ORCID Profile
0000-0002-2479-2933
Current Organisations
Gran Sasso Science Institute
,
University of Oxford
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Research Topics
In Research Link Australia (RLA), "Research Topics" refer to ANZSRC FOR and SEO codes. These topics are either sourced from ANZSRC FOR and SEO codes listed in researchers' related grants or generated by a large language model (LLM) based on their publications.
Top 4 Research Topics
ANZSRC Field of Research (FoR)
Cultural Studies not elsewhere classified | Cultural Studies
ANZSRC Socio-Economic Objective (SEO)
Human Capital Issues | Expanding Knowledge through Studies of the Creative Arts and Writing |
Related Links
Publications
Contrasting photochemical and thermal reactivity of Ru(CO)2(PPh3)(dppe) towards hydrogen rationalised by parahydrogen NMR and DFT studies
Publisher: Royal Society of Chemistry (RSC)
Date: 2006
DOI: 10.1039/B510616H
Abstract: The synthesis, characterisation and thermal and photochemical reactivity of Ru(CO)2(PPh3)(dppe) 1 towards hydrogen are described. Compound proved to exist in both fac (major) and mer forms in solution. Under thermal conditions, PPh3 is lost from 1 in the major reaction pathway and the known complex Ru(CO)2(dppe)(H)2 2 is formed. Photochemically, CO loss is the dominant process, leading to the alternative dihydride Ru(CO)(PPh3)(dppe)(H)2 3. The major isomer of 3, viz. 3a, contains hydride ligands that are trans to CO and trans to one of the phosphorus atoms of the dppe ligand but a second isomer, 3b, where both hydride ligands are trans to distinct phosphines, is also formed. On the NMR timescale, no interconversion of 3a and 3b was observed, although hydride site interchange is evident with activation parameters of DeltaH(double dagger) = 95 +/- 6 kJ mol(-1) and DeltaS(double dagger) = 26 +/- 17 J K(-1) mol(-1). Density functional theory confirms that the observed species are the most stable isomeric forms, and suggests that hydride exchange occurs via a transition state featuring an eta2-coordinated H2 unit.
Special issue on youth and graduate migration
Publisher: Springer Science and Business Media LLC
Date: 17-10-2017
Cross-Verification of Independent Quantum Devices
Publisher: American Physical Society (APS)
Date: 10-10-2021
The effects of guanidine hydrochloride on the 'random coil' conformations and NMR chemical shifts of the peptide series GGXGG
Publisher: Springer Science and Business Media LLC
Date: 1997
Applied Spatial Modelling and Planning
Publisher: Routledge
Date: 04-10-2016
Fidelity of single qubit maps
Publisher: Elsevier BV
Date: 03-2002
Evaluating the effects of Australian policy changes on human capital: the role of a graduate visa scheme
Publisher: SAGE Publications
Date: 12-2015
Abstract: High-skilled migration across international borders is becoming increasingly important in policy and academic debates. In Australia, the recognition of the importance of attracting and retaining highly skilled in iduals has stimulated fundamental shifts in immigration policies. This paper explores the impacts of one of these policy shifts in focusing on the introduction of a graduate visa scheme. The scheme was introduced in Australia for the first time in September 2007 offering international graduates from Australian universities 18 months of working rights post-graduation. Since the implementation of this visa scheme there has been a sharp increase in the number of overseas graduates staying in Australia. However, no research has been carried out that investigates the working conditions and interregional migration patterns of these graduates remaining in Australia under this temporary 18 months visa. Through the exploration of in idual survey data describing the 2005 and 2008 cohorts of graduates representing the ‘before’ and ‘after’ the graduate visa scheme introduction this paper explores the impact of the visa scheme through analysing and comparing the working conditions and migration patterns of two cohorts of graduates. Findings suggest that although the introduction of the graduate visa scheme attracted more international students/graduates into the country, our analysis highlighted that the average working conditions of the international graduates who decided to remain in Australia worsened. Comparing these results with their domestic (Australian) graduate counterparts revealed that this was not due to the overall state of the Australian economy over the period under consideration.
Human Capital in Remote and Rural Australia: The Role of Graduate Migration
Publisher: Wiley
Date: 25-05-2010
Geometric quantum computation
Publisher: Informa UK Limited
Date: 11-2000
Amyloid fibril formation by an SH3 domain
Publisher: Proceedings of the National Academy of Sciences
Date: 14-04-1998
Abstract: The SH3 domain is a well characterized small protein module with a simple fold found in many proteins. At acid pH, the SH3 domain (PI3-SH3) of the p85α subunit of bovine phosphatidylinositol 3-kinase slowly forms a gel that consists of typical amyloid fibrils as assessed by electron microscopy, a Congo red binding assay, and x-ray fiber diffraction. The soluble form of PI3-SH3 at acid pH (the A state by a variety of techniques) from which fibrils are generated has been characterized. Circular dichroism in the far- and near-UV regions and 1 H NMR indicate that the A state is substantially unfolded relative to the native protein at neutral pH. NMR diffusion measurements indicate, however, that the effective hydrodynamic radius of the A state is only 23% higher than that of the native protein and is 20% lower than that of the protein denatured in 3.5 M guanidinium chloride. In addition, the A state binds the hydrophobic dye 1-anilinonaphthalene-8-sulfonic acid, which suggests that SH3 in this state has a partially formed hydrophobic core. These results indicate that the A state is partially folded and support the hypothesis that partially folded states formed in solution are precursors of amyloid deposition. Moreover, that this domain aggregates into amyloid fibrils suggests that the potential for amyloid deposition may be a common property of proteins, and not only of a few proteins associated with disease.
Handbook on the Geographies of Innovation
Publisher: Edward Elgar Publishing
Date: 25-11-2016
The Circularization of Amyloid Fibrils Formed by Apolipoprotein C-II
Publisher: Elsevier BV
Date: 12-2003
Modelling geographical graduate job search using circular statistics
Publisher: Wiley
Date: 31-05-2013
DOI: 10.1111/PIRS.12026
Interregional migration analysis
Publisher: Edward Elgar Publishing
Date: 27-03-2015
Mobility Patterns of Overseas Human Capital in Australia: the role of a ‘new’ graduate visa scheme and rural development policy
Publisher: Informa UK Limited
Date: 06-2013
Related Organisations
University Of Oxford
Location: United Kingdom of Great Britain and Northern Ireland
Related Funding Activities
So What Do You Do? Tracking Creative Graduates In Australia And The UK
Start Date: 2016
End Date: 2018
Funder: Australian Research Council
View Funded ActivityDiscovery Projects - Grant ID: DP160101440
Start Date: 03-2016
End Date: 12-2020
Amount: $270,477.00
Funder: Australian Research Council
View Funded Activity