Thermal management of methane fuelled planar solid oxide fuel cells. Solid oxide fuel cells (SOFCs) are novel devices for generating energy with extremely low emissions. This project will conduct novel experiments and numerical simulations to improve the efficiency of SOFCs. This will then allow wider adoption of this technology, thus reducing CO2 and other environmental emissions from our power generation systems.
A defect mechanism for oxygen reduction reaction. This project aims to use defective carbon to replace expensive platinum as a catalyst for oxygen reduction reaction (ORR) in fuel cells. Defective carbons incorporating non-precious metals are better than platinum in terms of over-potential, current density and number of electron transfer. They reduce the overall fuel cell cost but their better stability and higher open voltage and power density promise huge commercial benefit. This project is ex ....A defect mechanism for oxygen reduction reaction. This project aims to use defective carbon to replace expensive platinum as a catalyst for oxygen reduction reaction (ORR) in fuel cells. Defective carbons incorporating non-precious metals are better than platinum in terms of over-potential, current density and number of electron transfer. They reduce the overall fuel cell cost but their better stability and higher open voltage and power density promise huge commercial benefit. This project is expected to be important for large-scale implementation of fuel cells.Read moreRead less
Doped metal perovskites for electrocatalysis. This project aims to discover and design perovskite metal-oxide electrocatalyst materials and develop electrocatalytic methods for efficiently driving the oxygen evolution reaction and the oxygen reduction reaction. These are the two most crucial reactions in sustainable energy cycles involving water, hydrogen and oxygen. The project’s anticipated advances in electrocatalysis efficiency for these two reactions will benefit sustainable energy technolo ....Doped metal perovskites for electrocatalysis. This project aims to discover and design perovskite metal-oxide electrocatalyst materials and develop electrocatalytic methods for efficiently driving the oxygen evolution reaction and the oxygen reduction reaction. These are the two most crucial reactions in sustainable energy cycles involving water, hydrogen and oxygen. The project’s anticipated advances in electrocatalysis efficiency for these two reactions will benefit sustainable energy technologies such as fuel cells, metal air batteries and water splitting.Read moreRead less
Engineering the Building Blocks of Novel Interfacial Metastable Oxide Materials. This project aims to engineer the building blocks of a new family of materials recently discovered and patented as interfacial metastable oxide (i-MOx). A key discovery is the interfacial columnar atom alignment adjacent to crystal structures, conferring the materials exceptional ionic conduction well beyond the state-of-the-art, with a broad appeal to ionic transport membranes, electrodes in fuel cells and thermal ....Engineering the Building Blocks of Novel Interfacial Metastable Oxide Materials. This project aims to engineer the building blocks of a new family of materials recently discovered and patented as interfacial metastable oxide (i-MOx). A key discovery is the interfacial columnar atom alignment adjacent to crystal structures, conferring the materials exceptional ionic conduction well beyond the state-of-the-art, with a broad appeal to ionic transport membranes, electrodes in fuel cells and thermal cycling oxygen production. Advanced characterisation techniques will be employed to fundamentally elucidate the role that the interfacial structure plays to deliver remarkable performance. The outcomes will lead to possible breakthroughs in advanced materials for emerging green energy applications.Read moreRead less
Controllable Synthesis of Defects in Catalysts for Electrocatalysis . This project aims to address the most critical issue of electrocatalysis: identification of active sites for carbon-based metal free catalysts (CMFCs). Through the development of new methodologies, this proposal will, for the first time, controllably synthesise the vacancy defects that are the major active sites for CMFCs. The expected outcomes from this project include in-depth understanding of the fundamentals of electrocata ....Controllable Synthesis of Defects in Catalysts for Electrocatalysis . This project aims to address the most critical issue of electrocatalysis: identification of active sites for carbon-based metal free catalysts (CMFCs). Through the development of new methodologies, this proposal will, for the first time, controllably synthesise the vacancy defects that are the major active sites for CMFCs. The expected outcomes from this project include in-depth understanding of the fundamentals of electrocatalysis: the reactivity of active sites and the catalytic performance with the number of active sites; which will not only significantly advance knowledge but also achieve breakthrough technologies that greatly benefit to the society and economy both for Australia and worldwide.Read moreRead less
