ORCID Profile
0000-0003-3164-6122
Current Organisations
Commonwealth Scientific and Industrial Research Organisation
,
University of Western Australia
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Publisher: American Chemical Society (ACS)
Date: 03-08-2017
DOI: 10.1021/ACS.INORGCHEM.7B00771
Abstract: We present here the efficient microwave-assisted synthesis and photophysical study of a family of ruthenium(II) complexes of the general formula [Ru(bpy)
Publisher: American Chemical Society (ACS)
Date: 23-07-2020
Publisher: Wiley
Date: 04-01-2022
Publisher: Wiley
Date: 16-12-2021
Abstract: Using photocatalysis with tetra‐n‐butylammonium decatungstate (TBADT), alkanes, cyclic acetals, cyclic ethers, formamide and aldehydes were added in a stereoselective way to levoglucosenone (LGO). A hydrogen atom is transferred from the donor compound to the photochemically excited TBADT, and the resulting radicals add onto LGO in a stereoselective way. In the case of the addition of adamantane, two regio‐isomers were obtained which form a crystalline solid solution. Cyrene™, obtained by hydrogenation of LGO, was added under the same conditions. In this case, only two of 32 possible isomers of the resulting Cyrene™ dimer were formed. The regio‐selectivity of the HAT step is discussed in detail. For this purpose, bond dissociation energies and partial charges have been calculated. Transition state calculations of the radical addition to LGO explain the stereospecificity of this reaction step.
Publisher: Royal Society of Chemistry (RSC)
Date: 2019
DOI: 10.1039/C9DT02372K
Abstract: Variation of alkyl substituents on pyridinophane ancillary ligands governs temperature-dependent valence tautomeric or spin crossover equilibria in a family of cobalt–dioxolene complexes.
Publisher: Association for Computing Machinery (ACM)
Date: 30-08-2019
DOI: 10.1145/3337064
Abstract: Data mining information about people is becoming increasingly important in the data-driven society of the 21st century. Unfortunately, sometimes there are real-world considerations that conflict with the goals of data mining sometimes the privacy of the people being data mined needs to be considered. This necessitates that the output of data mining algorithms be modified to preserve privacy while simultaneously not ruining the predictive power of the outputted model. Differential privacy is a strong, enforceable definition of privacy that can be used in data mining algorithms, guaranteeing that nothing will be learned about the people in the data that could not already be discovered without their participation. In this survey, we focus on one particular data mining algorithm—decision trees—and how differential privacy interacts with each of the components that constitute decision tree algorithms. We analyze both greedy and random decision trees, and the conflicts that arise when trying to balance privacy requirements with the accuracy of the model.
Publisher: Royal Society of Chemistry (RSC)
Date: 2017
DOI: 10.1039/C7DT02932B
Abstract: Two tetraoxolene-bridged dinuclear Dy( iii ) complexes exhibit slow relaxation in ac magnetic susceptibility studies with zero-field quantum tunnelling of the magnetisation that is suppressed by the application of a dc magnetic field.
Publisher: American Chemical Society (ACS)
Date: 02-11-2021
Publisher: American Chemical Society (ACS)
Date: 30-03-2020
Publisher: Royal Society of Chemistry (RSC)
Date: 2022
DOI: 10.1039/D1TC05495C
Abstract: The electronic properties of 6-oxo-verdazyl radicals are tuned by substituents at the 1- and 5-positions, with frontier orbital analysis indicating that each system should display constructive quantum interference in a molecular junction.
Publisher: Royal Society of Chemistry (RSC)
Date: 2015
DOI: 10.1039/C5CC02124C
Abstract: The ruthenium tris-quaterpyridine complex, obtained in quantitative yield, is an excellent photosensitiser for photocatalytic hydrogen production, especially under red-light irradiation.
Publisher: Wiley
Date: 14-12-2010
Publisher: Royal Society of Chemistry (RSC)
Date: 2021
DOI: 10.1039/D1DT00886B
Abstract: Fine tuning of the electronic properties of a series of homo- and heteroleptic Ru( ii ) complexes.
Publisher: Wiley
Date: 17-09-2018
Abstract: The combination of lanthanoid nitrates with 18-crown-6 (18-c-6) and tetrahalocatecholate (X
Publisher: American Chemical Society (ACS)
Date: 25-06-2019
DOI: 10.1021/ACS.INORGCHEM.9B00698
Abstract: Since the initial report by Lehn et al. in 1979, ruthenium tris(bipyridine) ([Ru(bpy)
Publisher: Wiley
Date: 02-2021
Publisher: American Chemical Society (ACS)
Date: 11-01-2023
Publisher: Royal Society of Chemistry (RSC)
Date: 2022
DOI: 10.1039/D2NJ00684G
Abstract: Polymethine dyes are prepared using a convenient synthesis and characterized by physicochemical and computational methods.
Publisher: American Chemical Society (ACS)
Date: 23-08-2022
DOI: 10.1021/ACS.INORGCHEM.2C01985
Abstract: Photophysical and magnetic properties arising from both ground and excited states of lanthanoid ions are relevant for numerous applications. These properties can be substantially affected, both adversely and beneficially, by ligand-to-metal charge-transfer (LMCT) states. However, probing LMCT states remains a significant challenge in f-block chemistry, particularly in the solid state. Intriguingly, the europium compounds [Eu
Location: Australia
No related grants have been discovered for Elodie Rousset.