ORCID Profile
0000-0001-7510-0223
Current Organisation
Macquarie University
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In Research Link Australia (RLA), "Research Topics" refer to ANZSRC FOR and SEO codes. These topics are either sourced from ANZSRC FOR and SEO codes listed in researchers' related grants or generated by a large language model (LLM) based on their publications.
Geology | Igneous and Metamorphic Petrology | Mineralogy and Crystallography | Geochemistry | Inorganic Geochemistry | Isotope Geochemistry | Ore Deposit Petrology | Archaeological Science | Geodynamics | Tectonics
Expanding Knowledge in the Earth Sciences | Mineral Exploration not elsewhere classified | Mineral Resources (excl. Energy Resources) not elsewhere classified | Understanding Australia's Past |
Publisher: Elsevier BV
Date: 2013
Publisher: Elsevier BV
Date: 08-2006
Publisher: Informa UK Limited
Date: 03-10-2014
Publisher: Springer Science and Business Media LLC
Date: 09-08-2023
Publisher: Elsevier BV
Date: 1984
Publisher: Elsevier BV
Date: 06-2009
Publisher: Springer Science and Business Media LLC
Date: 1985
DOI: 10.1007/BF01082963
Publisher: Elsevier BV
Date: 11-2009
Publisher: American Geophysical Union (AGU)
Date: 10-04-1989
Publisher: MDPI AG
Date: 03-09-2021
DOI: 10.3390/GEOSCIENCES11090372
Abstract: Subduction of oceanic crust buries an average thickness of 300–500 m of sediment that eventually dehydrates or partially melts. Progressive release of fluid/melt metasomatizes the fore-arc mantle, forming serpentinite at low temperatures and phlogopite-bearing pyroxenite where slab surface reaches 700–900 °C. This is sufficiently high to partially melt subducted sediments before they approach the depths where arc magmas are formed. Here, we present experiments on reactions between melts of subducted sediments and peridotite at 2–6 GPa/750–1100 °C, which correspond to the surface of a subducting slab. The reaction of volatile-bearing partial melts derived from sediments with depleted peridotite leads to separation of elements and a layered arrangement of metasomatic phases, with layers consisting of orthopyroxene, mica-pyroxenite, and clinopyroxenite. The selective incorporation of elements in these metasomatic layers closely resembles chemical patterns found in K-rich magmas. Trace elements were imaged using LA-ICP-TOFMS, which is applied here to investigate the distribution of trace elements within the metasomatic layers. Experiments of different duration enabled estimates of the growth of the metasomatic front, which ranges from 1–5 m/ky. These experiments explain the low contents of high-field strength elements in arc magmas as being due to their loss during melting of sedimentary materials in the fore-arc.
Publisher: Copernicus GmbH
Date: 24-05-2012
Abstract: Abstract. The oxidation of SO2 to sulfate on sea salt aerosols in the marine environment is highly important because of its effect on the size distribution of sulfate and the potential for new particle nucleation from H2SO4 (g). However, models of the sulfur cycle are not currently able to account for the complex relationship between particle size, alkalinity, oxidation pathway and rate – which is critical as SO2 oxidation by O3 and Cl catalysis are limited by aerosol alkalinity, whereas oxidation by hypohalous acids and transition metal ions can continue at low pH once alkalinity is titrated. We have measured 34S/32S fractionation factors for SO2 oxidation in sea salt, pure water and NaOCl aerosol, as well as the pH dependency of fractionation. Oxidation of SO2 by NaOCl aerosol was extremely efficient, with a reactive uptake coefficient of ≈0.5, and produced sulfate that was enriched in 32S with αOCl = 0.9882±0.0036 at 19 °C. Oxidation on sea salt aerosol was much less efficient than on NaOCl aerosol, suggesting alkalinity was already exhausted on the short timescale of the experiments. Measurements at pH = 2.1 and 7.2 were used to calculate fractionation factors for each step from SO2(g) → multiple steps → SOOCl2−. Oxidation on sea salt aerosol resulted in a lower fractionation factor than expected for oxidation of SO32− by O3 (αseasalt = 1.0124±0.0017 at 19 °C). Comparison of the lower fractionation during oxidation on sea salt aerosol to the fractionation factor for high pH oxidation shows HOCl contributed 29% of S(IV) oxidation on sea salt in the short experimental timescale, highlighting the potential importance of hypohalous acids in the marine environment. The sulfur isotope fractionation factors measured in this study allow differentiation between the alkalinity-limited pathways – oxidation by O3 and by Cl catalysis (α34 = 1.0163±0.0018 at 19 °C in pure water or 1.0199±0.0024 at pH = 7.2) – which favour the heavy isotope, and the alkalinity non-limited pathways – oxidation by transition metal catalysis (α34 = 0.9905±0.0031 at 19 °C, Harris et al., 2012a) and by hypohalites (α34 = 0.9882±0.0036 at 19 °C) – which favour the light isotope. In combination with field measurements of the oxygen and sulfur isotopic composition of SO2 and sulfate, the fractionation factors presented in this paper may be capable of constraining the relative importance of different oxidation pathways in the marine boundary layer.
