ORCID Profile
0000-0001-6679-3240
Does something not look right? The information on this page has been harvested from data sources that may not be up to date. We continue to work with information providers to improve coverage and quality. To report an issue, use the Feedback Form.
In Research Link Australia (RLA), "Research Topics" refer to ANZSRC FOR and SEO codes. These topics are either sourced from ANZSRC FOR and SEO codes listed in researchers' related grants or generated by a large language model (LLM) based on their publications.
Wastewater treatment processes | Environmental engineering | Environmentally sustainable engineering | Modelling and simulation |
Publisher: Elsevier BV
Date: 10-2023
Publisher: Elsevier BV
Date: 10-2021
Publisher: Elsevier BV
Date: 09-2022
DOI: 10.1016/J.WATRES.2022.119034
Abstract: As a promising energy- and carbon efficient process for nitrogen removal from wastewater, mainstream nitrite shunt has been extensively researched. However, beyond the laboratory it is challenging to maintain stable performance by suppressing nitrite-oxidising bacteria (NOB). In this study, a pilot-scale reactor system receiving real sewage was operated in two stages for >850 days to evaluate two novel NOB suppression strategies for achieving nitrite shunt: i) sidestream sludge treatment based on alternating free nitrous acid (FNA) and free ammonia (FA) and ii) sidestream FNA/FA sludge treatment integrated with in-situ NOB suppression via step-feed. The results showed that, with sidestream sludge treatment alone, NOB developed resistance relatively quickly to the treatment, leading to unstable nitrite shunt. In contrast, robust nitrite shunt was achieved and stably maintained for more than a year when sidestream sludge treatment was integrated with a step-feed strategy. Kinetic analyses suggested that sludge treatment and step-feed worked in synergy, leading to stable NOB suppression. The integrated strategy demonstrated in this study removes a key barrier to the implementation of stable mainstream nitrite shunt.
Publisher: Elsevier BV
Date: 08-2020
Publisher: Elsevier BV
Date: 09-2021
Publisher: Elsevier BV
Date: 04-2021
Publisher: Elsevier BV
Date: 10-2019
DOI: 10.1016/J.WATRES.2019.07.002
Abstract: Sidestream sludge treatment approaches have been developed in recent years to achieve mainstream nitrite shunt or partial nitritation, where NOB are selectively inactivated by biocidal factors such as free nitrous acid (FNA) or free ammonium (FA) in a sidestream reactor. The existence of NOB in raw wastewater has been increasingly realized and could pose critical challenge to stable NOB suppressions in those systems. This study, for the first time, evaluated the impact of influent NOB on the NOB suppressions in a mainstream nitrite shunt system achieved through sidestream sludge treatment. An over 500-day sequential batch reactor operation with six experimental phases rigorously demonstrated the negative effects of influent NOB on mainstream NOB control. Continuously seeding of NOB contained in influent stimulated NOB community shifts, leading to different extents of ineffective NOB suppression. The role of primary wastewater treatment in NOB removal from raw wastewater was also investigated. Results suggest primary settling and High Rate Activated Sludge system could remove a large part of NOB contained in raw wastewater. Primary treatment for raw wastewater is necessary for ensuring stable mainstream NOB suppressions.
Publisher: Elsevier BV
Date: 11-2021
Publisher: Elsevier BV
Date: 04-2020
DOI: 10.1016/J.WATRES.2020.115515
Abstract: In this study, the effects of free nitrous acid (FNA) pre-treatment on the rheological properties of digested sludge were investigated at a pilot-scale, along with the improvement in volatile solids (VS) destruction and biogas production. Two pilot-scale anaerobic sludge digesters were operated for one year, one receiving thickened waste activated sludge (TWAS) without pre-treatment (control) and one receiving TWAS pre-treated for 24 h at an FNA concentration of 4.9-6.1 mgN/L (nitrite = 250 mgN/L, pH = 5.0, T = 22-30 °C). The results confirmed the enhancing effect of FNA pre-treatment on methane production (37 ± 1%), consistent with previous laboratory studies. Equally importantly, FNA pre-treatment substantially reduced the shear viscosity of TWAS by 51 ± 8% at 100 s
Publisher: Elsevier BV
Date: 09-2022
Publisher: Elsevier BV
Date: 2023
DOI: 10.1016/J.SCITOTENV.2022.158648
Abstract: Reducing the water content of waste activated sludge (WAS) is critical for sludge treatment and disposal in wastewater treatment plants (WWTPs). In this study, a new combined conditioning processes by using lysozyme (LZM) and free nitrous acid (FNA) were proposed and demonstrated to enhance the dewaterability of WAS. The water content of sludge cake dropped from 82.82 % to 68.42 % (1 h FNA treatment + 1 h LZM treatment) and 69.52 % (6 h FNA treatment + 1 h LZM treatment) with the combined FNA and LZM treatment and the corresponding capillary suction time (CST) reduction efficiency increased 49.29 % (1 h FNA treatment + 1 h LZM treatment) and 52.98 % (6 h FNA treatment + 1 h LZM treatment). A comprehensive investigation conducted in this study revealed the underlying mechanism of dewaterability improvement lies in the transformations of extracellular polymeric substances (EPS). The combined conditioning led to enhanced hydrophobicity in the sludge, as suggested by FTIR protein secondary structure and interfacial free energy. The reduced zeta potential and the potential barrier indicated the reduction of the repulsive force of sludge particles and the bound water content in the conditioned floc. The hydrophobicity, flow permeability and flocculability were enhanced after combined treatment, leading to the release of bound water.
