ORCID Profile
0000-0002-5846-1905
Current Organisation
Johannes Gutenberg Universität Mainz
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Publisher: Wiley
Date: 09-10-2017
Abstract: Low-valent iron centers are critical intermediates in chemical and bio-chemical processes. Herein, we show the first ex le of a low-valent Fe
Publisher: American Chemical Society (ACS)
Date: 23-07-2003
DOI: 10.1021/JP035246F
Publisher: Wiley
Date: 03-07-2019
Abstract: The authors of the Communication "Stabilization of Low-Valent Iron(I) in a High-Valent Vanadium(V) Oxide Cluster" reply to a Comment by Dr. Sproules, who offered an alternative interpretation of the metal oxidation states in the two electron reduced iron vanadate (NH
Publisher: Wiley
Date: 14-07-2010
Publisher: Springer Science and Business Media LLC
Date: 03-2009
DOI: 10.1038/NCHEM.113
Abstract: We report the spontaneous and rapid growth of micrometre-scale tubes from crystals of a metal oxide-based inorganic solid when they are immersed in an aqueous solution containing a low concentration of an organic cation. A membrane immediately forms around the crystal, and this membrane then forms micrometre-scale tubes that grow with vast aspect ratios at controllable rates along the surface on which the crystal is placed. The tubes are composed of an amorphous mixture of polyoxometalate-based anions and organic cations. It is possible for liquid to flow through the tubes, and for the direction of growth and the overall tube diameter to be controlled. We demonstrate that tube growth is driven by osmotic pressure within the membrane sack around the crystal, which ruptures to release the pressure. These robust, self-growing, micrometre-scale tubes offer opportunities in many areas, including the growth of microfluidic devices and the self-assembly of metal oxide-based semipermeable membranes for erse applications.
Publisher: American Chemical Society (ACS)
Date: 12-01-2021
Publisher: American Chemical Society (ACS)
Date: 10-03-2009
DOI: 10.1021/JA809422K
Abstract: The framework materials [W(72)Mn(II/III)(12)O(268)X(7)](52-/40-) undergo heteroatom (X)-controlled reversible SC-SC redox reactions whereby the Ge-templated framework reduction is fast and reoxidation is slow. The opposite trend is set for the Si-templated framework, and these processes can be followed optically, spectroscopically and crystallographically.
Publisher: Wiley
Date: 20-08-2008
Publisher: Wiley
Date: 28-09-2007
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C4DT03763D
Abstract: The design, synthesis, and applications of polyoxometalate-conductive polymer (POM/CP) composites are critically discussed and future directions for their use in energy materials, sensors and supramolecular materials chemistry are envisioned.
Location: United Kingdom of Great Britain and Northern Ireland
Location: United Kingdom of Great Britain and Northern Ireland
No related grants have been discovered for Carsten Streb.