Publisher: AIP Publishing
Date: 05-2023
DOI: 10.1063/5.0129417
Abstract: The accurate and precise determination of the compositions of silicate glasses formed from melts containing volatile components H2O and CO2 recovered from high-pressure, high-temperature experiments is essential to our understanding of geodynamic processes taking place within the planet. Silicate melts are often difficult to analyze chemically because the formation of quench crystals and overgrowths on silicate phases is rapid and widespread upon quenching of experiments, preventing the formation of glasses in low-SiO2 and volatile-rich compositions. Here, we present experiments conducted in a novel rapid quench piston cylinder apparatus on a series of partially molten low-silica alkaline rock compositions (l roite, basanite, and calk-alkaline basalt) with a range of water contents between 3.5 and 10 wt %. Quench modification of the volatile-bearing silicate glasses is significantly reduced compared to those produced in older piston cylinder apparatuses. The recovered glasses are almost completely free of quench modification and facilitate the determination of precise chemical compositions. We illustrate significantly improved quench textures and provide an analytical protocol that recovers accurate chemical compositions from both poorly quenched and well-quenched silicate glasses.
Publisher: Copernicus GmbH
Date: 04-06-2012
Abstract: Abstract. Mineral dust is a major fraction of global atmospheric aerosol, and the oxidation of SO2 on mineral dust has implications for cloud formation, climate and the sulfur cycle. Stable sulfur isotopes can be used to understand the different oxidation processes occurring on mineral dust. This study presents measurements of the 34S/32S fractionation factor α34 for oxidation of SO2 on mineral dust surfaces and in the aqueous phase in mineral dust leachate. Sahara dust, which accounts for ~60% of global dust emissions and loading, was used for the experiments. The fractionation factor for aqueous oxidation in dust leachate is αleachate = 0.9917±0.0046, which is in agreement with previous measurements of aqueous SO2 oxidation by iron solutions. This fractionation factor is representative of a radical chain reaction oxidation pathway initiated by transition metal ions. Oxidation on the dust surface at subsaturated relative humidity (RH) had an overall fractionation factor of αhet = 1.0096±0.0036 and was found to be almost an order of magnitude faster when the dust was simultaneously exposed to ozone, light and RH of ~40%. However, the presence of ozone, light and humidity did not influence isotope fractionation during oxidation on dust surfaces at subsaturated relative humidity. All the investigated reactions showed mass-dependent fractionation of 33S relative to 34S. A positive matrix factorization model was used to investigate surface oxidation on the different components of dust. Ilmenite, rutile and iron oxide were found to be the most reactive components, accounting for 85% of sulfate production with a fractionation factor of α34 = 1.012±0.010. This overlaps within the analytical uncertainty with the fractionation of other major atmospheric oxidation pathways such as the oxidation of SO2 by H2O2 and O3 in the aqueous phase and OH in the gas phase. Clay minerals accounted for roughly 12% of the sulfate production, and oxidation on clay minerals resulted in a very distinct fractionation factor of α34 = 1.085±0.013. The fractionation factors measured in this study will be particularly useful in combination with field and modelling studies to understand the role of surface oxidation on clay minerals and aqueous oxidation by mineral dust and its leachate in global and regional sulfur cycles.
Publisher: Springer Science and Business Media LLC
Date: 2003
DOI: 10.1038/NATURE01319
Publisher: Oxford University Press (OUP)
Date: 03-04-2007
Publisher: Oxford University Press (OUP)
Date: 19-03-2012
Publisher: Springer Science and Business Media LLC
Date: 1994
DOI: 10.1007/BF00286840
Publisher: Springer Science and Business Media LLC
Date: 28-11-2022
DOI: 10.1038/S43247-022-00630-3
Abstract: The thick mantle lithosphere beneath cratons consists of strongly reduced rocks that have reacted with oxidized melts. These low-silica, incipient melts are rich in CO 2 and H 2 O and react with surrounding rocks forming an enriched zone at the base of the lithosphere, which is the source region for many diamonds. Here, we reproduce these reactions in novel experiments in which oxidised, hydrous carbonate-rich melts are reacted with reduced, depleted peridotite at 5 GPa pressure. Results explain several key features of the mantle s le in kimberlites as products of a single process, namely the formation of diamonds, phlogopite and alkali- hibole bearing rocks, iron-rich dunites, and garnets and clinopyroxenes with pyroxenitic compositions. Initially, redox freezing occurs where melts meet the reduced peridotite, depositing diamonds and associated garnet and clinopyroxenes. The spreading reaction front leaves behind Fe-rich dunite, and crystallizing phlogopite and hibole when the melt solidifies at the reaction front.
Publisher: Elsevier BV
Date: 09-2004
Publisher: Elsevier BV
Date: 06-2016
Publisher: Oxford University Press (OUP)
Date: 07-01-2009
Publisher: Elsevier BV
Date: 06-2015
Publisher: Oxford University Press (OUP)
Date: 03-11-2010
Publisher: Geological Society of America
Date: 11-04-2017
DOI: 10.1130/G39077Y.1
Publisher: Elsevier BV
Date: 2014
Publisher: Elsevier BV
Date: 09-1999
Publisher: Springer Science and Business Media LLC
Date: 13-11-2017
Publisher: American Association for the Advancement of Science (AAAS)
Date: 24-04-2020
Abstract: Diamond-bearing kimberlites were born from similar melts in the deep Earth and variably modified during ascent.
