What controls trace element levels in ore sulfides? A laser-ICPMS perspective. Sub-surface hydrothermal gold and base metal orebodies are surrounded by aprons of elevated metal concentrations, mainly within micro-sulfides, which is one sign mineral explorers use to widen their target. Here we test whether the hostrock contributes metal in the most distant parts of such halos, and if so, what factors control where hostrock metal begins to be detectable in a given system. We will make better model ....What controls trace element levels in ore sulfides? A laser-ICPMS perspective. Sub-surface hydrothermal gold and base metal orebodies are surrounded by aprons of elevated metal concentrations, mainly within micro-sulfides, which is one sign mineral explorers use to widen their target. Here we test whether the hostrock contributes metal in the most distant parts of such halos, and if so, what factors control where hostrock metal begins to be detectable in a given system. We will make better models of how metalliferous waters react with rock, potentially translating into million dollar savings through more efficient exploration. The ultrafine sampling and precision analyses required for this are possible because of an ARC-funded core program at CODES.Read moreRead less
3D printed microchemical devices and systems. This project aims to address the barriers faced by 3D printing in chemistry. 3D printing can create bespoke 3D structures within a fraction of time and cost compared to traditional fabrication. However, its scope in chemistry has been limited by the poor chemical robustness, biotoxicity and low resolution of the 3D printed components. Hence, this project will develop novel gold coating techniques and explore high-resolution 3D printing to overcome th ....3D printed microchemical devices and systems. This project aims to address the barriers faced by 3D printing in chemistry. 3D printing can create bespoke 3D structures within a fraction of time and cost compared to traditional fabrication. However, its scope in chemistry has been limited by the poor chemical robustness, biotoxicity and low resolution of the 3D printed components. Hence, this project will develop novel gold coating techniques and explore high-resolution 3D printing to overcome these challenges. The project should generate commercially significant products (analytical platforms), technology (gold coating) and patents. The developed systems and technologies will address Australian research challenges in advanced manufacturing and enable on-site environmental monitoring.Read moreRead less
ARC Centre of Excellence - in Ore Deposits. Australia's minerals industry faces a two-fold challenge - to find new ore deposits and to mine them with maximum efficiency and minimal environmental impact. Those challenges demand a new generation of focused ore deposit research, tailored specifically for the Australian context. The Centre of Excellence in Ore Deposits will provide the foundation of fundamental research required by a successful, efficient and sustainable Australian minerals industry ....ARC Centre of Excellence - in Ore Deposits. Australia's minerals industry faces a two-fold challenge - to find new ore deposits and to mine them with maximum efficiency and minimal environmental impact. Those challenges demand a new generation of focused ore deposit research, tailored specifically for the Australian context. The Centre of Excellence in Ore Deposits will provide the foundation of fundamental research required by a successful, efficient and sustainable Australian minerals industry. The Centre will also play a leading role in the undergraduate and postgraduate training of future geoscientists. The concentration of internationally recognised researchers in the Centre will ensure it maintains its premier position in the international ore deposit research arena.Read moreRead less
Genesis of platinum group element-rich, unconformity-style, hydrothermal mineral deposits, as inferred from a Northern Territory example. Mineral products currently provide a great deal of Australia's exports to international markets, and underpin much of our economy. However, Australia can only maintain this position through continued improvement of mineral discovery rates, particularly for high value, deep earth resources. This project aims to improve the likelihood of the discovery of higher ....Genesis of platinum group element-rich, unconformity-style, hydrothermal mineral deposits, as inferred from a Northern Territory example. Mineral products currently provide a great deal of Australia's exports to international markets, and underpin much of our economy. However, Australia can only maintain this position through continued improvement of mineral discovery rates, particularly for high value, deep earth resources. This project aims to improve the likelihood of the discovery of higher value hydrothermal orebodies. This will improve the value of mineral exports, raise exploration levels in some Australian provinces (thus stimulating economic activity in regional and industrial sectors), and help invigorate training within the geoscience arm of the university sector. Read moreRead less
Metal complexes for activation and scission of small, multiply-bonded molecules. The outcome of this work is a series of metal complexes capable of cleaving the strong bonds in a number of small molecules of chemical importance. This will have a significant impact on industry by providing cheaper and safer alternatives to currently expensive and hazardous processes for producing nitrogen and phosphorus containing compounds.