Experimental and modelling development of advanced symmetrical fuel cells. Fuel cells are advanced energy conversion devices with high efficiency and low emissions. The overall goal of this project is to increase the competitiveness of the fuel cell technology with currently matured power generation technologies based on fossil fuel combustion through innovations. Both experimental development and modelling studies will be performed. It is expected that: reduced materials, fabrication and mainte ....Experimental and modelling development of advanced symmetrical fuel cells. Fuel cells are advanced energy conversion devices with high efficiency and low emissions. The overall goal of this project is to increase the competitiveness of the fuel cell technology with currently matured power generation technologies based on fossil fuel combustion through innovations. Both experimental development and modelling studies will be performed. It is expected that: reduced materials, fabrication and maintenance costs; improved performance; increased coking resistance and sulfur tolerance; and prolonged lifetime of solid oxide fuel cells will be achieved. This project endeavours to advance the field of electrochemical energy conversion. It is also expected to expand the science and engineering knowledge base and pave the way to sustainable energy systems.Read moreRead less
Scale up of direct carbon fuel cells. As a modern society, Australia is highly reliant on energy which is derived predominantly from coal using pulverised fuel technology with low efficiency (35-40 per cent) and high greenhouse gas emissions. This project will develop a new method for the more efficient utilisation of Australia's coals. Consequently, the power generation industry in Australia will be able to export energy in the 80 per cent efficiency range, while pure carbon dioxide can be easi ....Scale up of direct carbon fuel cells. As a modern society, Australia is highly reliant on energy which is derived predominantly from coal using pulverised fuel technology with low efficiency (35-40 per cent) and high greenhouse gas emissions. This project will develop a new method for the more efficient utilisation of Australia's coals. Consequently, the power generation industry in Australia will be able to export energy in the 80 per cent efficiency range, while pure carbon dioxide can be easily sequestrated.Read moreRead less
Advanced Proton-Conducting Ceramic FCs for Power Generation from Ammonia . The project aims to design an innovative ammonia fuel cell using a new perovskite substrate decorated with metal nanoparticles, which demonstrates multi-functionalities and tackles most challenges of conventional fuel cells (FCs). The key concept of this project is the designing of the novel architected smart perovskite as both anode and electrolyte of the fuel cell by systematic modelling and experimental development. T ....Advanced Proton-Conducting Ceramic FCs for Power Generation from Ammonia . The project aims to design an innovative ammonia fuel cell using a new perovskite substrate decorated with metal nanoparticles, which demonstrates multi-functionalities and tackles most challenges of conventional fuel cells (FCs). The key concept of this project is the designing of the novel architected smart perovskite as both anode and electrolyte of the fuel cell by systematic modelling and experimental development. The versatile cell components developed in this project will improve the operational stability and efficiency of the fuel cell, thereby providing a promising pathway for ammonia fuel cells to replace hydrogen fuel cells. This study will reinforce the development of the future supply of reliable, low cost and clean energy. Read moreRead less
Hybrid Hydrocarbon-Carbon Fuel Cells for Long-Life Power Generation. This project aims to design an innovative high-energy portable power source based on a hybrid direct hydrocarbon-carbon fuel cell concept, in which the deposited carbon in the anode of a fuel cell during operation with liquid hydrocarbon fuels can be used as a fuel by subsequent operation in the direct carbon fuel cell mode. The key concept in this project is the controlled deposition and utilization of carbon over the anode of ....Hybrid Hydrocarbon-Carbon Fuel Cells for Long-Life Power Generation. This project aims to design an innovative high-energy portable power source based on a hybrid direct hydrocarbon-carbon fuel cell concept, in which the deposited carbon in the anode of a fuel cell during operation with liquid hydrocarbon fuels can be used as a fuel by subsequent operation in the direct carbon fuel cell mode. The key concept in this project is the controlled deposition and utilization of carbon over the anode of the fuel cell by systematic modelling and experimental development. A continuous power output will be realized via an intelligent cycling mode with an intermittent supply of pure liquid hydrocarbon fuels, thereby achieving an extremely high fuel utilization efficiency in a hybrid electrochemical system.Read moreRead less
Innovative High Temperature Carbon–Air Batteries for High Power Generation. The project intends to develop carbon-air batteries which are expected to have energy density 10 times that of lithium-ion batteries. The battery is designed to use naturally-rich carbon as fuel, highly energy-efficient solid oxide fuel cells as electrochemical reactors, and an integrated mixed conducting ceramic membrane for in situ carbon dioxide separation. The success of this project would provide us with a low-carbo ....Innovative High Temperature Carbon–Air Batteries for High Power Generation. The project intends to develop carbon-air batteries which are expected to have energy density 10 times that of lithium-ion batteries. The battery is designed to use naturally-rich carbon as fuel, highly energy-efficient solid oxide fuel cells as electrochemical reactors, and an integrated mixed conducting ceramic membrane for in situ carbon dioxide separation. The success of this project would provide us with a low-carbon energy system based on Australia’s rich coal resources. New knowledge about carbon dioxide separation may also facilitate carbon dioxide sequestration in other fields.Read moreRead less