Publisher: Elsevier BV
Date: 05-2022
DOI: 10.1016/J.SCITOTENV.2022.153231
Abstract: Buffer capacity is a critical parameter in sludge management of domestic wastewater treatment plants that determines acid/base usage. It is here shown that gravity settling or centrifugation significantly increased the buffer capacity in the supernatant of the sludge. The sludge thickening considerably elevated the total alkalinity of the sludge from 16.0 to 31.5 mgCaCO
Publisher: Elsevier BV
Date: 10-2022
Publisher: American Chemical Society (ACS)
Date: 26-05-2022
Abstract: Achieving stable long-term mainstream nitrite oxidizing bacteria (NOB) suppression is the bottleneck for the novel partial nitrification (PN) process toward energy- and carbon-efficient wastewater treatment. However, long-term PN stability remains a challenge due to NOB adaptation. This study proposed and demonstrated a novel strategy for achieving NOB suppression by the primary treatment of mainstream wastewater with a forward osmosis (FO) membrane process, which facilitated two external NOB inhibition factors (salinity and free nitrous acid, FNA). To evaluate the proposed strategy, a lab-scale sequencing batch reactor was operated for 200 days. A stable PN operation was achieved with a nitrite accumulation ratio of 97.7 ± 2.8%. NOB were suppressed under the combined inhibition effect of NaCl (7.9 ± 0.2 g/L, as introduced by the FO direct filtration) and FNA (0.11 ± 0.02 mg of HNO
Publisher: American Chemical Society (ACS)
Date: 21-08-2017
Abstract: Biological nitrogen removal through the nitrite pathway (NH
Publisher: American Chemical Society (ACS)
Date: 23-01-2023
Publisher: American Chemical Society (ACS)
Date: 11-04-2023
Publisher: Elsevier BV
Date: 09-2021
Publisher: Wiley
Date: 18-06-2021
Abstract: Electrochemical recovery of the cobalt in deep eutectic solvent shows its promise in recycling and recovery of valuable elements from the spent lithium‐ion battery due to its high selectivity and minimal environmental impacts. This work unveiled the roles of the substrates, applied potentials, and operating temperatures on the performance of cobalt electrochemical recovery in a deep eutectic choline chloride+urea solvent. The solvent contains cobalt and lithium ions extracted from lithium cobalt oxides – 3an essential lithium‐ion battery cathode material. Our results highlight that the substrate predetermines the cobalt recovery modes via substrate–cobalt interactions, which could be predicted by the cobalt surface segregation energies and crystallographic misfits. We also show that a moderate cathode potential under −1.0 V vs. silver quasi‐reference electrode at 94–104 °C is essential to ensure a selective cobalt recovery at an optimal rate. We also found that the stainless‐steel mesh is an optimal substrate for cobalt recovery due to its relatively high selectivity, fast recovery rate, and easy cobalt collection. Our work provides new insights on metal recovery in deep eutectic solvents and offers a new avenue to control the metal electrodeposition modes via modulation of substrate compositions and crystal structures.
