A reliable physical model of molecular motion in crystals. The scientific benefits would flow, in the first instance, to the large national and international communities of scientists whose research makes use of the results of X-ray diffraction experiments. Applications of the research to amino acids and peptides will benefit investigations into the structure and molecular dynamics of biological systems, including proteins and enzymes. Studies of charge densities in crystals will obtain a standa ....A reliable physical model of molecular motion in crystals. The scientific benefits would flow, in the first instance, to the large national and international communities of scientists whose research makes use of the results of X-ray diffraction experiments. Applications of the research to amino acids and peptides will benefit investigations into the structure and molecular dynamics of biological systems, including proteins and enzymes. Studies of charge densities in crystals will obtain a standard tool for improved modelling of molecular motion, resulting in physically more realistic charge density functions, and hence greater insight into the relationship between properties of crystals and their constituent molecules.Read moreRead less
Electronic and Optical Properties of Doped Titanium Dioxide. Titanium dioxide, is widely used as a white pigment, owing to its high refractive index, second, only after diamond. Yellowing of rutile pigment particles, observed on prolonged exposure to sunlight, is a serious problem that pigment manufacturers would like to overcome. It is proposed that aluminium-doping of rutile limits this discolouration by altering the electronic structure of the rutile particles. This project seeks to identify ....Electronic and Optical Properties of Doped Titanium Dioxide. Titanium dioxide, is widely used as a white pigment, owing to its high refractive index, second, only after diamond. Yellowing of rutile pigment particles, observed on prolonged exposure to sunlight, is a serious problem that pigment manufacturers would like to overcome. It is proposed that aluminium-doping of rutile limits this discolouration by altering the electronic structure of the rutile particles. This project seeks to identify the specific electronic cause of the yellowing process, the nature of the Al defect,it's effect on the electronic structure of rutile, and the electronic perturbations that may occur when other dopants are used.Read moreRead less
The role of water uptake in novel all solid-state polymeric ion sensors. This research will enable the development of robust all solid-state polymeric ion sensors based on unplasticized copolymers. Significantly, the physical and chemical robustness of these copolymer ion sensors will allow their widespread use in new and exciting analytical applications, e.g., in-situ analysis of environmental samples in submersible instruments, clinical analysis of whole blood, in-vivo use of miniaturized ele ....The role of water uptake in novel all solid-state polymeric ion sensors. This research will enable the development of robust all solid-state polymeric ion sensors based on unplasticized copolymers. Significantly, the physical and chemical robustness of these copolymer ion sensors will allow their widespread use in new and exciting analytical applications, e.g., in-situ analysis of environmental samples in submersible instruments, clinical analysis of whole blood, in-vivo use of miniaturized electrodes in biological media, especially single cells and minute samples in biology and forensic science, etc. Extensive use of neutron characterization techniques aligns strongly this project with the new OPAL reactor to be commissioned in 2007.Read moreRead less
Probing the internal contacts of all solid-state polymeric ion sensors. The results of this research will enable the development of robust and reliable all solid-state polymeric ion sensors. These sensors will enable solutions to significant environmental problems such as soil salinity and acidity, and may pave the way for new and exciting analytical applications, e.g., miniaturized implantable sensors for in-vivo use, microfluidics and Forensic Science, single blood droplet clinical analyzers, ....Probing the internal contacts of all solid-state polymeric ion sensors. The results of this research will enable the development of robust and reliable all solid-state polymeric ion sensors. These sensors will enable solutions to significant environmental problems such as soil salinity and acidity, and may pave the way for new and exciting analytical applications, e.g., miniaturized implantable sensors for in-vivo use, microfluidics and Forensic Science, single blood droplet clinical analyzers, rugged solid contact ion sensors for use in submersible oceanographic analyzers, etc. The research will develop a unique in-situ neutron reflectometry technique for the study of electrochemical interfaces, providing scientific opportunities for the new Australian Replacement Research Reactor.Read moreRead less
Probing the interfaces of electrochemical sensors. The nanostructured surfaces of electrochemical sensors for iron, mercury and cadmium will be characterised by using a range of state-of-the-art surface analysis techniques. Whilst electrochemical sensors are extremely valuable in monitoring of trace metals in the aquatic environment, a knowledge of the surface chemical physics of the systems is vital in order to widen their use in analytical/environmental chemistry. This project will derive a u ....Probing the interfaces of electrochemical sensors. The nanostructured surfaces of electrochemical sensors for iron, mercury and cadmium will be characterised by using a range of state-of-the-art surface analysis techniques. Whilst electrochemical sensors are extremely valuable in monitoring of trace metals in the aquatic environment, a knowledge of the surface chemical physics of the systems is vital in order to widen their use in analytical/environmental chemistry. This project will derive a universal model for the surface chemistry and physics of electrochemical sensors, enabling environmental scientists to develop unique sensor methods for studying the speciation of environmentally important trace metals such as those mentioned above.Read moreRead less