Publisher: Springer Science and Business Media LLC
Date: 28-08-2009
Publisher: Elsevier BV
Date: 07-2008
Publisher: Elsevier BV
Date: 11-1994
Publisher: Elsevier BV
Date: 09-2017
Publisher: Geological Society of America
Date: 2008
Publisher: Mineralogical Society
Date: 07-2013
Publisher: Springer Science and Business Media LLC
Date: 23-01-2018
Publisher: Springer Science and Business Media LLC
Date: 03-07-2018
Publisher: MDPI AG
Date: 18-10-2021
DOI: 10.3390/GEOSCIENCES11100432
Abstract: Dynamic metasomatism experiments were performed by reacting a l roite melt with garnet peridotite by drawing melt through the peridotite into a vitreous carbon melt trap, ensuring the flow of melt through the peridotite and facilitating analysis of the melt. Pressure (2–3 GPa) and temperature (1050–1125 °C) conditions were chosen where the l roite was molten but the peridotite was not. Phlogopite was formed and garnet and orthopyroxene reacted out, resulting in phlogopite wehrlite (2 GPa) and phlogopite harzburgite (3 GPa). Phlogopites in the peridotite have higher Mg/(Mg + Fe) and Cr2O3 and lower TiO2 than in the l roite due to buffering by peridotite minerals, with Cr2O3 from the elimination of garnet. Compositional trends in phlogopites in the peridotite are similar to those in natural garnet peridotite xenoliths in kimberlites. Changes in melt composition resulting from the reaction show decreased TiO2 and increased Cr2O3 and Mg/(Mg + Fe). The loss of phlogopite components during migration through the peridotite results in low K2O/Na2O and K/Al in melts, indicating that chemical characteristics of l roites are lost through reaction with peridotite so that emerging melts would be less extreme in composition. This indicates that l roites are unlikely to be derived from a source rich in peridotite, and more likely originate in a source dominated by phlogopite-rich hydrous pyroxenites. Phlogopites from an experiment in which l roite and peridotite were intimately mixed before the experiment did not produce the same phlogopite compositions, showing that care must be taken in the design of reaction experiments.
Publisher: Elsevier BV
Date: 2024
Publisher: MDPI AG
Date: 31-12-2019
DOI: 10.3390/MIN10010041
Abstract: The generation of strongly potassic melts in the mantle requires the presence of phlogopite in the melting assemblage, while isotopic and trace element analyses of ultrapotassic rocks frequently indicate the involvement of subducted crustal lithologies in the source. However, phlogopite-free experiments that focus on melting of sedimentary rocks and subsequent hybridization with mantle rocks at pressures of 1–3 GPa have not successfully produced melts with K2O wt%–6 wt%, while ultrapotassic igneous rocks reach up to 12 wt% K2O. Accordingly, a two-stage process that enriches K2O and increases K/Na in intermediary assemblages in the source prior to ultrapotassic magmatism seems likely. Here, we simulate this two-stage formation of ultrapotassic magmas using an experimental approach that involves re-melting of parts of an experimental product in a second experiment. In the first stage, reaction experiments containing layered sediment and dunite produced a modally metasomatized reaction zone at the border of a depleted peridotite. For the second-stage experiment, the metasomatized dunite was separated from the residue of the sedimentary rock and transferred to a smaller capsule, and melts were produced with 8 wt%–8.5 wt% K2O and K/Na of 6–7. This is the first time that extremely K-enriched ultrapotassic melts have been generated experimentally from sediments at low pressure applicable to a post-collisional setting.
Publisher: American Geophysical Union (AGU)
Date: 24-02-2023
DOI: 10.1029/2022JB025135
Abstract: The high flux of subaerial volcanic CO 2 emissions around the circum‐Mediterranean region requires the involvement of an unusually carbon‐rich reservoir, but the origin of which is still unclear. Here, we aim to resolve this problem by analyzing Mg and Zn isotopes for the widely distributed mafic potassic to ultrapotassic lavas in this region. These K‐rich lavas have lower δ 26 Mg but similar δ 66 Zn compared to mid‐ocean ridge basalts (MORB). No known magmatic processes can explain the isotopic data, which must therefore be characteristics of the mantle sources. Recycled carbonate sediments are capable of explaining the low δ 26 Mg, but they typically also have high δ 66 Zn. Thus, the low δ 26 Mg but unfractionated δ 66 Zn of these K‐rich lavas define “Mg‐Zn isotopic decoupling” which has not yet been observed for other types of mantle‐derived lavas. The carbonate‐bearing silicate sediments analyzed here possess low δ 26 Mg and MORB‐like δ 66 Zn, which can account for the Mg‐Zn isotopic decoupling. Therefore, the nature of recycled materials (carbonates vs. carbonate‐bearing silicate sediments) in the mantle can be distinguished by the coupling or decoupling of Mg and Zn isotopes of mantle‐derived magmas. The input flux of carbon from the sediments to the lithospheric mantle is estimated to be ∼8.1 Mt/yr, and ∼22.4 Mt/yr of CO 2 emissions are predicted, which fit well with the observed output flux of 20.1 ± 13.4 Mt/yr. Our results demonstrate that recycled crustal carbon stored in the lithospheric mantle is an important source for the extensive subaerial volcanic CO 2 emissions in the circum‐Mediterranean region.
