Bioinspired tuneable catalysts for renewable ammonia production. The project will design a new solar-powered system for electrosynthesis of ammonia to replace the current energy intensive, non-sustainable process that generates 1.5% of global CO2 emissions. An innovative new system will be developed by combining cutting edge electrochemical, spectroscopic and theoretical methods. Expected key outcomes include novel concepts in the design of advanced materials, and an efficient process for the gr ....Bioinspired tuneable catalysts for renewable ammonia production. The project will design a new solar-powered system for electrosynthesis of ammonia to replace the current energy intensive, non-sustainable process that generates 1.5% of global CO2 emissions. An innovative new system will be developed by combining cutting edge electrochemical, spectroscopic and theoretical methods. Expected key outcomes include novel concepts in the design of advanced materials, and an efficient process for the green ammonia synthesis. Given the strategic importance of ammonia as a future energy carrier for the export of Australian renewables and as a major source of fertilisers, this project should provide significant national economic and ecological benefits and is expected to have a broad reaching global impact.Read moreRead less
Sustainable nitrogen chemistry. The goal of this project is to develop sustainable methods to produce nitrates from air and water, using renewable electricity. This new electrochemical technology will be based on the design of new electrolytes and catalysts supported by advanced theoretical concepts to provide high rate of production and selectivity. This is expected to generate new fundamental knowledge in materials and catalysis science. As traditional production of nitrates for industry and a ....Sustainable nitrogen chemistry. The goal of this project is to develop sustainable methods to produce nitrates from air and water, using renewable electricity. This new electrochemical technology will be based on the design of new electrolytes and catalysts supported by advanced theoretical concepts to provide high rate of production and selectivity. This is expected to generate new fundamental knowledge in materials and catalysis science. As traditional production of nitrates for industry and agriculture generates significant greenhouse gas emissions, the core anticipated outcome of this project is a new, sustainable era of nitrogen chemistry. This is also expected to benefit farmers by providing a process for the generation of sustainable fertilisers on a local basis.Read moreRead less
Electrocatalytic Generation of Ammonia from Air and Water. The aim is to directly convert nitrogen under mild conditions, using renewable power, to form ammonia for fertilisers and fuels, enabled by new, nanostructured, electrocatalysts based on single-sheet and composite materials. Unlike nitrogen fixation using a three-electrode system, the project will use a novel mixed gas- and liquid-phase electrocatalytic nitrogen reduction two-electrode reactor. Based on fuel cells, it is designed to acce ....Electrocatalytic Generation of Ammonia from Air and Water. The aim is to directly convert nitrogen under mild conditions, using renewable power, to form ammonia for fertilisers and fuels, enabled by new, nanostructured, electrocatalysts based on single-sheet and composite materials. Unlike nitrogen fixation using a three-electrode system, the project will use a novel mixed gas- and liquid-phase electrocatalytic nitrogen reduction two-electrode reactor. Based on fuel cells, it is designed to accelerate the naturally sluggish nitrogen reduction reaction, NRR, significantly improving the reaction rate and selectivity. The project will also gain atomic-level understanding of the mechanism of NRR, based on in-situ spectroscopies used under operando conditions, e.g., Raman or X-ray absorption.Read moreRead less
Advanced electrocatalysts for ammonia synthesis with validated analysis. Ammonia is one of the most produced chemicals worldwide but current manufacturing industries consume massive amounts of energy and emit harmful greenhouse gases. This project aims to develop a sustainable electrochemical system for ammonia synthesis using electricity and atmospheric nitrogen. A family of porous catalysts with nanoconfined ionic liquids will be developed to drive nitrogen reduction by enhancing the reaction ....Advanced electrocatalysts for ammonia synthesis with validated analysis. Ammonia is one of the most produced chemicals worldwide but current manufacturing industries consume massive amounts of energy and emit harmful greenhouse gases. This project aims to develop a sustainable electrochemical system for ammonia synthesis using electricity and atmospheric nitrogen. A family of porous catalysts with nanoconfined ionic liquids will be developed to drive nitrogen reduction by enhancing the reaction kinetics. Rigorous experimental protocols and novel analytical methods will be developed for quantification of electro-synthesised ammonia. A prototype gas diffusion layer-assisted electrolyser will be demonstrated by coupling with oxygen evolution reactions for selective ammonia synthesis at a reasonable production rate.Read moreRead less
High-productivity ammonia electrosynthesis. The aim of this project is to develop and demonstrate high-performance devices for ammonia production from renewables by a scalable electrolysis method. This will be achieved by experimental and modelling investigations of the nitrogen reduction reaction to guide the design of tailor-made cathodes. New knowledge in catalysis and materials science is expected to be generated. The target outcome of the project is a sustainable and affordable ammonia synt ....High-productivity ammonia electrosynthesis. The aim of this project is to develop and demonstrate high-performance devices for ammonia production from renewables by a scalable electrolysis method. This will be achieved by experimental and modelling investigations of the nitrogen reduction reaction to guide the design of tailor-made cathodes. New knowledge in catalysis and materials science is expected to be generated. The target outcome of the project is a sustainable and affordable ammonia synthesis method as an alternative to the current fossil-fuels-based and excessively greenhouse-emitting process. The technology to be developed in this project is anticipated to be of significant benefit to the Australian agriculture sector as a local, on-demand source of low-cost fertilisers.Read moreRead less
New dimensions of electrocatalyst design for sustainable energy future. This project aims to produce valuable chemicals from air, water and Australia’s abundant renewable energy, by developing efficient, robust catalysts for water oxidation, nitrogen reduction and ammonia oxidation — key processes for sustainable production of green fuels and fertilisers. The interdisciplinary project strategy will use a suite of advanced instrumental and theoretical tools to understand and control how catalysts ....New dimensions of electrocatalyst design for sustainable energy future. This project aims to produce valuable chemicals from air, water and Australia’s abundant renewable energy, by developing efficient, robust catalysts for water oxidation, nitrogen reduction and ammonia oxidation — key processes for sustainable production of green fuels and fertilisers. The interdisciplinary project strategy will use a suite of advanced instrumental and theoretical tools to understand and control how catalysts operate. Expected outcomes include new techniques to study catalysts, new catalyst design concepts, and novel high-performance catalytic materials and devices for sustainable electrosynthesis. These new technologies should reduce emissions and help Australia be a world leader in renewable-energy and fertiliser export.Read moreRead less