Rapid structural condition assessment using adaptive model updating. The proposed project has potential to significantly enhance the accuracy with which the condition (and hence load bearing capacity) of existing infrastructure can be determined. By providing a technique of model updating that can be applied effectively in real time, location of damage will be able to be determined accurately. Economic benefits will be reaped, both through saving infrastructure from demolition where the conditio ....Rapid structural condition assessment using adaptive model updating. The proposed project has potential to significantly enhance the accuracy with which the condition (and hence load bearing capacity) of existing infrastructure can be determined. By providing a technique of model updating that can be applied effectively in real time, location of damage will be able to be determined accurately. Economic benefits will be reaped, both through saving infrastructure from demolition where the condition is found to be adequate, and by replacing or repairing inadequate structures before costly failure occurs. This is particularly important as much of Australia's infrastructure is aging, and unnecessary periodic replacement of infrastructure is not sustainable.Read moreRead less
Efficient reinforced concrete design using linear elastic finite element analysis. It is expected that this project will bring about changes in the design practice for reinforced concrete structures, particularly those of complex geometry, which will enhance the competitiveness of the Australian design community. Through reduction of the overuse of concrete often present in current conservative design procedures for such structures, the project will lead to a reduction in the impact of reinforce ....Efficient reinforced concrete design using linear elastic finite element analysis. It is expected that this project will bring about changes in the design practice for reinforced concrete structures, particularly those of complex geometry, which will enhance the competitiveness of the Australian design community. Through reduction of the overuse of concrete often present in current conservative design procedures for such structures, the project will lead to a reduction in the impact of reinforced concrete construction on the environment and contribute to sustainable engineering practise.Read moreRead less
Blast Damage and Fragmentation Prediction for Occupants and Structure Protection. Protecting infrastructures against blast loads from terrorist bombing or accidental explosion is a challenge. Researchers have been working on developing a numerical model, but the progress is slow owing to difficulties in modelling nonlinear and high strain rate damage process. Most blast effect assessment is based on empirical relations from blast tests. These have been demonstrated not necessarily yielding accur ....Blast Damage and Fragmentation Prediction for Occupants and Structure Protection. Protecting infrastructures against blast loads from terrorist bombing or accidental explosion is a challenge. Researchers have been working on developing a numerical model, but the progress is slow owing to difficulties in modelling nonlinear and high strain rate damage process. Most blast effect assessment is based on empirical relations from blast tests. These have been demonstrated not necessarily yielding accurate prediction owing to variations of structural properties from the test model. A reliable numerical model is therefore important. It will result in big savings from blast tests, and better prediction of blast effects for structure and occupant protection. It will have applications in civil, mining and defence engineering. Read moreRead less
NUMERICAL ANALYSIS OF DYNAMIC REPONSE AND DAMAGE OF FRAME STRUCTURES TO EXPLOSIVE LOADS. Understanding structural response to explosive loads is essential to protect critical infrastructure against terrorist bombing or industrial explosions. Current practice in analysis and design of structures to withstand explosive loads uses either empirical methods or a simplified structure model. In many cases, engineers need to know the structure response in more detail in order to protect the structure an ....NUMERICAL ANALYSIS OF DYNAMIC REPONSE AND DAMAGE OF FRAME STRUCTURES TO EXPLOSIVE LOADS. Understanding structural response to explosive loads is essential to protect critical infrastructure against terrorist bombing or industrial explosions. Current practice in analysis and design of structures to withstand explosive loads uses either empirical methods or a simplified structure model. In many cases, engineers need to know the structure response in more detail in order to protect the structure and plan evacuation procedures. This project will study the response and damage mechanism of structures to explosive loads, and develop a numerical model to predict structural response and damage. It will have immediate and wide-ranging applications in defence, construction and mining engineering.Read moreRead less