Publisher: Copernicus GmbH
Date: 28-04-2014
Abstract: Abstract. In-cloud production of sulfate modifies aerosol size distribution, with important implications for the magnitude of indirect and direct aerosol cooling and the impact of SO2 emissions on the environment. We investigate which sulfate sources dominate the in-cloud addition of sulfate to different particle classes as an air parcel passes through an orographic cloud. Sulfate aerosol, SO2 and H2SO4 were collected upwind, in-cloud and downwind of an orographic cloud for three cloud measurement events during the Hill Cap Cloud Thuringia c aign in autumn 2010 (HCCT-2010). Combined SEM and NanoSIMS analysis of single particles allowed the δ34S of particulate sulfate to be resolved for particle size and type. The most important in-cloud SO2 oxidation pathway at HCCT-2010 was aqueous oxidation catalysed by transition metal ions (TMI catalysis), which was shown with single particle isotope analyses to occur primarily in cloud droplets nucleated on coarse mineral dust. In contrast, direct uptake of H2SO4 (g) and ultrafine particulate were the most important sources modifying fine mineral dust, increasing its hygroscopicity and facilitating activation. Sulfate addition to "mixed" particles (secondary organic and inorganic aerosol) and coated soot was dominated by in-cloud aqueous SO2 oxidation by H2O2 and direct uptake of H2SO4 (g) and ultrafine particle sulfate, depending on particle size mode and time of day. These results provide new insight into in-cloud sulfate production mechanisms, and show the importance of single particle measurements and models to accurately assess the environmental effects of cloud processing.
Publisher: Cambridge University Press (CUP)
Date: 1989
DOI: 10.1017/S0016756800006129
Abstract: Alkaline and ultramafic l rophyre dykes at Aillik Bay on the coast of central Labrador exhibit features indicative of volatile-rich conditions at the time of emplacement. Aillikites (ultramafic l rophyres) are flanked by closely spaced fracture systems whose formation was promoted by a carbonate-rich fluid moving ahead of the intruding magma. Sannaites (alkaline l rophyres) frequently have horned termination structures which are interpreted to be partial reconnections between dyke segments which had separated at an earlier stage of intrusion. The l rophyre dykes comprise three sets which are interpreted as cone sheets and radial dykes related to an intrusive centre located beneath the Labrador Sea to the northeast of the coastal exposures. This complex is one of several on the margins of the Labrador Sea, and its position may be influenced by the Archean/Aphebian boundary and by a major oceanic structural feature represented by offsets in seafloor magnetic anomalies.
Publisher: Mineralogical Society
Date: 07-2013
Publisher: Elsevier BV
Date: 11-1992
Publisher: Elsevier BV
Date: 08-2007
Publisher: Elsevier BV
Date: 06-2010
Publisher: Elsevier BV
Date: 03-2000
Publisher: Elsevier BV
Date: 08-2007
Publisher: Elsevier BV
Date: 08-2007
Publisher: Research Square Platform LLC
Date: 28-02-2023
DOI: 10.21203/RS.3.RS-2610331/V1
Abstract: We present results from high-pressure, high-temperature experiments that generate incipient carbonate melts at mantle conditions (~90km depth and temperatures between 900 - 1050℃). We show that these melts can effectively sequester sulfur, in its oxidised form of sulfate, platinum group elements, and first-row transition metals from mantle lithologies of peridotite and pyroxenite. These primitive oxidised melts may be effective agents to dissolve, redistribute and concentrate sulfur as well as chalcophile metals within the mantle, and from the mantle to shallower regions within the Earth, where localised dynamic physio-chemical processes can lead to ore genesis at various crustal depths. It is proposed that these carbonate-sulfur rich melts may be more widespread than previously thought, and may play a first order role in the metallogenic enhancement of localised and predictable lithospheric domains.
Publisher: Research Square Platform LLC
Date: 28-08-2023
DOI: 10.21203/RS.3.RS-2610331/V2
Abstract: We present results from high-pressure, high-temperature experiments that generate incipient carbonate melts at mantle conditions (~ 90 km depth and temperatures between 900–1050°C). We show that these primitive carbonate melts can sequester sulfur in its oxidized form of sulfate, as well as base and precious metals from mantle lithologies of peridotite and pyroxenite. It is proposed that these carbonate-sulfur-rich melts may be more widespread than previously thought, and that they may play a first order role in the metallogenic enhancement of localized lithospheric domains. They act as effective agents to dissolve, redistribute and concentrate metals within discrete domains of the mantle and into shallower regions within the Earth, where dynamic physico-chemical processes can lead to ore genesis at various crustal depths. Green metals could be transported and concentrated into ores by their interaction with low temperature carbonate rich melts.
