ORCID Profile
0000-0002-9188-4619
Current Organisation
University of Electronic Science and Technology of China
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Publisher: American Chemical Society (ACS)
Date: 20-02-2017
DOI: 10.1021/ACS.NANOLETT.6B04459
Abstract: Folded graphene in which two layers are stacked with a twist angle between them has been predicted to exhibit unique electronic, thermal, and magnetic properties. We report the folding of a single crystal monolayer graphene film grown on a Cu(111) substrate by using a tailored substrate having a hydrophobic region and a hydrophilic region. Controlled film delamination from the hydrophilic region was used to prepare macroscopic folded graphene with good uniformity on the millimeter scale. This process was used to create many folded sheets each with a defined twist angle between the two sheets. By identifying the original lattice orientation of the monolayer graphene on Cu foil, or establishing the relation between the fold angle and twist angle, this folding technique allows for the preparation of twisted bilayer graphene films with defined stacking orientations and may also be extended to create folded structures of other two-dimensional nanomaterials.
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C5TA00634A
Abstract: The synthesis of MnO 2 with unique and complex 3-d morphology replicated from diatoms and their outstanding electrochemical properties for high-performance supercapacitors are demonstrated.
Publisher: Elsevier BV
Date: 06-2018
Publisher: American Chemical Society (ACS)
Date: 09-08-2017
Abstract: Rational bottom-up construction of two-dimensional (2D) covalent or noncovalent organic materials with precise structural control at the atomic or molecular level remains a challenge. The design and synthesis of metal-organic frameworks (MOFs) based on new building blocks is of great significance in achieving new types of 2D monolayer MOF films. Here, we demonstrate that a complexation between copper(II) ions and tri(β-diketone) ligands yields a novel 2D MOF structure, either in the form of a powder or as a monolayer film. It has been characterized by Fourier transform infrared, Raman, ultraviolet-visible, X-ray photoelectron, and electron paramagnetic resonance spectroscopies. Selected area electron diffraction and powder X-ray diffraction results show that the MOF is crystalline and has a hexagonal structure. A MOF-based membrane has been prepared by vacuum filtration of an aqueous dispersion of the MOF powder onto a porous Anodisc filter having pore size 0.02 μm. The porous MOF membrane filters gold nanoparticles with a cutoff of ∼2.4 nm.
Publisher: Springer Science and Business Media LLC
Date: 20-01-2020
DOI: 10.1038/S41565-019-0622-8
Abstract: High-quality AB-stacked bilayer or multilayer graphene larger than a centimetre has not been reported. Here, we report the fabrication and use of single-crystal Cu/Ni(111) alloy foils with controllable concentrations of Ni for the growth of large-area, high-quality AB-stacked bilayer and ABA-stacked trilayer graphene films by chemical vapour deposition. The stacking order, coverage and uniformity of the graphene films were evaluated by Raman spectroscopy and transmission electron microscopy including selected area electron diffraction and atomic resolution imaging. Electrical transport (carrier mobility and band-gap tunability) and thermal conductivity (the bilayer graphene has a thermal conductivity value of about 2,300 W m
Publisher: American Association for the Advancement of Science (AAAS)
Date: 18-10-2018
Abstract: Single-crystal metals have distinctive properties owing to the absence of grain boundaries and strong anisotropy. Commercial single-crystal metals are usually synthesized by bulk crystal growth or by deposition of thin films onto substrates, and they are expensive and small. We prepared extremely large single-crystal metal foils by “contact-free annealing” from commercial polycrystalline foils. The colossal grain growth (up to 32 square centimeters) is achieved by minimizing contact stresses, resulting in a preferred in-plane and out-of-plane crystal orientation, and is driven by surface energy minimization during the rotation of the crystal lattice followed by “consumption” of neighboring grains. Industrial-scale production of single-crystal metal foils is possible as a result of this discovery.
