Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-si ....Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-site metal-organic framework catalyst with high reaction-activity and chemo-selectivity in converting CO2 into valuable chemicals. This advancement will provide significant benefits for Australia’s emerging chemical manufacturing industry, and ultimately leading to a carbon-neutral energy economy and environment.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE220100583
Funder
Australian Research Council
Funding Amount
$445,000.00
Summary
Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous ....Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous polymeric MOF coating. This approach is expected to deliver robust biocatalysts with high reaction-activity and chemo-selectivity in converting CO2 into methanol under the industrial operating condition, involving thermal, pH, and chemical stressors. This advancement will contribute to a carbon-neutral industry and society.Read moreRead less
Covalently immobilised molecular catalysts for carbon dioxide reduction. This project aims to develop innovative catalytic systems on semiconductor surfaces, to use sunlight for conversion of carbon dioxide (CO2) into high energy-content products. Sustainable chemical transformation of CO2 into valuable products, especially fuels, is one of the most important chemical processing challenges. This project will use innovative molecular engineering to covalently fix light-harvester to semiconductors ....Covalently immobilised molecular catalysts for carbon dioxide reduction. This project aims to develop innovative catalytic systems on semiconductor surfaces, to use sunlight for conversion of carbon dioxide (CO2) into high energy-content products. Sustainable chemical transformation of CO2 into valuable products, especially fuels, is one of the most important chemical processing challenges. This project will use innovative molecular engineering to covalently fix light-harvester to semiconductors. The expected outcome will be an efficient system to enhance CO2 conversion, which will not only reduce the environmental impact but also generate a cheap source of energy by closing the carbon loop. Using this approach, existing high carbon-emitting processes will be able to be replaced by new carbon-neutral or even carbon-negative ones for much-reduced environmental impact on our society.Read moreRead less