Publisher: Elsevier BV
Date: 07-1990
Publisher: Elsevier BV
Date: 06-2004
Publisher: Elsevier BV
Date: 09-2011
Publisher: MDPI AG
Date: 10-09-2019
DOI: 10.3390/MIN9090546
Abstract: Eastern Australia contains a widespread suite of primitive (MgO ≥ 7.5 wt.%) intraplate basaltic provinces, including those sited along the longest continental hotspot track on Earth (≈2000 km), the Cosgrove track. The Buckland volcanic province is the most southerly basaltic province on the Cosgrove track before a km stretch that contains only sparse leucitite volcanism. Buckland is also situated just northeast of the edge of thick cratonic lithosphere where it transitions to a thinner continental lithosphere ( km) to the east, which may influence the production of plume-derived melts. Here, analysis of minor and trace elements in olivines in alkali basalts and basanites from the Buckland Province are combined with whole-rock compositions to elucidate the mantle source assemblages, and to calibrate minor and trace element indicators in olivine for application to source mineralogy. Olivine xenocrysts show element concentration ranges typical for peridotites Mn and Al concentrations indicate that the ambient mantle is spinel, rather than garnet, peridotite. High modal pyroxene content is indicated by high Ni, Zn/Fe, and Fe/Mn in olivines, while high Ti/Sc is consistent with hibole in the source. Residual phlogopite in the source of the basanites is indicated by low K/Nb in whole rocks, while apatite contains high P2O5 and low Rb/Sr (≥0.015) and Sr/La (≥13). The basanite source assemblage probably contains apatite, phlogopite, olivine, clinopyroxene and orthopyroxene, whereas the alkali basalt source assemblage is probably hibole, olivine, orthopyroxene and clinopyroxene ± phlogopite ± apatite. Both source assemblages correspond broadly to olivine websterite, with the basanite source lying deeper than that for alkali basalt, explaining the occurrence of phlogopite in the source. This mineralogy, along with whole-rock Ti/Eu, Zr/Hf and P2O5/TiO2 values approaching those of natural carbonatites, provide evidence showing that the Buckland source consists of a peridotite that has interacted with a carbonate-rich melt whose origin may be in the deep lithosphere or asthenosphere beneath the craton. Similar enrichment processes are probably common throughout eastern Australia, controlling trace element characteristics in basaltic provinces. The topography of the underside of the lithosphere may play a significant role in determining mantle source assemblages by erting and concentrating melt flow, and thus influence the location of basaltic provinces.
Publisher: Elsevier BV
Date: 1993
Publisher: Elsevier BV
Date: 11-1992
Publisher: Elsevier BV
Date: 11-2013
Publisher: Elsevier BV
Date: 04-2008
Publisher: Elsevier BV
Date: 10-2012
Publisher: Mineralogical Society
Date: 08-2004
Abstract: Tertiary ultrapotassic volcanic rocks from Serbia occasionally display low levels of K 2 O and K 2 O/ Na 2 O. In these rocks, analcime regularly appears as pseudomorphs after pre-existing leucite microphenocrysts. The process ofleucite transformation in Serbian ultrapotassic rocks is very thorough: fresh leucite survives only in ugandites from the Koritnik lava flows as well as in rare inclusions in Cpx. This paper focuses on the impact of ‘analcimization’ on the mineralogy and geochemistry ofthe Serbian ultrapotassic rocks, using the s les where leucite survived as a monitor for the process. Analcimization has had a great impact on the geochemistry of the rocks, but affects only a restricted number of chemical parameters. These are the falsification of the original K 2 O/Na 2 O ratio, the decoupling oflarge-ion lithophile elements resulting in considerable depletion of Rb and K 2 O, but not ofBa, and sporadic, but extreme enrichment ofCs in some analcime-bearing s les (up to 900 ppm). Analcimization is also recognized by an increase in whole-rock δ 18 O values of ∼3% compared to fresh rocks, which correlates with the level of whole-rock hydration. Finally, the 87 Sr/ 86 Sr enrichment at nearly constant 143 Nd/ 144 Nd demonstrated by some rocks can also be explained by the analcimization ofleucite. For s les with variable 87 Sr/ 86 Sr from the same lava flow, 87 Sr/ 86 Sr values correlate with modal analcime abundance (ex-leucite), loss on ignition of whole-rock and whole-rock δ 18 O values. The extreme depletion in K and enrichment in Na, together with modification of other geochemical parameters, may have led to the misinterpretation of the origin and geodynamic affiliations of the Serbian ultrapotassic rocks, had the effects of analcimization not been taken into account.