Geochronology, Metallogenesis and Deposit Styles of Loei Foldbelt in Thailand and Laos PDR. The Loei volcanic-plutonic belt occurs in Thailand and Laos PDR between two major crustal terranes in mainland SE Asia: Shan-Thai in the west and Indochina terrane in the east. Several skarn type copper-gold and porphyry related epithermal gold deposits are distributed along the Loei belt, and yet these deposits are not well documented in the literature. Detailed metallogenic relations and evolution of th ....Geochronology, Metallogenesis and Deposit Styles of Loei Foldbelt in Thailand and Laos PDR. The Loei volcanic-plutonic belt occurs in Thailand and Laos PDR between two major crustal terranes in mainland SE Asia: Shan-Thai in the west and Indochina terrane in the east. Several skarn type copper-gold and porphyry related epithermal gold deposits are distributed along the Loei belt, and yet these deposits are not well documented in the literature. Detailed metallogenic relations and evolution of these mineral deposits are also poorly understood; it is not known whether they formed from single, long-lived intrusive-centred mineralised systems or multiple/episodic mineralised systems. Understanding the geotectonic and metallogenic relations of this belt have a direct benefit to Australian companies exploring in SE Asia, and the research results also can be applied back in Australia for exploration of Cu-Au deposits.Read moreRead less
Metal-promoted bond functionalisation: new routes to amides and thioamides. This project aims to discover new metal-promoted methods to synthesise amides and thioamides, important structural motifs in chemistry and biology. The project will use a mechanism-based approach that integrates theory with gas- and solution-phase experiments to discover new chemical reactions. A benefit of this research will be new eco-friendly alternatives to existing processes, thereby reducing waste and eliminating t ....Metal-promoted bond functionalisation: new routes to amides and thioamides. This project aims to discover new metal-promoted methods to synthesise amides and thioamides, important structural motifs in chemistry and biology. The project will use a mechanism-based approach that integrates theory with gas- and solution-phase experiments to discover new chemical reactions. A benefit of this research will be new eco-friendly alternatives to existing processes, thereby reducing waste and eliminating toxic and expensive reagents.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE240100068
Funder
Australian Research Council
Funding Amount
$417,237.00
Summary
Original metal-based catalysts for enzyme-inspired CO2 activation. The chemical utilisation of CO2 is one of two major strategies in achieving net negative CO2 emissions mitigating the environmental and socioeconomic damage of global warming. Inspired by the ability of natural enzymes to efficiently utilise molecules like CO2, this project aims to develop original metal-based catalysts as enzyme mimics for the efficient transformation of CO2. It will deliver practical strategies to transform CO2 ....Original metal-based catalysts for enzyme-inspired CO2 activation. The chemical utilisation of CO2 is one of two major strategies in achieving net negative CO2 emissions mitigating the environmental and socioeconomic damage of global warming. Inspired by the ability of natural enzymes to efficiently utilise molecules like CO2, this project aims to develop original metal-based catalysts as enzyme mimics for the efficient transformation of CO2. It will deliver practical strategies to transform CO2 into value-added materials permanently removing it from the atmosphere. Project outcomes are expected to enhance industry’s capacity to use CO2 as a feedstock chemical for the production of fuels and materials, providing significant economic and environmental benefits through CO2 upcycling and recycling.Read moreRead less
Pyrite: a deep-time capsule of ocean chemistry and atmosphere oxidation. Surprisingly little is known about trace element trends in past oceans, even though these data are vital for interpreting the evolution of the Earth's atmosphere, evolutionary pathways of marine life and cycles of major mineral deposits. Using laser-based analysis of sedimentary pyrite in deep marine rocks, this project aims to produce, for the first time, temporal variation curves for 25 trace elements in seawater over the ....Pyrite: a deep-time capsule of ocean chemistry and atmosphere oxidation. Surprisingly little is known about trace element trends in past oceans, even though these data are vital for interpreting the evolution of the Earth's atmosphere, evolutionary pathways of marine life and cycles of major mineral deposits. Using laser-based analysis of sedimentary pyrite in deep marine rocks, this project aims to produce, for the first time, temporal variation curves for 25 trace elements in seawater over the last 3.5 billion years. Preliminary research has validated the technique and demonstrated major changes in certain trace elements over geologically short periods. Outcomes will assist the minerals industry in the discovery of new deposits of zinc, copper, gold and iron ore in Australia.Read moreRead less
Metal complexes for sustainable light-driven synthesis. The aim of this project is to use cheap, abundant transition metal ions and visible light to enable challenging synthetic chemical reactions. The significant problems addressed are that most synthetic reactions using visible light currently require expensive precious metals, and fundamental reaction pathways used by Nature remain inaccessible. Both of these problems limit the scope of synthetic applications. The outcomes will be new knowled ....Metal complexes for sustainable light-driven synthesis. The aim of this project is to use cheap, abundant transition metal ions and visible light to enable challenging synthetic chemical reactions. The significant problems addressed are that most synthetic reactions using visible light currently require expensive precious metals, and fundamental reaction pathways used by Nature remain inaccessible. Both of these problems limit the scope of synthetic applications. The outcomes will be new knowledge and sustainable technologies that can better harness visible light for useful synthetic chemistry applications. The benefits will be more efficient and cost-effective routes to valuable molecules ubiquitous in everyday life.Read moreRead less