ORCID Profile
0000-0001-9557-2658
Current Organisation
Xiamen University
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Publisher: American Chemical Society (ACS)
Date: 14-01-2020
DOI: 10.1021/JACS.9B12527
Abstract: A class of γ-cyclodextrin-containing hybrid frameworks (CD-HFs) has been synthesized, employing γ-cyclodextrin (γ-CD) as the primary building blocks, along with 4-methoxysalicylate (4-MS
Publisher: American Chemical Society (ACS)
Date: 04-02-2020
DOI: 10.1021/JACS.9B13790
Publisher: American Chemical Society (ACS)
Date: 09-08-2018
DOI: 10.1021/JACS.8B06609
Abstract: A class of metal-organic frameworks (MOFs)-namely CD-MOFs-obtained from natural products has been grown in an epitaxial fashion as films on the surfaces of glass substrates, which are modified with self-assembled monolayers (SAMs) of γ-cyclodextrin (γ-CD) molecules. The SAMs are created by host-guest complexation of γ-CD molecules with surface-functionalized pyrene units. The CD-MOF films have continuous polycrystalline morphology with a structurally out-of-plane ( c-axial) orientation, covering an area of several square millimeters, with a thickness of ∼2 μm. Furthermore, this versatile host-guest strategy has been applied successfully in the growth of CD-MOFs as the shell on the curved surface of microparticles as well as in the integration of CD-MOF films into electrochemical devices for sensing carbon dioxide. In striking contrast to the control devices prepared from CD-MOF crystalline powders, these CD-MOF film-based devices display an enhancement in proton conductance of up to 300-fold. In addition, the CD-MOF film-based device exhibits more rapid and highly reversible CO
Location: United States of America
Location: United States of America
Location: United States of America
No related grants have been discovered for Andrew Sue.