Publisher: Elsevier
Date: 1999
Publisher: Elsevier BV
Date: 12-2010
Publisher: Elsevier BV
Date: 06-2010
Publisher: Geological Society of America
Date: 20-10-2016
DOI: 10.1130/G38365.1
Publisher: Elsevier BV
Date: 06-2010
Publisher: Elsevier BV
Date: 02-2013
Publisher: Springer Science and Business Media LLC
Date: 17-09-2011
Publisher: Springer Science and Business Media LLC
Date: 03-2002
Publisher: American Geophysical Union (AGU)
Date: 30-09-2022
DOI: 10.1029/2022EA002533
Abstract: The immense Tibetan Plateau is a masterpiece of the ongoing India–Asia collision. The timing of the collision is a critical parameter to reconstruct the plateau evolution, but has been not well understood yet. Here, we report a newly discovered Eocene (53.8 Ma) shoshonitic intrusion with the input of Indian continental material in the Yangbajing area of the Lhasa Terrane, south Tibet. The reverse 207 Pb/ 206 Pb zoning exhibited by feldspars, the linear isotopic arrays between whole‐rock 187 Os/ 188 Os and 1/ 188 Os, the in‐situ feldspar 208 Pb/ 204 Pb and 206 Pb/ 204 Pb values, and the in‐situ zircon ε Hf (t) values and δ 18 O values strongly demonstrate a binary interaction process for the generation of the Yangbajing shoshonitic intrusion. Our Os isotopes further illustrate that the interaction process was dominated by recycled crustal melt assimilating minor mantle melt. In addition, different isotopic systems consistently point to an end‐member represented by the underthrust crust slice of Indian continent, which indicates that the Indian lithosphere must have already subducted beneath the Lhasa Terrane at 53.8 Ma. This is also supported by the abrupt isotopic shift toward the enriched values and the composition variation toward the high potassium contents in the subsequent Tibetan magmatism, corresponding to an increasing involvement of the Indian continental crust into the upper plate magmatism. Therefore, the Yangbajing shoshonitic intrusion is one of the earliest known magmatic evidence for the onset of the India–Asia collision.
Publisher: Oxford University Press (OUP)
Date: 14-03-2006
Publisher: Elsevier BV
Date: 07-2008
Publisher: Elsevier BV
Date: 07-2004
Publisher: Authorea, Inc.
Date: 17-08-2023
DOI: 10.22541/ESSOAR.169230197.72316079/V1
Abstract: The Northern Tanzanian Divergence in the East Africa Rift is arguably the best place on Earth to study the controls on rifting of thick lithosphere. Here, where the East Africa Rift intersects the Tanzanian Craton and the Mozambique Belt, the relationships between volcanism, faulting, pre-existing structures and lithospheric thickness and composition can be observed. In this work, we carry out the first lithospheric-scale 3D magnetotelluric modelling of the Northern Tanzanian Divergence and combine the results with experimental electrical conductivity and petrology models to calculate mantle composition, which is also inferred in the craton from reanalysis of garnet xenocryst data. Our results show that metasomatic materials exist in the cratonic lithospheric mantle and the relatively undeveloped southern part of the rift zone. However, the lithospheric mantle of the Mozambique Belt and the more developed northern section of the rift is more resistive and does not contain metasomatic phases. Combined with geochemical data from erupted lavas, these results suggest that, in zones that have experienced voluminous Cenozoic magmatism, melting events have destroyed the metasomes and dehydrated the mantle. Since the presence of magma is a primary control of lithospheric strength, rifting may become limited as the lithospheric mantle becomes dehydrated and harder to melt.
Publisher: Oxford University Press (OUP)
Date: 20-05-2010
Publisher: American Association for the Advancement of Science (AAAS)
Date: 09-05-2013
Publisher: American Association for the Advancement of Science (AAAS)
Date: 16-07-2021
Abstract: Unusually high Th/La in K-rich orogenic rocks may indicate shallow blueschist-rich sources in accretionary settings.
Publisher: Elsevier BV
Date: 10-2018
Publisher: Elsevier BV
Date: 12-1993
Publisher: Elsevier BV
Date: 07-2006
Publisher: Elsevier BV
Date: 15-04-2007
Publisher: Elsevier BV
Date: 2012
Publisher: Elsevier BV
Date: 04-2008
Publisher: Elsevier BV
Date: 07-2004
Publisher: Oxford University Press (OUP)
Date: 1988
Publisher: Elsevier BV
Date: 10-2000
Publisher: Elsevier BV
Date: 08-2006
Publisher: Springer Science and Business Media LLC
Date: 31-07-2007
Publisher: Elsevier BV
Date: 02-1996
Publisher: Springer Science and Business Media LLC
Date: 03-1990
DOI: 10.1007/BF02871896
Publisher: Elsevier BV
Date: 03-2002
Publisher: Elsevier BV
Date: 09-1991
Publisher: Springer Science and Business Media LLC
Date: 23-06-2015
DOI: 10.1038/SREP11547
Abstract: Carbon in rocks and its rate of exchange with the exosphere is the least understood part of the carbon cycle. The amount of carbonate subducted as sediments and ocean crust is poorly known, but essential to mass balance the cycle. We describe carbonatite melt pockets in mantle peridotite xenoliths from Dalihu (northern China), which provide firsthand evidence for the recycling of carbonate sediments within the subduction system. These pockets retain the low trace element contents and δ 18 O SMOW = 21.1 ± 0.3 of argillaceous carbonate sediments, representing wholesale melting of carbonates instead of filtered recycling of carbon by redox freezing and melting. They also contain microscopic diamonds, partly transformed to graphite, indicating that depths km were reached, as well as a bizarre mixture of carbides and metal alloys indicative of extremely reducing conditions. Subducted carbonates form diapirs that move rapidly upwards through the mantle wedge, reacting with peridotite, assimilating silicate minerals and releasing CO 2 , thus promoting their rapid emplacement. The assimilation process produces very local disequilibrium and ergent redox conditions that result in carbides and metal alloys, which help to interpret other occurrences of rock exhumed from ultra-deep conditions.
