ORCID Profile
0000-0002-6600-2055
Current Organisation
Central South University
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Publisher: American Chemical Society (ACS)
Date: 17-06-2019
Abstract: The dynamic behavior of arsenic (As) species is closely associated with iron mineral dissolution/transformation in the environment. Bacterially induced As(V) desorption from iron oxides may be another important process that facilitates As(V) release from iron oxides without significant reductive dissolution of iron oxides. Under the impact of bacterially induced desorption, As kinetic behavior is controlled by both the microbial reduction of As(V) and the As(III)&As(V) reactions on iron oxide surfaces. However, there is still a lack of quantitative understanding on the coupled kinetics of these processes in complex systems. We developed a quantitative model that integrated the time-dependent microbial reduction of As(V) with nonlinear As(III)&As(V) adsorption/desorption kinetics on iron oxides under the impact of bacterially induced As(V) desorption. We collected and modeled literature data from 11 representative studies, in which microbial reduction reactions occurred with minimal iron oxide dissolution/transformation. Our model highlighted the significance of microbially induced As(V) desorption and time-dependent changes of microbial reduction rates. The model can quantitatively assess the roles and the coupling of in idual reactions in controlling the overall reaction rates. It provided a basis for developing comprehensive models for As cycling in the environment by coupling with other chemical, physical, and microbial processes.
Publisher: American Chemical Society (ACS)
Date: 27-12-2019
Publisher: Proceedings of the National Academy of Sciences
Date: 30-03-2023
Abstract: Transforming CO 2 into valuable chemicals is an inevitable trend in our current society. Among the viable end-uses of CO 2 , fixing CO 2 as carbon or carbonates via Li-CO 2 chemistry could be an efficient approach, and promising achievements have been obtained in catalyst design in the past. Even so, the critical role of anions/solvents in the formation of a robust solid electrolyte interphase (SEI) layer on cathodes and the solvation structure have never been investigated. Herein, lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) in two common solvents with various donor numbers (DN) have been introduced as ideal ex les. The results indicate that the cells in dimethyl sulfoxide (DMSO)-based electrolytes with high DN possess a low proportion of solvent-separated ion pairs and contact ion pairs in electrolyte configuration, which are responsible for fast ion diffusion, high ionic conductivity, and small polarization. The 3 M DMSO cell delivered the lowest polarization of 1.3 V compared to all the tetraethylene glycol dimethyl ether (TEGDME)-based cells (about 1.7 V). In addition, the coordination of the O in the TFSI − anion to the central solvated Li + ion was located at around 2 Å in the concentrated DMSO-based electrolytes, indicating that TFSI − anions could access the primary solvation sheath to form an LiF-rich SEI layer. This deeper understanding of the electrolyte solvent property for SEI formation and buried interface side reactions provides beneficial clues for future Li-CO 2 battery development and electrolyte design.
Publisher: Elsevier BV
Date: 03-2017
DOI: 10.1016/J.JES.2016.01.015
Abstract: Mg-Al-Cl layered double hydroxide (Cl-LDH) was prepared to simultaneously remove Cu(II) and Cr(VI) from aqueous solution. The coexisting Cu(II) (20mg/L) and Cr(VI) (40mg/L) were completely removed within 30min by Cl-LDH in a dosage of 2.0g/L the removal rate of Cu(II) was accelerated in the presence of Cr(VI). Moreover, compared with the adsorption of single Cu(II) or Cr(VI), the adsorption capacities of Cl-LDH for Cu(II) and Cr(VI) can be improved by 81.05% and 49.56%, respectively, in the case of coexisting Cu(II) (200mg/L) and Cr(VI) (400mg/L). The affecting factors (such as solution initial pH, adsorbent dosage, and contact time) have been systematically investigated. Besides, the changes of pH values and the concentrations of Mg
Publisher: American Chemical Society (ACS)
Date: 03-02-2022
DOI: 10.1021/JACS.1C11253
Abstract: Electrochemical CO
Location: United States of America
Location: China
No related grants have been discovered for Zhang Lin.