Publisher: Elsevier BV
Date: 10-2023
Publisher: American Chemical Society (ACS)
Date: 02-02-2022
Abstract: Mathematical modeling plays a critical role toward the mitigation of nitrous oxide (N
Publisher: Elsevier BV
Date: 03-2018
Publisher: IWA Publishing
Date: 09-04-2022
Abstract: With increased commitment from the international community to reduce greenhouse gas (GHG) emissions from all sectors in accordance with the Paris Agreement, the water sector has never felt the pressure it is now under to transition to a low-carbon water management model. This requires reducing GHG emissions from grid-energy consumption (Scope 2 emissions), which is straightforward however, it also requires reducing Scope 1 emissions, which include nitrous oxide and methane emissions, predominantly from wastewater handling and treatment. The pathways and factors leading to biological nitrous oxide and methane formation and emissions from wastewater are highly complex and site-specific. Good emission factors for estimating the Scope 1 emissions are lacking, water utilities have little experience in directly measuring these emissions, and the mathematical modelling of these emissions is challenging. Therefore, this book aims to help the water sector address the Scope 1 emissions by breaking down their pathways and influencing factors, and providing guidance on both the use of emission factors, and performing direct measurements of nitrous oxide and methane emissions from sewers and wastewater treatment plants. The book also es into the mathematical modelling for predicting these emissions and provides guidance on the use of different mathematical models based upon your conditions, as well as an introduction to alternative modelling methods, including metabolic, data-driven, and AI methods. Finally, the book includes guidance on using the modelling tools for assessing different operating strategies and identifying promising mitigation actions. A must-have book for anyone needing to understand, account for, and reduce water utility Scope 1 emissions. ISBN: 9781789060454 (Paperback) ISBN: 9781789060461 (eBook) ISBN: 9781789060478 (ePub)
Publisher: IWA Publishing
Date: 20-04-2022
DOI: 10.2166/WST.2022.131
Abstract: This work gives an overview of the state-of-the-art in modelling of short-cut processes for nitrogen removal in mainstream wastewater treatment and presents future perspectives for directing research efforts in line with the needs of practice. The modelling status for deammonification (i.e., anammox-based) and nitrite-shunt processes is presented with its challenges and limitations. The importance of mathematical models for considering N2O emissions in the design and operation of short-cut nitrogen removal processes is considered as well. Modelling goals and potential benefits are presented and the needs for new and more advanced approaches are identified. Overall, this contribution presents how existing and future mathematical models can accelerate successful full-scale mainstream short-cut nitrogen removal applications.
Publisher: University of Queensland Library
Date: 2019
Publisher: Elsevier BV
Date: 07-2021
Publisher: Elsevier BV
Date: 02-2019
DOI: 10.1016/J.WATRES.2018.11.008
Abstract: Free nitrous acid (FNA) pre-treatment has been previously demonstrated to be effective in enhancing methane production and volatile solids (VS) destruction in the anaerobic digestion of waste activated sludge for an equivalent hydraulic retention time (HRT). We hypothesise that, due to enhancement of hydrolysis kinetics, FNA pre-treatment will also allow reduction in the HRT while retaining performance. This would allow for improvement of capacity constrained digesters. Two anaerobic sludge digesters (control-experiment) were fed with the same thickened waste activated sludge (TWAS) from a full-scale plant for 6 months. With 24 h pre-treatment of TWAS at an FNA concentration of 6.1 mgN/L (NO
Publisher: Elsevier BV
Date: 10-2017
DOI: 10.1016/J.WATRES.2017.05.054
Abstract: Nitrous oxide (N
Publisher: American Chemical Society (ACS)
Date: 12-05-2021
Publisher: Elsevier BV
Date: 11-2022
DOI: 10.1016/J.ENVRES.2022.113818
Abstract: With the growing concern of global warming, many water utilities are pioneering in mitigating greenhouse gas (GHG) emissions, with some water utilities aiming to achieve net-zero emissions operation in the next decade. However, for wastewater treatment plants (WWTPs), the carbon footprint of different treatment technologies and its contribution among various units within each treatment configuration is still unclear. This study evaluates the impacts of process design on the carbon footprint of WWTPs through the analysis of scope 1 (direct emission), scope 2 (indirect emission), and scope 3 (value chain emission) emissions. The comprehensive configuration design in this work considered three nutrient removal processes including typical aerobic and anaerobic wastewater treatment technologies. Emissions from the sludge management processes are also calculated, including aerobic and anaerobic sludge stabilization processes, short-term and long-term sludge storage, and three sludge disposal options. In total, 45 processes were analysed and the results were compared. The results showed the carbon footprints are highly dependent on the treatment configurations of WWTPs. Analysis suggested scope 2 & 3 emissions can be reduced by selecting suitable processes. In general, anaerobic wastewater and sludge stabilization technologies are more suitable than aerobic technologies to reduce scope 2 & 3 emissions, leading to a lower overall carbon footprint. In comparison, configuration design offers limited opportunities to reduce scope 1 emissions, which may be the future challenge for WWTP to achieve carbon neutrality.