Publisher: Elsevier
Date: 2018
Publisher: Oxford University Press (OUP)
Date: 18-03-2005
Publisher: American Geophysical Union (AGU)
Date: 10-2020
DOI: 10.1029/2020JB019910
Publisher: Schweizerbart
Date: 03-07-2014
Publisher: Elsevier BV
Date: 11-1992
Publisher: Springer Science and Business Media LLC
Date: 22-07-2021
DOI: 10.1038/S41467-021-24750-0
Abstract: Remobilization of sedimentary carbonate in subduction zones modulates arc volcanism emissions and thus Earth’s climate over geological timescales. Although limestones (or chalk) are thought to be the major carbon reservoir subducted to subarc depths, their fate is still unclear. Here we present high-pressure reaction experiments between impure limestone (7.4 wt.% clay) and dunite at 1.3–2.7 GPa to constrain the melting behaviour of subducted natural limestone in contact with peridotite. The results show that although clay impurities significantly depress the solidus of limestone, melting will not occur whilst limestones are still part of the subducting slab. Buoyancy calculations suggest that most of these limestones would form solid-state diapirs intruding into the mantle wedge, resulting in limited carbon flux to the deep mantle ( ~10 Mt C y −1 ). Less than 20% melting within the mantle wedge indicates that most limestones remain stable and are stored in subarc lithosphere, resulting in massive carbon storage in convergent margins considering their high carbon flux (~21.4 Mt C y −1 ). Assimilation and outgassing of these carbonates during arc magma ascent may dominate the carbon flux in volcanic arcs.
Publisher: Elsevier BV
Date: 04-2017
Publisher: Elsevier BV
Date: 08-2006
Publisher: Elsevier BV
Date: 09-1999
Publisher: Elsevier BV
Date: 12-2008
Publisher: Oxford University Press (OUP)
Date: 29-04-2005
Publisher: Elsevier BV
Date: 2011
Publisher: Informa UK Limited
Date: 15-04-2013
Publisher: Elsevier BV
Date: 04-2007
Publisher: Elsevier BV
Date: 10-2023
Publisher: Springer Science and Business Media LLC
Date: 06-2002
DOI: 10.1038/NATURE00799
Publisher: Elsevier BV
Date: 08-1988
Publisher: Elsevier BV
Date: 04-2017
Publisher: Wiley
Date: 04-2001
Publisher: Springer Science and Business Media LLC
Date: 27-07-2008
DOI: 10.1038/NGEO261
Publisher: Geological Society of America
Date: 2007
Publisher: Geological Society of America
Date: 15-03-2017
DOI: 10.1130/G38691.1
Publisher: Springer Science and Business Media LLC
Date: 03-06-2020
Publisher: Geological Society of London
Date: 03-06-2021
DOI: 10.1144/M56-2020-8
Abstract: Only three localities of mantle xenoliths are known from all of East Antarctica, occurring at the Jetty Peninsula (Lambert–Amery Rift), Vestfold Hills and Gaussberg volcano. The latter two are spinel-facies peridotites, whereas the Jetty Peninsula rocks also include garnet-spinel lherzolites all come from Indo-Antarctica. The mantle xenoliths of Jetty Peninsula and Vestfold Hills contain abundant geochemical and mineralogical evidence for multiple enrichment events that are attributed to infiltration of melts and their fluid products. Many of these episodes are spatially related to precursory activity along major trans-lithospheric structures that eventually led to the separation of India from Antarctica. Mantle rocks also occur at Schirmacher Oasis (Dronning Maud Land) and Haskard Highlands (Shackleton Ranges) as blocks tectonically emplaced in high-grade crustal rocks. These show varying degrees of alteration due to reaction with silicic crustal rocks or hydrous fluids: none correspond to unchanged mantle compositions. Geophysical surveys are our only information on the mantle lithosphere beneath the inland ice, and these can be used to infer the locations of thicker lithosphere probably related to cratons by southward extrapolation of coastal geological correlations. Intense local modification of the mantle lithosphere by melt infiltration and fluid movements may influence the large-scale images derived from geophysical data, and may be incorrectly interpreted as homogeneous compositions.