Publisher: American Chemical Society (ACS)
Date: 14-05-2018
Abstract: We report the assembly of graphene oxide (G-O) building blocks into a vertical and radially aligned structure by a bidirectional freeze-casting approach. The crystallization of water to ice assembles the G-O sheets into a structure, a G-O aerogel whose local structure mimics turbine blades. The centimeter-scale radiating structure in this aerogel has many channels whose width increases with distance from the center. This was achieved by controlling the formation of the ice crystals in the aqueous G-O dispersion that grew radially in the shape of lamellae during freezing. Because the shape and size of ice crystals is influenced by the G-O sheets, different additives (ethanol, cellulose nanofibers, and chitosan) that can form hydrogen bonds with H
Publisher: American Physical Society (APS)
Date: 03-05-2018
Publisher: American Chemical Society (ACS)
Date: 12-05-2017
Publisher: Wiley
Date: 08-10-2021
Abstract: A “cooling–contraction” method to separate large‐area (up to 4.2 cm in lateral size) graphene oxide (GO)‐assembled films (of nanoscale thickness) from substrates is reported. Heat treatment at 3000 °C of such free‐standing macroscale films yields highly crystalline “macroassembled graphene nanofilms” (nMAGs) with 16–48 nm thickness. These nMAGs present tensile strength of 5.5–11.3 GPa (with ≈3 µm gauge length), electrical conductivity of 1.8–2.1 MS m −1 , thermal conductivity of 2027–2820 W m −1 K −1 , and carrier relaxation time up to ≈23 ps. As a demonstration application, an nMAG‐based sound‐generator shows a 30 µs response and sound pressure level of 89 dB at 1 W cm −2 . A THz metasurface fabricated from nMAG has a light response of 8.2% for 0.159 W mm −2 and can detect down to 0.01 ppm of glucose. The approach provides a straightforward way to form highly crystallized graphene nanofilms from low‐cost GO sheets.
Publisher: Wiley
Date: 21-05-2018
Abstract: C hor is used to transfer centimeter-scale ultrathin films onto custom-designed substrates for mechanical (tensile) testing. Compared to traditional transfer methods using dissolving eeling to remove the support-layers, c hor is sublimed away in air at low temperature, thereby avoiding additional stress on the as-transferred films. Large-area ultrathin films can be transferred onto hollow substrates without damage by this method. Tensile measurements are made on centimeter-scale 300 nm-thick graphene oxide film specimens, much thinner than the ≈2 μm minimum thickness of macroscale graphene-oxide films previously reported. Tensile tests were also done on two different types of large-area s les of adlayer free CVD-grown single-layer graphene supported by a ≈100 nm thick polycarbonate film graphene stiffens this s le significantly, thus the intrinsic mechanical response of the graphene can be extracted. This is the first tensile measurement of centimeter-scale monolayer graphene films. The Young's modulus of polycrystalline graphene ranges from 637 to 793 GPa, while for near single-crystal graphene, it ranges from 728 to 908 GPa (folds parallel to the tensile loading direction) and from 683 to 775 GPa (folds orthogonal to the tensile loading direction), demonstrating the mechanical performance of large-area graphene in a size scale relevant to many applications.
Publisher: American Chemical Society (ACS)
Date: 20-12-2016
Abstract: "Paper-like" film material made from stacked and overlapping graphene oxide sheets can be exfoliated (expanded) through rapid heating, and this has until now been done with no control of the final geometry of the expanded graphene oxide material, i.e., the expansion has been physically unconstrained. (As a consequence of the heating and exfoliation, the graphene oxide is "reduced", i.e., the graphene oxide platelets are deoxygenated to a degree.) We have used a confined space to constrain the expanding films to a controllable and uniform thickness. By changing the gap above the film, the final thickness of expanded films prepared from, e.g., a 10 μm-thick graphene oxide film, could be controlled to values such as 20, 30, 50, or 100 μm. When the expansion of the films was unconstrained, the final film was broken into pieces or had many cracks. In contrast, when the expansion was constrained, it never cracked or broke. Hot pressing the expanded reduced graphene oxide films at 1000 °C yielded a highly compact structure and promoted graphitization. Such thickness-controlled expansion of graphene oxide films up to tens or hundreds of times the original film thickness was used to emboss patterns on the films to produce areas with different thicknesses that remain connected "in plane". In another set of experiments, we treated the original graphene oxide film with NaOH before its controlled expansion resulted in a different structure featuring uniformly distributed pores and interconnected layers as well as simultaneous activation of the carbon.
Location: China
Location: Korea, Republic of
Location: Korea, Republic of
No related grants have been discovered for Ming Huang.