Publisher: Elsevier BV
Date: 12-2018
DOI: 10.1016/J.SCITOTENV.2018.06.346
Abstract: Inline sludge treatment using free nitrous acid (FNA) was recently shown to be effective in establishing the nitrite pathway in a biological nitrogen removal system. However, the effects of FNA treatment conditions on the nitrite pathway performance remained to be investigated. In this study, three different FNA treatment frequencies (daily sludge treatment ratios of 0.22, 0.31 and 0.38, respectively), two FNA concentrations (1.35 mgN/L and 4.23 mgN/L, respectively) and two influent feeding regimes (one- and two-step feeding) were investigated in four laboratory-scale sequencing batch reactors. The nitrite accumulation ratio was positively correlated to the FNA treatment frequency. However, when a high treatment frequency was used e.g., daily sludge treatment ratio of 0.38, a significant reduction in ammonia oxidizing bacteria (AOB) activity occurred, leading to poor ammonium oxidation. AOB were able to acclimatise to FNA concentrations up to of 4.23 mgN/L, whereas nitrite oxidizing bacteria (NOB) were limited by an FNA concentration of 1.35 mgN/L over the duration of the study (up to 120 days). This difference in sensitivity to FNA could be used to further enhance nitrite accumulation, with 90% accumulation achieved at an FNA concentration of 4.23 mgN/L and a daily sludge treatment ratio of 0.31 in this study. However, this high level of nitrite accumulation led to increased N
Publisher: American Chemical Society (ACS)
Date: 03-06-2022
Publisher: American Chemical Society (ACS)
Date: 14-01-2019
Abstract: Stable suppression of nitrite oxidizing bacteria (NOB) is one of the major bottlenecks for achieving mainstream nitrite shunt or partial nitritation/anammox (PN/A). It is increasingly experienced that NOB could develop resistance to suppressions over an extended time, leading to failure of nitrite shunt or PN/A. This study reports and demonstrates the first effective strategy to overcome NOB adaptation through alternating sludge treatment with free nitrous acid (FNA) and free ammonia (FA). During over 650 days of reactor operation, NOB adaptation to both FNA and FA was observed, but the adaptation was successfully overcome by deploying the alternate treatment strategy. Microbial community analysis showed Nitrospira and Nitrobacter, the key NOB populations in the reactor, have the ability to adapt to FNA and FA, respectively, but do not adapt to the alternation. Stable nitrite shunt with nitrite accumulation ratio over 95% and excellent nitrogen removal were maintained for the last 10 months with only one alternation applied. N
Publisher: Elsevier BV
Date: 10-2020
Publisher: Elsevier BV
Date: 10-2021
Publisher: Elsevier BV
Date: 2015
Publisher: Elsevier BV
Date: 02-2023
Publisher: Elsevier BV
Date: 2021
Publisher: American Chemical Society (ACS)
Date: 23-06-2021
Publisher: Elsevier BV
Date: 05-2021
Publisher: Elsevier BV
Date: 05-2023
Publisher: American Chemical Society (ACS)
Date: 09-09-2021
Publisher: Wiley
Date: 29-06-2017
DOI: 10.1002/BIT.26348
Abstract: This study proposed a novel free ammonia (FA, i.e., NH
Publisher: Elsevier BV
Date: 11-2019
DOI: 10.1016/J.SCITOTENV.2019.06.435
Abstract: Ultrasound has in the past few decades found applications in a variety of disciplines including chemistry, medicine, physics, and to a much less extent microbiology. Our previous studies found that ultrasonic treatment increases the activity of ammonia-oxidizing bacteria (AOB) while suppressing nitrite-oxidizing bacteria (NOB), resulting in beneficial effects in wastewater treatment. In this study, the kinetic and microbiological features of nitrifying microorganisms in activated sludge intermittently treated with ultrasound were investigated to gain an improved understanding of the mechanism involved in ultrasound-induced stimulation of AOB kinetics. The nitrifying microorganisms were initially enriched over 100 days in a laboratory sequential batch reactor (SBR). Ultrasonic treatment of the sludge was then applied with the treatment time in each 12 h SBR cycle progressively increased from 4 to 24 min. Application of the treatment for 21 days led to a doubled maximum specific ammonia oxidation rate, and also the enhanced dominance of known AOB Nitrosomonas genus in the biomass. This stimulatory effect is well described by a modified enzyme catalyzed reaction model, showing a good linear relationship between the natural logarithm value of μ
Publisher: Elsevier BV
Date: 03-2023
Publisher: American Chemical Society (ACS)
Date: 13-11-2020
Publisher: American Chemical Society (ACS)
Date: 17-08-2015