Publisher: Copernicus GmbH
Date: 06-01-2012
Abstract: Abstract. The oxidation of SO2 to sulfate is a key reaction in determining the role of sulfate in the environment through its effect on aerosol size distribution and composition. Sulfur isotope analysis has been used to investigate sources and chemical processes of sulfur dioxide and sulfate in the atmosphere, however interpretation of measured sulfur isotope ratios is challenging due to a lack of reliable information on the isotopic fractionation involved in major transformation pathways. This paper presents laboratory measurements of the fractionation factors for the major atmospheric oxidation reactions for SO2: Gas-phase oxidation by OH radicals, and aqueous oxidation by H2O2, O3 and a radical chain reaction initiated by iron. The measured fractionation factor for 34S/32S during the gas-phase reaction is αOH = (1.0089±0.0007)−((4±5)×10−5) T(°C). The measured fractionation factor for 34S/32S during aqueous oxidation by H2O2 or O3 is αaq = (1.0167±0.0019)−((8.7±3.5) ×10−5)T(°C). The observed fractionation during oxidation by H2O2 and O3 appeared to be controlled primarily by protonation and acid-base equilibria of S(IV) in solution, which is the reason that there is no significant difference between the fractionation produced by the two oxidants within the experimental error. The isotopic fractionation factor from a radical chain reaction in solution catalysed by iron is αFe = (0.9894±0.0043) at 19 °C for 34S/32S. Fractionation was mass-dependent with regards to 33S/32S for all the reactions investigated. The radical chain reaction mechanism was the only measured reaction that had a faster rate for the light isotopes. The results presented in this study will be particularly useful to determine the importance of the transition metal-catalysed oxidation pathway compared to other oxidation pathways, but other main oxidation pathways can not be distinguished based on stable sulfur isotope measurements alone.
Publisher: Elsevier BV
Date: 09-2004
Publisher: Elsevier BV
Date: 06-2006
Publisher: American Geophysical Union (AGU)
Date: 08-2022
DOI: 10.1029/2022GC010536
Abstract: The Middle‒Late Mesozoic massive volcanism formed a considerable thickness of volcanic‐sedimentary strata in western Liaoning, northern China. Concomitantly, it elevated phosphorus (P) availability for the rapid bloom of the terrestrial Yanliao and Jehol biotas, which developed highly abundant bio ersity and biomass. Hence, systematic tectonic and geochemical analyses of these volcanic‐sedimentary sequences with a significant P fluctuation would advance our understanding of the coevolutionary relationship between terrestrial biotas and regional tectonics. Here, we show that the secular variation of P availability in the Mesozoic volcanic rocks were the immediate results of the changes in volcanic intensity and lithospheric thickness controlled by the geological background of the cratonic destruction resulting from the paleo‐Pacific plate subduction. This study reveals the constraint effect of regional tectonics on the evolution of terrestrial ecosystems through the volcanism and P cycle.
Publisher: Elsevier BV
Date: 08-2013
Publisher: Elsevier BV
Date: 02-2014
Publisher: Elsevier
Date: 1999
Publisher: Elsevier BV
Date: 07-1995
Publisher: Elsevier BV
Date: 2012
Publisher: Oxford University Press (OUP)
Date: 05-2016
Publisher: Springer Science and Business Media LLC
Date: 22-03-2002
Publisher: Wiley
Date: 15-08-2010
Publisher: Springer Netherlands
Date: 2016
Publisher: Elsevier BV
Date: 10-2010
Publisher: Elsevier BV
Date: 08-2006
Publisher: Research Square Platform LLC
Date: 03-11-2021
DOI: 10.21203/RS.3.RS-1029408/V1
Abstract: Silicate melts in arc environments are dominated by mafic (low-silica) and silicic (high-silica) compositions, often generating a characteristic bimodal pattern. We investigate the whole arc crust and show that the plutonic lower crust shares the bimodal pattern of melts from volcanoes. This key observation reveals that, contrary to some explanations of bimodal volcanism, variation in mantle source and mantle processes must fundamentally control bimodalism. We also recognise bimodalism in Th/La composition of the whole arc crust and suggest a new working hypothesis: bimodalism originates by melting of distinct sub-arc mantle sources, one dominated by relatively dry peridotite and the other by hydrous pyroxenite. The two groups of primary melts fractionate along distinct liquid lines of descent that lead to relatively dry mafic melts (Th/La~0.1) versus hydrous silicic melts (Th/La .2) by 65–80% fractional crystallisation. Common crustal processes such as crystal fractionation, assimilation, reactive flow and/or magma mixing may also lead to differentiation of both groups.
Publisher: Elsevier BV
Date: 06-2009
Publisher: Wiley
Date: 06-2008
Publisher: Springer Science and Business Media LLC
Date: 26-08-2019
Publisher: Elsevier BV
Date: 07-2022
Publisher: Elsevier BV
Date: 11-2017
Publisher: Elsevier BV
Date: 02-2010
Publisher: American Geophysical Union (AGU)
Date: 05-2018
DOI: 10.1029/2018JB015507
Publisher: Elsevier BV
Date: 04-2015
Publisher: Elsevier BV
Date: 11-2017
Publisher: Elsevier BV
Date: 06-2001
Publisher: Elsevier BV
Date: 2002
Publisher: Springer Science and Business Media LLC
Date: 02-06-2010
Start Date: 2019
End Date: 12-2025
Amount: $3,007,316.00
Funder: Australian Research Council
View Funded ActivityStart Date: 07-2022
End Date: 06-2024
Amount: $344,864.00
Funder: Australian Research Council
View Funded ActivityStart Date: 05-2016
End Date: 06-2018
Amount: $547,000.00
Funder: Australian Research Council
View Funded ActivityStart Date: 06-2011
End Date: 12-2018
Amount: $12,400,000.00
Funder: Australian Research Council
View Funded ActivityStart Date: 05-2020
End Date: 12-2023
Amount: $222,301.00
Funder: Australian Research Council
View Funded Activity