ORCID Profile
0000-0003-3909-1459
Current Organisation
Deakin University - Melbourne Burwood Campus
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Publisher: Elsevier BV
Date: 06-2020
Publisher: Elsevier BV
Date: 09-2019
Publisher: MDPI AG
Date: 15-09-2020
DOI: 10.3390/MA13184097
Abstract: Multiwalled carbon nanotubes have outstanding mechanical properties that, when combined with Portland cement, can provide cementitious composites that could lead to the innovative construction of stronger, lighter, and thinner built infrastructure. This paper addresses a knowledge gap that relates to the durability of CNT–cement composites. The durability to corrosive chloride, uptake of water by sorption, and flow of the permeability of water acting under high water pressure are addressed. Flow simulations were undertaken through segmented 3D pore networks, based on X-ray computed microtomography measurements, the creation of a virtual microstructure, and fluid simulations that were compared with larger-scale s les. The investigation showed decreased water sorptivity of CNT–cement mixtures, indicating improved durability for the cover zone of concrete that is prone to the uptake of water and water-borne corrosives. Chloride diffusion of CNT–cement composites provided up to 63% improvement compared with control s les. The favourable durability bodes well for the construction of long-life CNT-reinforced concrete infrastructure.
Publisher: Wiley
Date: 03-2023
Abstract: A new method of direct‐write nanolithography that is able to rapidly etch silica surfaces under a scanning atomic force microscopy (AFM) probe in tapping mode (TM) is reported. In this lithography technique, silica surfaces are etched using a recently described electro‐chemo‐mechanical phenomenon of frequency enhanced electrochemical pressure solution (FEEPS). In FEEPS, the tapping of the AFM tip generates oscillations of the Stern potential at the silica‐water interface that can accelerate the silica dissolution kinetics by more than 5–6 orders of magnitude when surface resonance states are achieved i.e., when the oscillation frequency is in phase with the dynamics of interfacial chemical reaction steps. By scanning silica surfaces in TM, silica is selectively dissolved below the tapping tip as it is scanned. The FEEPS accelerated silica dissolution rates can generate etched features with depths of more than 60 nm in a single AFM tip pass. The rate of etching can be controlled easily by varying the scanning rate or by modulating the tapping frequency. This fine control over the silica etching process and because material is removed (dissolved) rather than displaced as with nanoscratching, the FEEPS process lends itself to gray‐scale nanolithography which is demonstrated.
Publisher: LIDSEN Publishing Inc
Date: 31-12-2020
Abstract: This review synthesises the available published research on interactions of per- and polyfluoroalkyl substances (PFAS) with landfill liners, with the view to inform on the expected behaviour of these persistent environmental pollutants in landfills. The review addresses the nature and significant types of PFAS compounds that are destined for landfills, as well as their by-product. It discusses the known and anticipated interactions with separate landfill liner components, namely geomembranes, geosynthetic clay liners and compacted clay liners. Various water-soluble PFAS are shown to advectively transport through geosynthetic clay liners (GCL) and showcase the limitations of relying on mineral liners alone to retain PFAS. Addition of activated carbon, while increasing saturated hydraulic conductivity, significantly increases PFAS retention by the GCL and reduced PFAS flux to manageable concentrations. An assessment of the relative risk for environmental exposure of different types of PFAS from landfills through interaction with those liner components is achieved with reference to published case studies of PFAS detection in and around landfills from Australia and around the World.
Publisher: MDPI AG
Date: 21-06-2019
DOI: 10.3390/APP9122543
Abstract: The use of self-compacting concrete (SCC) reinforced with fibers has great potential in the precast concrete industry as the concrete can be delivered straight into the moulds, without any vibration or compacting effort. Similarly, it has the potential to replace traditional steel reinforcement depending on the design requirements. Novel synthetic fibers have recently become available in the market, but still, limited information is available on the performance of SCC reinforced with such fibers. This paper investigates the use of twisted-bundle macro-synthetic fiber in self-compacting concrete. Three different concrete mixtures with fiber dosage of 4, 6, and 8 kg/m3 were produced in large scale batches, and their performance was compared in terms of slump-flow, compressive strength, split tensile strength, modulus of elasticity, and flexural strength. Moreover, a comprehensive evaluation of the post-cracking residual strength is presented. It was found that the mixture with 4 kg/m3 fiber content has the most satisfactory flowability, whereas 8 kg/m3 mixture achieved the highest residual flexural strength. Based on the observed post-cracking behavior, a simplified stress-crack opening constitutive law is proposed. Since the fiber dosage affects the residual flexural strength, a factor related to fiber content is recommended while determining the ultimate residual flexural strength.
Publisher: Elsevier BV
Date: 03-2023
Publisher: Elsevier BV
Date: 05-2021
Publisher: Elsevier BV
Date: 10-2020
Publisher: Informa UK Limited
Date: 11-2011
No related grants have been discovered for Alastair MacLeod.