Abstract: Herein we report a self-cleaning coating derived from zwitterionic poly(2-methacryloyloxylethyl phosphorylcholine) (PMPC) brushes grafted on a solid substrate. The PMPC surface not only exhibits complete oil repellency in a water-wetted state (i.e., underwater superoleophobicity), but also allows effective cleaning of oil fouled on dry surfaces by water alone. The PMPC surface was compared with typical underwater superoleophobic surfaces realized with the aid of surface roughening by applying hydrophilic nanostructures and those realized by applying smooth hydrophilic polyelectrolyte multilayers. We show that underwater superoleophobicity of a surface is not sufficient to enable water to clean up oil fouling on a dry surface, because the latter circumstance demands the surface to be able to strongly bond water not only in its pristine state but also in an oil-wetted state. The PMPC surface is unique with its described self-cleaning performance because the zwitterionic phosphorylcholine groups exhibit exceptional binding affinity to water even when they are already wetted by oil. Further, we show that applying this PMPC coating onto steel meshes produces oil-water separation membranes that are resilient to oil contamination with simply water rinsing. Consequently, we provide an effective solution to the oil contamination issue on the oil-water separation membranes, which is an imperative challenge in this field. Thanks to the self-cleaning effect of the PMPC surface, PMPC-coated steel meshes can not only separate oil from oil-water mixtures in a water-wetted state, but also can lift oil out from oil-water mixtures even in a dry state, which is a very promising technology for practical oil-spill remediation. In contrast, we show that oil contamination on conventional hydrophilic oil-water separation membranes would permanently induce the loss of oil-water separation function, and thus they have to be always used in a completely water-wetted state, which significantly restricts their application in practice.
Publisher: American Chemical Society (ACS)
Date: 24-12-2018
Abstract: Aerobic sludge digestion of waste activated sludge (WAS) is widely used as a stabilization option in small- and midsized wastewater treatment plants. However, the digestion process is often limited by low volatile solids (VS) destruction and poor pathogen removal efficiency. This study presents a novel operational strategy that achieves enhanced VS destruction and nitrogen removal by inducing sustained nitrite accumulation via a single spike of nitrite to aerobic digester operated at a natively low pH (<5.5). The strategy was demonstrated through the use of three laboratory aerobic sludge digesters, each continuously operated for over 300 days. Compared to control reactors, the strategy enhanced volatile solids destruction by 35.0-38.4%, nitrogen removal by 58.5-70.8%, and pathogen reduction by approximately 1 log. The standard oxygen uptake rate (SOUR) was reduced to 0.49 ± 0.03 mgO
Publisher: Elsevier BV
Date: 03-2020
DOI: 10.1016/J.WATRES.2019.115382
Abstract: Free nitrous acid (FNA), the protonated form of nitrite, has historically been an unwanted substance in wastewater systems due to its inhibition on a wide range of microorganisms. However, in recent years, advanced understanding of FNA inhibitory and biocidal effects on microorganisms has led to the development of a series of FNA-based applications that improve wastewater management practices. FNA has been used in sewer systems to control sewer corrosion and odor in wastewater treatment to achieve carbon and energy efficient nitrogen removal in sludge management to improve the sludge reduction and energy recovery in membrane systems to address membrane fouling and in wastewater algae systems to facilitate algae harvesting. This paper aims to comprehensively and critically review the current status of FNA-based applications in improving wastewater management. The underlying mechanisms of FNA inhibitory and biocidal effects are also reviewed and discussed. Knowledge gaps and current limitations of the FNA-based applications are identified and perspectives on the development of FNA-based applications are discussed. We conclude that the FNA-based technologies have great potential for enhancing the performance of wastewater systems however, further development and demonstration at larger scales are still required for their wider applications.
Start Date: 06-2024
End Date: 06-2027
Amount: $701,069.00
Funder: Australian Research Council
View Funded ActivityStart Date: 07-2023
End Date: 06-2026
Amount: $386,637.00
Funder: Australian Research Council
View Funded Activity