, by applying a suitable constant magnetic field, the top-Fe moment could undergo reversible 90°-rotation following hydrogen exposure. The results suggest that the Pd space layer used for mediating the magnetic interlayer coupling is sensitive to hydrogen, and therefore, the multilayer system can function as a giant magnetoresistance-type sensor suitable for hydrogen gas.
Publisher: Elsevier BV
Date: 2019
DOI: 10.2139/SSRN.3358845
Publisher: Trans Tech Publications Ltd.
Date: 15-03-2007
Publisher: Elsevier BV
Date: 12-2022
Publisher: Elsevier BV
Date: 03-2015
Publisher: Elsevier BV
Date: 2015
Publisher: Springer Science and Business Media LLC
Date: 13-08-2015
Publisher: Elsevier BV
Date: 03-2022
Publisher: Elsevier BV
Date: 11-2014
Publisher: Springer Science and Business Media LLC
Date: 28-08-2023
DOI: 10.1038/S41529-023-00392-Z
Abstract: We investigated the unique passive behaviour of Hybrid steel in de-aerated sulfuric acid and aqueous sodium chloride solutions through corrosion tests, surface analysis, and thermochemical modelling. Electrochemical measurements confirmed that Hybrid steel possesses stainless steel characteristics, including passivity, breakdown, and pitting, akin to low-alloyed stainless steel. Synchrotron hard X-ray photoelectron spectroscopy revealed a dynamically protective nanoscale passive film composed of Fe, Cr, Ni, and Al oxides, contributing to its stainless nature. The presence of Al and Ni enhances Cr’s role in forming a spontaneously passive and protective surface, resulting in exceptional corrosion resistance in acidic and chloride-containing solutions. Hybrid steel’s surface oxides remain robust even beyond the Cr(III)-to-Cr(VI) redox potential, distinguishing it from other stainless steels. This work demonstrates the potential for designing sustainable stainless steel with high-strength properties without requiring the conventional Cr threshold concentration of 10.5 per cent.
Publisher: Elsevier BV
Date: 2017
Publisher: American Chemical Society (ACS)
Date: 24-01-2020
Abstract: The spin-orbit torques (SOTs) generated from topological insulators (TIs) have gained increasing attention in recent years. These TIs, which are typically formed by epitaxially grown chalcogenides, possess extremely high SOT efficiencies and have great potential to be employed in next-generation spintronics devices. However, epitaxy of these chalcogenides is required to ensure the existence of the topologically protected surface state (TSS), which limits the feasibility of using these materials in industry. In this work, we show that nonepitaxial Bi
Publisher: Elsevier BV
Date: 04-2018
Publisher: American Physical Society (APS)
Date: 11-01-2018
Publisher: Elsevier BV
Date: 02-2017
Publisher: Elsevier BV
Date: 08-2014
Publisher: AIP Publishing
Date: 14-08-2017
DOI: 10.1063/1.4999767
Abstract: We investigated the origin of morphological instability in 2 μm thick Al0.6Ga0.4N/AlN heteroepitaxy. The primary morphology was driven by the residual epitaxial strain, forming hill-like morphologies via surface diffusion. The secondary morphology was driven by the interaction between the primary morphology and dislocation clusters in the epitaxial layers. The difference in the local growth rate yields volcano-like morphologies centering on deep pits. Insertion of multi-stack superlattice transition layers between AlGaN and GaN effectively suppressed the secondary morphologies by simultaneously pre-relaxing the template and filtering treading dislocations.
Publisher: MDPI AG
Date: 23-10-2020
Abstract: Based on the predicted phase diagram of super duplex stainless steel (DSS) calculated by Thermo-Calc, the maximum peak temperature 1100 °C was selected to ensure no σ phase existence. This target temperature fell into the two-phase solid solution (SS) region. A series of different thermal cycling tests were carried out with the notations of 2SS, 2SS + 3 cycles, 2SS + 7 cycles, 2SS + 13 cycles, and 2SS + 20 cycles. It was found that the trend of two-phase volume ratio variation by thermal cycling followed the predicted thermodynamic equilibrium trend. After 2SS + 7 cycles, the ratio of two-phase δ/γ tended toward the ideal 1:1. According to the electron backscatter diffraction (EBSD) analysis, the δ phase crystal orientation changed from the most frequent directions of and of the as-received s le to the most frequent orientation of after two SS treatments. While the γ phase grain always remained at orientation. The grain boundary misorientation angles of the γ grains were relatively stable, ranging from 53° to 63°, but those of the δ grains were widely distributed actively presuming the lattice rotation. The Kernel Average Misorientation (KAM) value of the local strain in face center cubic (fcc) γ grains was varied and greater than that of the body center cubic (bcc) δ phase, indicating that the former, with a large grain boundary misorientation had larger local deformation than the latter, which possesses wide random misorientation angle distribution.
Publisher: Elsevier BV
Date: 2019
DOI: 10.2139/SSRN.3406399
Publisher: Institute of Electrical and Electronics Engineers (IEEE)
Date: 02-2022
Publisher: Elsevier BV
Date: 09-2011
Publisher: Elsevier BV
Date: 07-2019
Publisher: Elsevier BV
Date: 10-2020
Publisher: Royal Society of Chemistry (RSC)
Date: 2014
DOI: 10.1039/C4NR00415A
Abstract: Advanced microscopy techniques and computational simulation to reveal the atomic-scale mechanisms for the highest ever recorded enhancement of supercurrent in MgB 2 -based superconductors.
Publisher: Elsevier BV
Date: 04-2007
Publisher: Springer Science and Business Media LLC
Date: 13-02-2019
Publisher: Elsevier BV
Date: 05-2020
Publisher: Elsevier BV
Date: 2015
Publisher: Elsevier BV
Date: 05-2022
Publisher: Elsevier BV
Date: 03-2022
Start Date: 03-2023
End Date: 03-2026
Amount: $530,000.00
Funder: Australian Research Council
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