Unravelling mechanisms in plasma growth of polymers. Surface engineering broadens the breadth of applications for many materials, and enhances the performance and value of current and emerging technologies. Surface engineering is particularly important to maintaining the competitiveness of manufacturing in developed economies such as Australia, that can not compete on a cost basis with emerging economies. Plasma coating replaces (alternative) environmentally-questionable surface treatments. This ....Unravelling mechanisms in plasma growth of polymers. Surface engineering broadens the breadth of applications for many materials, and enhances the performance and value of current and emerging technologies. Surface engineering is particularly important to maintaining the competitiveness of manufacturing in developed economies such as Australia, that can not compete on a cost basis with emerging economies. Plasma coating replaces (alternative) environmentally-questionable surface treatments. This project enhances Australian competitiveness; it cuts across industrial sectors and will deliver the new knowledge required to enhance material/technology functionality/performance. A PhD student will receive a multi-disciplinary training in a frontier technology and advanced analytical tools.Read moreRead less
New Methodology for the Stereoselective Construction of Oxygen Heterocycles and Rare Sugar Analogues. The overall goal of this research is to develop new synthetic methods, particularly ones that exhibit high levels of stereocontrol. Current research efforts are directed towards the stereoselective construction of oxygen heterocycles and rare sugar analogues both in their racemic and chiral forms utilising 1,2-dioxines containing tethered hydroxyl moieties as the key chemical precursors. It is e ....New Methodology for the Stereoselective Construction of Oxygen Heterocycles and Rare Sugar Analogues. The overall goal of this research is to develop new synthetic methods, particularly ones that exhibit high levels of stereocontrol. Current research efforts are directed towards the stereoselective construction of oxygen heterocycles and rare sugar analogues both in their racemic and chiral forms utilising 1,2-dioxines containing tethered hydroxyl moieties as the key chemical precursors. It is envisaged that these investigations will lead to the development of simple experimental protocols for the synthesis of new bioactive organics.Read moreRead less
The recovery of Cu from chalcopyrite-pyrite containing concentrates, ores and tailings. Chalcopyrite, a major source of Cu, is often associated in ores with the valueless mineral pyrite. The development of more efficient methods for the retrieval of the Cu is of considerable economic importance to Australian minerals processing companies. We aim to develop methodologies allowing the more efficient :
- separation of chalcopyrite and pyrite;
- leaching of Cu from ores and tailing in a heap leach ....The recovery of Cu from chalcopyrite-pyrite containing concentrates, ores and tailings. Chalcopyrite, a major source of Cu, is often associated in ores with the valueless mineral pyrite. The development of more efficient methods for the retrieval of the Cu is of considerable economic importance to Australian minerals processing companies. We aim to develop methodologies allowing the more efficient :
- separation of chalcopyrite and pyrite;
- leaching of Cu from ores and tailing in a heap leach environment and
- leaching of Cu in a concentrated chalcopyrite-pyrite reactor environment.
These aims will be achieved via an integrated surface-solution speciation approach allowing the manipulation of surface properties.
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Laser Diagnostics of Soot Formation in Precessing Jet Flames. In many practical combustion systems (e.g., boiler furnaces and rotary kilns), flame radiation is the major contributor to the required heat transfer. Soot formation is a means of enhancing flame radiation provided the soot is completely oxidised within the flame so that there are no soot emissions. The enhanced flame radiation can have a significant economic and environmental impact on plant operation (changes to the parameters tha ....Laser Diagnostics of Soot Formation in Precessing Jet Flames. In many practical combustion systems (e.g., boiler furnaces and rotary kilns), flame radiation is the major contributor to the required heat transfer. Soot formation is a means of enhancing flame radiation provided the soot is completely oxidised within the flame so that there are no soot emissions. The enhanced flame radiation can have a significant economic and environmental impact on plant operation (changes to the parameters that influence soot formation can also influence NOx and greenhouse gas emissions). The objectives of this project are to identify and quantify the operating parameters that influence soot formation and destruction in such flames.Read moreRead less
The formation of negative ions and neutrals in the gas phase. Structure, reactivity and mechanism. Mass spectrometry is an analytical technique used to provide information concerning the structure of a chemical compound: it is particularly useful when dealing with small amounts of biologically important molecules. It is also a facility in which charged species can be converted into transient neutrals. This project will (i) produce information about negative ion fragmentations in order to extend ....The formation of negative ions and neutrals in the gas phase. Structure, reactivity and mechanism. Mass spectrometry is an analytical technique used to provide information concerning the structure of a chemical compound: it is particularly useful when dealing with small amounts of biologically important molecules. It is also a facility in which charged species can be converted into transient neutrals. This project will (i) produce information about negative ion fragmentations in order to extend the applicability of analytical negative-ion mass spectrometry, (ii) form neutral molecules and related species which are found in stellar dust clouds and investigate their chemistry, and (iii) train graduates in ion chemistry to the highest international standards.Read moreRead less
Cumulenes and Heterocumulenes - Stellar Molecules and New Materials. This project involves the formation and characterisation of transient neutrals (formed in the mass spectrometer by neutralisation of charged precursor ions) which are either found in stellar dust clouds, or related molecules which may be either potential stellar molecules or have importance in the development of new materials. This work may lead to a better understanding of how biomolecules are formed in interstellar environs. ....Cumulenes and Heterocumulenes - Stellar Molecules and New Materials. This project involves the formation and characterisation of transient neutrals (formed in the mass spectrometer by neutralisation of charged precursor ions) which are either found in stellar dust clouds, or related molecules which may be either potential stellar molecules or have importance in the development of new materials. This work may lead to a better understanding of how biomolecules are formed in interstellar environs. The Adelaide and Berlin groups are internationally known, already with ongoing collaboration. This application seeks to extend the scope of this world-class research, and to train the premier graduate students in astrochemistry.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE100100236
Funder
Australian Research Council
Funding Amount
$180,000.00
Summary
Facilities for spectroscopy and diffraction at high pressures. The provision of infrastructure for the study of novel materials under high pressures will enhance Australia's capability in creating new materials and in creating new devices that meet needs in communication, environment and medicine applications. The new facility will enable researchers to understand the response of structures to extreme pressures and will exploit the unique capabilities of the synchrotron light.
Advanced Nanoscale Materials Engineered from Diatomaceous Earth. Using natural materials of diatomaceous earth (DE) as a cheap and available resource by applying synthetic routes this project is directed towards the innovative development of new nanoscale materials with advanced properties. New mesoporous materials with intricate 3-D structures and nano sized features will be engineered from diatom silica for use in demanding applications such as separation and catalysis. These research outcomes ....Advanced Nanoscale Materials Engineered from Diatomaceous Earth. Using natural materials of diatomaceous earth (DE) as a cheap and available resource by applying synthetic routes this project is directed towards the innovative development of new nanoscale materials with advanced properties. New mesoporous materials with intricate 3-D structures and nano sized features will be engineered from diatom silica for use in demanding applications such as separation and catalysis. These research outcomes will enhance Australia's capacity in frontier technology and advanced materials, as well as bringing a competitive advantage to local industry through the development of such advanced materials.Read moreRead less
Optimising Froth Zone Performance in Mineral Flotation. Froth flotation is the most widely applied technique for the selective separation of valuable mineral from gangue mineral particles. This project aims to optimize the selective separation of valuable minerals from gangue minerals within the froth zone of flotation. This project has very high national significance as deficiencies in the froth zone performance of industrial flotation plants, leads to a significant loss of valuable mineral f ....Optimising Froth Zone Performance in Mineral Flotation. Froth flotation is the most widely applied technique for the selective separation of valuable mineral from gangue mineral particles. This project aims to optimize the selective separation of valuable minerals from gangue minerals within the froth zone of flotation. This project has very high national significance as deficiencies in the froth zone performance of industrial flotation plants, leads to a significant loss of valuable mineral from mineral concentrates, as well as a reduction in concentrate grade and quality. An expected outcome of this project will be a series of new tools and methodologies to optimize froth zone performance, which will have industry wide application.Read moreRead less
Optimizing tailings dewatering through interfacial chemistry and particle interactions. This project aims to improve the dewatering behaviour of waste tailings from mineral processing activites. Dewatering and disposal of tailings containing fine particles are serious issues which confront the mineral industry. Effective dewatering of tailings is determined by particle-solution interfacial chemistry and particle interactions. These properties will be manipulated by matching the molecular arch ....Optimizing tailings dewatering through interfacial chemistry and particle interactions. This project aims to improve the dewatering behaviour of waste tailings from mineral processing activites. Dewatering and disposal of tailings containing fine particles are serious issues which confront the mineral industry. Effective dewatering of tailings is determined by particle-solution interfacial chemistry and particle interactions. These properties will be manipulated by matching the molecular architecture and functionality of flocculants to mineral particle surface chemistry. Optimization of tails interfacial chemistry and particle interactions through conventional and non-conventional flocculants will be investigated and electoosmosis will be applied to achieve maximum dewatering behaviour.The scientific and environmental outcomes will be beneficial to all stakeholders.Read moreRead less